0893 114 - WURTH ZINC SPRAY, LIGHT 400ML
Chemwatch Material Safety Data Sheet
Issue Date: 20-Aug-2004 CHEMWATCH 4598-63
NA477ECP Version No:3
CD 2007/2 Page 1 of 28
Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME
0893 114 - WURTH ZINC SPRAY, LIGHT 400ML
STATEMENT OF HAZARDOUS NATURE
Considered a Hazardous Substance according to the criteria of the New
Zealand Hazardous Substances New Organisms legislation.
OTHER NAMES
"metal surface protection"
PROPER SHIPPING NAME
AEROSOLS
PRODUCT USE
Application is by spray atomisation from a hand held aerosol pack.
Used for protection of metal surfaces.
SUPPLIER
Company: Wurth New Zealand Limited
Address:
42 Hobill Avenue
Manukau City
Auckland
NZL
Telephone: 0800 683 040
Fax: 0800 100 104
Section 2 - HAZARDS IDENTIFICATION
GHS Classification
Acute Aquatic Hazard Category 3
Acute Toxicity (Inhalation) Category 4
Carcinogen Category 2
Eye Irritation Category 2A
Flammable Aerosol Category 1
Reproductive Toxicity Category 1B
Respiratory Irritation Category 3
Skin Corrosion/Irritation Category 3
EMERGENCY OVERVIEW
HAZARD
DANGER
Determined by Chemwatch using GHS/HSNO criteria:
2.1.2A 6.1D 6.3B 6.4A 6.7B 6.8A 9.1C
May cause respiratory irritation
Extremely flammable aerosol
Harmful if inhaled
Causes mild skin irritation
Causes serious eye irritation
continued...
0893 114 - WURTH ZINC SPRAY, LIGHT 400ML
Chemwatch Material Safety Data Sheet
Issue Date: 20-Aug-2004 CHEMWATCH 4598-63
NA477ECP Version No:3
CD 2007/2 Page 2 of 28
Section 2 - HAZARDS IDENTIFICATION
Suspected of causing cancer
May damage the unborn child
Harmful to aquatic life
PRECAUTIONARY STATEMENTS
Prevention
Obtain special instructions before use.
Do not spray on an open flame or other ignition source.
Wash hands thoroughly after handling.
Avoid breathing dust/fume/gas/mist/vapours/spray.
Use only outdoors or in a well ventilated area.
Pressurized container: Do not pierce or burn, even after use.
Keep away from heat/sparks/open flame - No smoking.
Do not handle until all safety precautions have been read and understood.
Use personal protective equipment as required.
Response
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
If skin irritation occurs, seek medical advice/attention.
If exposed or concerned: Get medical attention advice.
If eye irritation persists, get medical advice/attention.
Wear eye/face protection.
Specific treatment: refer to Label or MSDS.
Eliminate all ignition sources if safe to do so.
Leaking gas fire: Do not extinguish, unless leak can be stopped safely
Call a POISON CENTER or doctor/physician if you feel unwell.
IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.
Storage
Store locked up.
Protect from sunlight and do not expose to temperatures exceeding 50??C/122??F.
Disposal
Dispose of contents and container in accordance with relevant legislation.
Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS
NAME CAS RN %
acetone 67-64-1 1-19
ethyl acetate 141-78-6 1-19
xylene 1330-20-7 1-12.4
naphtha petroleum, heavy, hydrotreated 64742-48-9. 1-9
n- butyl acetate 123-86-4 1-10
aluminium 7429-90-5 1-10
n- butanol 71-36-3 1-4
propellant, as
dimethyl ether 115-10-6 30-60
Section 4 - FIRST AID MEASURES
NEW ZEALAND POISONS INFORMATION CENTRE 0800 POISON (0800 764 766)
NZ EMERGENCY SERVICES: 111
continued...
0893 114 - WURTH ZINC SPRAY, LIGHT 400ML
Chemwatch Material Safety Data Sheet
Issue Date: 20-Aug-2004 CHEMWATCH 4598-63
NA477ECP Version No:3
CD 2007/2 Page 3 of 28
Section 4 - FIRST AID MEASURES
SWALLOWED
Not considered a normal route of entry.
路 For advice, contact a Poisons Information Centre or a doctor at once.
路 Urgent hospital treatment is likely to be needed.
路 If swallowed do NOT induce vomiting.
路 If vomiting occurs, lean patient forward or place on left side (head-down position, if
possible) to maintain open airway and prevent aspiration.
路 Observe the patient carefully.
路 Never give liquid to a person showing signs of being sleepy or with reduced awareness;
i.e. becoming unconscious.
路 Give water to rinse out mouth, then provide liquid slowly and as much as casualty can
comfortably drink.
路 Transport to hospital or doctor without delay.
EYE
If aerosols come in contact with the eyes:
路 Immediately hold the eyelids apart and flush the eye continuously for at least 15
minutes with fresh running water.
路 Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and
moving the eyelids by occasionally lifting the upper and lower lids.
路 Transport to hospital or doctor without delay.
路 Removal of contact lenses after an eye injury should only be undertaken by skilled
personnel.
SKIN
If solids or aerosol mists are deposited upon the skin:
路 Flush skin and hair with running water (and soap if available).
路 Remove any adhering solids with industrial skin cleansing cream.
路 DO NOT use solvents.
路 Seek medical attention in the event of irritation.
INHALED
If aerosols, fumes or combustion products are inhaled:
路 Remove to fresh air.
路 Lay patient down. Keep warm and rested.
路 Prostheses such as false teeth, which may block airway, should be removed, where
possible, prior to initiating first aid procedures.
路 If breathing is shallow or has stopped, ensure clear airway and apply resuscitation,
preferably with a demand valve resuscitator, bag-valve mask device, or pocket mask as
trained. Perform CPR if necessary.
路 Transport to hospital, or doctor.
NOTES TO PHYSICIAN
for lower alkyl ethers:
--------------------------------------------------------------
BASIC TREATMENT
--------------------------------------------------------------
路 Establish a patent airway with suction where necessary.
路 Watch for signs of respiratory insufficiency and assist ventilation as necessary.
路 Administer oxygen by non-rebreather mask at 10 to 15 l/min.
路 A low-stimulus environment must be maintained.
路 Monitor and treat, where necessary, for shock.
路 Anticipate and treat, where necessary, for seizures.
路 DO NOT use emetics. Where ingestion is suspected rinse mouth and give up to 200 ml
water (5 ml/kg recommended) for dilution where patient is able to swallow, has a strong
gag reflex and does not drool.
--------------------------------------------------------------
ADVANCED TREATMENT
--------------------------------------------------------------
continued...
0893 114 - WURTH ZINC SPRAY, LIGHT 400ML
Chemwatch Material Safety Data Sheet
Issue Date: 20-Aug-2004 CHEMWATCH 4598-63
NA477ECP Version No:3
CD 2007/2 Page 4 of 28
Section 4 - FIRST AID MEASURES
路 Consider orotracheal or nasotracheal intubation for airway control in unconscious
patient or where respiratory arrest has occurred.
路 Positive-pressure ventilation using a bag-valve mask might be of use.
路 Monitor and treat, where necessary, for arrhythmias.
路 Start an IV D5W TKO. If signs of hypovolaemia are present use lactated Ringers
solution. Fluid overload might create complications.
路 Drug therapy should be considered for pulmonary oedema.
路 Hypotension without signs of hypovolaemia may require vasopressors.
路 Treat seizures with diazepam.
路 Proparacaine hydrochloride should be used to assist eye irrigation.
--------------------------------------------------------------
EMERGENCY DEPARTMENT
--------------------------------------------------------------
路 Laboratory analysis of complete blood count, serum electrolytes, BUN, creatinine,
glucose, urinalysis, baseline for serum aminotransferases (ALT and AST), calcium,
phosphorus and magnesium, may assist in establishing a treatment regime. Other useful
analyses include anion and osmolar gaps, arterial blood gases (ABGs), chest radiographs
and electrocardiograph.
路 Ethers may produce anion gap acidosis. Hyperventilation and bicarbonate therapy might
be indicated.
路 Haemodialysis might be considered in patients with impaired renal function.
路 Consult a toxicologist as necessary.
BRONSTEIN, A.C. and CURRANCE, P.L.
EMERGENCY CARE FOR HAZARDOUS MATERIALS EXPOSURE: 2nd Ed. 1994.
for simple esters:
--------------------------------------------------------------
BASIC TREATMENT
--------------------------------------------------------------
路 Establish a patent airway with suction where necessary.
路 Watch for signs of respiratory insufficiency and assist ventilation as necessary.
路 Administer oxygen by non-rebreather mask at 10 to 15 l/min.
路 Monitor and treat, where necessary, for pulmonary oedema .
路 Monitor and treat, where necessary, for shock.
路 DO NOT use emetics. Where ingestion is suspected rinse mouth and give up to 200 ml
water (5 ml/kg recommended) for dilution where patient is able to swallow, has a strong
gag reflex and does not drool.
路 Give activated charcoal.
--------------------------------------------------------------
ADVANCED TREATMENT
--------------------------------------------------------------
路 Consider orotracheal or nasotracheal intubation for airway control in unconscious
patient or where respiratory arrest has occurred.
路 Positive-pressure ventilation using a bag-valve mask might be of use.
路 Monitor and treat, where necessary, for arrhythmias.
路 Start an IV D5W TKO. If signs of hypovolaemia are present use lactated Ringers
solution. Fluid overload might create complications.
路 Drug therapy should be considered for pulmonary oedema.
路 Hypotension with signs of hypovolaemia requires the cautious administration of fluids.
Fluid overload might create complications.
路 Treat seizures with diazepam.
路 Proparacaine hydrochloride should be used to assist eye irrigation.
