0893 140 - WURTH INDUSTRY CLEANER 500ML
Chemwatch Material Safety Data Sheet
Issue Date: 1-Feb-2005 CHEMWATCH 4922-2
NA477ECP Version No:3
CD 2007/2 Page 1 of 17
Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME
0893 140 - WURTH INDUSTRY CLEANER 500ML
STATEMENT OF HAZARDOUS NATURE
Considered a Hazardous Substance according to the criteria of the New
Zealand Hazardous Substances New Organisms legislation.
OTHER NAMES
PROPER SHIPPING NAME
AEROSOLS
PRODUCT USE
Industry cleaner.
The use of a quantity of material in an unventilated or confined space may result in
increased exposure and an irritating atmosphere developing.
Before starting consider control of exposure by mechanical ventilation.
Application is by spray atomisation from a hand held aerosol pack.
SUPPLIER
Company: Wurth New Zealand Limited
Address:
42 Hobill Avenue
Manukau City
Auckland
NZL
Telephone: 0800 683 040
Fax: 0800 100 104
Section 2 - HAZARDS IDENTIFICATION
GHS Classification
Chronic Aquatic Hazard Category 2
Flammable Aerosol Category 1
Organ Damage Category 2
Reproductive Toxicity Category 1B
Respiratory Irritation Category 3
Respiratory Sensitizer Category 1
Skin Corrosion/Irritation Category 2
Skin Sensitizer Category 1
EMERGENCY OVERVIEW
HAZARD
DANGER
Determined by Chemwatch using GHS/HSNO criteria:
2.1.2A 6.3A 6.5A 6.5B 6.8A 6.9B 9.1B
May cause respiratory irritation
Extremely flammable aerosol
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0893 140 - WURTH INDUSTRY CLEANER 500ML
Chemwatch Material Safety Data Sheet
Issue Date: 1-Feb-2005 CHEMWATCH 4922-2
NA477ECP Version No:3
CD 2007/2 Page 2 of 17
Section 2 - HAZARDS IDENTIFICATION
Causes skin irritation
May cause allergic or asthmatic symptoms or breathing difficulties if inhaled
May cause allergic skin reaction
May damage the unborn child
May cause damage to organs through prolonged or repeated exposure by inhalation.
Toxic to aquatic life with long lasting effects
PRECAUTIONARY STATEMENTS
Prevention
Avoid breathing dust/fume/gas/mist/vapours/spray.
Do not spray on an open flame or other ignition source.
Pressurized container: Do not pierce or burn, even after use.
In case of inadequate ventilation wear respiratory protection.
Do not breathe dust/fume/gas/mist/vapours/spray.
Contaminated clothing should not be allowed out of the workplace.
Wash thoroughly after handling.
Keep away from heat/sparks/open flame - No smoking.
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
Use personal protective equipment as required.
Response
If skin irritation occurs, seek medical advice/attention.
If skin irritation or rash occurs, seek medical advice/attention.
If exposed or concerned: Get medical attention advice.
IF INHALED: If breathing is difficult, remove to fresh air and keep at rest in a position
comfortable for breathing.
If experiencing respiratory symptoms call a POISON CENTER or doctor/physician.
Wash contaminated clothing before reuse.
Eliminate all ignition sources if safe to do so.
Specific treatment: refer to Label or MSDS.
Get medical advice/attention if you feel unwell.
Leaking gas fire: Do not extinguish, unless leak can be stopped safely
Wash/Decontaminate removed clothing before reuse.
IF ON SKIN: Gently wash with plenty of soap and water.
Remove/Take off immediately all contaminated clothing
Storage
Store locked up.
Protect from sunlight and do not expose to temperatures exceeding 50??C/122??F.
Disposal
Dispose of contents and container in accordance with relevant legislation.
Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS
NAME CAS RN %
naphtha petroleum, light, hydrotreated 64742-49-0. 50-90
orange, sweet, extract 8028-48-6 1-19
carbon dioxide 124-38-9 1-10
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0893 140 - WURTH INDUSTRY CLEANER 500ML
Chemwatch Material Safety Data Sheet
Issue Date: 1-Feb-2005 CHEMWATCH 4922-2
NA477ECP Version No:3
CD 2007/2 Page 3 of 17
Section 4 - FIRST AID MEASURES
NEW ZEALAND POISONS INFORMATION CENTRE 0800 POISON (0800 764 766)
NZ EMERGENCY SERVICES: 111
SWALLOWED
Not considered a normal route of entry.
路 If swallowed do NOT induce vomiting.
路 If vomiting occurs, lean patient forward or place on left side (head-down position, if
possible) to maintain open airway and prevent aspiration.
路 Observe the patient carefully.
路 Never give liquid to a person showing signs of being sleepy or with reduced awareness;
i.e. becoming unconscious.
路 Give water to rinse out mouth, then provide liquid slowly and as much as casualty can
comfortably drink.
路 Seek medical advice.
EYE
If aerosols come in contact with the eyes:
路 Immediately hold the eyelids apart and flush the eye continuously for at least 15
minutes with fresh running water.
路 Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and
moving the eyelids by occasionally lifting the upper and lower lids.
路 Transport to hospital or doctor without delay.
路 Removal of contact lenses after an eye injury should only be undertaken by skilled
personnel.
SKIN
If solids or aerosol mists are deposited upon the skin:
路 Flush skin and hair with running water (and soap if available).
路 Remove any adhering solids with industrial skin cleansing cream.
路 DO NOT use solvents.
路 Seek medical attention in the event of irritation.
INHALED
If aerosols, fumes or combustion products are inhaled:
路 Remove to fresh air.
