0893 280 1 - WURTH DYE F. PLASTIK BLACK 75ML
Chemwatch Material Safety Data Sheet
Issue Date: 14-Oct-2003 CHEMWATCH 4599-5
NA477ECP Version No:3
CD 2007/2 Page 1 of 12
Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME
0893 280 1 - WURTH DYE F. PLASTIK BLACK 75ML
STATEMENT OF HAZARDOUS NATURE
Considered a Hazardous Substance according to the criteria of the New
Zealand Hazardous Substances New Organisms legislation.
OTHER NAMES
PRODUCT USE
Dye for recolouring plastic bumper bars.
SUPPLIER
Company: Wurth New Zealand Limited
Address:
42 Hobill Avenue
Manukau City
Auckland
NZL
Telephone: 0800 683 040
Fax: 0800 100 104
Section 2 - HAZARDS IDENTIFICATION
GHS Classification
Reproductive Toxicity Category 1B
EMERGENCY OVERVIEW
HAZARD
DANGER
Determined by Chemwatch using GHS/HSNO criteria:
6.8A 6.8A
May damage fertility
May damage the unborn child
PRECAUTIONARY STATEMENTS
Prevention
Do not handle until all safety precautions have been read and understood.
Use personal protective equipment as required.
Obtain special instructions before use.
Response
If exposed or concerned: Get medical attention advice.
Storage
Store locked up.
continued...
0893 280 1 - WURTH DYE F. PLASTIK BLACK 75ML
Chemwatch Material Safety Data Sheet
Issue Date: 14-Oct-2003 CHEMWATCH 4599-5
NA477ECP Version No:3
CD 2007/2 Page 2 of 12
Section 2 - HAZARDS IDENTIFICATION
Disposal
Dispose of contents and container in accordance with relevant legislation.
Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS
NAME CAS RN %
cristobalite 14464-46-1 1-5
isopropanol 67-63-0 1-5
ethylene glycol 107-21-1 1-5
diuron 330-54-1 0.1-<0.25
Section 4 - FIRST AID MEASURES
NEW ZEALAND POISONS INFORMATION CENTRE 0800 POISON (0800 764 766)
NZ EMERGENCY SERVICES: 111
SWALLOWED
路 If swallowed do NOT induce vomiting.
路 If vomiting occurs, lean patient forward or place on left side (head-down position, if
possible) to maintain open airway and prevent aspiration.
路 Observe the patient carefully.
路 Never give liquid to a person showing signs of being sleepy or with reduced awareness;
i.e. becoming unconscious.
路 Give water to rinse out mouth, then provide liquid slowly and as much as casualty can
comfortably drink.
路 Seek medical advice.
EYE
If this product comes in contact with the eyes:
路 Wash out immediately with fresh running water.
路 Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and
moving the eyelids by occasionally lifting the upper and lower lids.
路 If pain persists or recurs seek medical attention.
路 Removal of contact lenses after an eye injury should only be undertaken by skilled
personnel.
SKIN
If skin contact occurs:
路 Immediately remove all contaminated clothing, including footwear.
路 Flush skin and hair with running water (and soap if available).
路 Seek medical attention in event of irritation.
INHALED
路 If fumes or combustion products are inhaled remove from contaminated area.
路 Other measures are usually unnecessary.
NOTES TO PHYSICIAN
Treat symptomatically.
Section 5 - FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA
路 There is no restriction on the type of extinguisher which may be used.
路 Use extinguishing media suitable for surrounding area.
continued...
0893 280 1 - WURTH DYE F. PLASTIK BLACK 75ML
Chemwatch Material Safety Data Sheet
Issue Date: 14-Oct-2003 CHEMWATCH 4599-5
NA477ECP Version No:3
CD 2007/2 Page 3 of 12
Section 5 - FIRE FIGHTING MEASURES
FIRE FIGHTING
路 Alert Fire Brigade and tell them location and nature of hazard.
