- - - - - - - - - - - - - - - - MATERIAL SAFETY DATA SHEET - - - - - - - - - - - - - - -
Butcher COMMAND CENTER ACID-FREE WASHROOM CLEANER
CONCENTRATE 16
BATH MATE Acid-Free Washroom Cleaner Concentrate INGESTION: Harmful if swallowed. May cause mouth, throat
Date Prepared: 10/26/2000 and stomach burns. Symptoms may include nausea, vomit-
Date Revised: 10/26/2000 ing, diarrhea, and severe stomach pain. May also cause
----------------------------------------------------------- central nervous system effects including headache,
1. PRODUCT AND COMPANY IDENTIFICATION dizziness and weakness.
----------------------------------------------------------- EFFECTS OF CHRONIC EXPOSURE: Prolonged or repeated contact
Product Name/Use: BATH MATE Acid-Free Washroom Cleaner can cause defatting and drying of the skin which may
Concentrate result in skin irritation and dermatitis (rash).
Product Synonyms: Command Center 16 BATH MATE Acid-Free MEDICAL CONDITIONS AGGRAVATED: May aggravate pre-existing
Washroom Cleaner Concentrate; Outpost 16 BATH MATE Acid- eye, skin and respiratory conditions.
Free Washroom Cleaner Concentrate; Command Center ACID- -----------------------------------------------------------
FREE WASHROOM CLEANER Concentrate 16; KDS 16 BATH MATE 4. FIRST AID MEASURES
Acid-Free Washroom Cleaner Concentrate; 16 BATH MATE -----------------------------------------------------------
Acid-Free Washroom Cleaner Concentrate EYES: Immediately flush eyes with plenty of water while
MANUFACTURER: The Butcher Company holding eyelids apart. After initial flushing, remove any
67 Forest Street contact lenses and continue flushing for at least 15
Marlborough, MA 01752-3012 minutes. Do not put any medication in the victim's eyes
Butcher Telephone Number: 800-225-9475 unless instructed by a physician. Get immediate medical
Emergency Telephone (24 hours): 800-228-5635 attention.
CHEMTREC (U.S./Can.): 800-424-9300 SKIN: Flush thoroughly with plenty of water, then wash with
CHEMTREC (Int'l): +1 703-527-3887 soap and water. Remove saturated clothing. Get medical
----------------------------------------------------------- attention if irritation develops or persists. Thoroughly
2. COMPOSITION / INFORMATION ON INGREDIENTS wash (or discard) clothing and shoes before reuse.
----------------------------------------------------------- INHALATION: Remove to fresh air. If not breathing, give
INGREDIENT(S) CAS NO. % BY WEIGHT respiration; if breathing is difficult, give oxygen (by
----------------------------------------------------------- trained personnel only). Get medical attention if
2-Butoxyethanol 111-76-2 25 - 40 symptoms persist.
Secondary alcohol ethoxylate 68131-40-8 10 - 25 INGESTION: Do not induce vomiting. Drink large quantities
Ethanolamine 141-43-5 7 - 10 of water. Get immediate medical attention. Never give
Fragrance NA 3-5 anything by mouth to an unconscious person.
Tetrasodium ethylenediamine -----------------------------------------------------------
tetraacetate 64-02-8 1 - 1.5 5. FIRE FIGHTING MEASURES
n-Alkyl dimethyl benzyl -----------------------------------------------------------
ammonium chloride 68424-85-1 0.25 - <1.0 FLASH POINT AND METHOD: >200 deg F 93 deg C TCC
Didecyl dimethyl ammonium FLAMMABLE LIMITS: Not applicable.
chloride 7173-51-5 0.1 - 0.5 AUTOIGNITION TEMPERATURE: Not applicable.
----------------------------------------------------------- EXTINGUISHING MEDIA: Use extinguishing media appropriate
See Section 8 for Exposure Limits for surrounding fire.
NA - Not Applicable HAZARDOUS COMBUSTION PRODUCTS: Normal products of
OSHA REGULATORY STATUS: This product is classified as combustion (carbon monoxide and carbon dioxide) and
hazardous under OSHA regulations. nitrogen oxides.
WHMIS CLASS: Class D- Division 2B FIRE AND EXPLOSION HAZARDS: None known.
----------------------------------------------------------- FIRE FIGHTING INSTRUCTIONS: This product is not flammable.
3. HAZARDS IDENTIFICATION As in any fire, MSHA/NIOSH approved self-contained
----------------------------------------------------------- breathing apparatus (SCBA) and full protective gear
EMERGENCY OVERVIEW Clear, Green Liquid. Fresh Odor. May should be worn.
Cause Eye Burns and Skin Irritation. Harmful if -----------------------------------------------------------
Swallowed. 6. ACCIDENTAL RELEASE MEASURES
POTENTIAL HEALTH EFFECTS (See Section 11 for Toxicological -----------------------------------------------------------
Information) See Section 8, Exposure Controls/Personal Protection and
PRIMARY ROUTE(s) OF EXPOSURE: Section 3, Hazard Identification. Floors may be slippery.