路 Lay patient down. Keep warm and rested.
路 Prostheses such as false teeth, which may block airway, should be removed, where
possible, prior to initiating first aid procedures.
路 If breathing is shallow or has stopped, ensure clear airway and apply resuscitation,
preferably with a demand valve resuscitator, bag-valve mask device, or pocket mask as
trained. Perform CPR if necessary.
路 Transport to hospital, or doctor.
NOTES TO PHYSICIAN
Treat symptomatically.
For acute or short term repeated exposures to petroleum distillates or related
hydrocarbons:
路 Primary threat to life, from pure petroleum distillate ingestion and/or inhalation, is
respiratory failure.
路 Patients should be quickly evaluated for signs of respiratory distress (e.g. cyanosis,
tachypnoea, intercostal retraction, obtundation) and given oxygen. Patients with
inadequate tidal volumes or poor arterial blood gases (pO2 50 mm Hg) should be intubated.
路 Arrhythmias complicate some hydrocarbon ingestion and/or inhalation and
electrocardiographic evidence of myocardial injury has been reported; intravenous lines
and cardiac monitors should be established in obviously symptomatic patients. The lungs
excrete inhaled solvents, so that hyperventilation improves clearance.
路 A chest x-ray should be taken immediately after stabilisation of breathing and
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0893 140 - WURTH INDUSTRY CLEANER 500ML
Chemwatch Material Safety Data Sheet
Issue Date: 1-Feb-2005 CHEMWATCH 4922-2
NA477ECP Version No:3
CD 2007/2 Page 4 of 17
Section 4 - FIRST AID MEASURES
circulation to document aspiration and detect the presence of pneumothorax.
路 Epinephrine (adrenalin) is not recommended for treatment of bronchospasm because of
potential myocardial sensitisation to catecholamines. Inhaled cardioselective
bronchodilators (e.g. Alupent, Salbutamol) are the preferred agents, with aminophylline a
second choice.
路 Lavage is indicated in patients who require decontamination; ensure use of cuffed
endotracheal tube in adult patients. [Ellenhorn and Barceloux: Medical Toxicology].
Section 5 - FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA
SMALL FIRE:
路 Water spray, dry chemical or CO2
LARGE FIRE:
路 Water spray or fog.
FIRE FIGHTING
路 Alert Fire Brigade and tell them location and nature of hazard.
路 May be violently or explosively reactive.
路 Wear breathing apparatus plus protective gloves.
路 Prevent, by any means available, spillage from entering drains or water course.
路 If safe, switch off electrical equipment until vapour fire hazard removed.
路 Use water delivered as a fine spray to control fire and cool adjacent area.
路 DO NOT approach containers suspected to be hot.
路 Cool fire exposed containers with water spray from a protected location.
路 If safe to do so, remove containers from path of fire.
路 Equipment should be thoroughly decontaminated after use.
When any large container (including road and rail tankers) is involved in a fire,
consider evacuation by 100 metres in all directions.
FIRE/EXPLOSION HAZARD
路 Liquid and vapour are flammable.
路 Moderate fire hazard when exposed to heat or flame.
路 Vapour forms an explosive mixture with air.
路 Moderate explosion hazard when exposed to heat or flame.
路 Vapour may travel a considerable distance to source of ignition.
路 Heating may cause expansion or decomposition leading to violent rupture of containers.
路 Aerosol cans may explode on exposure to naked flame.
路 Rupturing containers may rocket and scatter burning materials.
路 Hazards may not be restricted to pressure effects.
路 May emit acrid, poisonous or corrosive fumes.
路 On combustion, may emit toxic fumes of carbon monoxide (CO).
Combustion products include:.
carbon dioxide (CO2).
other pyrolysis products typical of burning organic material.
FIRE INCOMPATIBILITY
Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine
bleaches, pool chlorine etc. as ignition may result.
Personal Protective Equipment
Breathing apparatus.
Gas tight chemical resistant suit.
Limit exposure duration to 1 BA set 30 mins.
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0893 140 - WURTH INDUSTRY CLEANER 500ML
Chemwatch Material Safety Data Sheet
Issue Date: 1-Feb-2005 CHEMWATCH 4922-2
NA477ECP Version No:3
CD 2007/2 Page 5 of 17
Section 6 - ACCIDENTAL RELEASE MEASURES
EMERGENCY PROCEDURES
MINOR SPILLS
路 Clean up all spills immediately.
路 Avoid breathing vapours and contact with skin and eyes.
路 Wear protective clothing, impervious gloves and safety glasses.
路 Shut off all possible sources of ignition and increase ventilation.
路 Wipe up.
路 If safe, damaged cans should be placed in a container outdoors, away from all ignition
sources, until pressure has dissipated.
路 Undamaged cans should be gathered and stowed safely.
MAJOR SPILLS
路 Clear area of personnel and move upwind.
路 Alert Fire Brigade and tell them location and nature of hazard.
路 May be violently or explosively reactive.
路 Wear breathing apparatus plus protective gloves.
路 Prevent, by any means available, spillage from entering drains or water courses
路 No smoking, naked lights or ignition sources.
路 Increase ventilation.
路 Stop leak if safe to do so.
路 Water spray or fog may be used to disperse / absorb vapour.
路 Absorb or cover spill with sand, earth, inert materials or vermiculite.
路 If safe, damaged cans should be placed in a container outdoors, away from ignition
sources, until pressure has dissipated.
路 Undamaged cans should be gathered and stowed safely.
路 Collect residues and seal in labelled drums for disposal.