路 Wear breathing apparatus plus protective gloves for fire only.
路 Prevent, by any means available, spillage from entering drains or water courses.
路 Use fire fighting procedures suitable for surrounding area.
路 DO NOT approach containers suspected to be hot.
路 Cool fire exposed containers with water spray from a protected location.
路 If safe to do so, remove containers from path of fire.
路 Equipment should be thoroughly decontaminated after use.
FIRE/EXPLOSION HAZARD
路 The material is not readily combustible under normal conditions.
路 However, it will break down under fire conditions and the organic component may burn.
路 Not considered to be a significant fire risk.
路 Heat may cause expansion or decomposition with violent rupture of containers.
路 Decomposes on heating and may produce toxic fumes of carbon monoxide (CO).
路 May emit acrid smoke.
Other decomposition products include:.
carbon dioxide (CO2).
FIRE INCOMPATIBILITY
None known.
Section 6 - ACCIDENTAL RELEASE MEASURES
EMERGENCY PROCEDURES
MINOR SPILLS
路 Clean up all spills immediately.
路 Avoid breathing vapours and contact with skin and eyes.
路 Control personal contact by using protective equipment.
路 Contain and absorb spill with sand, earth, inert material or vermiculite.
路 Wipe up.
路 Place in a suitable labelled container for waste disposal.
MAJOR SPILLS
Moderate hazard.
路 Clear area of personnel and move upwind.
路 Alert Fire Brigade and tell them location and nature of hazard.
路 Wear breathing apparatus plus protective gloves.
路 Prevent, by any means available, spillage from entering drains or water course.
路 Stop leak if safe to do so.
路 Contain spill with sand, earth or vermiculite.
路 Collect recoverable product into labelled containers for recycling.
路 Neutralise/decontaminate residue.
路 Collect solid residues and seal in labelled drums for disposal.
路 Wash area and prevent runoff into drains.
路 After clean up operations, decontaminate and launder all protective clothing and
equipment before storing and re-using.
路 If contamination of drains or waterways occurs, advise emergency services.
Personal Protective Equipment advice is contained in Section 8 of the MSDS.
continued...
0893 280 1 - WURTH DYE F. PLASTIK BLACK 75ML
Chemwatch Material Safety Data Sheet
Issue Date: 14-Oct-2003 CHEMWATCH 4599-5
NA477ECP Version No:3
CD 2007/2 Page 4 of 12
Section 7 - HANDLING AND STORAGE
PROCEDURE FOR HANDLING
路 Limit all unnecessary personal contact.
路 Wear protective clothing when risk of exposure occurs.
路 Use in a well-ventilated area.
路 Avoid contact with incompatible materials.
路 When handling, DO NOT eat, drink or smoke.
路 Keep containers securely sealed when not in use.
路 Avoid physical damage to containers.
路 Always wash hands with soap and water after handling.
路 Work clothes should be laundered separately.
路 Use good occupational work practice.
路 Observe manufacturer's storing and handling recommendations.
路 Atmosphere should be regularly checked against established exposure standards to ensure
safe working conditions are maintained.
SUITABLE CONTAINER
路 Polyethylene or polypropylene container.
路 Packing as recommended by manufacturer.
路 Check all containers are clearly labelled and free from leaks.
STORAGE INCOMPATIBILITY
None known.
STORAGE REQUIREMENTS
路 Store in original containers.
路 Keep containers securely sealed.
路 Store in a cool, dry, well-ventilated area.
路 Store away from incompatible materials and foodstuff containers.
路 Protect containers against physical damage and check regularly for leaks.
路 Observe manufacturer's storing and handling recommendations.
