0893 349 005 - WURTH LACQUER SPRAY BLACK STAIN
Chemwatch Material Safety Data Sheet
Issue Date: 27-Jan-2005 CHEMWATCH 4598-25
NA477ECP Version No:3
CD 2007/2 Page 1 of 27
Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME
0893 349 005 - WURTH LACQUER SPRAY BLACK STAIN
STATEMENT OF HAZARDOUS NATURE
Considered a Hazardous Substance according to the criteria of the New
Zealand Hazardous Substances New Organisms legislation.
OTHER NAMES
PROPER SHIPPING NAME
AEROSOLS
PRODUCT USE
Spray paint for applying to surfaces.
Application is by spray atomisation from a hand held aerosol pack.
SUPPLIER
Company: Wurth New Zealand Limited
Address:
42 Hobill Avenue
Manukau City
Auckland
NZL
Telephone: 0800 683 040
Fax: 0800 100 104
Section 2 - HAZARDS IDENTIFICATION
GHS Classification
Acute Toxicity (Inhalation) Category 3
Carcinogen Category 2
Chronic Aquatic Hazard Category 2
Eye Irritation Category 2A
Flammable Aerosol Category 1
Organ Damage Category 2
Respiratory Irritation Category 3
Skin Corrosion/Irritation Category 2
EMERGENCY OVERVIEW
HAZARD
DANGER
Determined by Chemwatch using GHS/HSNO criteria:
2.1.2A 6.1C 6.3A 6.4A 6.7B 6.9B 9.1B
May cause respiratory irritation
Extremely flammable aerosol
Toxic if inhaled
Causes skin irritation
Causes serious eye irritation
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0893 349 005 - WURTH LACQUER SPRAY BLACK STAIN
Chemwatch Material Safety Data Sheet
Issue Date: 27-Jan-2005 CHEMWATCH 4598-25
NA477ECP Version No:3
CD 2007/2 Page 2 of 27
Section 2 - HAZARDS IDENTIFICATION
Suspected of causing cancer
May cause damage to organs through prolonged or repeated exposure by inhalation.
Toxic to aquatic life with long lasting effects
PRECAUTIONARY STATEMENTS
Prevention
Do not breathe dust/fume/gas/mist/vapours/spray.
Do not spray on an open flame or other ignition source.
Pressurized container: Do not pierce or burn, even after use.
Wash thoroughly after handling.
Avoid breathing dust/fume/gas/mist/vapours/spray.
Wash hands thoroughly after handling.
Use only outdoors or in a well ventilated area.
Keep away from heat/sparks/open flame - No smoking.
Do not handle until all safety precautions have been read and understood.
Obtain special instructions before use.
Use personal protective equipment as required.
Response
Keep container tightly closed.
If eye irritation persists, get medical advice/attention.
If exposed or concerned: Get medical attention advice.
Wear eye/face protection.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
If skin irritation occurs, seek medical advice/attention.
IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.
Eliminate all ignition sources if safe to do so.
Specific treatment: refer to Label or MSDS.
Get medical advice/attention if you feel unwell.
Leaking gas fire: Do not extinguish, unless leak can be stopped safely
Remove/Take off immediately all contaminated clothing
Wash/Decontaminate removed clothing before reuse.
IF ON SKIN: Gently wash with plenty of soap and water.
Call a POISON CENTER or doctor/physician if you feel unwell.
Storage
Store locked up.
Protect from sunlight and do not expose to temperatures exceeding 50??C/122??F.
Disposal
Dispose of contents and container in accordance with relevant legislation.
Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS
NAME CAS RN %
acetone 67-64-1 20-50
n- butyl acetate 123-86-4 1-40
propylene glycol monomethyl ether acetate, alpha- isomer 108-65-6 1-20
isopropanol 67-63-0 1-20
xylene 1330-20-7 1-12
toluene 108-88-3 1-12
butyl benzyl phthalate 85-68-7 1-10
hydrocarbon propellant 68476-85-7. 2-40
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0893 349 005 - WURTH LACQUER SPRAY BLACK STAIN
Chemwatch Material Safety Data Sheet
Issue Date: 27-Jan-2005 CHEMWATCH 4598-25
NA477ECP Version No:3
CD 2007/2 Page 3 of 27
Section 4 - FIRST AID MEASURES
NEW ZEALAND POISONS INFORMATION CENTRE 0800 POISON (0800 764 766)
NZ EMERGENCY SERVICES: 111
SWALLOWED
For advice, contact a Poisons Information Centre or a doctor.
路 If swallowed do NOT induce vomiting.
路 If vomiting occurs, lean patient forward or place on left side (head-down position, if
possible) to maintain open airway and prevent aspiration.
路 Observe the patient carefully.
路 Never give liquid to a person showing signs of being sleepy or with reduced awareness;
i.e. becoming unconscious
路 Give water to rinse out mouth, then provide liquid slowly and as much as casualty can
comfortably drink.
路 Seek medical advice.
EYE
If this product comes in contact with the eyes:
路 Immediately hold eyelids apart and flush the eye continuously with running water.
路 Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and
moving the eyelids by occasionally lifting the upper and lower lids.
路 Continue flushing until advised to stop by the Poisons Information Centre or a doctor,
or for at least 15 minutes.
路 Transport to hospital or doctor without delay.
路 Removal of contact lenses after an eye injury should only be undertaken by skilled
personnel.
SKIN
If solids or aerosol mists are deposited upon the skin:
路 Flush skin and hair with running water (and soap if available).
路 Remove any adhering solids with industrial skin cleansing cream.
路 DO NOT use solvents.
路 Seek medical attention in the event of irritation.
INHALED
路 If fumes or combustion products are inhaled remove from contaminated area.
路 Lay patient down. Keep warm and rested.
路 Prostheses such as false teeth, which may block airway, should be removed, where
possible, prior to initiating first aid procedures.
路 Apply artificial respiration if not breathing, preferably with a demand valve
resuscitator, bag-valve mask device, or pocket mask as trained. Perform CPR if necessary.
路 Transport to hospital, or doctor.
NOTES TO PHYSICIAN
For acute or short term repeated exposures to petroleum distillates or related
hydrocarbons:
路 Primary threat to life, from pure petroleum distillate ingestion and/or inhalation, is
respiratory failure.
路 Patients should be quickly evaluated for signs of respiratory distress (e.g. cyanosis,
tachypnoea, intercostal retraction, obtundation) and given oxygen. Patients with
inadequate tidal volumes or poor arterial blood gases (pO2 50 mm Hg) should be intubated.
路 Arrhythmias complicate some hydrocarbon ingestion and/or inhalation and
electrocardiographic evidence of myocardial injury has been reported; intravenous lines
and cardiac monitors should be established in obviously symptomatic patients. The lungs
excrete inhaled solvents, so that hyperventilation improves clearance.
路 A chest x-ray should be taken immediately after stabilisation of breathing and
circulation to document aspiration and detect the presence of pneumothorax.
路 Epinephrine (adrenalin) is not recommended for treatment of bronchospasm because of
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0893 349 005 - WURTH LACQUER SPRAY BLACK STAIN
Chemwatch Material Safety Data Sheet
Issue Date: 27-Jan-2005 CHEMWATCH 4598-25
NA477ECP Version No:3
CD 2007/2 Page 4 of 27
Section 4 - FIRST AID MEASURES
potential myocardial sensitisation to catecholamines. Inhaled cardioselective
bronchodilators (e.g. Alupent, Salbutamol) are the preferred agents, with aminophylline a
second choice.
路 Lavage is indicated in patients who require decontamination; ensure use of cuffed
endotracheal tube in adult patients. [Ellenhorn and Barceloux: Medical Toxicology].
Section 5 - FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA
路 Water spray or fog.
路 Foam.
路 Dry chemical powder.
路 BCF (where regulations permit).
路 Carbon dioxide.
FIRE FIGHTING
路 Alert Fire Brigade and tell them location and nature of hazard.
路 May be violently or explosively reactive.
路 Wear breathing apparatus plus protective gloves.
路 Prevent, by any means available, spillage from entering drains or water course.
路 If safe, switch off electrical equipment until vapour fire hazard removed.
路 Use water delivered as a fine spray to control fire and cool adjacent area.
路 DO NOT approach containers suspected to be hot.
路 Cool fire exposed containers with water spray from a protected location.
路 If safe to do so, remove containers from path of fire.
路 Equipment should be thoroughly decontaminated after use.
When any large container (including road and rail tankers) is involved in a fire,
consider evacuation by 100 metres in all directions.
FIRE/EXPLOSION HAZARD
路 Liquid and vapour are highly flammable.
路 Severe fire hazard when exposed to heat or flame.
路 Vapour forms an explosive mixture with air.
路 Severe explosion hazard, in the form of vapour, when exposed to flame or spark.
路 Vapour may travel a considerable distance to source of ignition.
路 Heating may cause expansion or decomposition with violent container rupture.
路 Aerosol cans may explode on exposure to naked flames.
路 Rupturing containers may rocket and scatter burning materials.
路 Hazards may not be restricted to pressure effects.
路 May emit acrid, poisonous or corrosive fumes.
路 On combustion, may emit toxic fumes of carbon monoxide (CO).
Other combustion products include:.
carbon dioxide (CO2).