PROTECTIVE ACTIONS FOR SPILL
PROTECTIVE ACTION ZONE
half
evacuation
downwind
direction
distance
down wind distance
wind isolation
distance
direction
half
evacuation downwind
INITIAL direction distance
ISOLATION
ZONE
From IERG (Canada/Australia)
Isolation Distance -
Downwind Protection Distance 8 metres
IERG Number 49
FOOTNOTES
1 PROTECTIVE ACTION ZONE is defined as the area in which people are at risk of harmful exposure. This zone
assumes that random changes in wind direction confines the vapour plume to an area within 30 degrees on
either side of the predominant wind direction, resulting in a crosswind protective action distance equal
to the downwind protective action distance.
2 PROTECTIVE ACTIONS should be initiated to the extent possible, beginning with those closest to the spill
and working away from the site in the downwind direction. Within the protective action zone a level of
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0893 140 - WURTH INDUSTRY CLEANER 500ML
Chemwatch Material Safety Data Sheet
Issue Date: 1-Feb-2005 CHEMWATCH 4922-2
NA477ECP Version No:3
CD 2007/2 Page 6 of 17
Section 6 - ACCIDENTAL RELEASE MEASURES
vapour concentration may exist resulting in nearly all unprotected persons becoming incapacitated and
unable to take protective action and/or incurring serious or irreversible health effects.
3 INITIAL ISOLATION ZONE is determined as an area, including upwind of the incident, within which a high
probability of localised wind reversal may expose nearly all persons without appropriate protection to
life-threatening concentrations of the material.
4 SMALL SPILLS involve a leaking package of 200 litres (55 US gallons) or less, such as a drum (jerrican or
box with inner containers). Larger packages leaking less than 200 litres and compressed gas leaking from
a small cylinder are also considered "small spills".
LARGE SPILLS involve many small leaking packages or a leaking package of greater than 200 litres, such as
a cargo tank, portable tank or a "one-tonne" compressed gas cylinder.
5 Guide 126 is taken from the US DOT emergency response guide book.
6 IERG information is derived from CANUTEC - Transport Canada.
EMERGENCY RESPONSE PLANNING GUIDELINES (ERPG)
The maximum airborne concentration below which it is believed that nearly all individuals could be exposed
for up to one hour WITHOUT experiencing or developing
life-threatening health effects is:
carbon dioxide 40000 ppm
irreversible or other serious effects or symptoms which could impair an individual's ability to take
protective action is:
carbon dioxide 30000 ppm
other than mild, transient adverse effects without perceiving a clearly defined odour is:
carbon dioxide 30000 ppm
The threshold concentration below which most people will experience no appreciable risk of health effects:
carbon dioxide 5000 ppm
American Industrial Hygiene Association (AIHA)
Ingredients considered according to the following cutoffs
Very Toxic (T+) >= 0.1% Toxic (T) >= 3.0%
R50 >= 0.25% Corrosive (C) >= 5.0%
R51 >= 2.5%
else >= 10%
where percentage is percentage of ingredient found in the mixture
Personal Protective Equipment advice is contained in Section 8 of the MSDS.
Section 7 - HANDLING AND STORAGE
PROCEDURE FOR HANDLING
路 Avoid all personal contact, including inhalation.
路 Wear protective clothing when risk of exposure occurs.
路 Use in a well-ventilated area.
路 Prevent concentration in hollows and sumps.
路 DO NOT enter confined spaces until atmosphere has been checked.
路 Avoid smoking, naked lights or ignition sources.
路 Avoid contact with incompatible materials.
路 When handling, DO NOT eat, drink or smoke.
路 DO NOT incinerate or puncture aerosol cans.
路 DO NOT spray directly on humans, exposed food or food utensils.
路 Avoid physical damage to containers.
路 Always wash hands with soap and water after handling.
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0893 140 - WURTH INDUSTRY CLEANER 500ML
Chemwatch Material Safety Data Sheet
Issue Date: 1-Feb-2005 CHEMWATCH 4922-2
NA477ECP Version No:3
CD 2007/2 Page 7 of 17
Section 7 - HANDLING AND STORAGE
路 Work clothes should be laundered separately.
路 Use good occupational work practice.
路 Observe manufacturer's storing and handling recommendations.
路 Atmosphere should be regularly checked against established exposure standards to ensure
safe working conditions are maintained.
SUITABLE CONTAINER
路 Aerosol dispenser.
路 Check that containers are clearly labelled.
STORAGE INCOMPATIBILITY
Avoid reaction with oxidising agents.
STORAGE REQUIREMENTS
Keep dry to avoid corrosion of cans. Corrosion may result in container perforation and
internal pressure may eject contents of can.
路 Store in original containers in approved flammable liquid storage area.
路 DO NOT store in pits, depressions, basements or areas where vapours may be trapped.
路 No smoking, naked lights, heat or ignition sources.
路 Keep containers securely sealed. Contents under pressure.
路 Store away from incompatible materials.
路 Store in a cool, dry, well ventilated area.
路 Avoid storage at temperatures higher than 40 deg C.
路 Store in an upright position.
路 Protect containers against physical damage.
路 Check regularly for spills and leaks.
路 Observe manufacturer's storing and handling recommendations.
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE CONTROLS
Source Material TWA ppm TWA mg/m鲁 STEL ppm STEL mg/m鲁Peak ppm Peak mg/m鲁 TWA F/CC
_________ _________ _____ _____ _____ _____ _____ _____ _____
New carbon 5, 000 9, 000 30, 000 54, 000
Zealand dioxide
Workplace (Carbon
Exposure dioxide)
Standards
(WES)
The following materials had no OELs on our records
鈥? naphtha petroleum, light, hydrotreated: CAS:64742- 49- 0
鈥? orange, sweet, extract: CAS:8028- 48- 6
EMERGENCY EXPOSURE LIMITS
Material Revised IDLH Value (mg/m3) Revised IDLH Value (ppm)
carbon dioxide 40, 000
ODOUR SAFETY FACTOR (OSF)
OSF=0.068
Exposed individuals are NOT reasonably expected to be warned, by smell, that the Exposure
Standard is being exceeded.