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE CONTROLS
Source Material TWA ppm TWA mg/m鲁 STEL ppm STEL mg/m鲁Peak ppm Peak mg/m鲁 TWA F/CC
_________ _________ _____ _____ _____ _____ _____ _____ _____
New cristobali 0.1
Zealand te
Workplace (Cristobal
Exposure ite)
Standards
(WES)
New isopropano 400 983 500 1, 230
Zealand l
Workplace (Isopropyl
Exposure alcohol)
Standards
(WES)
New ethylene 50 127
Zealand glycol
Workplace (Ethylene
Exposure glycol
Standards vapour &
(WES) mist)
continued...
0893 280 1 - WURTH DYE F. PLASTIK BLACK 75ML
Chemwatch Material Safety Data Sheet
Issue Date: 14-Oct-2003 CHEMWATCH 4599-5
NA477ECP Version No:3
CD 2007/2 Page 5 of 12
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
Source Material TWA ppm TWA mg/m鲁 STEL ppm STEL mg/m鲁Peak ppm Peak mg/m鲁 TWA F/CC
_________ _________ _____ _____ _____ _____ _____ _____ _____
New diuron 10
Zealand (Diuron)
Workplace
Exposure
Standards
(WES)
EMERGENCY EXPOSURE LIMITS
Material Revised IDLH Value (mg/m3) Revised IDLH Value (ppm)
cristobalite 25
isopropanol 2, 000 [LEL]
NOTES
Values marked LEL indicate that the IDLH was based on 10% of the lower explosive limit
for safety considerations even though the relevant toxicological data indicated that
irreversible health effects or impairment of escape existed only at higher
concentrations.
MATERIAL DATA
Not available. Refer to individual constituents.
INGREDIENT DATA
CRISTOBALITE:
The concentration of respirable dust for application of this limit is to be determined
from the fraction that penetrates a separator whose size collection efficiency is
described by a cumulative lognormal function with a median aerodynamic diameter of 4.0 碌m
(+-) 0.3 碌m and with a geometric standard deviation of 1.5 碌m (+-) 0.1 碌m, i.e..generally
less than 5 碌m.
Cristobalite produces a more severe response, than does quartz, on lung
function and disease. The fibrosis produced by cristobalite is diffuse
rather than nodular. The TLV-TWA is thought to be protective against
pulmonary fibrosis associated with exposure at higher levels. NIOSH has
designated cristobalite as a potential occupational carcinogen.
ISOPROPANOL:
Odour Threshold Value: 3.3 ppm (detection), 7.6 ppm (recognition)
Exposure at or below the recommended TLV-TWA and STEL is thought to
minimise the potential for inducing narcotic effects or significant
irritation of the eyes or upper respiratory tract. It is believed, in the
absence of hard evidence, that this limit also provides protection against
the development of chronic health effects. The limit is intermediate to
that set for ethanol, which is less toxic, and n-propyl alcohol, which is
more toxic, than isopropanol.
ETHYLENE GLYCOL:
Odour Threshold: 25 ppm
NOTE: Detector tubes for ethylene glycol, measuring in excess of 10 mg/m3,
are commercially available.
It appears impractical to establish separate TLVs for ethylene glycol
vapour and mists. Atmospheric concentration that do not cause discomfort
are unlikely to cause adverse effects. The TLV-C is thought to be
protective against throat and respiratory irritation and headache reported
in exposed humans. NIOSH has not established a limit for this substance
due to the potential teratogenicity associated with exposure and because
continued...
0893 280 1 - WURTH DYE F. PLASTIK BLACK 75ML
Chemwatch Material Safety Data Sheet
Issue Date: 14-Oct-2003 CHEMWATCH 4599-5
NA477ECP Version No:3
CD 2007/2 Page 6 of 12
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
respiratory irritation reported at the TLV justified a lower value.
DIURON:
Exposures at or below the recommended TLV-TWA is thought to ptotect the
worker from the significant risk of anaemia and methaemoglobinaemia
associated with use of the product.
PERSONAL PROTECTION
EYE
路 Safety glasses with side shields; or as required,
路 Chemical goggles.