--------------------------------------------------------------
EMERGENCY DEPARTMENT
--------------------------------------------------------------
路 Laboratory analysis of complete blood count, serum electrolytes, BUN, creatinine,
glucose, urinalysis, baseline for serum aminotransferases (ALT and AST), calcium,
phosphorus and magnesium, may assist in establishing a treatment regime. Other useful
analyses include anion and osmolar gaps, arterial blood gases (ABGs), chest radiographs
and electrocardiograph.
continued...
0893 114 - WURTH ZINC SPRAY, LIGHT 400ML
Chemwatch Material Safety Data Sheet
Issue Date: 20-Aug-2004 CHEMWATCH 4598-63
NA477ECP Version No:3
CD 2007/2 Page 5 of 28
Section 4 - FIRST AID MEASURES
路 Positive end-expiratory pressure (PEEP)-assisted ventilation may be required for acute
parenchymal injury or adult respiratory distress syndrome.
路 Consult a toxicologist as necessary.
BRONSTEIN, A.C. and CURRANCE, P.L. EMERGENCY CARE FOR HAZARDOUS MATERIALS EXPOSURE: 2nd
Ed. 1994.
for simple ketones:
--------------------------------------------------------------
BASIC TREATMENT
--------------------------------------------------------------
路 Establish a patent airway with suction where necessary.
路 Watch for signs of respiratory insufficiency and assist ventilation as necessary.
路 Administer oxygen by non-rebreather mask at 10 to 15 l/min.
路 Monitor and treat, where necessary, for pulmonary oedema .
路 Monitor and treat, where necessary, for shock.
路 DO NOT use emetics. Where ingestion is suspected rinse mouth and give up to 200 ml
water (5mL/kg recommended) for dilution where patient is able to swallow, has a strong
gag reflex and does not drool.
路 Give activated charcoal.
--------------------------------------------------------------
ADVANCED TREATMENT
--------------------------------------------------------------
路 Consider orotracheal or nasotracheal intubation for airway control in unconscious
patient or where respiratory arrest has occurred.
路 Consider intubation at first sign of upper airway obstruction resulting from oedema.
路 Positive-pressure ventilation using a bag-valve mask might be of use.
路 Monitor and treat, where necessary, for arrhythmias.
路 Start an IV D5W TKO. If signs of hypovolaemia are present use lactated Ringers
solution. Fluid overload might create complications.
路 Drug therapy should be considered for pulmonary oedema.
路 Hypotension with signs of hypovolaemia requires the cautious administration of fluids.
Fluid overload might create complications.
路 Treat seizures with diazepam.
路 Proparacaine hydrochloride should be used to assist eye irrigation.
--------------------------------------------------------------
EMERGENCY DEPARTMENT
--------------------------------------------------------------
路 Laboratory analysis of complete blood count, serum electrolytes, BUN, creatinine,
glucose, urinalysis, baseline for serum aminotransferases (ALT and AST), calcium,
phosphorus and magnesium, may assist in establishing a treatment regime. Other useful
analyses include anion and osmolar gaps, arterial blood gases (ABGs), chest radiographs
and electrocardiograph.
路 Positive end-expiratory pressure (PEEP)-assisted ventilation may be required for acute
parenchymal injury or adult respiratory distress syndrome.
路 Consult a toxicologist as necessary.
BRONSTEIN, A.C. and CURRANCE, P.L.
EMERGENCY CARE FOR HAZARDOUS MATERIALS EXPOSURE: 2nd Ed. 1994.
Treat symptomatically.
For acute or short term repeated exposures to petroleum distillates or related
hydrocarbons:
路 Primary threat to life, from pure petroleum distillate ingestion and/or inhalation, is
respiratory failure.
路 Patients should be quickly evaluated for signs of respiratory distress (e.g. cyanosis,
tachypnoea, intercostal retraction, obtundation) and given oxygen. Patients with
inadequate tidal volumes or poor arterial blood gases (pO2 50 mm Hg) should be intubated.
路 Arrhythmias complicate some hydrocarbon ingestion and/or inhalation and
electrocardiographic evidence of myocardial injury has been reported; intravenous lines
and cardiac monitors should be established in obviously symptomatic patients. The lungs
excrete inhaled solvents, so that hyperventilation improves clearance.
路 A chest x-ray should be taken immediately after stabilisation of breathing and
continued...
0893 114 - WURTH ZINC SPRAY, LIGHT 400ML
Chemwatch Material Safety Data Sheet
Issue Date: 20-Aug-2004 CHEMWATCH 4598-63
NA477ECP Version No:3
CD 2007/2 Page 6 of 28
Section 4 - FIRST AID MEASURES
circulation to document aspiration and detect the presence of pneumothorax.
路 Epinephrine (adrenalin) is not recommended for treatment of bronchospasm because of
potential myocardial sensitisation to catecholamines. Inhaled cardioselective
bronchodilators (e.g. Alupent, Salbutamol) are the preferred agents, with aminophylline a
second choice.
路 Lavage is indicated in patients who require decontamination; ensure use of cuffed
endotracheal tube in adult patients. [Ellenhorn and Barceloux: Medical Toxicology].
Section 5 - FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA
SMALL FIRE:
路 Water spray, dry chemical or CO2
LARGE FIRE:
路 Water spray or fog.
FIRE FIGHTING
路 Alert Fire Brigade and tell them location and nature of hazard.
路 May be violently or explosively reactive.
路 Wear breathing apparatus plus protective gloves.
路 Prevent, by any means available, spillage from entering drains or water course.
路 If safe, switch off electrical equipment until vapour fire hazard removed.
路 Use water delivered as a fine spray to control fire and cool adjacent area.
路 DO NOT approach containers suspected to be hot.
路 Cool fire exposed containers with water spray from a protected location.
路 If safe to do so, remove containers from path of fire.
路 Equipment should be thoroughly decontaminated after use.
When any large container (including road and rail tankers) is involved in a fire,
consider evacuation by 100 metres in all directions.
FIRE/EXPLOSION HAZARD
路 Hot organic vapours or mist are capable of sudden spontaneous combustion when mixed
with air even at temperatures below their published autoignition temperatures.
路 The temperature of ignition decreases with increasing vapour volume and vapour/air
contact times and is influenced by pressure change.
路 Ignition may occur under elevated-temperature process conditions especially in
processes performed under vacuum subjected to sudden ingress of air or in processes
performed at elevated pressure, where sudden escape of vapours or mists to the atmosphere
occurs.
Contains low boiling substance: Closed containers may rupture due to pressure
buildup under fire conditions.
路 Liquid and vapour are flammable.
路 Moderate fire hazard when exposed to heat or flame.
路 Vapour forms an explosive mixture with air.
路 Moderate explosion hazard when exposed to heat or flame.
路 Vapour may travel a considerable distance to source of ignition.
路 Heating may cause expansion or decomposition leading to violent rupture of containers.
路 Aerosol cans may explode on exposure to naked flame.
路 Rupturing containers may rocket and scatter burning materials.
路 Hazards may not be restricted to pressure effects.
路 May emit acrid, poisonous or corrosive fumes.
路 On combustion, may emit toxic fumes of carbon monoxide (CO).
WARNING: In use may form flammable/ explosive vapour-air mixtures.
Combustion products include:.
carbon dioxide (CO2).
other pyrolysis products typical of burning organic material.
continued...
0893 114 - WURTH ZINC SPRAY, LIGHT 400ML
Chemwatch Material Safety Data Sheet
Issue Date: 20-Aug-2004 CHEMWATCH 4598-63
NA477ECP Version No:3
CD 2007/2 Page 7 of 28
Section 5 - FIRE FIGHTING MEASURES
FIRE INCOMPATIBILITY
Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine
bleaches, pool chlorine etc. as ignition may result.
Personal Protective Equipment
Breathing apparatus.
Gas tight chemical resistant suit.
Limit exposure duration to 1 BA set 30 mins.
Section 6 - ACCIDENTAL RELEASE MEASURES
EMERGENCY PROCEDURES
MINOR SPILLS
路 Clean up all spills immediately.
路 Avoid breathing vapours and contact with skin and eyes.
路 Wear protective clothing, impervious gloves and safety glasses.
路 Shut off all possible sources of ignition and increase ventilation.
路 Wipe up.
路 If safe, damaged cans should be placed in a container outdoors, away from all ignition
sources, until pressure has dissipated.
路 Undamaged cans should be gathered and stowed safely.
MAJOR SPILLS
路 Clear area of personnel and move upwind.
路 Alert Fire Brigade and tell them location and nature of hazard.
路 May be violently or explosively reactive.
路 Wear breathing apparatus plus protective gloves.
路 Prevent, by any means available, spillage from entering drains or water courses
路 No smoking, naked lights or ignition sources.
路 Increase ventilation.
路 Stop leak if safe to do so.
路 Water spray or fog may be used to disperse / absorb vapour.
路 Absorb or cover spill with sand, earth, inert materials or vermiculite.
路 If safe, damaged cans should be placed in a container outdoors, away from ignition
sources, until pressure has dissipated.
路 Undamaged cans should be gathered and stowed safely.
路 Collect residues and seal in labelled drums for disposal.
PROTECTIVE ACTIONS FOR SPILL
PROTECTIVE ACTION ZONE
half
evacuation
downwind
direction
distance
down wind distance
wind isolation
distance
direction
half
evacuation downwind
INITIAL direction distance
ISOLATION
ZONE
From IERG (Canada/Australia)
Isolation Distance -
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0893 114 - WURTH ZINC SPRAY, LIGHT 400ML
Chemwatch Material Safety Data Sheet
Issue Date: 20-Aug-2004 CHEMWATCH 4598-63
NA477ECP Version No:3
CD 2007/2 Page 8 of 28
Section 6 - ACCIDENTAL RELEASE MEASURES
Downwind Protection Distance 8 metres
IERG Number 49
FOOTNOTES
1 PROTECTIVE ACTION ZONE is defined as the area in which people are at risk of harmful exposure. This zone
assumes that random changes in wind direction confines the vapour plume to an area within 30 degrees on
either side of the predominant wind direction, resulting in a crosswind protective action distance equal
to the downwind protective action distance.