Odour Safety Factor (OSF) is determined to fall into either Class C, D or E.
The Odour Safety Factor (OSF) is defined as:
OSF= Exposure Standard (TWA) ppm/ Odour Threshold Value (OTV) ppm
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0893 140 - WURTH INDUSTRY CLEANER 500ML
Chemwatch Material Safety Data Sheet
Issue Date: 1-Feb-2005 CHEMWATCH 4922-2
NA477ECP Version No:3
CD 2007/2 Page 8 of 17
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
Classification into classes follows:
Class OSF Description
A 550 Over 90% of exposed individuals
are aware by smell that the
Exposure Standard (TLV- TWA for
example) is being reached, even
when distracted by working
activities
B 26- 550 As " A" for 50- 90% of persons
being distracted
C 1- 26 As " A" for less than 50% of
persons being distracted
D 0.18- 1 10- 50% of persons aware of
being tested perceive by smell
that the Exposure Standard is
being reached
E <0.18 As " D" for less than 10% of
persons aware of being tested
.
MATERIAL DATA
Not available. Refer to individual constituents.
INGREDIENT DATA
NAPHTHA PETROLEUM, LIGHT, HYDROTREATED:
ORANGE, SWEET, EXTRACT:
Sensory irritants are chemicals that produce temporary and undesirable side-effects on
the eyes, nose or throat. Historically occupational exposure standards for these
irritants have been based on observation of workers' responses to various airborne
concentrations. Present day expectations require that nearly every individual should be
protected against even minor sensory irritation and exposure standards are established
using uncertainty factors or safety factors of 5 to 10 or more. On occasion animal no
-observable-effect-levels (NOEL) are used to determine these limits where human results
are unavailable. An additional approach, typically used by the TLV committee (USA) in
determining respiratory standards for this group of chemicals, has been to assign ceiling
values (TLV C) to rapidly acting irritants and to assign short-term exposure limits (TLV
STELs) when the weight of evidence from irritation, bioaccumulation and other endpoints
combine to warrant such a limit. In contrast the MAK Commission (Germany) uses a five
-category system based on intensive odour, local irritation, and elimination half-life.
However this system is being replaced to be consistent with the European Union (EU)
Scientific Committee for Occupational Exposure Limits (SCOEL); this is more closely
allied to that of the USA.
OSHA (USA) concluded that exposure to sensory irritants can:
路 cause inflammation
路 cause increased susceptibility to other irritants and infectious agents
路 lead to permanent injury or dysfunction
路 permit greater absorption of hazardous substances and
路 acclimate the worker to the irritant warning properties of these substances thus
increasing the risk of overexposure.
NAPHTHA PETROLEUM, LIGHT, HYDROTREATED:
for petroleum distillates:
CEL TWA: 500 ppm, 2000 mg/m3 (compare OSHA TWA).
ORANGE, SWEET, EXTRACT:
CEL TWA: 100 ppm, 550 mg/m3
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0893 140 - WURTH INDUSTRY CLEANER 500ML
Chemwatch Material Safety Data Sheet
Issue Date: 1-Feb-2005 CHEMWATCH 4922-2
NA477ECP Version No:3
CD 2007/2 Page 9 of 17
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
CARBON DIOXIDE:
NOTE: Detector tubes for carbon dioxide, measuring in excess of 0.01 % vol.,
are commercially available. Long-term measurements (4 hrs) may be
conducted to detect concentrations exceeding 250 ppm.
Studies using physically fit males in confined spaces indicate the TLV-TWA
and STEL provides a wide margin of safety against asphyxiation and from
undue metabolic stress, provided normal amounts of oxygen are present in
inhaled air. Lowered oxygen content, increased physical activity and
prolonged exposures each impact on systemic and respiratory effects.
Stimulation of the respiratory centre is produced at 50,000 ppm (5%). The
gas is weakly narcotic at 30,000 ppm giving rise to reduced acuity of
hearing and increasing blood pressure and pulse, Persons exposed at
20,000 ppm for several hours developed headaches and dyspnea on mild
exertion, Acidosis and adrenal cortical exhaustion occurred as a result
of prolonged continuous exposure at 10,000-20,0000 ppm.
Intoxication occurs after a 30 minute exposure at 50,000 ppm whilst
exposure at 70,000-100,000 ppm produces unconsciousness within a few
minutes.
PERSONAL PROTECTION
EYE
No special equipment for minor exposure i.e. when handling small quantities.
OTHERWISE: For potentially moderate or heavy exposures:
路 Safety glasses with side shields.
路 NOTE: Contact lenses pose a special hazard; soft lenses may absorb irritants and ALL
lenses concentrate them.
HANDS/FEET
No special equipment needed when handling small quantities.
OTHERWISE:
For potentially moderate exposures:
Wear general protective gloves, eg. light weight rubber gloves.
For potentially heavy exposures:
Wear chemical protective gloves, eg. PVC. and safety footwear.
OTHER
No special equipment needed when handling small quantities.
OTHERWISE:
路 Overalls.
路 Skin cleansing cream.
路 Eyewash unit.
路 Do not spray on hot surfaces.