路 Contact lenses may pose a special hazard; soft contact lenses may absorb and
concentrate irritants. A written policy document, describing the wearing of lens or
restrictions on use, should be created for each workplace or task. This should include a
review of lens absorption and adsorption for the class of chemicals in use and an account
of injury experience. Medical and first-aid personnel should be trained in their removal
and suitable equipment should be readily available. In the event of chemical exposure,
begin eye irrigation immediately and remove contact lens as soon as practicable. Lens
should be removed at the first signs of eye redness or irritation - lens should be
removed in a clean environment only after workers have washed hands thoroughly. [CDC
NIOSH Current Intelligence Bulletin 59].
HANDS/FEET
Wear protective gloves, eg. PVC.
OTHER
路 Overalls.
路 Eyewash unit.
RESPIRATOR
Selection of the Class and Type of respirator will depend upon the level of breathing
zone contaminant and the chemical nature of the contaminant. Protection Factors (defined
as the ratio of contaminant outside and inside the mask) may also be important.
Breathing Zone Level Maximum Protection Half- face Respirator Full- Face Respirator
ppm (volume) Factor
1000 10 A- AUS P -
1000 50 - A- AUS P
5000 50 Airline * -
5000 100 - A- 2 P
10000 100 - A- 3 P
100+ Airline**
* - Continuous Flow ** - Continuous-flow or positive pressure demand.
The local concentration of material, quantity and conditions of use determine the type of
personal protective equipment required.
For further information consult site specific
CHEMWATCH data (if available), or your
Occupational Health and Safety Advisor.
ENGINEERING CONTROLS
General exhaust is adequate under normal operating conditions. If risk of overexposure
exists, wear SAA approved respirator. Correct fit is essential to obtain adequate
protection. Provide adequate ventilation in warehouse or closed storage areas.
continued...
0893 280 1 - WURTH DYE F. PLASTIK BLACK 75ML
Chemwatch Material Safety Data Sheet
Issue Date: 14-Oct-2003 CHEMWATCH 4599-5
NA477ECP Version No:3
CD 2007/2 Page 7 of 12
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE
Black liquid with a characteristic odour; mixes with water.
Viscosity: 90 sec / 4m.
PHYSICAL PROPERTIES
Liquid.
Mixes with water.
Molecular Weight: Not Applicable Boiling Range (掳 >107
C):
Melting Range (掳 Not Available
C): Specific Gravity (water= 1): 1.2- 1.4
Solubility in water (g/L): Miscible pH (as supplied): 8.5
pH (1% solution): Not Available Vapour Pressure (kPa): Not Available
Volatile Component (%vol): Not Available Evaporation Rate: Not Available
Relative Vapour Density (air=1): Not Available Flash Point (掳 Not Available
C):
Lower Explosive Limit (%): Not Available Upper Explosive Limit (%): Not Available
Autoignition Temp (掳 Not Available
C): Decomposition Temp ( 掳 Not Available
C):
State: Liquid Viscosity: Not Available
log Kow (Sangster 1997): 0.05
log Kow: -0.16- 0.28
log Kow (Prager 1995): - 1.36
log Kow (Sangster 1997): - 1.36
log Kow: -1.93- -1.36
Section 10 - CHEMICAL STABILITY AND REACTIVITY INFORMATION
CONDITIONS CONTRIBUTING TO INSTABILITY
路 Presence of incompatible materials.
路 Product is considered stable.
路 Hazardous polymerisation will not occur.
Section 11 - TOXICOLOGICAL INFORMATION
POTENTIAL HEALTH EFFECTS
ACUTE HEALTH EFFECTS
SWALLOWED
The material has NOT been classified by EC Directives or other classification systems as
"harmful by ingestion". This is because of the lack of corroborating animal or human
evidence. The material may still be damaging to the health of the individual, following
ingestion, especially where pre-existing organ (e.g liver, kidney) damage is evident.