2 PROTECTIVE ACTIONS should be initiated to the extent possible, beginning with those closest to the spill
and working away from the site in the downwind direction. Within the protective action zone a level of
vapour concentration may exist resulting in nearly all unprotected persons becoming incapacitated and
unable to take protective action and/or incurring serious or irreversible health effects.
3 INITIAL ISOLATION ZONE is determined as an area, including upwind of the incident, within which a high
probability of localised wind reversal may expose nearly all persons without appropriate protection to
life-threatening concentrations of the material.
4 SMALL SPILLS involve a leaking package of 200 litres (55 US gallons) or less, such as a drum (jerrican or
box with inner containers). Larger packages leaking less than 200 litres and compressed gas leaking from
a small cylinder are also considered "small spills".
LARGE SPILLS involve many small leaking packages or a leaking package of greater than 200 litres, such as
a cargo tank, portable tank or a "one-tonne" compressed gas cylinder.
5 Guide 126 is taken from the US DOT emergency response guide book.
6 IERG information is derived from CANUTEC - Transport Canada.
EMERGENCY RESPONSE PLANNING GUIDELINES (ERPG)
The maximum airborne concentration below which it is believed that nearly all individuals could be exposed
for up to one hour WITHOUT experiencing or developing
life-threatening health effects is:
acetone 8500 ppm
ethyl acetate 2000 ppm
xylene 900 ppm
n-butyl acetate 3000 ppm
aluminium 250 mg/m鲁
dimethyl ether 60000 ppm
irreversible or other serious effects or symptoms which could impair an individual's ability to take
protective action is:
acetone 8500 ppm
ethyl acetate 400 ppm
xylene 200 ppm
n-butyl acetate 200 ppm
aluminium 50 mg/m鲁
dimethyl ether 50000 ppm
other than mild, transient adverse effects without perceiving a clearly defined odour is:
acetone 1000 ppm
ethyl acetate 400 ppm
xylene 150 ppm
n-butyl acetate 5 ppm
aluminium 30 mg/m鲁
dimethyl ether 3000 ppm
The threshold concentration below which most people will experience no appreciable risk of health effects:
acetone 1000 ppm
ethyl acetate 400 ppm
xylene 100 ppm
n-butyl acetate 5 ppm
aluminium 15 mg/m鲁
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0893 114 - WURTH ZINC SPRAY, LIGHT 400ML
Chemwatch Material Safety Data Sheet
Issue Date: 20-Aug-2004 CHEMWATCH 4598-63
NA477ECP Version No:3
CD 2007/2 Page 9 of 28
Section 6 - ACCIDENTAL RELEASE MEASURES
dimethyl ether 1000 ppm
American Industrial Hygiene Association (AIHA)
Ingredients considered according to the following cutoffs
Very Toxic (T+) >= 0.1% Toxic (T) >= 3.0%
R50 >= 0.25% Corrosive (C) >= 5.0%
R51 >= 2.5%
else >= 10%
where percentage is percentage of ingredient found in the mixture
Personal Protective Equipment advice is contained in Section 8 of the MSDS.
Section 7 - HANDLING AND STORAGE
PROCEDURE FOR HANDLING
DO NOT allow clothing wet with material to stay in contact with skin.
路 Avoid all personal contact, including inhalation.
路 Wear protective clothing when risk of exposure occurs.
路 Use in a well-ventilated area.
路 Prevent concentration in hollows and sumps.
路 DO NOT enter confined spaces until atmosphere has been checked.
路 Avoid smoking, naked lights or ignition sources.
路 Avoid contact with incompatible materials.
路 When handling, DO NOT eat, drink or smoke.
路 DO NOT incinerate or puncture aerosol cans.
路 DO NOT spray directly on humans, exposed food or food utensils.
路 Avoid physical damage to containers.
路 Always wash hands with soap and water after handling.
路 Work clothes should be laundered separately.
路 Use good occupational work practice.
路 Observe manufacturer's storing and handling recommendations.
路 Atmosphere should be regularly checked against established exposure standards to ensure
safe working conditions are maintained.
SUITABLE CONTAINER
路 Aerosol dispenser.
路 Check that containers are clearly labelled.
STORAGE INCOMPATIBILITY
Reacts violently with caustic soda, other alkalies - generating heat, highly flammable
hydrogen gas. If alkali is dry, heat generated may ignite hydrogen - if alkali is in
solution may cause violent foaming.
Avoid reaction with oxidising agents.
STORAGE REQUIREMENTS
Keep dry to avoid corrosion of cans. Corrosion may result in container perforation and
internal pressure may eject contents of can.
路 Store in original containers in approved flammable liquid storage area.
路 DO NOT store in pits, depressions, basements or areas where vapours may be trapped.
路 No smoking, naked lights, heat or ignition sources.
路 Keep containers securely sealed. Contents under pressure.
路 Store away from incompatible materials.
路 Store in a cool, dry, well ventilated area.
路 Avoid storage at temperatures higher than 40 deg C.
路 Store in an upright position.
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0893 114 - WURTH ZINC SPRAY, LIGHT 400ML
Chemwatch Material Safety Data Sheet
Issue Date: 20-Aug-2004 CHEMWATCH 4598-63
NA477ECP Version No:3
CD 2007/2 Page 10 of 28
Section 7 - HANDLING AND STORAGE
路 Protect containers against physical damage.
路 Check regularly for spills and leaks.
路 Observe manufacturer's storing and handling recommendations.
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE CONTROLS
Source Material TWA ppm TWA mg/m鲁 STEL ppm STEL mg/m鲁Peak ppm Peak mg/m鲁 TWA F/CC
_________ _________ _____ _____ _____ _____ _____ _____ _____
New acetone 500 1, 185 1, 000 2, 375
Zealand (Acetone)
Workplace
Exposure
Standards
(WES)
New ethyl 200 720
Zealand acetate
Workplace (Ethyl
Exposure acetate)
Standards
(WES)
New xylene 50 217
Zealand (Xylene)
Workplace
Exposure
Standards
(WES)
New xylene 50 217
Zealand (Xylene)
Workplace
Exposure
Standards
(WES)
New xylene 50 217
Zealand (Xylene)
Workplace
Exposure
Standards
(WES)
New xylene 50 217
Zealand (Xylene)
Workplace
Exposure
Standards
(WES)
New n- butyl 150 713 200 950
Zealand acetate
Workplace (n- Butyl
Exposure acetate)
Standards
(WES)
New aluminium 5
Zealand (Aluminium
Workplace , as Al)
Exposure
Standards
(WES)
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0893 114 - WURTH ZINC SPRAY, LIGHT 400ML
Chemwatch Material Safety Data Sheet
Issue Date: 20-Aug-2004 CHEMWATCH 4598-63
NA477ECP Version No:3
CD 2007/2 Page 11 of 28
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
Source Material TWA ppm TWA mg/m鲁 STEL ppm STEL mg/m鲁Peak ppm Peak mg/m鲁 TWA F/CC
_________ _________ _____ _____ _____ _____ _____ _____ _____
New aluminium 5
Zealand (Aluminium
Workplace , as Al)
Exposure
Standards
(WES)
New aluminium 10
Zealand (Aluminium
Workplace , as Al)
Exposure
Standards
(WES)
New n- butanol 50 150
Zealand (n- Butyl
Workplace alcohol)
Exposure
Standards
(WES)
New dimethyl 400 766 500 958
Zealand ether
Workplace (Dimethyle
Exposure ther)
Standards
(WES)
The following materials had no OELs on our records
鈥? naphtha petroleum, heavy, hydrotreated: CAS:64742- 48- 9
EMERGENCY EXPOSURE LIMITS
Material Revised IDLH Value (mg/m3) Revised IDLH Value (ppm)
acetone 2, 500 [LEL]
ethyl acetate 2, 000 [LEL]
xylene 900
n- butyl acetate 1, 700 [LEL]
n- butanol 1, 400 [LEL]
NOTES
Values marked LEL indicate that the IDLH was based on 10% of the lower explosive limit
for safety considerations even though the relevant toxicological data indicated that
irreversible health effects or impairment of escape existed only at higher
concentrations.
ODOUR SAFETY FACTOR (OSF)
OSF=4 (XYLENE)
Exposed individuals are NOT reasonably expected to be warned, by smell, that the Exposure
Standard is being exceeded.
Odour Safety Factor (OSF) is determined to fall into either Class C, D or E.
The Odour Safety Factor (OSF) is defined as:
OSF= Exposure Standard (TWA) ppm/ Odour Threshold Value (OTV) ppm
Classification into classes follows:
Class OSF Description
A 550 Over 90% of exposed individuals
are aware by smell that the
continued...
0893 114 - WURTH ZINC SPRAY, LIGHT 400ML
Chemwatch Material Safety Data Sheet
Issue Date: 20-Aug-2004 CHEMWATCH 4598-63
NA477ECP Version No:3
CD 2007/2 Page 12 of 28
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure Standard (TLV- TWA for
example) is being reached, even
when distracted by working
activities
B 26- 550 As " A" for 50- 90% of persons
being distracted
C 1- 26 As " A" for less than 50% of
persons being distracted
D 0.18- 1 10- 50% of persons aware of
being tested perceive by smell
that the Exposure Standard is
being reached
E <0.18 As " D" for less than 10% of
persons aware of being tested
.
MATERIAL DATA
Not available. Refer to individual constituents.
INGREDIENT DATA
ACETONE:
ETHYL ACETATE:
N-BUTANOL:
N-BUTYL ACETATE:
Exposed individuals are reasonably expected to be warned, by smell, that the Exposure
Standard is being exceeded.