FIRE INCOMPATIBILITY
Avoid contamination with strong oxidising agents as ignition may result.
Personal Protective Equipment
Breathing apparatus.
Gas tight chemical resistant suit.
Limit exposure duration to 1 BA set 30 mins.
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0893 349 005 - WURTH LACQUER SPRAY BLACK STAIN
Chemwatch Material Safety Data Sheet
Issue Date: 27-Jan-2005 CHEMWATCH 4598-25
NA477ECP Version No:3
CD 2007/2 Page 5 of 27
Section 6 - ACCIDENTAL RELEASE MEASURES
EMERGENCY PROCEDURES
MINOR SPILLS
路 Clean up all spills immediately.
路 Avoid breathing vapours and contact with skin and eyes.
路 Wear protective clothing, impervious gloves and safety glasses.
路 Shut off all possible sources of ignition and increase ventilation.
路 Wipe up.
路 If safe, damaged cans should be placed in a container outdoors, away from all ignition
sources, until pressure has dissipated.
路 Undamaged cans should be gathered and stowed safely.
MAJOR SPILLS
路 Clear area of personnel and move upwind.
路 Alert Fire Brigade and tell them location and nature of hazard.
路 May be violently or explosively reactive.
路 Wear breathing apparatus plus protective gloves.
路 Prevent, by any means available, spillage from entering drains or water courses
路 No smoking, naked lights or ignition sources.
路 Increase ventilation.
路 Stop leak if safe to do so.
路 Water spray or fog may be used to disperse / absorb vapour.
路 Absorb or cover spill with sand, earth, inert materials or vermiculite.
路 If safe, damaged cans should be placed in a container outdoors, away from ignition
sources, until pressure has dissipated.
路 Undamaged cans should be gathered and stowed safely.
路 Collect residues and seal in labelled drums for disposal.
PROTECTIVE ACTIONS FOR SPILL
PROTECTIVE ACTION ZONE
half
evacuation
downwind
direction
distance
down wind distance
wind isolation
distance
direction
half
evacuation downwind
INITIAL direction distance
ISOLATION
ZONE
From IERG (Canada/Australia)
Isolation Distance -
Downwind Protection Distance 8 metres
IERG Number 49
FOOTNOTES
1 PROTECTIVE ACTION ZONE is defined as the area in which people are at risk of harmful exposure. This zone
assumes that random changes in wind direction confines the vapour plume to an area within 30 degrees on
either side of the predominant wind direction, resulting in a crosswind protective action distance equal
to the downwind protective action distance.
2 PROTECTIVE ACTIONS should be initiated to the extent possible, beginning with those closest to the spill
and working away from the site in the downwind direction. Within the protective action zone a level of
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0893 349 005 - WURTH LACQUER SPRAY BLACK STAIN
Chemwatch Material Safety Data Sheet
Issue Date: 27-Jan-2005 CHEMWATCH 4598-25
NA477ECP Version No:3
CD 2007/2 Page 6 of 27
Section 6 - ACCIDENTAL RELEASE MEASURES
vapour concentration may exist resulting in nearly all unprotected persons becoming incapacitated and
unable to take protective action and/or incurring serious or irreversible health effects.
3 INITIAL ISOLATION ZONE is determined as an area, including upwind of the incident, within which a high
probability of localised wind reversal may expose nearly all persons without appropriate protection to
life-threatening concentrations of the material.
4 SMALL SPILLS involve a leaking package of 200 litres (55 US gallons) or less, such as a drum (jerrican or
box with inner containers). Larger packages leaking less than 200 litres and compressed gas leaking from
a small cylinder are also considered "small spills".
LARGE SPILLS involve many small leaking packages or a leaking package of greater than 200 litres, such as
a cargo tank, portable tank or a "one-tonne" compressed gas cylinder.
5 Guide 126 is taken from the US DOT emergency response guide book.
6 IERG information is derived from CANUTEC - Transport Canada.
EMERGENCY RESPONSE PLANNING GUIDELINES (ERPG)
The maximum airborne concentration below which it is believed that nearly all individuals could be exposed
for up to one hour WITHOUT experiencing or developing
life-threatening health effects is:
acetone 8500 ppm
n-butyl acetate 3000 ppm
propylene glycol monomethyl ether acetate, alpha-isomer 600 ppm
isopropanol 2000 ppm
xylene 900 ppm
toluene 1000 ppm
butyl benzyl phthalate 500 mg/m鲁
hydrocarbon propellant 2000 ppm
irreversible or other serious effects or symptoms which could impair an individual's ability to take
protective action is:
acetone 8500 ppm
n-butyl acetate 200 ppm
propylene glycol monomethyl ether acetate, alpha-isomer 250 ppm
isopropanol 2000 ppm
xylene 200 ppm
toluene 300 ppm
butyl benzyl phthalate 500 mg/m鲁
hydrocarbon propellant 2000 ppm
other than mild, transient adverse effects without perceiving a clearly defined odour is:
acetone 1000 ppm
n-butyl acetate 5 ppm
propylene glycol monomethyl ether acetate, alpha-isomer 150 ppm
isopropanol 400 ppm
xylene 150 ppm
toluene 50 ppm
butyl benzyl phthalate 15 mg/m鲁
hydrocarbon propellant 2000 ppm
The threshold concentration below which most people will experience no appreciable risk of health effects:
acetone 1000 ppm
n-butyl acetate 5 ppm
propylene glycol monomethyl ether acetate, alpha-isomer 50 ppm
isopropanol 400 ppm
xylene 100 ppm
toluene 50 ppm
butyl benzyl phthalate 5 mg/m鲁
hydrocarbon propellant 1000 ppm
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0893 349 005 - WURTH LACQUER SPRAY BLACK STAIN
Chemwatch Material Safety Data Sheet
Issue Date: 27-Jan-2005 CHEMWATCH 4598-25
NA477ECP Version No:3
CD 2007/2 Page 7 of 27
Section 6 - ACCIDENTAL RELEASE MEASURES
American Industrial Hygiene Association (AIHA)
Ingredients considered according to the following cutoffs
Very Toxic (T+) >= 0.1% Toxic (T) >= 3.0%
R50 >= 0.25% Corrosive (C) >= 5.0%
R51 >= 2.5%
else >= 10%
where percentage is percentage of ingredient found in the mixture
Personal Protective Equipment advice is contained in Section 8 of the MSDS.
Section 7 - HANDLING AND STORAGE
PROCEDURE FOR HANDLING
路 Avoid all personal contact, including inhalation.
路 Wear protective clothing when risk of exposure occurs.
路 Use in a well-ventilated area.
路 Prevent concentration in hollows and sumps.
路 DO NOT enter confined spaces until atmosphere has been checked.
路 Avoid smoking, naked lights or ignition sources.
路 Avoid contact with incompatible materials.
路 When handling, DO NOT eat, drink or smoke.
路 DO NOT incinerate or puncture aerosol cans.
路 DO NOT spray directly on humans, exposed food or food utensils.
路 Avoid physical damage to containers.
路 Always wash hands with soap and water after handling.
路 Work clothes should be laundered separately.
路 Use good occupational work practice.
路 Observe manufacturer's storing and handling recommendations.
路 Atmosphere should be regularly checked against established exposure standards to ensure
safe working conditions are maintained.
SUITABLE CONTAINER
路 Aerosol dispenser.
路 Check that containers are clearly labelled.
STORAGE INCOMPATIBILITY
Avoid storage with oxidisers.
STORAGE REQUIREMENTS
路 Store in original containers in approved flame-proof area.
路 DO NOT store in pits, depressions, basements or areas where vapours may be trapped.
路 No smoking, naked lights, heat or ignition sources.
路 Keep containers securely sealed. Contents under pressure.
路 Store away from incompatible materials.
路 Store in a cool, dry, well ventilated area in an upright position.
路 Avoid storage at temperatures higher than 40 deg C.
路 Protect containers against physical damage and check regularly for leaks.
路 Observe manufacturer's storing and handling recommendations.