RESPIRATOR
Respiratory protection may be required when ANY "Worst Case" vapour-phase concentration
is exceeded (see Computer Prediction in "Exposure Standards").
Protection Factor Half- Face Respirator Full- Face Respirator
10 x ES A- AUS -
A- PAPR- AUS
50 x ES Air- line* -
100 x ES - A- 3
100+ x ES - Air- line**
* - Continuous-flow; ** - Continuous-flow or positive pressure demand
^ - Full-face.
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0893 140 - WURTH INDUSTRY CLEANER 500ML
Chemwatch Material Safety Data Sheet
Issue Date: 1-Feb-2005 CHEMWATCH 4922-2
NA477ECP Version No:3
CD 2007/2 Page 10 of 17
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
The local concentration of material, quantity and conditions of use determine the type of
personal protective equipment required.
For further information consult site specific
CHEMWATCH data (if available), or your
Occupational Health and Safety Advisor.
ENGINEERING CONTROLS
General exhaust is adequate under normal conditions. If risk of overexposure exists, wear
SAA approved respirator. Correct fit is essential to obtain adequate protection.
Provide adequate ventilation in warehouse or closed storage areas.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE
highly flammable liquid with a naptha and orange odour; does not mix with water.
Supplied in aerosol pack containing carbon dioxide propellant.
PHYSICAL PROPERTIES
Liquid.
Gas.
Does not mix with water.
Floats on water.
Molecular Weight: Not Applicable Boiling Range (掳 Not Av ailable
C):
Melting Range (掳 Not Available
C): Specific Gravity (water= 1): 0.74
Solubility in water (g/L): Immiscible pH (as supplied): Not Applicable
pH (1% solution): Not Applicable Vapour Pressure (kPa): Not Available
Volatile Component (%vol): Not Available Evaporation Rate: Not Available
Relative Vapour Density (air=1): Not Available Flash Point (掳 <10 eff. substance
C):
Lower Explosive Limit (%): Not Available Upper Explosive Limit (%): Not Available
Autoignition Temp (掳 Not Available
C): Decomposition Temp ( 掳 Not Available
C):
State: Liquid Viscosity: Not Available
log Kow (Sangster 1997): 0.83
Section 10 - CHEMICAL STABILITY AND REACTIVITY INFORMATION
CONDITIONS CONTRIBUTING TO INSTABILITY
路 Elevated temperatures.
路 Presence of open flame.
路 Product is considered stable.
路 Hazardous polymerisation will not occur.
Odour Safety Factor(OSF)
OSF=0.068
Section 11 - TOXICOLOGICAL INFORMATION
POTENTIAL HEALTH EFFECTS
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0893 140 - WURTH INDUSTRY CLEANER 500ML
Chemwatch Material Safety Data Sheet
Issue Date: 1-Feb-2005 CHEMWATCH 4922-2
NA477ECP Version No:3
CD 2007/2 Page 11 of 17
Section 11 - TOXICOLOGICAL INFORMATION
ACUTE HEALTH EFFECTS
SWALLOWED
Although ingestion is not thought to produce harmful effects (as classified under EC
Directives), the material may still be damaging to the health of the individual,
following ingestion, especially where pre-existing organ (e.g liver, kidney) damage is
evident. Present definitions of harmful or toxic substances are generally based on doses
producing mortality rather than those producing morbidity (disease, ill-health).
Gastrointestinal tract discomfort may produce nausea and vomiting. In an occupational
setting however, ingestion of insignificant quantities is not thought to be cause for
concern.
Not normally a hazard due to physical form of product.
Considered an unlikely route of entry in commercial/industrial environments.
Swallowing of the liquid may cause aspiration into the lungs with the risk of chemical
pneumonitis; serious consequences may result.
(ICSC13733).
EYE
Although the material is not thought to be an irritant (as classified by EC Directives),
direct contact with the eye may produce transient discomfort characterised by tearing or
conjunctival redness (as with windburn).
Petroleum hydrocarbons may produce pain after direct contact with the eyes. Slight, but
transient disturbances of the corneal epithelium may also result. The aromatic fraction
may produce irritation and lachrymation.
SKIN
Evidence exists, or practical experience predicts, that the material either produces
inflammation of the skin in a substantial number of individuals following direct contact,
and/or produces significant inflammation when applied to the healthy intact skin of
animals, for up to four hours, such inflammation being present twenty-four hours or more
after the end of the exposure period. Skin irritation may also be present after prolonged
or repeated exposure; this may result in a form of contact dermatitis (nonallergic). The
dermatitis is often characterised by skin redness (erythema) and swelling (oedema) which
may progress to blistering (vesiculation), scaling and thickening of the epidermis. At
the microscopic level there may be intercellular oedema of the spongy layer of the skin
(spongiosis) and intracellular oedema of the epidermis.
Skin contact is not thought to have harmful health effects (as classified under EC
Directives); the material may still produce health damage following entry through wounds,
lesions or abrasions.
Spray mist may produce discomfort.
Toxic effects may result from skin absorption.
The material may cause skin irritation after prolonged or repeated exposure and may
produce a contact dermatitis (nonallergic). This form of dermatitis is often
characterised by skin redness (erythema) and swelling epidermis. Histologically there may
be intercellular oedema of the spongy layer (spongiosis) and intracellular oedema of the
epidermis.
INHALED
The material is not thought to produce adverse health effects or irritation of the
respiratory tract (as classified by EC Directives using animal models). Nevertheless,
good hygiene practice requires that exposure be kept to a minimum and that suitable
control measures be used in an occupational setting.
Not normally a hazard due to non-volatile nature of product.