Odour Safety Factor (OSF) is determined to fall into either Class A or B.
The Odour Safety Factor (OSF) is defined as:
OSF= Exposure Standard (TWA) ppm/ Odour Threshold Value (OTV) ppm
Classification into classes follows:
Class OSF Description
A 550 Over 90% of exposed individuals
are aware by smell that the
Exposure Standard (TLV- TWA for
example) is being reached, even
when distracted by working
activities
B 26- 550 As " A" for 50- 90% of persons
being distracted
C 1- 26 As " A" for less than 50% of
persons being distracted
D 0.18- 1 10- 50% of persons aware of
being tested perceive by smell
that the Exposure Standard is
being reached
E <0.18 As " D" for less than 10% of
persons aware of being tested
.
ACETONE:
Odour Threshold Value: 3.6 ppm (detection), 699 ppm (recognition)
Saturation vapour concentration: 237000 ppm @ 20 C
NOTE: Detector tubes measuring in excess of 40 ppm, are available.
Exposure at or below the recommended TLV-TWA is thought to protect the
worker against mild irritation associated with brief exposures and the
continued...
0893 114 - WURTH ZINC SPRAY, LIGHT 400ML
Chemwatch Material Safety Data Sheet
Issue Date: 20-Aug-2004 CHEMWATCH 4598-63
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Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
bioaccumulation, chronic irritation of the respiratory tract and headaches
associated with long-term acetone exposures. The NIOSH REL-TWA is
substantially lower and has taken into account slight irritation
experienced by volunteer subjects at 300 ppm. Mild irritation to
acclimatised workers begins at about 750 ppm - unacclimatised subjects
will experience irritation at about 350-500 ppm but acclimatisation can
occur rapidly. Disagreement between the peak bodies is based largely on
the view by ACGIH that widespread use of acetone, without evidence of
significant adverse health effects at higher concentrations, allows
acceptance of a higher limit.
Half-life of acetone in blood is 3 hours which means that no adjustment
for shift-length has to be made with reference to the standard 8 hour/day,
40 hours per week because body clearance occurs within any shift with low
potential for accumulation.
A STEL has been established to prevent excursions of acetone vapours that
could cause depression of the central nervous system.
ETHYL ACETATE:
Odour Threshold Value: 6.4-50 ppm (detection), 13.3-75 ppm (recognition)
The TLV-TWA provides a significant margin of safety from the standpoint of
adverse health effects. Unacclimated subjects found the odour
objectionably strong at 200 ppm. Mild nose, eye and throat irritation was
experienced at 400 ppm. Workers exposed regularly at concentrations
ranging from 375 ppm to 1500 ppm for several months showed no unusual
signs or symptoms.
XYLENE:
Sensory irritants are chemicals that produce temporary and undesirable side-effects on
the eyes, nose or throat. Historically occupational exposure standards for these
irritants have been based on observation of workers' responses to various airborne
concentrations. Present day expectations require that nearly every individual should be
protected against even minor sensory irritation and exposure standards are established
using uncertainty factors or safety factors of 5 to 10 or more. On occasion animal no
-observable-effect-levels (NOEL) are used to determine these limits where human results
are unavailable. An additional approach, typically used by the TLV committee (USA) in
determining respiratory standards for this group of chemicals, has been to assign ceiling
values (TLV C) to rapidly acting irritants and to assign short-term exposure limits (TLV
STELs) when the weight of evidence from irritation, bioaccumulation and other endpoints
combine to warrant such a limit. In contrast the MAK Commission (Germany) uses a five
-category system based on intensive odour, local irritation, and elimination half-life.
However this system is being replaced to be consistent with the European Union (EU)
Scientific Committee for Occupational Exposure Limits (SCOEL); this is more closely
allied to that of the USA.
OSHA (USA) concluded that exposure to sensory irritants can:
路 cause inflammation
路 cause increased susceptibility to other irritants and infectious agents
路 lead to permanent injury or dysfunction
路 permit greater absorption of hazardous substances and
路 acclimate the worker to the irritant warning properties of these substances thus
increasing the risk of overexposure.
IDLH Level: 900 ppm
Odour Threshold Value: 20 ppm (detection), 40 ppm (recognition)
NOTE: Detector tubes for o-xylene, measuring in excess of 10 ppm, are
available commercially. (m-xylene and p-xylene give almost the same
response)
Xylene vapour is an irritant to the eyes, mucous membranes and skin and
causes narcosis at high concentrations. Exposure to doses sufficiently high
to produce intoxication and unconsciousness also produces transient liver
continued...
0893 114 - WURTH ZINC SPRAY, LIGHT 400ML
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Issue Date: 20-Aug-2004 CHEMWATCH 4598-63
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Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
and kidney toxicity. Neurologic impairment is NOT evident amongst
volunteers inhaling up to 400 ppm though complaints of ocular and upper
respiratory tract irritation occur at 200 ppm for 3 to 5 minutes.
Exposure to xylene at or below the recommended TLV-TWA and STEL is thought
to minimise the risk of irritant effects and to produce neither significant
narcosis or chronic injury. An earlier skin notation was deleted because
percutaneous absorption is gradual and protracted and does not
substantially contribute to the dose received by inhalation.
NAPHTHA PETROLEUM, HEAVY, HYDROTREATED:
REL TWA: 300 ppm [EXXON]
as VM & P naphtha
TLV TWA: 300 ppm, 1370 mg/m3
N-BUTYL ACETATE:
Odour Threshold Value: 0.0063 ppm (detection), 0.038-12 ppm (recognition)
Exposure at or below the recommended TLV-TWA is thought to prevent
significant irritation of the eyes and respiratory passages as well as
narcotic effects. In light of the lack of substantive evidence regarding
teratogenicity and a review of acute oral data a STEL is considered
inappropriate.
ALUMINIUM:
Twenty seven year experience with aluminium oxide dust (particle size 96%
1,2 um) without adverse effects either systemically or on the lung, and at
a calculated concentration equivalent to 2 mg/m3 over an 8-hour shift has
lead to the current recommendation of the TLV-TWA.
The limit should also apply to aluminium pyro powders whose toxicity is
reportedly greater than aluminium dusts and should be protective against
lung changes.
N-BUTANOL:
Odour Threshold Value: 0.12-3.4 ppm (detection), 1.0-3.5 ppm (recognition)
NOTE: Detector tubes for n-butanol, measuring in excess of 5 ppm are
commercially available.
Exposure at or below the TLV-TWA is thought to provide protection against
hearing loss due to vestibular and auditory nerve damage in younger
workers and to protect against the significant risk of headache and
irritation.
25 ppm may produce mild irritation of the respiratory tract
50 ppm may produce headache and vertigo.
Higher concentrations may produce marked irritation, sore throat,
coughing, nausea, shortness of breath, pulmonary injury and central
nervous system depression characterised by headache, dizziness, dullness
and drowsiness.
6000 ppm may produce giddiness, prostration, narcosis, ataxia, and death.
DIMETHYL ETHER:
The no-effect-level for dimethyl ether is somewhere between 2000 ppm
(rabbits) and 50,000 ppm (humans) with possible cardiac sensitisation
occurring around 200,000 ppm (dogs). The AIHA has adopted a safety factor
of 100 in respect to the 50,000 ppm level in its recommendation for a
workplace environmental exposure level (WEEL) which is thought to protect
against both narcotic and sensitising effects. This level is consistent
with the TLV-TWA of 400 ppm for diethyl ether and should be easily
achievable using current technologies. The use of the traditionally
allowable excursion of 1.25 to the level of 6.25 ppm is felt to be more
continued...
0893 114 - WURTH ZINC SPRAY, LIGHT 400ML
Chemwatch Material Safety Data Sheet
Issue Date: 20-Aug-2004 CHEMWATCH 4598-63
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Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
than adequate as an upper safe limit of exposure.
Human data:
50,000 ppm (12 mins): Feelings of mild intoxication.
75,000 ppm (12 mins): As above plus slight lack of attenuation.
82,000 ppm (12 mins): Some incoordination, slight blurring of vision
(30 mins): As above plus analgesia of the face and rushing of
blood to the face.
100,000 ppm (10-20 mins): Narcotic symptoms
(64 mins) : Sickness (assumed to be nausea)
144,000 ppm (36 mins): Unconsciousness
PERSONAL PROTECTION
EYE
No special equipment for minor exposure i.e. when handling small quantities.
OTHERWISE: For potentially moderate or heavy exposures:
路 Safety glasses with side shields.
路 NOTE: Contact lenses pose a special hazard; soft lenses may absorb irritants and ALL
lenses concentrate them.
路 Safety glasses with side shields.
路 Chemical goggles.
路 Contact lenses may pose a special hazard; soft contact lenses may absorb and
concentrate irritants. A written policy document, describing the wearing of lens or
restrictions on use, should be created for each workplace or task. This should include a
review of lens absorption and adsorption for the class of chemicals in use and an account
of injury experience. Medical and first-aid personnel should be trained in their removal
and suitable equipment should be readily available. In the event of chemical exposure,
begin eye irrigation immediately and remove contact lens as soon as practicable. Lens
should be removed at the first signs of eye redness or irritation - lens should be
removed in a clean environment only after workers have washed hands thoroughly. [CDC
NIOSH Current Intelligence Bulletin 59].
HANDS/FEET
No special equipment needed when handling small quantities.
OTHERWISE:
For potentially moderate exposures:
Wear general protective gloves, eg. light weight rubber gloves.
For potentially heavy exposures:
Wear chemical protective gloves, eg. PVC. and safety footwear.
OTHER
No special equipment needed when handling small quantities.
OTHERWISE:
路 Overalls.
路 Skin cleansing cream.
路 Eyewash unit.
路 Do not spray on hot surfaces.