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE CONTROLS
Source Material TWA ppm TWA mg/m鲁 STEL ppm STEL mg/m鲁Peak ppm Peak mg/m鲁 TWA F/CC
_________ _________ _____ _____ _____ _____ _____ _____ _____
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0893 349 005 - WURTH LACQUER SPRAY BLACK STAIN
Chemwatch Material Safety Data Sheet
Issue Date: 27-Jan-2005 CHEMWATCH 4598-25
NA477ECP Version No:3
CD 2007/2 Page 8 of 27
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
Source Material TWA ppm TWA mg/m鲁 STEL ppm STEL mg/m鲁Peak ppm Peak mg/m鲁 TWA F/CC
_________ _________ _____ _____ _____ _____ _____ _____ _____
New acetone 500 1, 185 1, 000 2, 375
Zealand (Acetone)
Workplace
Exposure
Standards
(WES)
New n- butyl 150 713 200 950
Zealand acetate
Workplace (n- Butyl
Exposure acetate)
Standards
(WES)
New isopropano 400 983 500 1, 230
Zealand l
Workplace (Isopropyl
Exposure alcohol)
Standards
(WES)
New xylene 50 217
Zealand (Xylene)
Workplace
Exposure
Standards
(WES)
New xylene 50 217
Zealand (Xylene)
Workplace
Exposure
Standards
(WES)
New xylene 50 217
Zealand (Xylene)
Workplace
Exposure
Standards
(WES)
New xylene 50 217
Zealand (Xylene)
Workplace
Exposure
Standards
(WES)
New toluene 50 188
Zealand (Toluene)
Workplace
Exposure
Standards
(WES)
New butyl 5
Zealand benzyl
Workplace phthalate
Exposure (Benzyl
Standards butyl
(WES) phthalate)
New hydrocarbo 1, 000 1, 800
Zealand n
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0893 349 005 - WURTH LACQUER SPRAY BLACK STAIN
Chemwatch Material Safety Data Sheet
Issue Date: 27-Jan-2005 CHEMWATCH 4598-25
NA477ECP Version No:3
CD 2007/2 Page 9 of 27
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
Source Material TWA ppm TWA mg/m鲁 STEL ppm STEL mg/m鲁Peak ppm Peak mg/m鲁 TWA F/CC
_________ _________ _____ _____ _____ _____ _____ _____ _____
Workplace propellant
Exposure (LPG
Standards (Liquefied
(WES) petroleum
gas))
EMERGENCY EXPOSURE LIMITS
Material Revised IDLH Value (mg/m3) Revised IDLH Value (ppm)
acetone 2, 500 [LEL]
n- butyl acetate 1, 700 [LEL]
isopropanol 2, 000 [LEL]
xylene 900
toluene 500
hydrocarbon propellant 2, 000 [LEL]
NOTES
Values marked LEL indicate that the IDLH was based on 10% of the lower explosive limit
for safety considerations even though the relevant toxicological data indicated that
irreversible health effects or impairment of escape existed only at higher
concentrations.
ODOUR SAFETY FACTOR (OSF)
OSF=0.16 (hydrocarbon propellant)
Exposed individuals are NOT reasonably expected to be warned, by smell, that the Exposure
Standard is being exceeded.
Odour Safety Factor (OSF) is determined to fall into either Class C, D or E.
The Odour Safety Factor (OSF) is defined as:
OSF= Exposure Standard (TWA) ppm/ Odour Threshold Value (OTV) ppm
Classification into classes follows:
Class OSF Description
A 550 Over 90% of exposed individuals
are aware by smell that the
Exposure Standard (TLV- TWA for
example) is being reached, even
when distracted by working
activities
B 26- 550 As " A" for 50- 90% of persons
being distracted
C 1- 26 As " A" for less than 50% of
persons being distracted
D 0.18- 1 10- 50% of persons aware of
being tested perceive by smell
that the Exposure Standard is
being reached
E <0.18 As " D" for less than 10% of
persons aware of being tested
.
MATERIAL DATA
None assigned. Refer to individual constituents.
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0893 349 005 - WURTH LACQUER SPRAY BLACK STAIN
Chemwatch Material Safety Data Sheet
Issue Date: 27-Jan-2005 CHEMWATCH 4598-25
NA477ECP Version No:3
CD 2007/2 Page 10 of 27
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
INGREDIENT DATA
HYDROCARBON PROPELLANT:
TOLUENE:
XYLENE:
Exposed individuals are NOT reasonably expected to be warned, by smell, that the
Exposure Standard is being exceeded.
Odour Safety Factor (OSF) is determined to fall into either Class C, D or E.
The Odour Safety Factor (OSF) is defined as:
OSF= Exposure Standard (TWA) ppm/ Odour Threshold Value (OTV) ppm
Classification into classes follows:
Class OSF Description
A 550 Over 90% of exposed individuals
are aware by smell that the
Exposure Standard (TLV- TWA for
example) is being reached, even
when distracted by working
activities
B 26- 550 As " A" for 50- 90% of persons
being distracted
C 1- 26 As " A" for less than 50% of
persons being distracted
D 0.18- 1 10- 50% of persons aware of
being tested perceive by smell
that the Exposure Standard is
being reached
E <0.18 As " D" for less than 10% of
persons aware of being tested
.
TOLUENE:
XYLENE:
Exposure limits with "skin" notation indicate that vapour and liquid may be absorbed
through intact skin. Absorption by skin may readily exceed vapour inhalation exposure.
Symptoms for skin absorption are the same as for inhalation. Contact with eyes and mucous
membranes may also contribute to overall exposure and may also invalidate the exposure
standard.
PROPYLENE GLYCOL MONOMETHYL ETHER ACETATE, ALPHA-ISOMER:
XYLENE:
Sensory irritants are chemicals that produce temporary and undesirable side-effects on
the eyes, nose or throat. Historically occupational exposure standards for these
irritants have been based on observation of workers' responses to various airborne
concentrations. Present day expectations require that nearly every individual should be
protected against even minor sensory irritation and exposure standards are established
using uncertainty factors or safety factors of 5 to 10 or more. On occasion animal no
-observable-effect-levels (NOEL) are used to determine these limits where human results
are unavailable. An additional approach, typically used by the TLV committee (USA) in
determining respiratory standards for this group of chemicals, has been to assign ceiling
values (TLV C) to rapidly acting irritants and to assign short-term exposure limits (TLV
STELs) when the weight of evidence from irritation, bioaccumulation and other endpoints
combine to warrant such a limit. In contrast the MAK Commission (Germany) uses a five
-category system based on intensive odour, local irritation, and elimination half-life.
However this system is being replaced to be consistent with the European Union (EU)
Scientific Committee for Occupational Exposure Limits (SCOEL); this is more closely
allied to that of the USA.
OSHA (USA) concluded that exposure to sensory irritants can:
路 cause inflammation
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0893 349 005 - WURTH LACQUER SPRAY BLACK STAIN
Chemwatch Material Safety Data Sheet
Issue Date: 27-Jan-2005 CHEMWATCH 4598-25
NA477ECP Version No:3
CD 2007/2 Page 11 of 27
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
路 cause increased susceptibility to other irritants and infectious agents
路 lead to permanent injury or dysfunction
路 permit greater absorption of hazardous substances and
路 acclimate the worker to the irritant warning properties of these substances thus
increasing the risk of overexposure.
ACETONE:
N-BUTYL ACETATE:
Exposed individuals are reasonably expected to be warned, by smell, that the Exposure
Standard is being exceeded.
Odour Safety Factor (OSF) is determined to fall into either Class A or B.
The Odour Safety Factor (OSF) is defined as:
OSF= Exposure Standard (TWA) ppm/ Odour Threshold Value (OTV) ppm
Classification into classes follows:
Class OSF Description
A 550 Over 90% of exposed individuals
are aware by smell that the
Exposure Standard (TLV- TWA for
example) is being reached, even
when distracted by working
activities
B 26- 550 As " A" for 50- 90% of persons
being distracted
C 1- 26 As " A" for less than 50% of
persons being distracted
D 0.18- 1 10- 50% of persons aware of
being tested perceive by smell
that the Exposure Standard is
being reached
E <0.18 As " D" for less than 10% of
persons aware of being tested
.
TOLUENE:
XYLENE:
These exposure guidelines have been derived from a screening level of risk assessment
and should not be construed as unequivocally safe limits. ORGS represent an 8-hour time
-weighted average unless specified otherwise.
CR = Cancer Risk/10000; UF = Uncertainty factor:
TLV believed to be adequate to protect reproductive health:
LOD: Limit of detection
Toxic endpoints have also been identified as:
D = Developmental; R = Reproductive; TC = Transplacental carcinogen
Jankovic J., Drake F.: A Screening Method for Occupational Reproductive
American Industrial Hygiene Association Journal 57: 641-649 (1996).
TOLUENE:
XYLENE:
Established occupational exposure limits frequently do not take into consideration
reproductive end points that are clearly below the thresholds for other toxic effects.
Occupational reproductive guidelines (ORGs) have been suggested as an additional
standard. These have been established after a literature search for reproductive no
-observed-adverse effect-level (NOAEL) and the lowest-observed-adverse-effect-level
(LOAEL). In addition the US EPA's procedures for risk assessment for hazard
identification and dose-response assessment as applied by NIOSH were used in the creation
of such limits. Uncertainty factors (UFs) have also been incorporated.
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0893 349 005 - WURTH LACQUER SPRAY BLACK STAIN
Chemwatch Material Safety Data Sheet
Issue Date: 27-Jan-2005 CHEMWATCH 4598-25
NA477ECP Version No:3
CD 2007/2 Page 12 of 27
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
ACETONE:
Odour Threshold Value: 3.6 ppm (detection), 699 ppm (recognition)
Saturation vapour concentration: 237000 ppm @ 20 C
NOTE: Detector tubes measuring in excess of 40 ppm, are available.
Exposure at or below the recommended TLV-TWA is thought to protect the
worker against mild irritation associated with brief exposures and the
bioaccumulation, chronic irritation of the respiratory tract and headaches
associated with long-term acetone exposures. The NIOSH REL-TWA is
substantially lower and has taken into account slight irritation
experienced by volunteer subjects at 300 ppm. Mild irritation to
acclimatised workers begins at about 750 ppm - unacclimatised subjects
will experience irritation at about 350-500 ppm but acclimatisation can
occur rapidly. Disagreement between the peak bodies is based largely on
the view by ACGIH that widespread use of acetone, without evidence of
significant adverse health effects at higher concentrations, allows
acceptance of a higher limit.