Acute effects from inhalation of high vapour concentrations may be chest and nasal
irritation with coughing, sneezing, headache and even nausea.
WARNING:Intentional misuse by concentrating/inhaling contents may be lethal.
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0893 140 - WURTH INDUSTRY CLEANER 500ML
Chemwatch Material Safety Data Sheet
Issue Date: 1-Feb-2005 CHEMWATCH 4922-2
NA477ECP Version No:3
CD 2007/2 Page 12 of 17
Section 11 - TOXICOLOGICAL INFORMATION
CHRONIC HEALTH EFFECTS
Practical experience shows that skin contact with the material is capable either of
inducing a sensitisation reaction in a substantial number of individuals, and/or of
producing a positive response in experimental animals.
Exposure to the material may cause concerns for human fertility, generally on the basis
that results in animal studies provide sufficient evidence to cause a strong suspicion of
impaired fertility in the absence of toxic effects, or evidence of impaired fertility
occurring at around the same dose levels as other toxic effects, but which are not a
secondary non-specific consequence of other toxic effects.
Principal routes of exposure are by accidental skin and eye contact and by inhalation of
vapours especially at higher temperatures.
Prolonged or continuous skin contact with the liquid may cause defatting with drying,
cracking, irritation and dermatitis following.
Chronic solvent inhalation exposures may result in nervous system impairment
and liver and blood changes. [PATTYS].
WARNING: Aerosol containers may present pressure related hazards.
TOXICITY AND IRRITATION
Not available. Refer to individual constituents.
NAPHTHA PETROLEUM, LIGHT, HYDROTREATED:
No significant acute toxicological data identified in literature search.
ORANGE, SWEET, EXTRACT:
unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances.
TOXICITY IRRITATION
Skin (rabbit): 500mg/24h Moderate
Contact allergies quickly manifest themselves as contact eczema, more rarely as urticaria
or Quincke's oedema. The pathogenesis of contact eczema involves a cell-mediated (T
lymphocytes) immune reaction of the delayed type. Other allergic skin reactions, e.g.
contact urticaria, involve antibody-mediated immune reactions. The significance of the
contact allergen is not simply determined by its sensitisation potential: the
distribution of the substance and the opportunities for contact with it are equally
important. A weakly sensitising substance which is widely distributed can be a more
important allergen than one with stronger sensitising potential with which few
individuals come into contact. From a clinical point of view, substances are noteworthy
if they produce an allergic test reaction in more than 1% of the persons tested.
for cold-pressed oil
CARBON DIOXIDE:
unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances.
TOXICITY IRRITATION
Inhalation (rat) LCLo: 657190 ppm/15 m
Inhalation (human) TCLo: 2000 ppm
Inhalation (human) LCLo: 9 pph/5 m (9%)
- pulmonary effects
IDLH: 50,000 ppm
Section 12 - ECOLOGICAL INFORMATION
Marine Pollutant:Not Determined
Refer to data for ingredients, which follows:
NAPHTHA PETROLEUM, LIGHT, HYDROTREATED:
The lower molecular weight hydrocarbons are expected to form a "slick" on the surface of
waters after release in calm sea conditions. This is expected to evaporate and enter the
atmosphere where it will be degraded through reaction with hydroxy radicals.
continued...
0893 140 - WURTH INDUSTRY CLEANER 500ML
Chemwatch Material Safety Data Sheet
Issue Date: 1-Feb-2005 CHEMWATCH 4922-2
NA477ECP Version No:3
CD 2007/2 Page 13 of 17
Section 12 - ECOLOGICAL INFORMATION
Some of the material will become associated with benthic sediments, and it is likely to
be spread over a fairly wide area of sea floor. Marine sediments may be either aerobic or
anaerobic. The material, in probability, is biodegradable, under aerobic conditions
(isomerised olefins and alkenes show variable results). Evidence also suggests that the
hydrocarbons may be degradable under anaerobic conditions although such degradation in
benthic sediments may be a relatively slow process.
Under aerobic conditions the material will degrade to water and carbon dioxide, while
under anaerobic processes it will produce water, methane and carbon dioxide.
Based on test results, as well as theoretical considerations, the potential for
bioaccumulation may be high. Toxic effects are often observed in species such as blue
mussel, daphnia, freshwater green algae, marine copepods and amphipods.
Drinking Water Standards:
hydrocarbon total: 10 ug/l (UK max.).
Do NOT allow product to come in contact with surface waters or to intertidal areas below
the mean high water mark. Do not contaminate water when cleaning equipment or disposing
of equipment wash-waters.
Wastes resulting from use of the product must be disposed of on site or at approved waste
sites.
DO NOT discharge into sewer or waterways.
ORANGE, SWEET, EXTRACT:
Do NOT allow product to come in contact with surface waters or to intertidal areas below
the mean high water mark. Do not contaminate water when cleaning equipment or disposing
of equipment wash-waters.
Wastes resulting from use of the product must be disposed of on site or at approved waste
sites.
Substances containing unsaturated carbons are ubiquitous in indoor environments. They
result from many sources (see below). Most are reactive with environmental ozone and many
produce stable products which are thought to adversely affect human health.The potential
for surfaces in an enclosed space to facilitate reactions should be considered.
Source of unsaturated Unsaturated substances Major Stable Products produced
substances (Reactive Emissions) following reaction with ozone.
Occupants (exhaled breath, ski Isoprene, nitric oxide, Methacrolein, methyl vinyl
oils, personal care products) squalene, unsaturated sterols, ketone, nitrogen dioxide,
oleic acid and other acetone, 6MHQ, geranyl acetone,
unsaturated fatty acids, 4OPA, formaldehyde, nonanol,
unsaturated oxidation products decanal, 9- oxo- nonanoic acid,
azelaic acid, nonanoic acid.