Eye: X Use care to avoid falling. Ventilate spill area. Contain
Skin Contact: X and isolate spill. Keep non-essential personnel from
Skin Absorption: X entering spill area. Use mop and absorbent to collect
Inhalation: X material for proper disposal. Rinse area with water.
Ingestion: X -----------------------------------------------------------
EFFECTS OF ACUTE EXPOSURE: 7. HANDLING AND STORAGE
EYES: May cause eye burns. Symptoms may include pain, -----------------------------------------------------------
tearing, redness, swelling, and eye injury. HANDLING: Follow label use directions. Do not mix with
SKIN: May cause skin irritation. Symptoms may include other chemicals unless instructed by label directions.
redness, rash and mild swelling. May be absorbed Avoid contact with eyes, skin, and clothing. Avoid
through the skin and may cause effects as described breathing vapor or mist. Wash thoroughly after handling.
under Inhalation (see below). Remove contaminated clothing. Wash clothing and equipment
INHALATION: High concentrations of vapor or mist may before reuse.
cause nose, throat and respiratory tract irritation. STORAGE: Keep container closed when not in use. Store away
Symptoms may include coughing, a burning sensation in from incompatible materials. (See Section 10, Stability
the nose and throat, and disagreeable metallic taste. and Reactivity).
May also cause central nervous system effects including
headache, dizziness and nausea.
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Butcher COMMAND CENTER ACID-FREE WASHROOM CLEANER
CONCENTRATE 16
----------------------------------------------------------- -----------------------------------------------------------
8. EXPOSURE CONTROLS / PERSONAL PROTECTION 11. TOXICOLOGICAL INFORMATION
----------------------------------------------------------- -----------------------------------------------------------
PERSONAL PROTECTIVE EQUIPMENT (PPE) ACUTE DATA: This product causes moderate skin irritation
EYE: Where eye contact is possible, wear chemical splash and may cause severe eye irritation or burns. Based on
goggles (ANSI Z87.1-approved). acute toxicity testing, this product may be harmful if
SKIN: Where skin contact is possible, chemical-resistant swallowed. It is not considered to be toxic by skin
clothing (e.g., gloves) should be worn. absorption or inhalation. Acute dermal overexposure to
RESPIRATORY: No respiratory protection is required if the secondary alcohol ethoxylate has caused inflammatory
general room ventilation is adequate and airborne changes of the lung in laboratory animals. Acute
concentrations are kept below exposure limits. When overexposure to high concentrations of 2-butoxyethanol by
exposure limits are exceeded, use appropriate skin absorption, ingestion and inhalation has caused
respiratory protection (NIOSH/MSHA) to prevent blood, liver and kidney effects in laboratory animals.
overexposure. The following data are available for this product and its
ENGINEERING CONTROLS: Good general room ventilation is ingredients:
expected to be adequate. If user operations generate -----------------------------------------------------------
vapor or mist, ventilation should be used to keep PRODUCT/ ORAL LD50 DERMAL LD50 INHALATION
airborne concentrations below exposure limits. INGREDIENT (rat) (rabbit) LC50 (rat)
EXPOSURE LIMITS: -----------------------------------------------------------
----------------------------------------------------------- BATH MATE Acid-Free
INGREDIENT(S) OSHA PEL/STEL ACGIH TLV/STEL Washroom Cleaner
----------------------------------------------------------- Concentrate 2400 mg/kg >2000 mg/kg >10.3 mg/L
2-Butoxyethanol 25ppm (120mg/m3)/ 25 ppm (121mg/m3)/ (4-hr)
(Skin) (Skin) 2-Butoxyethanol 470 mg/kg 220 mg/kg 450 ppm
Secondary alcohol (4-hr)
ethoxylate NA NA Secondary alcohol
Ethanolamine 3 ppm (8 mg/m3)/ 3 ppm (7.5mg/m3)/ ethoxylate 2380 - 2856 2000 mg/kg Not
6 ppm (15 mg/m3) 6 ppm (15 mg/m3) mg/kg Available
Fragrance NA NA Ethanolamine 1720 mg/kg 1018 mg/kg Not
Tetrasodium Available
ethylenediamine Fragrance Not Not Not
tetraacetate NA NA Available Available Available
n-Alkyl dimethyl Tetrasodium
benzyl ammonium ethylenediamine
chloride NA NA tetraacetate 3030 mg/kg >5000 mg/kg Not
Didecyl dimethyl Available
ammonium chloride NA NA n-Alkyl dimethyl
----------------------------------------------------------- benzyl ammonium
NA - Not Available chloride 366 - 400 645 - 3400 Not
----------------------------------------------------------- mg/kg mg/kg Available
9. PHYSICAL AND CHEMICAL PROPERTIES Didecyl dimethyl
----------------------------------------------------------- ammonium chloride 450 mg/kg 3342 mg/kg Not
PHYSICAL STATE: Liquid Available
ODOR: Fresh -----------------------------------------------------------
APPEARANCE: Clear, Green SENSITIZATION DATA: No data available.
pH: 11.0 to 12.2 CHRONIC DATA: Prolonged overexposure to high concentrations
PERCENT VOLATILE BY WEIGHT: 88 of ethanolamine by inhalation and ingestion has caused
VAPOR PRESSURE: Not Available liver and kidney effects in laboratory animals. Prolonged
VAPOR DENSITY: Not Available overexposure to high concentrations of 2-butoxyethanol by
BOILING POINT: Not Available skin absorption, ingestion and inhalation has caused
FREEZING/MELTING POINT: Not Available blood, liver and kidney effects in laboratory animals.