Present definitions of harmful or toxic substances are generally based on doses producing
mortality rather than those producing morbidity (disease, ill-health). Gastrointestinal
tract discomfort may produce nausea and vomiting. In an occupational setting however,
ingestion of insignificant quantities is not thought to be cause for concern.
EYE
Although the liquid is not thought to be an irritant (as classified by EC Directives),
direct contact with the eye may produce transient discomfort characterised by tearing or
conjunctival redness (as with windburn).
continued...
0893 280 1 - WURTH DYE F. PLASTIK BLACK 75ML
Chemwatch Material Safety Data Sheet
Issue Date: 14-Oct-2003 CHEMWATCH 4599-5
NA477ECP Version No:3
CD 2007/2 Page 8 of 12
Section 11 - TOXICOLOGICAL INFORMATION
SKIN
The material is not thought to produce adverse health effects or skin irritation
following contact (as classified by EC Directives using animal models). Nevertheless,
good hygiene practice requires that exposure be kept to a minimum and that suitable
gloves be used in an occupational setting.
Entry into the blood-stream, through, for example, cuts, abrasions or lesions, may
produce systemic injury with harmful effects. Examine the skin prior to the use of the
material and ensure that any external damage is suitably protected.
INHALED
The material is not thought to produce adverse health effects or irritation of the
respiratory tract (as classified by EC Directives using animal models). Nevertheless,
good hygiene practice requires that exposure be kept to a minimum and that suitable
control measures be used in an occupational setting.
CHRONIC HEALTH EFFECTS
Principal routes of exposure are by accidental skin and eye contact and by inhalation of
vapours especially at higher temperatures.
As with any chemical product, contact with unprotected bare skin; inhalation of vapour,
mist or dust in work place atmosphere; or ingestion in any form, should be avoided by
observing good occupational work practice.
TOXICITY AND IRRITATION
None assigned. Refer to individual constituents.
CRISTOBALITE:
unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances.
TOXICITY IRRITATION
Inhalation (human) TCLo: 16 mppcf*/8H/17.9y- I
* Millions of particles per cubic foot
WARNING: For inhalation exposure ONLY: This substance has been classified by the IARC as
Group 1: CARCINOGENIC TO HUMANS.
ISOPROPANOL:
unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances.
TOXICITY IRRITATION
Oral (human) LDLo: 3570 mg/kg Skin (rabbit): 500 mg - Mild
Oral (human) TDLo: 223 mg/kg Eye (rabbit): 10 mg - Moderate
Oral (man) TDLo: 14432 mg/kg Eye (rabbit): 100mg/24hr- Moderate
Oral (rat) LD50: 5045 mg/kg Eye (rabbit): 100 mg - SEVERE
Dermal (rabbit) LD50: 12800 mg/kg
The substance is classified by IARC as Group 3:
NOT classifiable as to its carcinogenicity to humans.
Evidence of carcinogenicity may be inadequate or limited in animal testing.
ETHYLENE GLYCOL:
unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances.
TOXICITY IRRITATION
Oral (rat) LD50: 4700 mg/kg Skin (rabbit): 555 mg(open)- Mild
Oral (human) LDLo: 398 mg/kg Eye (rabbit): 100 mg/1h - Mild
Oral (child) TDLo: 5500 mg/kg Eye (rabbit): 1440mg/6h- Moderate
Inhalation (human) TCLo: 10000 mg/m鲁 Eye (rabbit): 500 mg/24h - Mild
Dermal (rabbit) LD50: 9530 mg/kg Eye (rabbit): 12 mg/m鲁/3D
Inhalation (rat) LC50: 50100 mg/m鲁/8 hr
[Estimated Lethal Dose (human) 100 ml; RTECS
quoted by Orica]
Substance is reproductive effector in rats (birth defects).
Mutagenic to rat cells.
continued...