RESPIRATOR
Respiratory protection may be required when ANY "Worst Case" vapour-phase concentration
is exceeded (see Computer Prediction in "Exposure Standards")
Protection Factor (Min) Half- Face Respirator Full- Face Respirator
10 x ES Air- line* AX- 2
- AX- PAPR- 2
20 x ES - AX- 3
20+ x ES - Air- line**
* - Continuous-flow; ** - Continuous-flow or positive pressure demand
continued...
0893 114 - WURTH ZINC SPRAY, LIGHT 400ML
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Issue Date: 20-Aug-2004 CHEMWATCH 4598-63
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Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
^ - Full-face.
The local concentration of material, quantity and conditions of use determine the type of
personal protective equipment required.
For further information consult site specific
CHEMWATCH data (if available), or your
Occupational Health and Safety Advisor.
ENGINEERING CONTROLS
General exhaust is adequate under normal conditions. If risk of overexposure exists, wear
SAA approved respirator. Correct fit is essential to obtain adequate protection.
Provide adequate ventilation in warehouse or closed storage areas.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE
Supplied as an aerosol pack. Contents under PRESSURE. Contains highly flammable
hydrocarbon propellant.
Silver coloured liquid with a characteristic odour; does not mix with water.
Supplied as an aerosol pack. Contents under PRESSURE. Contains highly flammable ether
propellant.
PHYSICAL PROPERTIES
Liquid.
Gas.
Does not mix with water.
Molecular Weight: Not Applicable Boiling Range (掳 55 app rox.
C):
Melting Range (掳 Not Available
C): Specific Gravity (water= 1): 0.9- 1.1
Solubility in water (g/L): Immiscible pH (as supplied): Not Applicable
pH (1% solution): Not Applicable Vapour Pressure (kPa): Not Available
Volatile Component (%vol): >60 Evaporation Rate: Not Available
Relative Vapour Density (air=1): Not Available Flash Point (掳 - 19 approx.
C):
Lower Explosive Limit (%): 0.6 Upper Explosive Limit (%): 13
Autoignition Temp (掳 240
C): Decomposition Temp (掳 Not Av ailable
C):
State: Liquid Viscosity: Not Available
log Kow (Prager 1995): - 0.24
log Kow (Sangster 1997): - 0.24
log Kow: -0.24
log Kow: 0.66-0.73
log Kow (Prager 1995): 3.12- 3.20
log Kow (Prager 1995): 1.82
log Kow (Sangster 1997): 1.78
log Kow (Prager 1995): 0.88
log Kow (Sangster 1997): 0.84
log Kow: 0.88
log Kow (Sangster 1997): 0.1
log Kow: 0.1-0.12
continued...
0893 114 - WURTH ZINC SPRAY, LIGHT 400ML
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Section 10 - CHEMICAL STABILITY AND REACTIVITY INFORMATION
CONDITIONS CONTRIBUTING TO INSTABILITY
路 Elevated temperatures.
路 Presence of open flame.
路 Product is considered stable.
路 Hazardous polymerisation will not occur.
Section 11 - TOXICOLOGICAL INFORMATION
POTENTIAL HEALTH EFFECTS
ACUTE HEALTH EFFECTS
SWALLOWED
Considered an unlikely route of entry in commercial/industrial environments.
Accidental ingestion of the material may be damaging to the health of the individual.
Rats given isoparaffinic hydrocarbons (after 18-24 hours fasting) showed lethargy and/or
general weakness, ataxia and diarrhoea. Symptoms disappeared within 24-28 hours.
Ingestion of petroleum hydrocarbons may produce irritation of the pharynx, oesophagus,
stomach and small intestine with oedema and mucosal ulceration resulting; symptoms
include a burning sensation in the mouth and throat. Large amounts may produce narcosis
with nausea and vomiting, weakness or dizziness, slow and shallow respiration, swelling
of the abdomen, unconsciousness and convulsions. Myocardial injury may produce
arrhythmias, ventricular fibrillation and electrocardiographic changes. Central nervous
system depression may also occur. Light aromatic hydrocarbons produce a warm, sharp,
tingling sensation on contact with taste buds and may anaesthetise the tongue. Aspiration
into the lungs may produce coughing, gagging and a chemical pneumonitis with pulmonary
oedema and haemorrhage.
Not normally a hazard due to physical form of product.
Considered an unlikely route of entry in commercial/industrial environments. The liquid
may produce gastrointestinal discomfort and may be harmful if swallowed. Ingestion may
result in nausea, pain and vomiting. Vomit entering the lungs by aspiration may cause
potentially lethal chemical pneumonitis.
EYE
Evidence exists, or practical experience predicts, that the material may cause eye
irritation in a substantial number of individuals and/or may produce significant ocular
lesions which are present twenty-four hours or more after instillation into the eye(s) of
experimental animals.
Repeated or prolonged eye contact may cause inflammation characterised by temporary
redness (similar to windburn) of the conjunctiva (conjunctivitis); temporary impairment
of vision and/or other transient eye damage/ulceration may occur.
When applied to the eye(s) of animals, the material produces severe ocular lesions which
are present twenty-four hours or more after instillation.
The liquid produces a high level of eye discomfort and is capable of causing pain and
severe conjunctivitis. Corneal injury may develop, with possible permanent impairment of
vision, if not promptly and adequately treated.
Petroleum hydrocarbons may produce pain after direct contact with the eyes. Slight, but
transient disturbances of the corneal epithelium may also result. The aromatic fraction
may produce irritation and lachrymation.
The material may produce severe irritation to the eye causing pronounced inflammation.
Repeated or prolonged exposure to irritants may produce conjunctivitis.
continued...
0893 114 - WURTH ZINC SPRAY, LIGHT 400ML
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Issue Date: 20-Aug-2004 CHEMWATCH 4598-63
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Section 11 - TOXICOLOGICAL INFORMATION
SKIN
Limited evidence exists that exposure to the material may produce irreversible damage
(other than carcinogenesis, mutagenesis and teratogenesis) following a single exposure by
skin contact.
The material produces mild skin irritation; evidence exists, or practical experience
predicts, that the material either
路 produces mild inflammation of the skin in a substantial number of individuals following
direct contact, and/or
路 produces significant, but mild, inflammation when applied to the healthy intact skin of
animals (for up to four hours), such inflammation being present twenty-four hours or more
after the end of the exposure period.
Skin irritation may also be present after prolonged or repeated exposure; this may result
in a form of contact dermatitis (nonallergic). The dermatitis is often characterised by
skin redness (erythema) and swelling (oedema) which may progress to blistering
(vesiculation), scaling and thickening of the epidermis. At the microscopic level there
may be intercellular oedema of the spongy layer of the skin (spongiosis) and
intracellular oedema of the epidermis.
Toxic effects may result from skin absorption.
Exposure limits with "skin" notation indicate that vapour and liquid may be absorbed
through intact skin. Absorption by skin may readily exceed vapour inhalation exposure.
Symptoms for skin absorption are the same as for inhalation. Contact with eyes and mucous
membranes may also contribute to overall exposure and may also invalidate the exposure
standard.
Spray mist may produce discomfort.
Repeated exposure may cause skin cracking, flaking or drying following normal handling
and use.
Entry into the blood-stream, through, for example, cuts, abrasions or lesions, may
produce systemic injury with harmful effects. Examine the skin prior to the use of the
material and ensure that any external damage is suitably protected.
INHALED
Inhalation of vapours or aerosols (mists, fumes), generated by the material during the
course of normal handling, may be harmful.
Limited evidence exists that exposure to the material may produce irreversible damage
(other than carcinogenesis, mutagenesis and teratogenesis) following a single exposure by
inhalation.
Limited evidence or practical experience suggests that the material may produce
irritation of the respiratory system, in a significant number of individuals, following
inhalation. In contrast to most organs, the lung is able to respond to a chemical insult
by first removing or neutralising the irritant and then repairing the damage. The repair
process, which initially evolved to protect mammalian lungs from foreign matter and
antigens, may however, produce further lung damage resulting in the impairment of gas
exchange, the primary function of the lungs. Respiratory tract irritation often results
in an inflammatory response involving the recruitment and activation of many cell types,
mainly derived from the vascular system.
Common, generalised symptoms associated with toxic gas inhalation include:
路 central nervous system effects such as depression, headache, confusion, dizziness,
progressive stupor, coma and seizures;
路 respiratory system complications may include acute pulmonary oedema, dyspnoea, stridor,
tachypnoea, bronchospasm, wheezing and other reactive airway symptoms, and respiratory
arrest;
路 cardiovascular effects may include cardiovascular collapse, arrhythmias and cardiac
arrest;
路 gastrointestinal effects may also be present and may include mucous membrane irritation
, nausea and vomiting (sometimes bloody), and abdominal pain.
Inhalation of vapours may cause drowsiness and dizziness. This may be accompanied by
narcosis, reduced alertness, loss of reflexes, lack of coordination and vertigo.
continued...
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Section 11 - TOXICOLOGICAL INFORMATION
Material is highly volatile and may quickly form a concentrated atmosphere in confined or
unventilated areas. Vapour is heavier than air and may displace and replace air in
breathing zone, acting as a simple asphyxiant. This may happen with little warning of
overexposure.
WARNING:Intentional misuse by concentrating/inhaling contents may be lethal.
Inhalation of freshly formed zinc oxide particles sized below 1.5 microns and generally
between 0.02 to 0.05 microns may result in "metal fume fever", with symptoms resembling
influenza. Symptoms may be delayed for up to 12 hours and begin with the sudden onset of
thirst, and a sweet, metallic or foul taste in the mouth. Other symptoms include upper
respiratory tract irritation accompanied by coughing and a dryness of the mucous
membranes, lassitude and a generalised feeling of malaise. Mild to severe headache,
nausea, occasional vomiting, fever or chills, exaggerated mental activity, profuse
sweating, diarrhoea, excessive urination and prostration may also occur. Tolerance to the
fumes develops rapidly, but is quickly lost. All symptoms usually subside within 24-36
hours following removal from exposure. Leucocytosis, a transient increase in white blood
cell counts, is reported as a common finding in metal fume fever but is not known to be
common amongst welders. Severe over-exposure to zinc oxide, following inhalation of fumes
or finely divided dusts may result in bronchitis or pneumonia; a bluish skin tint may be
present.