Half-life of acetone in blood is 3 hours which means that no adjustment
for shift-length has to be made with reference to the standard 8 hour/day,
40 hours per week because body clearance occurs within any shift with low
potential for accumulation.
A STEL has been established to prevent excursions of acetone vapours that
could cause depression of the central nervous system.
N-BUTYL ACETATE:
Odour Threshold Value: 0.0063 ppm (detection), 0.038-12 ppm (recognition)
Exposure at or below the recommended TLV-TWA is thought to prevent
significant irritation of the eyes and respiratory passages as well as
narcotic effects. In light of the lack of substantive evidence regarding
teratogenicity and a review of acute oral data a STEL is considered
inappropriate.
PROPYLENE GLYCOL MONOMETHYL ETHER ACETATE, ALPHA-ISOMER:
Saturated vapour concentration: 4868 ppm at 20 C.
A two-week inhalation study found nasal effects to the nasal mucosa in
animals at concentrations up to 3000 ppm. Differences in the teratogenic
potential of the alpha (commercial grade) and beta isomers of PGMEA may
be explained by the formation of different metabolites. The beta-isomer is
thought to be oxidised to methoxypropionic acid, a homologue to
methoxyacetic acid which is a known teratogen. The alpha- form is
conjugated and excreted.
PGMEA mixture (containing 2% to 5% beta isomer) is a mild skin and eye
irritant, produces mild central nervous system effects in animals at
3000 ppm and produces mild CNS impairment and upper respiratory tract
and eye irritation in humans at 1000 ppm. In rats exposed to 3000 ppm
PGMEA produced slight foetotoxic effects (delayed sternabral ossification)
- no effects on foetal development were seen in rabbits exposed at 3000 ppm.
ISOPROPANOL:
Odour Threshold Value: 3.3 ppm (detection), 7.6 ppm (recognition)
Exposure at or below the recommended TLV-TWA and STEL is thought to
minimise the potential for inducing narcotic effects or significant
irritation of the eyes or upper respiratory tract. It is believed, in the
absence of hard evidence, that this limit also provides protection against
the development of chronic health effects. The limit is intermediate to
that set for ethanol, which is less toxic, and n-propyl alcohol, which is
more toxic, than isopropanol.
continued...
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Issue Date: 27-Jan-2005 CHEMWATCH 4598-25
NA477ECP Version No:3
CD 2007/2 Page 13 of 27
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
XYLENE:
IDLH Level: 900 ppm
Odour Threshold Value: 20 ppm (detection), 40 ppm (recognition)
NOTE: Detector tubes for o-xylene, measuring in excess of 10 ppm, are
available commercially. (m-xylene and p-xylene give almost the same
response)
Xylene vapour is an irritant to the eyes, mucous membranes and skin and
causes narcosis at high concentrations. Exposure to doses sufficiently high
to produce intoxication and unconsciousness also produces transient liver
and kidney toxicity. Neurologic impairment is NOT evident amongst
volunteers inhaling up to 400 ppm though complaints of ocular and upper
respiratory tract irritation occur at 200 ppm for 3 to 5 minutes.
Exposure to xylene at or below the recommended TLV-TWA and STEL is thought
to minimise the risk of irritant effects and to produce neither significant
narcosis or chronic injury. An earlier skin notation was deleted because
percutaneous absorption is gradual and protracted and does not
substantially contribute to the dose received by inhalation.
TOLUENE:
Odour Threshold Value: 0.16-6.7 (detection), 1.9-69 (recognition)
NOTE: Detector tubes measuring in excess of 5 ppm, are available.
High concentrations of toluene in the air produce depression of the
central nervous system (CNS) in humans. Intentional toluene exposure
(glue-sniffing) at maternally-intoxicating concentration has also produced
birth defects. Foetotoxicity appears at levels associated with CNS
narcosis and probably occurs only in those with chronic toluene-induced
kidney failure. Exposure at or below the recommended TLV-TWA is thought
to prevent transient headache and irritation, to provide a measure of
safety for possible disturbances to human reproduction, the prevention of
reductions in cognitive responses reported amongst humans inhaling
greater than 40 ppm, and the significant risks of hepatotoxic, behavioural
and nervous system effects (including impaired reaction time and
incoordination). Although toluene/ethanol interactions are well
recognised, the degree of protection afforded by the TLV-TWA among
drinkers is not known.
BUTYL BENZYL PHTHALATE:
No exposure limits set by NOHSC or ACGIH.
OES TWA: 5 mg/m3
CEL TWA: 3 mg/m3; STEL: 5 mg/m3
[compare OEL TWA (Sweden): 3 mg/m3; STEL: 5 mg/m3]
PERSONAL PROTECTION
EYE
路 Safety glasses with side shields; or as required,
路 Chemical goggles.
路 Contact lenses may pose a special hazard; soft contact lenses may absorb and
concentrate irritants. A written policy document, describing the wearing of lens or
restrictions on use, should be created for each workplace or task. This should include a
review of lens absorption and adsorption for the class of chemicals in use and an account
of injury experience. Medical and first-aid personnel should be trained in their removal
and suitable equipment should be readily available. In the event of chemical exposure,
begin eye irrigation immediately and remove contact lens as soon as practicable. Lens
should be removed at the first signs of eye redness or irritation - lens should be
removed in a clean environment only after workers have washed hands thoroughly. [CDC
continued...
0893 349 005 - WURTH LACQUER SPRAY BLACK STAIN
Chemwatch Material Safety Data Sheet
Issue Date: 27-Jan-2005 CHEMWATCH 4598-25
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CD 2007/2 Page 14 of 27
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
NIOSH Current Intelligence Bulletin 59].
HANDS/FEET
No special equipment needed when handling small quantities.
OTHERWISE: Wear general protective gloves, eg. light weight rubber gloves. Or as required
: Wear chemical protective gloves, eg. PVC. Wear safety footwear.
OTHER
No special equipment needed when handling small quantities.
OTHERWISE:
路 Overalls.
路 Skin cleansing cream.
路 Eyewash unit.
路 Do not spray on hot surfaces.
RESPIRATOR
Selection of the Class and Type of respirator will depend upon the level of breathing
zone contaminant and the chemical nature of the contaminant. Protection Factors (defined
as the ratio of contaminant outside and inside the mask) may also be important.
Breathing Zone Level Maximum Protection Half- face Respirator Full- Face Respirator
ppm (volume) Factor
1000 10 AX- AUS P -
1000 50 - AX- AUS P
5000 50 Airline * -
5000 100 - AX- 2 P
10000 100 - AX- 3 P
100+ Airline**
* - Continuous Flow ** - Continuous-flow or positive pressure demand.
The local concentration of material, quantity and conditions of use determine the type of
personal protective equipment required.
For further information consult site specific
CHEMWATCH data (if available), or your
Occupational Health and Safety Advisor.
ENGINEERING CONTROLS
General exhaust is adequate under normal operating conditions. If risk of overexposure
exists, wear SAA approved respirator. Correct fit is essential to obtain adequate
protection. Provide adequate ventilation in warehouse or closed storage areas.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE
Black liquid with a characteristic solvent odour; does not mix with water.
Supplied as an aerosol pack. Contents under PRESSURE. Contains highly flammable
hydrocarbon propellant.
PHYSICAL PROPERTIES
Liquid.
Gas.
Does not mix with water.
Molecular Weight: Not Applicable Boiling Range (掳 Not Av ailable
C):
Melting Range (掳 Not Available
C): Specific Gravity (water= 1): Not Available
Solubility in water (g/L): Immiscible pH (as supplied): Not Applicable
continued...
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Chemwatch Material Safety Data Sheet
Issue Date: 27-Jan-2005 CHEMWATCH 4598-25
NA477ECP Version No:3
CD 2007/2 Page 15 of 27
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
pH (1% solution): Not Applicable Vapour Pressure (kPa): 26.8
Volatile Component (%vol): Not Available Evaporation Rate: Not Available
Relative Vapour Density (air=1): Not Available Flash Point (掳 - 4
C):
Lower Explosive Limit (%): 2.3 Upper Explosive Limit (%): 13
Autoignition Temp (掳 315
C): Decomposition Temp (掳 Not Av ailable
C):
State: Liquid Viscosity: Not Available
log Kow (Prager 1995): - 0.24
log Kow (Sangster 1997): - 0.24
log Kow: -0.24
log Kow (Prager 1995): 1.82
log Kow (Sangster 1997): 1.78
log Kow (Sangster 1997): 0.05
log Kow: -0.16- 0.28
log Kow (Prager 1995): 3.12- 3.20
log Kow (Sangster 1997): 2.73
log Kow: 2.1-3
log Kow: 4.78-4.91
Section 10 - CHEMICAL STABILITY AND REACTIVITY INFORMATION
CONDITIONS CONTRIBUTING TO INSTABILITY
路 Elevated temperatures.
路 Presence of open flame.
路 Product is considered stable.
路 Hazardous polymerisation will not occur.
Section 11 - TOXICOLOGICAL INFORMATION
POTENTIAL HEALTH EFFECTS
ACUTE HEALTH EFFECTS
SWALLOWED
Although ingestion is not thought to produce harmful effects (as classified under EC
Directives), the material may still be damaging to the health of the individual,
following ingestion, especially where pre-existing organ (e.g liver, kidney) damage is
evident. Present definitions of harmful or toxic substances are generally based on doses
producing mortality rather than those producing morbidity (disease, ill-health).