0893 280 1 - WURTH DYE F. PLASTIK BLACK 75ML
Chemwatch Material Safety Data Sheet
Issue Date: 14-Oct-2003 CHEMWATCH 4599-5
NA477ECP Version No:3
CD 2007/2 Page 9 of 12
Section 11 - TOXICOLOGICAL INFORMATION
DIURON:
unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances.
TOXICITY IRRITATION
Oral (rat) LD50: 1017 mg/kg Nil Reported
Dermal (rat) LD50: >5000 mg/kg
Note: Equivocal animal tumorigenic agent by
RTECS criteria.
NOTE: This substance may contain impurities (tetrachlorazobenzene and
tetrachloroazoxybenzene).
Maximum impurity levels are proscribed under various jurisdictions
ADI: 0.006 mg/kg/day
NOEL: 0.625 mg/kg/day
Section 12 - ECOLOGICAL INFORMATION
DO NOT discharge into sewer or waterways.
Water hazard class 2 (Self-assessment): hazardous to water.
Refer to data for ingredients, which follows:
ISOPROPANOL:
log Kow (Sangster 1997): 0.05
log Pow (Verschueren 1983): - 0.5714285
BOD5: 60%
BOD20: 78%
COD: 2.23
ThOD: 2.4
Half- life Soil - High (hours): 168
Half- life Soil - Low (hours): 24
Half- life Air - High (hours): 72
Half- life Air - Low (hours): 6.2
Half- life Surface water - High (hours): 168
Half- life Surface water - Low (hours): 24
Half- life Ground water - High (hours): 336
Half- life Ground water - Low (hours): 48
Aqueous biodegradation - Aerobic - High (hours): 168
Aqueous biodegradation - Aerobic - Low (hours): 24
Aqueous biodegradation - Anaerobic - High (hours): 672
Aqueous biodegradation - Anaerobic - Low (hours): 96
Photooxidation half- life water - High (hours): 1.90E+05
Photooxidation half- life water - Low (hours): 4728
Photooxidation half- life air - High (hours): 72
Photooxidation half- life air - Low (hours): 6.2
DO NOT discharge into sewer or waterways.
log Kow: -0.16- 0.28
Half-life (hr) air: 33-84
Half-life (hr) H2O surface water: 130
Henry's atm m鲁 /mol: 8.07E-06
BOD 5 if unstated: 1.19,60%
COD: 1.61-2.30,97%
ThOD: 2.4
Aquatic toxicity
(fish) 24-96h TLm: 42.5-240 mg/l
(fish) 96h LC50: 4200-9640 mg/l *
(daphnia) 48h EC50: 2285 mg/l *
BOD 20: >70% * * [Akzo Nobel]
ETHYLENE GLYCOL:
continued...
0893 280 1 - WURTH DYE F. PLASTIK BLACK 75ML
Chemwatch Material Safety Data Sheet
Issue Date: 14-Oct-2003 CHEMWATCH 4599-5
NA477ECP Version No:3
CD 2007/2 Page 10 of 12
Section 12 - ECOLOGICAL INFORMATION
Hazardous Air Pollutant: Yes
Fish LC50 (96hr.) (mg/l): 18500- 4100
Algae IC50 (72hr.) (mg/l): 180000
log Kow (Prager 1995): - 1.36
log Kow (Sangster 1997): - 1.36
log Pow (Verschueren 1983): - 1.93
BOD5: 35%
COD: 94%
ThOD: 1.26
Half- life Soil - High (hours): 288
Half- life Soil - Low (hours): 48
Half- life Air - High (hours): 83
Half- life Air - Low (hours): 8.3
Half- life Surface water - High (hours): 288
Half- life Surface water - Low (hours): 48
Half- life Ground water - High (hours): 576
Half- life Ground water - Low (hours): 96
Aqueous biodegradation - Aerobic - High (hours): 288
Aqueous biodegradation - Aerobic - Low (hours): 48
Aqueous biodegradation - Anaerobic - High (hours): 1152
Aqueous biodegradation - Anaerobic - Low (hours): 192
Aqueous biodegradation - Removal secondary treatment - High (hours): 100%
Aqueous biodegradation - Removal secondary treatment - Low (hours): 80%
Photooxidation half- life water - High (hours): 566000
Photooxidation half- life water - Low (hours): 6400
Photooxidation half- life air - High (hours): 83
Photooxidation half- life air - Low (hours): 8.3
DO NOT discharge into sewer or waterways.