Exposure to ketone vapours may produce nose, throat and mucous membrane irritation. High
concentrations of vapour may produce central nervous system depression characterised by
headache, vertigo, loss of coordination, narcosis and cardiorespiratory failure. Some
ketones produce neurological disorders (polyneuropathy) characterised by bilateral
symmetrical paresthesia and muscle weakness primarily in the legs and arms.
Systemic effects of acetone inhalation exposure include central nervous system depression
, light-headedness, incoherent speech, ataxia, stupor, hypotension, tachycardia,
metabolic acidosis, hyperglycaemia and ketosis. Rarely, convulsions and tubular necrosis
may be evident. Other symptoms of exposure may include restlessness, headache, vomiting,
low blood-pressure and rapid and irregular pulse, eye and throat irritation, weakness of
the legs and dizziness. Inhalation of high concentrations may produce dryness of the
mouth and throat, nausea, uncoordinated movement, loss of coordinated speech, drowsiness
and, in severe cases, coma. Inhalation of acetone vapours over long periods causes
irritation of the respiratory tract, coughing and headache. Rats exposed to 52200 ppm
vapour for 1 hour showed clear signs of narcosis; fatalities occurred at 126600 ppm.
Inhalation of aerosols (mists, fumes), generated by the material during the course of
normal handling, may be harmful.
CHRONIC HEALTH EFFECTS
Substance accumulation, in the human body, may occur and may cause some concern following
repeated or long-term occupational exposure.
There has been some concern that this material can cause cancer or mutations but there is
not enough data to make an assessment.
There is some evidence from animal testing that exposure to this material may result in
toxic effects to the unborn baby.
Exposure to the material for prolonged periods may cause physical defects in the
developing embryo (teratogenesis).
Metallic dusts generated by the industrial process give rise to a number of potential
health problems. The larger particles, above 5 micron, are nose and throat irritants.
Smaller particles however, may cause lung deterioration. Particles of less than 1.5
micron can be trapped in the lungs and, dependent on the nature of the particle, may give
rise to further serious health consequences.
Workers exposed to acetone for long periods showed inflammation of the airways, stomach
and small bowel, attacks of giddiness and loss of strength. Exposure to acetone may
enhance the liver toxicity of chlorinated solvents.
Principal route of occupational exposure to the gas is by inhalation.
Prolonged or continuous skin contact with the liquid may cause defatting with drying,
cracking, irritation and dermatitis following.
Chronic solvent inhalation exposures may result in nervous system impairment
and liver and blood changes. [PATTYS].
continued...
0893 114 - WURTH ZINC SPRAY, LIGHT 400ML
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Issue Date: 20-Aug-2004 CHEMWATCH 4598-63
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Section 11 - TOXICOLOGICAL INFORMATION
As with any chemical product, contact with unprotected bare skin; inhalation of vapour,
mist or dust in work place atmosphere; or ingestion in any form, should be avoided by
observing good occupational work practice.
TOXICITY AND IRRITATION
Not available. Refer to individual constituents.
ACETONE:
unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances.
TOXICITY IRRITATION
Oral (man) TDLo: 2857 mg/kg Eye (human): 500 ppm - Irritant
Oral (rat) LD50: 5800 mg/kg Eye (rabbit): 3.95 mg - SEVERE
Inhalation (human) TCLo: 500 ppm Eye (rabbit): 20mg/24hr - Moderate
Inhalation (man) TCLo: 12000 ppm/4 hr Skin (rabbit):395mg (open) - Mild
Inhalation (man) TCLo: 10 mg/m鲁/6 hr Skin (rabbit): 500 mg/24hr - Mild
Inhalation (rat) LC50: 50100 mg/m鲁/8 hr
Dermal (rabbit) LD50: 20000 mg/kg
ETHYL ACETATE:
unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances.
TOXICITY IRRITATION
Oral (rat) LD50: 5620 mg/kg Eye (human): 400 ppm
Inhalation (rat) LC50: 1600 ppm/8h
Inhalation (human) TCLo: 400 ppm
Inhalation (Human) TCLo: 400 ppm/4h
Oral (Mouse) LD50: 4100 mg/kg
Intraperitoneal (Mouse) LD50: 709 mg/kg
Oral (Rabbit) LD50: 4935 mg/kg
Oral (Guinea) pig: LD50 5500 mg/kg
XYLENE:
unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances.
TOXICITY IRRITATION
Oral (human) LDLo: 50 mg/kg Skin (rabbit):500 mg/24h Moderate
Oral (rat) LD50: 4300 mg/kg Eye (human): 200 ppm Irritant
Inhalation (human) TCLo: 200 ppm Eye (rabbit): 87 mg Mild
Inhalation (man) LCLo: 10000 ppm/6h Eye (rabbit): 5 mg/24h SEVERE
Inhalation (rat) LC50: 5000 ppm/4h
Oral (Human) LD: 50 mg/kg
Inhalation (Human) TCLo: 200 ppm/4h
Intraperitoneal (Rat) LD50: 2459 mg/kg
Subcutaneous (Rat) LD50: 1700 mg/kg
Oral (Mouse) LD50: 2119 mg/kg
Intraperitoneal (Mouse) LD50: 1548 mg/kg
Intravenous (Rabbit) LD: 129 mg/kg
Inhalation (Guinea) pig: LC 450 ppm/4h
The material may produce severe irritation to the eye causing pronounced inflammation.
Repeated or prolonged exposure to irritants may produce conjunctivitis.
The material may cause skin irritation after prolonged or repeated exposure and may
produce a contact dermatitis (nonallergic). This form of dermatitis is often
characterised by skin redness (erythema) and swelling the epidermis. Histologically there
may be intercellular oedema of the spongy layer (spongiosis) and intracellular oedema of
the epidermis.
The substance is classified by IARC as Group 3:
NOT classifiable as to its carcinogenicity to humans.
Evidence of carcinogenicity may be inadequate or limited in animal testing.
Reproductive effector in rats
NAPHTHA PETROLEUM, HEAVY, HYDROTREATED:
continued...
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Section 11 - TOXICOLOGICAL INFORMATION
unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances.
TOXICITY IRRITATION
Inhalation (rat) LC50: 3400 ppm/4h None reported
Dermal (rat) LD50: >4000 mg/kg [EXXON]
Dermal (rat) LC50: >11 mg/l [CCINFO- Shell]
Oral (rat) LD50: >8000 mg/kg
N-BUTYL ACETATE:
unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances.
TOXICITY IRRITATION
Oral (rat) LD50: 13100 mg/kg Skin (rabbit): 500 mg/24h- Moderate
Dermal (rabbit) LD50: 3200 mg/kg* Eye (rabbit): 20 mg (open)- SEVERE
Inhalation (human) TCLo: 200 ppm Eye (rabbit): 20 mg/24h - Moderate
Inhalation (rat) LC50: 2000 ppm/4h Eye ( human): 300 mg
Inhalation (Human) TCLo: 200 ppm/4h * [PPG]
Oral (Rat) LD50: 10768 mg/kg
Inhalation (Rat) LC50: 390 ppm/4h
Intraperitoneal (Mouse) LD50: 1230 mg/kg
Oral (Rabbit) LD50: 3200 mg/kg
Oral (Guinea) pig: LD50 4700 mg/kg
Intraperitoneal (Guinea) pig: LD 1500 mg/kg
The material may produce severe irritation to the eye causing pronounced inflammation.
Repeated or prolonged exposure to irritants may produce conjunctivitis.
The material may cause skin irritation after prolonged or repeated exposure and may
produce a contact dermatitis (nonallergic). This form of dermatitis is often
characterised by skin redness (erythema) and swelling the epidermis. Histologically there
may be intercellular oedema of the spongy layer (spongiosis) and intracellular oedema of
the epidermis.
ALUMINIUM:
Not available. Refer to individual constituents.
N-BUTANOL:
unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances.
TOXICITY IRRITATION
Oral (rat) LD50: 790 mg/kg Skin (rabbit): 405 mg/24h- Moderate
Inhalation (human) TCLo: 25 ppm Eye (human): 50 ppm - Irritant
Inhalation (rat) LC50: 8000 ppm/4h Eye (rabbit): 1.6 mg- SEVERE
Dermal (rabbit) LD50: 3400 mg/kg Eye (rabbit): 24 mg/24h- SEVERE
Inhalation (human) TCLo: 86000 mg/m鲁
DIMETHYL ETHER:
unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances.
TOXICITY IRRITATION
Inhalation (rat) LC50: 308000 mg/m鲁 Nil Reported
Section 12 - ECOLOGICAL INFORMATION
Marine Pollutant:Not Determined
Drinking Water Standards:
hydrocarbon total: 10 ug/l (UK max.).
DO NOT discharge into sewer or waterways.
Water hazard class 2 (Self-assessment): hazardous to water.
Refer to data for ingredients, which follows:
ACETONE:
Fish LC50 (96hr.) (mg/l): 8300- 40000
Daphnia magna EC50 (48hr.) (mg/l): 10
continued...