Soft woods, wood flooring, Isoprene, limonene, alpha- Formaldehyde, 4- AMC,
including cypress, cedar and pinene, other terpenes and pinoaldehyde, pinic acid,
silver fir boards, houseplants sesquiterpenes pinonic acid, formic acid,
methacrolein, methyl vinyl
ketone, SOAs including
ultrafine particles
Carpets and carpet backing 4- Phenylcyclohexene, 4- Formaldehyde, acetaldehyde,
vinylcyclohexene, styrene, 2- benzaldehyde, hexanal, nonanal,
ethylhexyl acrylate, 2 - nonenal
unsaturated fatty acids and
esters
Linoleum and paints/polishes Linoleic acid, linolenic acid Propanal, hexanal, nonanal, 2-
containing linseed oil heptenal, 2- nonenal, 2-
decenal, 1- pentene- 3 - one,
propionic acid, n- butyric acid
Latex paint Residual monomers Formaldehyde
Certain cleaning products, Limonene, alpha- pinene, Formaldehyde, acetaldehyde,
polishes, waxes, air fresheners terpinolene, alpha- terpineol, glycoaldehyde, formic acid,
continued...
0893 140 - WURTH INDUSTRY CLEANER 500ML
Chemwatch Material Safety Data Sheet
Issue Date: 1-Feb-2005 CHEMWATCH 4922-2
NA477ECP Version No:3
CD 2007/2 Page 14 of 17
Section 12 - ECOLOGICAL INFORMATION
linalool, linalyl acetate and acetic acid, hydrogen and
other terpinoids, longifolene organic peroxides, acetone,
and other sesquiterpenes benzaldehyde, 4- hydroxy- 4-
methyl- 5- hexen- 1- al, 5 -
ethenyl- dihydro- 5- methyl-
2(3H)- furanone, 4- AMC, SOAs
including ultrafine particles
Natural rubber adhesive Isoprene, terpenes Formaldehyde, methacrolein,
methyl vinyl ketone
Photocopier toner, printed Styrene Formaldehyde, benzaldehyde
paper, styrene polymers
Environmental tobacco smoke Styrene, acrolein, nicotine Formaldehyde, benzaldehyde,
hexanal, glyoxal, N-
methylformamide,
nicotinaldehyde, cotinine
Soiled clothing, fabrics, Squalene, unsaturated sterols, Acetone, geranyl acetone, 6MHO,
bedding oleic acid and other saturated 40PA, formaldehyde, nonanal,
fatty acids decanal, 9 - oxo- nonanoic
acid, azelaic acid, nonanoic
acid
Soiled particle filters Unsaturated fatty acids from Formaldehyde, nonanal, and
plant waxes, leaf litter, and other aldehydes; azelaic acid;
other vegetative debris; soot; nonanoic acid; 9- oxo- nonanoic
diesel particles acid and other oxo- acids;
compounds with mixed functional
groups (=O, - OH, and - COOH)
Ventilation ducts and duct Unsaturated fatty acids and C5 to C10 aldehydes
liners esters, unsaturated oils,
neoprene
" Urban grime" Polycyclic aromatic Oxidized polycyclic aromatic
hydrocarbons hydrocarbons
Perfumes, colognes, essential Limonene, alpha- pinene, Formaldehyde, 4- AMC, acetone,
oils (e.g. lavender, linalool, linalyl acetate, 4- hydroxy- 4- methyl- 5-
eucalyptus, tea tree) terpinene- 4- ol, gamma - hexen- 1- al, 5- ethenyl -
terpinene dihydro- 5- methyl- 2(3H)
furanone, SOAs including
ultrafine particles
Overall home emissions Limonene, alpha- pinene, Formaldehyde, 4- AMC,
styrene pinonaldehyde, acetone, pinic
acid, pinonic acid, formic
acid, benzaldehyde, SOAs
including ultrafine particles
Abbreviations: 4-AMC, 4-acetyl-1-methylcyclohexene; 6MHQ, 6-methyl-5-heptene-2-one, 4OPA,
4-oxopentanal, SOA, Secondary Organic Aerosols
Reference: Charles J Weschler; Environmental Helath Perspectives, Vol 114, October 2006.
The lower molecular weight hydrocarbons are expected to form a "slick" on the surface of
waters after release in calm sea conditions. This is expected to evaporate and enter the
atmosphere where it will be degraded through reaction with hydroxy radicals.
Some of the material will become associated with benthic sediments, and it is likely to
be spread over a fairly wide area of sea floor. Marine sediments may be either aerobic or
anaerobic. The material, in probability, is biodegradable, under aerobic conditions
(isomerised olefins and alkenes show variable results). Evidence also suggests that the
hydrocarbons may be degradable under anaerobic conditions although such degradation in
benthic sediments may be a relatively slow process.
Under aerobic conditions the material will degrade to water and carbon dioxide, while
under anaerobic processes it will produce water, methane and carbon dioxide.
continued...
0893 140 - WURTH INDUSTRY CLEANER 500ML
Chemwatch Material Safety Data Sheet
Issue Date: 1-Feb-2005 CHEMWATCH 4922-2
NA477ECP Version No:3
CD 2007/2 Page 15 of 17
Section 12 - ECOLOGICAL INFORMATION
Based on test results, as well as theoretical considerations, the potential for
bioaccumulation may be high. Toxic effects are often observed in species such as blue
mussel, daphnia, freshwater green algae, marine copepods and amphipods.
Drinking Water Standards:
hydrocarbon total: 10 ug/l (UK max.).