log Kow: -1.93- -1.36
Half-life (hr) air: 24
Henry's atm m鲁 /mol: 6.00E-08
BOD 5 if unstated: 0.15-0.81,12%
COD: 1.21-1.29
ThOD: 1.26
BCF: 10-190
Toxicity Fish: LC50(96)118-550mg/L
Toxicity invertebrate: cell mult. inhib.135-1127mg/L
Bioaccumulation: not sig
Nitrif. inhib.: inhib at 125mg/L
Anaerobic effects: no degrad
Effects on algae and plankton: cell mult. inhib. algae 105-710mg/L
Degradation Biological: little
processes Abiotic: photol&hydrol notsig,RxnOH*
In the atmosphere ethylene glycol exists mainly in the vapour phase. It
is degraded in the atmosphere by reaction with photochemically produced
hydroxy radicals (estimated half-life 24-50 hours).
Ethylene glycol does not concentrate in the food chain.
DIURON:
Fish LC50 (96hr.) (mg/l): 150- 190 (4
Daphnia magna EC50 (48hr.) (mg/l): 1.4
The material is classified as an ecotoxin* because it is NOT readily biodegradable and
the Fish LC50 (96 hours) is less than or equal to 1 mg/l.
Substances are considered to be readily biodegradable if the following levels of
degradation are achieved in 28 days:
路 In tests based on dissolved organic carbon: 70%
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0893 280 1 - WURTH DYE F. PLASTIK BLACK 75ML
Chemwatch Material Safety Data Sheet
Issue Date: 14-Oct-2003 CHEMWATCH 4599-5
NA477ECP Version No:3
CD 2007/2 Page 11 of 12
Section 12 - ECOLOGICAL INFORMATION
路 In tests based on oxygen depletion or carbon dioxide generation: 60% of the
theoretical maxima
These levels of biodegradation must be achieved within 10 days of the start of
biodegradation, which point is taken as the time when 10% of the substance has been
degraded.
* Classification of Substances as Ecotoxic (Dangerous to the Environment)
Appendix 8,Table 1
Compiler's Guide for the Preparation of International Chemical Safety Cards: 1993
Commission of the European Communities.
The phenylurea herbicides may be divided into three categories based on water solubility.
The most soluble, fenuron (water solubility 2900 to 3850 ppm) moves substantially in a
lateral direction over the soil surface and in a vertical direction in the subsoil. Its
movement is also related to soil texture and organic matter content. Movement is greater
in coarse-textured soils and decreases at higher organic contents. The middle group
(water-solubilities 18 to 580 ppm) are moderately mobile in soil; their relative movement
decreases as water solubility decreases. Movement of members of this group also decreases
as the organic content matter of the soil increases. The least soluble group (water
solubility 2 to 4.8 ppm) are immobile in the soil. Most phenylurea compounds have low
vapour pressure and are not volatile from soil. Soil pH does not significantly affect
adsorption, mobility or herbicidal activity. The field persistence of these compounds is
moderate with residues remaining for several months following application, at most. These
herbicides are readily metabolised by most biological systems. A combination of their low
mammalian toxicity and biodegradability indicate that they are not significant factors in
the contamination of soil and water systems: their significance as environmental
pollutants is minimal.
Section 13 - DISPOSAL CONSIDERATIONS
路 Recycle wherever possible or consult manufacturer for recycling options.