0893 114 - WURTH ZINC SPRAY, LIGHT 400ML
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Issue Date: 20-Aug-2004 CHEMWATCH 4598-63
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Section 12 - ECOLOGICAL INFORMATION
log Kow (Prager 1995): - 0.24
log Kow (Sangster 1997): - 0.24
log Pow (Verschueren 1983): - 0.24
BOD5: 122%
ThOD: 72
Half- life Soil - High (hours): 168
Half- life Soil - Low (hours): 24
Half- life Air - High (hours): 2790
Half- life Air - Low (hours): 279
Half- life Surface water - High (hours): 168
Half- life Surface water - Low (hours): 24
Half- life Ground water - High (hours): 336
Half- life Ground water - Low (hours): 48
Aqueous biodegradation - Aerobic - High (hours): 168
Aqueous biodegradation - Aerobic - Low (hours): 24
Aqueous biodegradation - Anaerobic - High (hours): 672
Aqueous biodegradation - Anaerobic - Low (hours): 96
Aqueous biodegradation - Removal secondary treatment - High (hours): 75%
Aqueous biodegradation - Removal secondary treatment - Low (hours): 54%
Aqueous photolysis half- life - High (hours): 270
Photooxidation half- life water - High (hours): 3.97E+06
Photooxidation half- life water - Low (hours): 9.92E+04
Photooxidation half- life air - High (hours): 2790
Photooxidation half- life air - Low (hours): 279
DO NOT discharge into sewer or waterways.
log Kow: -0.24
Half-life (hr) air: 312-1896
Half-life (hr) H2O surface water: 20
Henry's atm m鲁 /mol: 3.67E-05
BOD 5 if unstated: 0.31-1.76,46-55%
COD: 1.12-2.07
ThOD: 2.2
BCF: 0.69
Toxicity Fish: LC50(96) 5540-13000mg/L
Toxicity invertebrate: cell mult. inhib. 28-7500mg/L
Bioaccumulation: not sig
Nitrif. inhib.: 75% decr. at 840mg/L
Anaerobic effects: sig degrad
Degradation Biological: sig
processes Abiotic: Rxn OH*,photodissoc
In air, acetone is lost by photolysis and reaction with photochemically
produced hydroxyl radicals; the estimated half-life of these combined
processes is about 22 days. The relatively long half-life allows acetone
to be transported long distances from its emission source.
Acetone is highly soluble and slightly persistent in water, with a
half-life of about 20 hours; it is minimally toxic to aquatic life.
Acetone released to soil volatilises although some may leach into the
ground where it rapidly biodegrades.
Acetone does not concentrate in the food chain.
Drinking Water Standard: none available.
Soil Guidelines: none available.
Air Quality Standards: none available.
ETHYL ACETATE:
log Pow (Verschueren 1983): 0.66/0.73
ThOD: 50.4
log Pow (Verschueren 1983): 0.66/0.73
BOD5: 15%
continued...
0893 114 - WURTH ZINC SPRAY, LIGHT 400ML
Chemwatch Material Safety Data Sheet
Issue Date: 20-Aug-2004 CHEMWATCH 4598-63
NA477ECP Version No:3
CD 2007/2 Page 23 of 28
Section 12 - ECOLOGICAL INFORMATION
COD: 1.54 (83%)
ThOD: 1.82
Half- life Soil - High (hours): 168
Half- life Soil - Low (hours): 24
Half- life Air - High (hours): 353
Half- life Air - Low (hours): 35.3
Half- life Surface water - High (hours): 168
Half- life Surface water - Low (hours): 24
Half- life Ground water - High (hours): 336
Half- life Ground water - Low (hours): 48
Aqueous biodegradation - Aerobic - High (hours): 168
Aqueous biodegradation - Aerobic - Low (hours): 24
Aqueous biodegradation - Anaerobic - High (hours): 672
Aqueous biodegradation - Anaerobic - Low (hours): 96
Aqueous biodegradation - Removal secondary treatment - High (hours): 96%
Aqueous biodegradation - Removal secondary treatment - Low (hours): 99.90%
Photooxidation half- life water - High (hours): 9.60E+05
Photooxidation half- life water - Low (hours): 24090
Photooxidation half- life air - High (hours): 353
Photooxidation half- life air - Low (hours): 35.3
First order hydrolysis half- life (hours): 1.77E+04
Acid rate constant [M(H+)- HR]- 1: 3.05E- 08
Base rate constant [MOH)- HR]- 1: 2.99E- 05
DO NOT discharge into sewer or waterways.
log Kow: 0.66-0.73
Half-life (hr) air: 200
Half-life (hr) H2O surface water: 10
Henry's atm m鲁 /mol: 1.20E-04
BOD 5 if unstated: 0.1-1.24,16-36%
COD: 1.54,83%
ThOD: 1.82
XYLENE:
Fish LC50 (96hr.) (mg/l): 13.5
BCF<100: 2.14- 2.20
log Kow (Prager 1995): 3.12- 3.20
Half- life Soil - High (hours): 672
Half- life Soil - Low (hours): 168
Half- life Air - High (hours): 44
Half- life Air - Low (hours): 2.6
Half- life Surface water - High (hours): 672
Half- life Surface water - Low (hours): 168
Half- life Ground water - High (hours): 8640
Half- life Ground water - Low (hours): 336
Aqueous biodegradation - Aerobic - High (hours): 672
Aqueous biodegradation - Aerobic - Low (hours): 168
Aqueous biodegradation - Anaerobic - High (hours): 8640
Aqueous biodegradation - Anaerobic - Low (hours): 4320
Photolysis maximum light absorption - High (nano- m): 269.5
Photolysis maximum light absorption - Low (nano- m): 265
Photooxidation half- life water - High (hours): 2.70E+08
Photooxidation half- life water - Low (hours): 3.90E+05
Photooxidation half- life air - High (hours): 44
Photooxidation half- life air - Low (hours): 2.6
The lower molecular weight hydrocarbons are expected to form a "slick" on the surface of
waters after release in calm sea conditions. This is expected to evaporate and enter the
atmosphere where it will be degraded through reaction with hydroxy radicals.
continued...
0893 114 - WURTH ZINC SPRAY, LIGHT 400ML
Chemwatch Material Safety Data Sheet
Issue Date: 20-Aug-2004 CHEMWATCH 4598-63
NA477ECP Version No:3
CD 2007/2 Page 24 of 28
Section 12 - ECOLOGICAL INFORMATION
Some of the material will become associated with benthic sediments, and it is likely to
be spread over a fairly wide area of sea floor. Marine sediments may be either aerobic or
anaerobic. The material, in probability, is biodegradable, under aerobic conditions
(isomerised olefins and alkenes show variable results). Evidence also suggests that the
hydrocarbons may be degradable under anaerobic conditions although such degradation in
benthic sediments may be a relatively slow process.
Under aerobic conditions the material will degrade to water and carbon dioxide, while
under anaerobic processes it will produce water, methane and carbon dioxide.
Based on test results, as well as theoretical considerations, the potential for
bioaccumulation may be high. Toxic effects are often observed in species such as blue
mussel, daphnia, freshwater green algae, marine copepods and amphipods.
Drinking Water Standards:
hydrocarbon total: 10 ug/l (UK max.).
DO NOT discharge into sewer or waterways.
The material is classified as an ecotoxin* because the Fish LC50 (96 hours) is less than
or equal to 0.1 mg/l
* Classification of Substances as Ecotoxic (Dangerous to the Environment)
Appendix 8, Table 1
Compiler's Guide for the Preparation of International Chemical Safety Cards: 1993
Commission of the European Communities.
N-BUTYL ACETATE:
Fish LC50 (96hr.) (mg/l): 18
Daphnia magna EC50 (48hr.) (mg/l): 44
log Kow (Prager 1995): 1.82
Fish LC50 (96hr.) (mg/l): 100- 185
Daphnia magna EC50 (48hr.) (mg/l): 44
Algae IC50 (72hr.) (mg/l): 280
log Kow (Sangster 1997): 1.78
COD: 78%
DO NOT discharge into sewer or waterways.
Half-life (hr) air: 144
Half-life (hr) H2O surface water: 178-27156
Henry's atm m鲁 /mol: 3.20E-04
BOD 5 if unstated: 0.15-1.02,7%
COD: 78%
ThOD: 2.207
BCF: 4-14
Toxicity Fish: LC50(96)100-185ppm
Toxicity invertebrate: cell mult. inhib.78-3700mg/L
Effects on algae and plankton: cell mult. inhib.21-280mg/L
Degradation Biological: sig
processes Abiotic: hydrol,RxnOH*
N-BUTANOL:
Fish LC50 (96hr.) (mg/l): 1910- 1940
Daphnia magna EC50 (48hr.) (mg/l): 1983
Algae IC50 (72hr.) (mg/l): 650
log Kow (Prager 1995): 0.88
log Kow (Sangster 1997): 0.84
log Pow (Verschueren 1983): 0.88
Half- life Soil - High (hours): 168
Half- life Soil - Low (hours): 24
Half- life Air - High (hours): 87.7
continued...