DO NOT discharge into sewer or waterways.
CARBON DIOXIDE:
log Kow (Sangster 1997): 0.83
Section 13 - DISPOSAL CONSIDERATIONS
路 Consult State Land Waste Management Authority for disposal.
路 Discharge contents of damaged aerosol cans at an approved site.
路 Allow small quantities to evaporate.
路 DO NOT incinerate or puncture aerosol cans.
路 Bury residues and emptied aerosol cans at an approved site.
Section 14 - TRANSPORTATION INFORMATION
Labels Required: FLAMMABLE GAS
HAZCHEM: 2Y
UNDG:
Dangerous Goods Class: 2.1 Subrisk: None
UN Number: 1950 Packing Group: None
Shipping Name:AEROSOLS
Air Transport IATA:
ICAO/IATA Class: 2.1 ICAO/IATA Subrisk: None
UN/ID Number: 1950 Packing Group: None
ERG Code: 10L
Shipping name:AEROSOLS
Maritime Transport IMDG:
IMDG Class: 2.1 IMDG Subrisk: SP63
UN Number: 1950 Packing Group: None
EMS Number: F- D, S- U Marine Pollutant: Not Determined
Shipping name:AEROSOLS
Section 15 - REGULATORY INFORMATION
REGULATIONS
0893 140 - Wurth Industry Cleaner 500ml (CAS No: None):
No regulations applicable
continued...
0893 140 - WURTH INDUSTRY CLEANER 500ML
Chemwatch Material Safety Data Sheet
Issue Date: 1-Feb-2005 CHEMWATCH 4922-2
NA477ECP Version No:3
CD 2007/2 Page 16 of 17
Section 15 - REGULATORY INFORMATION
naphtha petroleum, light, hydrotreated (CAS: 64742-49-0) is found on the following regulatory lists;
International Council of Chemical Associations (ICCA) - High Production Volume List
New Zealand Transferred List of Single Component Substances
OECD Representative List of High Production Volume (HPV) Chemicals
orange, sweet, extract (CAS: 8028-48-6) is found on the following regulatory lists;
OECD Representative List of High Production Volume (HPV) Chemicals
carbon dioxide (CAS: 124-38-9) is found on the following regulatory lists;
CODEX General Standard for Food Additives (GSFA) - Additives Permitted for Use in Food in General, Unless Otherwise Specified, in Accordance with GMP
New Zealand Hazardous Substances Transfer Notice 2004 - Schedule I, List of Substances (Dangerous Goods) to be transferred
New Zealand Workplace Exposure Standards (WES)
OECD Representative List of High Production Volume (HPV) Chemicals
Specific advice on controls required for materials used in
New Zealand can be found at
http://www.ermanz.govt.nz/search/registers.html
Section 16 - OTHER INFORMATION
NEW ZEALAND POISONS INFORMATION CENTRE
0800 POISON (0800 764 766)
NZ EMERGENCY SERVICES: 111
REPRODUCTIVE HEALTH GUIDELINES
Established occupational exposure limits frequently do not take into consideration
reproductive end points that are clearly below the thresholds for other toxic effects.
Occupational reproductive guidelines (ORGs) have been suggested as an additional
standard. These have been established after a literature search for reproductive no
-observed-adverse effect-level (NOAEL) and the lowest-observed-adverse-effect-level
(LOAEL). In addition the US EPA's procedures for risk assessment for hazard
identification and dose-response assessment as applied by NIOSH were used in the creation
of such limits. Uncertainty factors (UFs) have also been incorporated.
Ingredient ORG UF Endpoi CR Adeq
nt TLV
carbon dioxide 1800 mg/m3 10 D/R NA -
These exposure guidelines have been derived from a screening level of risk assessment and
should not be construed as unequivocally safe limits. ORGS represent an 8-hour time
-weighted average unless specified otherwise.
CR = Cancer Risk/10000; UF = Uncertainty factor:
TLV believed to be adequate to protect reproductive health:
LOD: Limit of detection
Toxic endpoints have also been identified as:
D = Developmental; R = Reproductive; TC = Transplacental carcinogen
Jankovic J., Drake F.: A Screening Method for Occupational Reproductive
American Industrial Hygiene Association Journal 57: 641-649 (1996).
EXPOSURE STANDARD FOR MIXTURES
"Worst Case" computer-aided prediction of vapour components/concentrations:
Composite Exposure Standard for Mixture (TWA) (mg/m3): 550 mg/m鲁
If the breathing zone concentration of ANY of the components listed below is exceeded,
"Worst Case" considerations deem the individual to be overexposed.
Component Breathing Zone ppm Breathing Zone mg/m3 Mixture Conc: (%).
Component Breathing zone Breathing Zone Mixture Conc
(ppm) (mg/m鲁) (%)
orange, sweet, extract 100.00 550.0000 19.0
Classification of the preparation and its individual components has drawn on official and
authoritative sources as well as independent review by the Chemwatch Classification
continued...
0893 140 - WURTH INDUSTRY CLEANER 500ML
Chemwatch Material Safety Data Sheet
Issue Date: 1-Feb-2005 CHEMWATCH 4922-2
NA477ECP Version No:3
CD 2007/2 Page 17 of 17
Section 16 - OTHER INFORMATION
committee using available literature references.
This document is copyright. Apart from any fair dealing for the purposes of
private study, research, review or criticism, as permitted under the Copyright
Act, no part may be reproduced by any process without written permission from
CHEMWATCH. TEL (+61 3) 9572 4700.
Issue Date: 1-Feb-2005
Print Date: 20-Jul-2007
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