路 Consult State Land Waste Management Authority for disposal.
路 Bury residue in an authorised landfill.
路 Recycle containers if possible, or dispose of in an authorised landfill.
Section 14 - TRANSPORTATION INFORMATION
Labels Required:
HAZCHEM: None
NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS:UN, IATA,
IMDG
Section 15 - REGULATORY INFORMATION
REGULATIONS
0893 280 1 - Wurth Dye F. Plastik Black 75ml (CAS No: None):
No regulations applicable
cristobalite (CAS: 14464-46-1) is found on the following regulatory lists;
New Zealand Workplace Exposure Standards (WES)
OECD Representative List of High Production Volume (HPV) Chemicals
isopropanol (CAS: 67-63-0) is found on the following regulatory lists;
IMO MARPOL 73/78 (Annex II) - List of Other Liquid Substances
International Agency for Research on Cancer (IARC) Carcinogens
continued...
0893 280 1 - WURTH DYE F. PLASTIK BLACK 75ML
Chemwatch Material Safety Data Sheet
Issue Date: 14-Oct-2003 CHEMWATCH 4599-5
NA477ECP Version No:3
CD 2007/2 Page 12 of 12
Section 15 - REGULATORY INFORMATION
New Zealand Hazardous Substances Transfer Notice 2004 - Schedule I, List of Substances (Dangerous Goods) to be transferred
New Zealand Transferred List of Single Component Substances
New Zealand Workplace Exposure Standards (WES)
OECD Representative List of High Production Volume (HPV) Chemicals
ethylene glycol (CAS: 107-21-1) is found on the following regulatory lists;
IMO MARPOL 73/78 (Annex II) - List of Noxious Liquid Substances Carried in Bulk
IMO MARPOL 73/78 (Annex II) - List of Other Liquid Substances
International Council of Chemical Associations (ICCA) - High Production Volume List
New Zealand Hazardous Substances Transfer Notice 2004 - Schedule 2, List of substances (scheduled toxic substances) to be transferred
New Zealand Poisons Schedule
New Zealand Transferred List of Single Component Substances
New Zealand Workplace Exposure Standards (WES)
OECD Representative List of High Production Volume (HPV) Chemicals
diuron (CAS: 330-54-1) is found on the following regulatory lists;
New Zealand Workplace Exposure Standards (WES)
OECD Representative List of High Production Volume (HPV) Chemicals
Specific advice on controls required for materials used in
New Zealand can be found at
http://www.ermanz.govt.nz/search/registers.html
Section 16 - OTHER INFORMATION
NEW ZEALAND POISONS INFORMATION CENTRE
0800 POISON (0800 764 766)
NZ EMERGENCY SERVICES: 111
REPRODUCTIVE HEALTH GUIDELINES
Ingredient ORG UF
Endpoi CR Adeq
nt TLV
ethylene glycol 26 mg/m3 100 R NA -
These exposure guidelines have been derived from a screening level of risk assessment and
should not be construed as unequivocally safe limits. ORGS represent an 8-hour time
-weighted average unless specified otherwise.
CR = Cancer Risk/10000; UF = Uncertainty factor:
TLV believed to be adequate to protect reproductive health:
LOD: Limit of detection
Toxic endpoints have also been identified as:
D = Developmental; R = Reproductive; TC = Transplacental carcinogen
Jankovic J., Drake F.: A Screening Method for Occupational Reproductive
American Industrial Hygiene Association Journal 57: 641-649 (1996).
Classification of the preparation and its individual components has drawn on official and
authoritative sources as well as independent review by the Chemwatch Classification
committee using available literature references.
This document is copyright. Apart from any fair dealing for the purposes of
private study, research, review or criticism, as permitted under the Copyright
Act, no part may be reproduced by any process without written permission from
CHEMWATCH. TEL (+61 3) 9572 4700.
Issue Date: 14-Oct-2003
Print Date: 20-Jul-2007
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