0893 114 - WURTH ZINC SPRAY, LIGHT 400ML
Chemwatch Material Safety Data Sheet
Issue Date: 20-Aug-2004 CHEMWATCH 4598-63
NA477ECP Version No:3
CD 2007/2 Page 25 of 28
Section 12 - ECOLOGICAL INFORMATION
Half- life Air - Low (hours): 8.8
Half- life Surface water - High (hours): 168
Half- life Surface water - Low (hours): 24
Half- life Ground water - High (hours): 1296
Half- life Ground water - Low (hours): 48
Aqueous biodegradation - Aerobic - High (hours): 168
Aqueous biodegradation - Aerobic - Low (hours): 24
Aqueous biodegradation - Anaerobic - High (hours): 1296
Aqueous biodegradation - Anaerobic - Low (hours): 96
Aqueous biodegradation - Removal secondary treatment - High (hours): 99%
Aqueous biodegradation - Removal secondary treatment - Low (hours): 31%
Photooxidation half- life water - High (hours): 104000
Photooxidation half- life water - Low (hours): 2602
Photooxidation half- life air - High (hours): 87.7
Photooxidation half- life air - Low (hours): 8.8
DO NOT discharge into sewer or waterways.
log Kow: 0.88
Koc: 71.6
Half-life (hr) air: 5-52
Half-life (hr) H2O surface water: 2.4-3022
Henry's atm m鲁 /mol: 5.57E-06
BOD 5 if unstated: 1.1-2.04,33%
COD: 1.9,92%
ThOD: 2.594
Toxicity Fish: LD100(24)1.4g/L,LC50(96)1.91g/L
Toxicity invertebrate: cell mult. inhib.8-650mg/L
Bioacculmulation: not sig
Nitrif. inhib.: 50% inhib at 8200mg/L
Effects on algae and plankton: cell mult. inhib.100-875mg/L
Degradation Biological: sig
processes Abiotic: RxnOH*
DIMETHYL ETHER:
Water solubility (g/l): 35300
log Kow (Sangster 1997): 0.1
log Kow: 0.1-0.12
Koc: 14
Half-life (hr) air: 528
Half-life (hr) H2O surface water: 2.6-30
Henry's atm m鲁 /mol: 9.78E-04
BCF: 1.7
Bioaccumulation: not sig
processes Abiotic: RxnOH*
Section 13 - DISPOSAL CONSIDERATIONS
路 Consult State Land Waste Management Authority for disposal.
路 Discharge contents of damaged aerosol cans at an approved site.
路 Allow small quantities to evaporate.
路 DO NOT incinerate or puncture aerosol cans.
路 Bury residues and emptied aerosol cans at an approved site.
continued...
0893 114 - WURTH ZINC SPRAY, LIGHT 400ML
Chemwatch Material Safety Data Sheet
Issue Date: 20-Aug-2004 CHEMWATCH 4598-63
NA477ECP Version No:3
CD 2007/2 Page 26 of 28
Section 14 - TRANSPORTATION INFORMATION
Labels Required: FLAMMABLE GAS
HAZCHEM: 2Y
UNDG:
Dangerous Goods Class: 2.1 Subrisk: None
UN Number: 1950 Packing Group: None
Shipping Name:AEROSOLS
Air Transport IATA:
ICAO/IATA Class: 2.1 ICAO/IATA Subrisk: None
UN/ID Number: 1950 Packing Group: None
ERG Code: 10L
Shipping name:AEROSOLS
Maritime Transport IMDG:
IMDG Class: 2.1 IMDG Subrisk: SP63
UN Number: 1950 Packing Group: None
EMS Number: F- D, S- U Marine Pollutant: Not Determined
Shipping name:AEROSOLS
Section 15 - REGULATORY INFORMATION
REGULATIONS
0893 114 - Wurth Zinc Spray, Light 400ml (CAS No: None):
No regulations applicable
acetone (CAS: 67-64-1) is found on the following regulatory lists;
IMO MARPOL 73/78 (Annex II) - List of Other Liquid Substances
New Zealand Hazardous Substances Transfer Notice 2004 - Schedule I, List of Substances (Dangerous Goods) to be transferred
New Zealand Poisons Schedule
New Zealand Transferred List of Single Component Substances
New Zealand Workplace Exposure Standards (WES)
OECD Representative List of High Production Volume (HPV) Chemicals
United Nations Convention Against Illicit Traffic in Narcotic Drugs and Psychotropic Substances - Table II
United Nations List of Precursors and Chemicals Frequently used in the Illicit Manufacture of Narcotic Drugs and Psychotropic Substances Under International
Control - Table II
ethyl acetate (CAS: 141-78-6) is found on the following regulatory lists;
IMO MARPOL 73/78 (Annex II) - List of Noxious Liquid Substances Carried in Bulk
International Council of Chemical Associations (ICCA) - High Production Volume List
New Zealand Hazardous Substances Transfer Notice 2004 - Schedule I, List of Substances (Dangerous Goods) to be transferred
New Zealand Transferred List of Single Component Substances
New Zealand Workplace Exposure Standards (WES)
OECD Representative List of High Production Volume (HPV) Chemicals
xylene (CAS: 1330-20-7) is found on the following regulatory lists;
IMO MARPOL 73/78 (Annex II) - List of Noxious Liquid Substances Carried in Bulk
International Agency for Research on Cancer (IARC) Carcinogens
International Council of Chemical Associations (ICCA) - High Production Volume List
New Zealand Biological Exposure Indices
New Zealand Hazardous Substances Transfer Notice 2004 - Schedule I, List of Substances (Dangerous Goods) to be transferred
New Zealand Poisons Schedule
New Zealand Transferred List of Single Component Substances
New Zealand Workplace Exposure Standards (WES)
OECD Representative List of High Production Volume (HPV) Chemicals
WHO Guidelines for Drinking-water Quality - Guideline values for chemicals that are of health significance in drinking-water
continued...
0893 114 - WURTH ZINC SPRAY, LIGHT 400ML
Chemwatch Material Safety Data Sheet
Issue Date: 20-Aug-2004 CHEMWATCH 4598-63
NA477ECP Version No:3
CD 2007/2 Page 27 of 28
Section 15 - REGULATORY INFORMATION
naphtha petroleum, heavy, hydrotreated (CAS: 64742-48-9) is found on the following regulatory lists;
International Council of Chemical Associations (ICCA) - High Production Volume List
OECD Representative List of High Production Volume (HPV) Chemicals
n-butyl acetate (CAS: 123-86-4) is found on the following regulatory lists;
IMO MARPOL 73/78 (Annex II) - List of Noxious Liquid Substances Carried in Bulk
International Council of Chemical Associations (ICCA) - High Production Volume List
New Zealand Hazardous Substances Transfer Notice 2004 - Schedule I, List of Substances (Dangerous Goods) to be transferred
New Zealand Transferred List of Single Component Substances
New Zealand Workplace Exposure Standards (WES)
OECD Representative List of High Production Volume (HPV) Chemicals
United Nations Convention Against Illicit Traffic in Narcotic Drugs and Psychotropic Substances - Table II
aluminium (CAS: 7429-90-5) is found on the following regulatory lists;
New Zealand Hazardous Substances Transfer Notice 2004 - Schedule I, List of Substances (Dangerous Goods) to be transferred
New Zealand Transferred List of Single Component Substances
New Zealand Workplace Exposure Standards (WES)
OECD Representative List of High Production Volume (HPV) Chemicals
WHO Guidelines for Drinking-water Quality - Chemicals for which guideline values have not been established
n-butanol (CAS: 71-36-3) is found on the following regulatory lists;
IMO MARPOL 73/78 (Annex II) - List of Other Liquid Substances
International Council of Chemical Associations (ICCA) - High Production Volume List
New Zealand Hazardous Substances Transfer Notice 2004 - Schedule I, List of Substances (Dangerous Goods) to be transferred
New Zealand Transferred List of Single Component Substances
New Zealand Workplace Exposure Standards (WES)
OECD Representative List of High Production Volume (HPV) Chemicals
dimethyl ether (CAS: 115-10-6) is found on the following regulatory lists;
International Council of Chemical Associations (ICCA) - High Production Volume List
New Zealand Hazardous Substances Transfer Notice 2004 - Schedule I, List of Substances (Dangerous Goods) to be transferred
New Zealand Transferred List of Single Component Substances
New Zealand Workplace Exposure Standards (WES)
OECD Representative List of High Production Volume (HPV) Chemicals
Specific advice on controls required for materials used in
New Zealand can be found at
http://www.ermanz.govt.nz/search/registers.html
Section 16 - OTHER INFORMATION
NEW ZEALAND POISONS INFORMATION CENTRE
0800 POISON (0800 764 766)
NZ EMERGENCY SERVICES: 111
REPRODUCTIVE HEALTH GUIDELINES
Ingredient ORG UF
Endpoi CR Adeq
nt TLV
xylene 1.5 mg/m3 10 D NA -
These exposure guidelines have been derived from a screening level of risk assessment and
should not be construed as unequivocally safe limits. ORGS represent an 8-hour time
-weighted average unless specified otherwise.
CR = Cancer Risk/10000; UF = Uncertainty factor:
TLV believed to be adequate to protect reproductive health:
LOD: Limit of detection
Toxic endpoints have also been identified as:
D = Developmental; R = Reproductive; TC = Transplacental carcinogen
Jankovic J., Drake F.: A Screening Method for Occupational Reproductive
American Industrial Hygiene Association Journal 57: 641-649 (1996).
EXPOSURE STANDARD FOR MIXTURES
"Worst Case" computer-aided prediction of vapour components/concentrations:
Composite Exposure Standard for Mixture (TWA) (mg/m3): 1370 mg/m鲁
If the breathing zone concentration of ANY of the components listed below is exceeded,
"Worst Case" considerations deem the individual to be overexposed.
Component Breathing Zone ppm Breathing Zone mg/m3 Mixture Conc: (%).
Component Breathing zone Breathing Zone Mixture Conc
continued...
0893 114 - WURTH ZINC SPRAY, LIGHT 400ML
Chemwatch Material Safety Data Sheet
Issue Date: 20-Aug-2004 CHEMWATCH 4598-63
NA477ECP Version No:3
CD 2007/2 Page 28 of 28
Section 16 - OTHER INFORMATION
(ppm) (mg/m鲁) (%)
naphtha petroleum, heavy, hydrotreated 300.00 1370.0000 9.0
Classification of the preparation and its individual components has drawn on official and
authoritative sources as well as independent review by the Chemwatch Classification
committee using available literature references.
This document is copyright. Apart from any fair dealing for the purposes of
private study, research, review or criticism, as permitted under the Copyright
Act, no part may be reproduced by any process without written permission from
CHEMWATCH. TEL (+61 3) 9572 4700.
Issue Date: 20-Aug-2004
Print Date: 20-Jul-2007
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