Gastrointestinal tract discomfort may produce nausea and vomiting. In an occupational
setting however, ingestion of insignificant quantities is not thought to be cause for
concern.
Ingestion may result in nausea, pain, vomiting. Vomit entering the lungs by aspiration
may cause potentially lethal chemical pneumonitis.
Considered an unlikely route of entry in commercial/industrial environments.
EYE
Evidence exists, or practical experience predicts, that the material may cause eye
irritation in a substantial number of individuals and/or may produce significant ocular
lesions which are present twenty-four hours or more after instillation into the eye(s) of
experimental animals.
Repeated or prolonged eye contact may cause inflammation characterised by temporary
redness (similar to windburn) of the conjunctiva (conjunctivitis); temporary impairment
of vision and/or other transient eye damage/ulceration may occur.
The material may produce severe irritation to the eye causing pronounced inflammation.
continued...
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Issue Date: 27-Jan-2005 CHEMWATCH 4598-25
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CD 2007/2 Page 16 of 27
Section 11 - TOXICOLOGICAL INFORMATION
Repeated or prolonged exposure to irritants may produce conjunctivitis.
SKIN
Evidence exists, or practical experience predicts, that the material either produces
inflammation of the skin in a substantial number of individuals following direct contact,
and/or produces significant inflammation when applied to the healthy intact skin of
animals, for up to four hours, such inflammation being present twenty-four hours or more
after the end of the exposure period. Skin irritation may also be present after prolonged
or repeated exposure; this may result in a form of contact dermatitis (nonallergic). The
dermatitis is often characterised by skin redness (erythema) and swelling (oedema) which
may progress to blistering (vesiculation), scaling and thickening of the epidermis. At
the microscopic level there may be intercellular oedema of the spongy layer of the skin
(spongiosis) and intracellular oedema of the epidermis.
Skin contact is not thought to have harmful health effects (as classified under EC
Directives); the material may still produce health damage following entry through wounds,
lesions or abrasions.
Toxic effects may result from skin absorption.
The material may accentuate any pre-existing skin condition.
The material may cause skin irritation after prolonged or repeated exposure and may
produce a contact dermatitis (nonallergic). This form of dermatitis is often
characterised by skin redness (erythema) and swelling the epidermis. Histologically there
may be intercellular oedema of the spongy layer (spongiosis) and intracellular oedema of
the epidermis.
INHALED
The material is not thought to produce respiratory irritation (as classified by EC
Directives using animal models). Nevertheless inhalation, of the material, especially for
prolonged periods, may produce respiratory discomfort and occasionally, distress.
Inhalation hazard is increased at higher temperatures.
Acute effects from inhalation of high concentrations of vapour are pulmonary irritation,
including coughing, with nausea; central nervous system depression - characterised by
headache and dizziness, increased reaction time, fatigue and loss of co-ordination.
If exposure to highly concentrated solvent atmosphere is prolonged this may lead to
narcosis, unconsciousness, even coma and possible death.
WARNING:Intentional misuse by concentrating/inhaling contents may be lethal.
CHRONIC HEALTH EFFECTS
On the basis, primarily, of animal experiments, concern has been expressed that the
material may produce carcinogenic or mutagenic effects; in respect of the available
information, however, there presently exists inadequate data for making a satisfactory
assessment.
Principal routes of exposure are by accidental skin and eye contact and by inhalation of
vapours especially at higher temperatures.
Chronic solvent inhalation exposures may result in nervous system impairment
and liver and blood changes. [PATTYS].
Prolonged or continuous skin contact with the liquid may cause defatting with drying,
cracking, irritation and dermatitis following.
WARNING: Aerosol containers may present pressure related hazards.
TOXICITY AND IRRITATION
Not available. Refer to individual constituents.
ACETONE:
unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances.
TOXICITY IRRITATION
Oral (man) TDLo: 2857 mg/kg Eye (human): 500 ppm - Irritant
Oral (rat) LD50: 5800 mg/kg Eye (rabbit): 3.95 mg - SEVERE
Inhalation (human) TCLo: 500 ppm Eye (rabbit): 20mg/24hr - Moderate
Inhalation (man) TCLo: 12000 ppm/4 hr Skin (rabbit):395mg (open) - Mild
continued...
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Issue Date: 27-Jan-2005 CHEMWATCH 4598-25
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CD 2007/2 Page 17 of 27
Section 11 - TOXICOLOGICAL INFORMATION
Inhalation (man) TCLo: 10 mg/m鲁/6 hr Skin (rabbit): 500 mg/24hr - Mild
Inhalation (rat) LC50: 50100 mg/m鲁/8 hr
Dermal (rabbit) LD50: 20000 mg/kg
N-BUTYL ACETATE:
unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances.
TOXICITY IRRITATION
Oral (rat) LD50: 13100 mg/kg Skin (rabbit): 500 mg/24h- Moderate
Dermal (rabbit) LD50: 3200 mg/kg* Eye (rabbit): 20 mg (open)- SEVERE
Inhalation (human) TCLo: 200 ppm Eye (rabbit): 20 mg/24h - Moderate
Inhalation (rat) LC50: 2000 ppm/4h Eye ( human): 300 mg
Inhalation (Human) TCLo: 200 ppm/4h * [PPG]
Oral (Rat) LD50: 10768 mg/kg
Inhalation (Rat) LC50: 390 ppm/4h
Intraperitoneal (Mouse) LD50: 1230 mg/kg
Oral (Rabbit) LD50: 3200 mg/kg
Oral (Guinea) pig: LD50 4700 mg/kg
Intraperitoneal (Guinea) pig: LD 1500 mg/kg
The material may produce severe irritation to the eye causing pronounced inflammation.
Repeated or prolonged exposure to irritants may produce conjunctivitis.
The material may cause skin irritation after prolonged or repeated exposure and may
produce a contact dermatitis (nonallergic). This form of dermatitis is often
characterised by skin redness (erythema) and swelling the epidermis. Histologically there
may be intercellular oedema of the spongy layer (spongiosis) and intracellular oedema of
the epidermis.
PROPYLENE GLYCOL MONOMETHYL ETHER ACETATE, ALPHA-ISOMER:
unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances.
TOXICITY IRRITATION
Oral (rat) LD50: 8532 mg/kg Nil Reported
Dermal (rabbit) LD50: >5000 mg/kg* * [CCINFO]
Inhalation (rat) LC50: 4345 ppm/6h
A BASF report (in ECETOC ) showed that inhalation exposure to 545 ppm PGMEA
(beta isomer) was associated with a teratogenic response in rabbits; but
exposure to 145 ppm and 36 ppm had no adverse effects.
The beta isomer of PGMEA comprises only 10% of the commercial material, the
remaining 90% is alpha isomer. Hazard appears low but emphasizes the need
for care in handling this chemical. [I.C.I]
ISOPROPANOL:
unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances.
TOXICITY IRRITATION
Oral (human) LDLo: 3570 mg/kg Skin (rabbit): 500 mg - Mild
Oral (human) TDLo: 223 mg/kg Eye (rabbit): 10 mg - Moderate
Oral (man) TDLo: 14432 mg/kg Eye (rabbit): 100mg/24hr- Moderate
Oral (rat) LD50: 5045 mg/kg Eye (rabbit): 100 mg - SEVERE
Dermal (rabbit) LD50: 12800 mg/kg
The substance is classified by IARC as Group 3:
NOT classifiable as to its carcinogenicity to humans.
Evidence of carcinogenicity may be inadequate or limited in animal testing.
XYLENE:
unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances.
TOXICITY IRRITATION
Oral (human) LDLo: 50 mg/kg Skin (rabbit):500 mg/24h Moderate
Oral (rat) LD50: 4300 mg/kg Eye (human): 200 ppm Irritant
Inhalation (human) TCLo: 200 ppm Eye (rabbit): 87 mg Mild
Inhalation (man) LCLo: 10000 ppm/6h Eye (rabbit): 5 mg/24h SEVERE
Inhalation (rat) LC50: 5000 ppm/4h
continued...
0893 349 005 - WURTH LACQUER SPRAY BLACK STAIN
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Issue Date: 27-Jan-2005 CHEMWATCH 4598-25
NA477ECP Version No:3
CD 2007/2 Page 18 of 27
Section 11 - TOXICOLOGICAL INFORMATION
Oral (Human) LD: 50 mg/kg
Inhalation (Human) TCLo: 200 ppm/4h
Intraperitoneal (Rat) LD50: 2459 mg/kg
Subcutaneous (Rat) LD50: 1700 mg/kg
Oral (Mouse) LD50: 2119 mg/kg
Intraperitoneal (Mouse) LD50: 1548 mg/kg
Intravenous (Rabbit) LD: 129 mg/kg
Inhalation (Guinea) pig: LC 450 ppm/4h
The material may produce severe irritation to the eye causing pronounced inflammation.
Repeated or prolonged exposure to irritants may produce conjunctivitis.
The material may cause skin irritation after prolonged or repeated exposure and may
produce a contact dermatitis (nonallergic). This form of dermatitis is often
characterised by skin redness (erythema) and swelling the epidermis. Histologically there
may be intercellular oedema of the spongy layer (spongiosis) and intracellular oedema of
the epidermis.
The substance is classified by IARC as Group 3:
NOT classifiable as to its carcinogenicity to humans.
Evidence of carcinogenicity may be inadequate or limited in animal testing.
Reproductive effector in rats
TOLUENE:
unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances.
TOXICITY IRRITATION
Oral (human) LDLo: 50 mg/kg Skin (rabbit):20 mg/24h- Moderate
Oral (rat) LD50: 636 mg/kg Skin (rabbit):500 mg - Moderate
Inhalation (human) TCLo: 100 ppm Eye (rabbit):0.87 mg - Mild
Inhalation (man) TCLo: 200 ppm Eye (rabbit): 2mg/24h - SEVERE
Inhalation (rat) LC50: >26700 ppm/1h Eye (rabbit):100 mg/30sec - Mild
Dermal (rabbit) LD50: 12124 mg/kg
The material may cause skin irritation after prolonged or repeated exposure and may
produce a contact dermatitis (nonallergic). This form of dermatitis is often
characterised by skin redness (erythema) and swelling the epidermis. Histologically there
may be intercellular oedema of the spongy layer (spongiosis) and intracellular oedema of
the epidermis.
BUTYL BENZYL PHTHALATE:
unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances.
TOXICITY IRRITATION
Oral (rat) LD50: 2330 mg/kg Nil Reported
Oral (rat) LD50: 20400 mg/kg* ** [MONSANTO]**
Dermal (rabbit) LD50: >10, 000 mg/kg* [BASF]*
Dermal (mammal) LD50: 13, 100 mg/kg**
Exposure to the material for prolonged periods may cause physical defects in the
developing embryo (teratogenesis).
The substance is classified by IARC as Group 3:
NOT classifiable as to its carcinogenicity to humans.
Evidence of carcinogenicity may be inadequate or limited in animal testing.
Reproductive effector in rats.
HYDROCARBON PROPELLANT:
Not available. Refer to individual constituents.
Section 12 - ECOLOGICAL INFORMATION
Marine Pollutant:Not Determined
Water hazard class 2 (self assessment): hazardous to water.
Refer to data for ingredients, which follows:
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Issue Date: 27-Jan-2005 CHEMWATCH 4598-25
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CD 2007/2 Page 19 of 27
Section 12 - ECOLOGICAL INFORMATION
ACETONE:
Fish LC50 (96hr.) (mg/l): 8300- 40000
Daphnia magna EC50 (48hr.) (mg/l): 10
log Kow (Prager 1995): - 0.24
log Kow (Sangster 1997): - 0.24
log Pow (Verschueren 1983): - 0.24
BOD5: 122%
ThOD: 72
Half- life Soil - High (hours): 168
Half- life Soil - Low (hours): 24
Half- life Air - High (hours): 2790
Half- life Air - Low (hours): 279
Half- life Surface water - High (hours): 168
Half- life Surface water - Low (hours): 24
Half- life Ground water - High (hours): 336
Half- life Ground water - Low (hours): 48
Aqueous biodegradation - Aerobic - High (hours): 168
Aqueous biodegradation - Aerobic - Low (hours): 24
Aqueous biodegradation - Anaerobic - High (hours): 672
Aqueous biodegradation - Anaerobic - Low (hours): 96
Aqueous biodegradation - Removal secondary treatment - High (hours): 75%
Aqueous biodegradation - Removal secondary treatment - Low (hours): 54%
Aqueous photolysis half- life - High (hours): 270
Photooxidation half- life water - High (hours): 3.97E+06
Photooxidation half- life water - Low (hours): 9.92E+04
Photooxidation half- life air - High (hours): 2790
Photooxidation half- life air - Low (hours): 279
DO NOT discharge into sewer or waterways.
log Kow: -0.24
Half-life (hr) air: 312-1896
Half-life (hr) H2O surface water: 20
Henry's atm m鲁 /mol: 3.67E-05
BOD 5 if unstated: 0.31-1.76,46-55%
COD: 1.12-2.07
ThOD: 2.2
BCF: 0.69
Toxicity Fish: LC50(96) 5540-13000mg/L
Toxicity invertebrate: cell mult. inhib. 28-7500mg/L
Bioaccumulation: not sig
Nitrif. inhib.: 75% decr. at 840mg/L
Anaerobic effects: sig degrad
Degradation Biological: sig
processes Abiotic: Rxn OH*,photodissoc
In air, acetone is lost by photolysis and reaction with photochemically
produced hydroxyl radicals; the estimated half-life of these combined
processes is about 22 days. The relatively long half-life allows acetone
to be transported long distances from its emission source.
Acetone is highly soluble and slightly persistent in water, with a
half-life of about 20 hours; it is minimally toxic to aquatic life.
Acetone released to soil volatilises although some may leach into the
ground where it rapidly biodegrades.
Acetone does not concentrate in the food chain.
Drinking Water Standard: none available.
Soil Guidelines: none available.
Air Quality Standards: none available.
N-BUTYL ACETATE:
Fish LC50 (96hr.) (mg/l): 18
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Issue Date: 27-Jan-2005 CHEMWATCH 4598-25
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CD 2007/2 Page 20 of 27
Section 12 - ECOLOGICAL INFORMATION
Daphnia magna EC50 (48hr.) (mg/l): 44
log Kow (Prager 1995): 1.82
Fish LC50 (96hr.) (mg/l): 100- 185
Daphnia magna EC50 (48hr.) (mg/l): 44
Algae IC50 (72hr.) (mg/l): 280
log Kow (Sangster 1997): 1.78
COD: 78%
DO NOT discharge into sewer or waterways.
Half-life (hr) air: 144
Half-life (hr) H2O surface water: 178-27156
Henry's atm m鲁 /mol: 3.20E-04
BOD 5 if unstated: 0.15-1.02,7%
COD: 78%
ThOD: 2.207
BCF: 4-14
Toxicity Fish: LC50(96)100-185ppm
Toxicity invertebrate: cell mult. inhib.78-3700mg/L
Effects on algae and plankton: cell mult. inhib.21-280mg/L
Degradation Biological: sig
processes Abiotic: hydrol,RxnOH*
PROPYLENE GLYCOL MONOMETHYL ETHER ACETATE, ALPHA-ISOMER:
DO NOT discharge into sewer or waterways.
ISOPROPANOL:
log Kow (Sangster 1997): 0.05
log Pow (Verschueren 1983): - 0.5714285
BOD5: 60%
BOD20: 78%
COD: 2.23
ThOD: 2.4
Half- life Soil - High (hours): 168
Half- life Soil - Low (hours): 24
Half- life Air - High (hours): 72
Half- life Air - Low (hours): 6.2
Half- life Surface water - High (hours): 168
Half- life Surface water - Low (hours): 24
Half- life Ground water - High (hours): 336
Half- life Ground water - Low (hours): 48
Aqueous biodegradation - Aerobic - High (hours): 168
Aqueous biodegradation - Aerobic - Low (hours): 24
Aqueous biodegradation - Anaerobic - High (hours): 672
Aqueous biodegradation - Anaerobic - Low (hours): 96
Photooxidation half- life water - High (hours): 1.90E+05
Photooxidation half- life water - Low (hours): 4728
Photooxidation half- life air - High (hours): 72
Photooxidation half- life air - Low (hours): 6.2
DO NOT discharge into sewer or waterways.
log Kow: -0.16- 0.28
Half-life (hr) air: 33-84
Half-life (hr) H2O surface water: 130
Henry's atm m鲁 /mol: 8.07E-06
BOD 5 if unstated: 1.19,60%
COD: 1.61-2.30,97%
ThOD: 2.4
Aquatic toxicity
(fish) 24-96h TLm: 42.5-240 mg/l
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Issue Date: 27-Jan-2005 CHEMWATCH 4598-25
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Section 12 - ECOLOGICAL INFORMATION
(fish) 96h LC50: 4200-9640 mg/l *
(daphnia) 48h EC50: 2285 mg/l *
BOD 20: >70% * * [Akzo Nobel]
XYLENE:
Fish LC50 (96hr.) (mg/l): 13.5
BCF<100: 2.14- 2.20
log Kow (Prager 1995): 3.12- 3.20
Half- life Soil - High (hours): 672
Half- life Soil - Low (hours): 168
Half- life Air - High (hours): 44
Half- life Air - Low (hours): 2.6
Half- life Surface water - High (hours): 672
Half- life Surface water - Low (hours): 168
Half- life Ground water - High (hours): 8640
Half- life Ground water - Low (hours): 336
Aqueous biodegradation - Aerobic - High (hours): 672
Aqueous biodegradation - Aerobic - Low (hours): 168
Aqueous biodegradation - Anaerobic - High (hours): 8640
Aqueous biodegradation - Anaerobic - Low (hours): 4320
Photolysis maximum light absorption - High (nano- m): 269.5
Photolysis maximum light absorption - Low (nano- m): 265
Photooxidation half- life water - High (hours): 2.70E+08
Photooxidation half- life water - Low (hours): 3.90E+05
Photooxidation half- life air - High (hours): 44
Photooxidation half- life air - Low (hours): 2.6
The lower molecular weight hydrocarbons are expected to form a "slick" on the surface of
waters after release in calm sea conditions. This is expected to evaporate and enter the
atmosphere where it will be degraded through reaction with hydroxy radicals.
Some of the material will become associated with benthic sediments, and it is likely to
be spread over a fairly wide area of sea floor. Marine sediments may be either aerobic or
anaerobic. The material, in probability, is biodegradable, under aerobic conditions
(isomerised olefins and alkenes show variable results). Evidence also suggests that the
hydrocarbons may be degradable under anaerobic conditions although such degradation in
benthic sediments may be a relatively slow process.
Under aerobic conditions the material will degrade to water and carbon dioxide, while
under anaerobic processes it will produce water, methane and carbon dioxide.
Based on test results, as well as theoretical considerations, the potential for
bioaccumulation may be high. Toxic effects are often observed in species such as blue
mussel, daphnia, freshwater green algae, marine copepods and amphipods.
Drinking Water Standards:
hydrocarbon total: 10 ug/l (UK max.).
DO NOT discharge into sewer or waterways.
The material is classified as an ecotoxin* because the Fish LC50 (96 hours) is less than
or equal to 0.1 mg/l
* Classification of Substances as Ecotoxic (Dangerous to the Environment)
Appendix 8, Table 1
Compiler's Guide for the Preparation of International Chemical Safety Cards: 1993
Commission of the European Communities.
TOLUENE:
Hazardous Air Pollutant: Yes
Fish LC50 (96hr.) (mg/l): 7.3- 22.8
BCF<100: 13.2 (EELS
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Issue Date: 27-Jan-2005 CHEMWATCH 4598-25
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Section 12 - ECOLOGICAL INFORMATION
log Kow (Sangster 1997): 2.73
log Pow (Verschueren 1983): 2.69
BOD5: 5%
COD: 21%
ThOD: 3.13
Half- life Soil - High (hours): 528
Half- life Soil - Low (hours): 96
Half- life Air - High (hours): 104
Half- life Air - Low (hours): 10
Half- life Surface water - High (hours): 528
Half- life Surface water - Low (hours): 96
Half- life Ground water - High (hours): 672
Half- life Ground water - Low (hours): 168
Aqueous biodegradation - Aerobic - High (hours): 528
Aqueous biodegradation - Aerobic - Low (hours): 96
Aqueous biodegradation - Anaerobic - High (hours): 5040
Aqueous biodegradation - Anaerobic - Low (hours): 1344
Aqueous biodegradation - Removal secondary treatment - High (hours): 75%
Photolysis maximum light absorption - High (nano- m): 268
Photolysis maximum light absorption - Low (nano- m): 253.5
Photooxidation half- life water - High (hours): 1284
Photooxidation half- life water - Low (hours): 321
Photooxidation half- life air - High (hours): 104
Photooxidation half- life air - Low (hours): 10
The lower molecular weight hydrocarbons are expected to form a "slick" on the surface of
waters after release in calm sea conditions. This is expected to evaporate and enter the
atmosphere where it will be degraded through reaction with hydroxy radicals.
Some of the material will become associated with benthic sediments, and it is likely to
be spread over a fairly wide area of sea floor. Marine sediments may be either aerobic or
anaerobic. The material, in probability, is biodegradable, under aerobic conditions
(isomerised olefins and alkenes show variable results). Evidence also suggests that the
hydrocarbons may be degradable under anaerobic conditions although such degradation in
benthic sediments may be a relatively slow process.
Under aerobic conditions the material will degrade to water and carbon dioxide, while
under anaerobic processes it will produce water, methane and carbon dioxide.
Based on test results, as well as theoretical considerations, the potential for
bioaccumulation may be high. Toxic effects are often observed in species such as blue
mussel, daphnia, freshwater green algae, marine copepods and amphipods.
DO NOT discharge into sewer or waterways.
log Kow: 2.1-3
log Koc: 1.12-2.85
Koc: 37-250
log Kom: 1.39-2.89
Half-life (hr) air: 2.4-104
Half-life (hr) H2O surface water: 5.55-528
Half-life (hr) H2O ground: 168-2628
Half-life (hr) soil: <48-240
Henry's Pa m鲁 /mol: 518-694
Henry's atm m鲁 /mol: 5.94E-03
BOD 5 if unstated: 0.86-2.12,5%
COD: 0.7-2.52,21-27%
ThOD: 3.13
BCF: 1.67-380
Log BCF: 0.22-3.28
continued...
0893 349 005 - WURTH LACQUER SPRAY BLACK STAIN
Chemwatch Material Safety Data Sheet
Issue Date: 27-Jan-2005 CHEMWATCH 4598-25
NA477ECP Version No:3
CD 2007/2 Page 23 of 27
Section 12 - ECOLOGICAL INFORMATION
BUTYL BENZYL PHTHALATE:
Fish LC50 (96hr.) (mg/l): 1.7- 5.3
Daphnia magna EC50 (48hr.) (mg/l): 0.26- 0.76
log Pow (Verschueren 1983): 4.78
Half- life Soil - High (hours): 168
Half- life Soil - Low (hours): 24
Half- life Air - High (hours): 60
Half- life Air - Low (hours): 6
Half- life Surface water - High (hours): 168
Half- life Surface water - Low (hours): 24
Half- life Ground water - High (hours): 4320
Half- life Ground water - Low (hours): 48
Aqueous biodegradation - Aerobic - High (hours): 168
Aqueous biodegradation - Aerobic - Low (hours): 24
Aqueous biodegradation - Anaerobic - High (hours): 4320
Aqueous biodegradation - Anaerobic - Low (hours): 672
Aqueous photolysis half- life - Low (hours): 876000
Photooxidation half- life air - High (hours): 60
Photooxidation half- life air - Low (hours): 6
The phthalate esters are distributed throughout the environment ubiquitously. They are
found complexed with fulvic acid components of the humic substances in soil and marine
and estuarine waters. Fulvic acid appears to act as a solubiliser for the otherwise
insoluble ester and serves to mediate its transport and mobilisation in water or
immobilisation in soil. Phthalate esters have been found in open ocean environments, in
deep sea jelly fish, Atlantic herring and in mackerel. Phthalic ester plasticisers are
clearly recognised as general contaminants of almost every soil and water ecosystem. In
general they have low acute toxicity but the weight of evidence supporting their
carcinogenicity is substantial. Other subtle chronic effects have also been reported. As
little as 4 ug/ml in culture medium is lethal to chick embryo heart cells. This
concentration is similar to that reached in human blood stored in vinyl plastic bags for
as little as one day. Some phthalates (notably di2-ethylhexyl phthalate and dibutyl
phthalate) may also be detrimental to the reproduction of the water flea (Daphnia magna),
zebra fish and guppies. As phthalates are present in drinking water and food, concerns
have been raised about their long term effects on humans.
log Kow: 4.78-4.91
Half-life (hr) air: 24-120
Henry's atm m鲁 /mol: 1.30E-06
BCF: 663
Toxicity Fish: LC50(96)1.7-43mg/L
Toxicity invertebrate: LC50(96)3.7mg/L
Bioacculmulation: little
Anaerobic effects: sig degrad
Effects on algae and plankton: LC50(96)0.4-1mg/L
Degradation Biological: sig
processes Abiotic: not sig
HYDROCARBON PROPELLANT:
The lower molecular weight hydrocarbons are expected to form a "slick" on the surface of
waters after release in calm sea conditions. This is expected to evaporate and enter the
atmosphere where it will be degraded through reaction with hydroxy radicals.
Some of the material will become associated with benthic sediments, and it is likely to
be spread over a fairly wide area of sea floor. Marine sediments may be either aerobic or
anaerobic. The material, in probability, is biodegradable, under aerobic conditions
(isomerised olefins and alkenes show variable results). Evidence also suggests that the
hydrocarbons may be degradable under anaerobic conditions although such degradation in
benthic sediments may be a relatively slow process.
continued...
0893 349 005 - WURTH LACQUER SPRAY BLACK STAIN
Chemwatch Material Safety Data Sheet
Issue Date: 27-Jan-2005 CHEMWATCH 4598-25
NA477ECP Version No:3
CD 2007/2 Page 24 of 27
Section 12 - ECOLOGICAL INFORMATION
Under aerobic conditions the material will degrade to water and carbon dioxide, while
under anaerobic processes it will produce water, methane and carbon dioxide.
Based on test results, as well as theoretical considerations, the potential for
bioaccumulation may be high. Toxic effects are often observed in species such as blue
mussel, daphnia, freshwater green algae, marine copepods and amphipods.
Drinking Water Standards:
hydrocarbon total: 10 ug/l (UK max.).
DO NOT discharge into sewer or waterways.
Section 13 - DISPOSAL CONSIDERATIONS
路 Consult State Land Waste Management Authority for disposal.
路 Discharge contents of damaged aerosol cans at an approved site.
路 Allow small quantities to evaporate.
路 DO NOT incinerate or puncture aerosol cans.
路 Bury residues and emptied aerosol cans at an approved site.
Section 14 - TRANSPORTATION INFORMATION
Labels Required: FLAMMABLE GAS
HAZCHEM: 2Y
UNDG:
Dangerous Goods Class: 2.1 Subrisk: None
UN Number: 1950 Packing Group: None
Shipping Name:AEROSOLS
Air Transport IATA:
ICAO/IATA Class: 2.1 ICAO/IATA Subrisk: None
UN/ID Number: 1950 Packing Group: None
ERG Code: 10L
Shipping name:AEROSOLS
Maritime Transport IMDG:
IMDG Class: 2.1 IMDG Subrisk: SP63
UN Number: 1950 Packing Group: None
EMS Number: F- D, S- U Marine Pollutant: Not Determined
Shipping name:AEROSOLS
Section 15 - REGULATORY INFORMATION
REGULATIONS
0893 349 005 - Wurth Lacquer Spray Black Stain (CAS No: None):
No regulations applicable
continued...
0893 349 005 - WURTH LACQUER SPRAY BLACK STAIN
Chemwatch Material Safety Data Sheet
Issue Date: 27-Jan-2005 CHEMWATCH 4598-25
NA477ECP Version No:3
CD 2007/2 Page 25 of 27
Section 15 - REGULATORY INFORMATION
acetone (CAS: 67-64-1) is found on the following regulatory lists;
IMO MARPOL 73/78 (Annex II) - List of Other Liquid Substances
New Zealand Hazardous Substances Transfer Notice 2004 - Schedule I, List of Substances (Dangerous Goods) to be transferred
New Zealand Poisons Schedule
New Zealand Transferred List of Single Component Substances
New Zealand Workplace Exposure Standards (WES)
OECD Representative List of High Production Volume (HPV) Chemicals
United Nations Convention Against Illicit Traffic in Narcotic Drugs and Psychotropic Substances - Table II
United Nations List of Precursors and Chemicals Frequently used in the Illicit Manufacture of Narcotic Drugs and Psychotropic Substances Under International
Control - Table II
n-butyl acetate (CAS: 123-86-4) is found on the following regulatory lists;
IMO MARPOL 73/78 (Annex II) - List of Noxious Liquid Substances Carried in Bulk
International Council of Chemical Associations (ICCA) - High Production Volume List
New Zealand Hazardous Substances Transfer Notice 2004 - Schedule I, List of Substances (Dangerous Goods) to be transferred
New Zealand Transferred List of Single Component Substances
New Zealand Workplace Exposure Standards (WES)
OECD Representative List of High Production Volume (HPV) Chemicals
United Nations Convention Against Illicit Traffic in Narcotic Drugs and Psychotropic Substances - Table II
propylene glycol monomethyl ether acetate, alpha-isomer (CAS: 108-65-6) is found on the following regulatory lists;
International Council of Chemical Associations (ICCA) - High Production Volume List
New Zealand Hazardous Substances Transfer Notice 2004 - Schedule I, List of Substances (Dangerous Goods) to be transferred
New Zealand Transferred List of Single Component Substances
New Zealand Workplace Exposure Standards (WES)
OECD Representative List of High Production Volume (HPV) Chemicals
isopropanol (CAS: 67-63-0) is found on the following regulatory lists;
IMO MARPOL 73/78 (Annex II) - List of Other Liquid Substances
International Agency for Research on Cancer (IARC) Carcinogens
New Zealand Hazardous Substances Transfer Notice 2004 - Schedule I, List of Substances (Dangerous Goods) to be transferred
New Zealand Transferred List of Single Component Substances
New Zealand Workplace Exposure Standards (WES)
OECD Representative List of High Production Volume (HPV) Chemicals
xylene (CAS: 1330-20-7) is found on the following regulatory lists;
IMO MARPOL 73/78 (Annex II) - List of Noxious Liquid Substances Carried in Bulk
International Agency for Research on Cancer (IARC) Carcinogens
International Council of Chemical Associations (ICCA) - High Production Volume List
New Zealand Biological Exposure Indices
New Zealand Hazardous Substances Transfer Notice 2004 - Schedule I, List of Substances (Dangerous Goods) to be transferred
New Zealand Poisons Schedule
New Zealand Transferred List of Single Component Substances
New Zealand Workplace Exposure Standards (WES)
OECD Representative List of High Production Volume (HPV) Chemicals
WHO Guidelines for Drinking-water Quality - Guideline values for chemicals that are of health significance in drinking-water
toluene (CAS: 108-88-3) is found on the following regulatory lists;
IMO MARPOL 73/78 (Annex II) - List of Noxious Liquid Substances Carried in Bulk
International Agency for Research on Cancer (IARC) Carcinogens
New Zealand Hazardous Substances Transfer Notice 2004 - Schedule I, List of Substances (Dangerous Goods) to be transferred
New Zealand Poisons Schedule
New Zealand Transferred List of Single Component Substances
New Zealand Workplace Exposure Standards (WES)
OECD Representative List of High Production Volume (HPV) Chemicals
United Nations Convention Against Illicit Traffic in Narcotic Drugs and Psychotropic Substances - Table II
United Nations List of Precursors and Chemicals Frequently used in the Illicit Manufacture of Narcotic Drugs and Psychotropic Substances Under International
Control - Table II
WHO Guidelines for Drinking-water Quality - Guideline values for chemicals that are of health significance in drinking-water
butyl benzyl phthalate (CAS: 85-68-7) is found on the following regulatory lists;
IMO MARPOL 73/78 (Annex II) - List of Noxious Liquid Substances Carried in Bulk
International Agency for Research on Cancer (IARC) Carcinogens
New Zealand Transferred List of Single Component Substances
New Zealand Workplace Exposure Standards (WES)
OECD Representative List of High Production Volume (HPV) Chemicals
OSPAR List of Substances of Possible Concern
hydrocarbon propellant (CAS: 68476-85-7) is found on the following regulatory lists;
New Zealand Hazardous Substances Transfer Notice 2004 - Schedule I, List of Substances (Dangerous Goods) to be transferred
New Zealand Transferred List of Single Component Substances
New Zealand Workplace Exposure Standards (WES)
OECD Representative List of High Production Volume (HPV) Chemicals
hydrocarbon propellant (CAS: 68476-86-8) is found on the following regulatory lists;
OECD Representative List of High Production Volume (HPV) Chemicals
No data available for propylene glycol monomethyl ether acetate, alpha-isomer as CAS: 84540-57-8.
Specific advice on controls required for materials used in
New Zealand can be found at
http://www.ermanz.govt.nz/search/registers.html
continued...
0893 349 005 - WURTH LACQUER SPRAY BLACK STAIN
Chemwatch Material Safety Data Sheet
Issue Date: 27-Jan-2005 CHEMWATCH 4598-25
NA477ECP Version No:3
CD 2007/2 Page 26 of 27
Section 16 - OTHER INFORMATION
NEW ZEALAND POISONS INFORMATION CENTRE
0800 POISON (0800 764 766)
NZ EMERGENCY SERVICES: 111
Denmark Advisory list for selfclassification of dangerous substances
Substance CAS Suggested codes
butyl benzyl phthalate 85- 68- 7 N; R50/53
INGREDIENTS WITH MULTIPLE CAS NUMBERS
Ingredient Name CAS
propylene glycol monomethyl ether acetate, 108- 65- 6, 84540- 57- 8
alpha- isomer
hydrocarbon propellant 68476- 85- 7, 68476- 86- 8
REPRODUCTIVE HEALTH GUIDELINES
Ingredient ORG UF Endpoi CR Adeq
nt TLV
xylene 1.5 mg/m3 10 D NA -
toluene 9.6 mg/m3 10 D NA -
These exposure guidelines have been derived from a screening level of risk assessment and
should not be construed as unequivocally safe limits. ORGS represent an 8-hour time
-weighted average unless specified otherwise.
CR = Cancer Risk/10000; UF = Uncertainty factor:
TLV believed to be adequate to protect reproductive health:
LOD: Limit of detection
Toxic endpoints have also been identified as:
D = Developmental; R = Reproductive; TC = Transplacental carcinogen
Jankovic J., Drake F.: A Screening Method for Occupational Reproductive
American Industrial Hygiene Association Journal 57: 641-649 (1996).
EXPOSURE STANDARD FOR MIXTURES
"Worst Case" computer-aided prediction of spray/ mist or fume/ dust components and
concentration:
Composite Exposure Standard for Mixture (TWA) :3 mg/m鲁.
Operations which produce a spray/mist or fume/dust, introduce particulates to the
breathing zone.
If the breathing zone concentration of ANY of the components listed below is exceeded,
"Worst Case" considerations deem the individual to be overexposed.
Component Breathing Zone ppm Breathing Zone mg/m3 Mixture Conc (%).
Component Breathing Zone Mixture Conc
(mg/m鲁) (%)
butyl benzyl phthalate 3.0000 10.0
Classification of the preparation and its individual components has drawn on official and
authoritative sources as well as independent review by the Chemwatch Classification
committee using available literature references.
This document is copyright. Apart from any fair dealing for the purposes of
private study, research, review or criticism, as permitted under the Copyright
Act, no part may be reproduced by any process without written permission from
continued...
0893 349 005 - WURTH LACQUER SPRAY BLACK STAIN
Chemwatch Material Safety Data Sheet
Issue Date: 27-Jan-2005 CHEMWATCH 4598-25
NA477ECP Version No:3
CD 2007/2 Page 27 of 27
Section 16 - OTHER INFORMATION
CHEMWATCH. TEL (+61 3) 9572 4700.
Issue Date: 27-Jan-2005
Print Date: 24-Jul-2007
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