SOLUBILITY IN WATER: Complete REPRODUCTIVE/TERATOGENIC DATA: No data available.
EVAPORATION RATE: Not Available CARCINOGENIC/MUTAGENIC DATA: Not listed as carcinogenic by
SPECIFIC GRAVITY: 1.00 NTP, IARC, or ACGIH or regulated as a carcinogen by OSHA.
VISCOSITY: 20cps SYNERGISTIC MATERIALS: No data available.
OCTANOL/WATER PARTITION COEFFICIENT: Not Available -----------------------------------------------------------
ODOR THRESHOLD: Not Available 12. ECOLOGICAL INFORMATION
----------------------------------------------------------- -----------------------------------------------------------
10. STABILITY AND REACTIVITY No data available.
----------------------------------------------------------- -----------------------------------------------------------
STABILITY (CONDITIONS TO AVOID): Stable. 13. DISPOSAL CONSIDERATIONS
POLYMERIZATION: Will not occur. -----------------------------------------------------------
HAZARDOUS DECOMPOSITION: None known. Disposal of this material should be in accordance with
INCOMPATIBLE MATERIALS: Strong acids (e.g., hydrochloric), local, state or provincial and federal regulations. The
oxidizers (e.g., bleach) and sodium nitrite. unused product, as manufactured, may be a RCRA hazardous
waste in accordance with 40 CFR 261. The product's pH
should be verified prior to disposal. According to RCRA,
it is the responsibility of the waste generator to ensure
proper disposal.
-----------------------------------------------------------
14. TRANSPORT INFORMATION
-----------------------------------------------------------
DOT/TDG HAZARDOUS MATERIAL DESCRIPTION: Not regulated
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Butcher COMMAND CENTER ACID-FREE WASHROOM CLEANER
CONCENTRATE 16
----------------------------------------------------------- In Section 9: Odor (Group Field) for Vapor Pressure
15. REGULATORY INFORMATION (Group Field) for Vapor Pressure Density Odor
----------------------------------------------------------- Threshold (Group Field) for Boiling Point (Group
Not meant to be all-inclusiveselected regulations Field) for Freezing Point (Group Field) for
represented. Evaporation Rate Coeff Oil/Water
UNITED STATES In Section 10: Hazardous Decomposition Products
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION In Section 11: Toxicological
ACT) In Section 15: OSHA Hazard Comm. Rule WHMIS WHMIS Class
311/312 HAZARD CATEGORIES: Under 40 CFR 370.2, this APPROVED BY: EH&S/Regulatory Affairs
product meets the following hazard categories: APPROVAL DATE: 10/26/2000
Immediate, Delayed. MSDS No: 4101
313 REPORTABLE INGREDIENTS: 2-Butoxyethanol is subject -----------------------------------------------------------
to the reporting requirements of Section 313 of Title The information on this data sheet represents our current
III of the Superfund Amendments and Reauthorization data and best opinion as to the proper use in handling of
Act of 1986 and 40 CFR Part 372 under the chemical the product under normal foreseeable conditions. Any use of
category Glycol Ethers. this product which is not in conformance with this data
CERCLA (COMPREHENSIVE RESPONSE, COMPENSATION, AND sheet or product label, or which involves using the product
LIABILITY ACT) in combination with any other product or any other process
CERCLA REGULATORY: None of the ingredients in this is the responsibility of the user.
product are reportable under CERCLA. -----------------------------------------------------------
TSCA (TOXIC SUBSTANCE CONTROL ACT) DISCLAIMER OF EXPRESSED AND IMPLIED WARRANTIES:
TSCA STATUS: This product complies with all TSCA Although preparer and owner have taken reasonable
inventory requirements. care in the preparation of this document, we
USDA (U.S. DEPARTMENT OF AGRICULTURE): This product is extend no warranties and make no representation
authorized for use in federally inspected meat and as to the accuracy or completeness of the information
poultry plants. contained herein, and assume no responsibility
MASSACHUSETTS, NEW JERSEY, PENNSYLVANIA RIGHT-TO-KNOW: regarding the suitability of this information for
----------------------------------------------------------- the user's intended purposes or for the consequences
INGREDIENT(S) CAS NO. STATE LISTING of its use. Each user should make a determination as
----------------------------------------------------------- to the suitability of the information for their
Water 7732-18-5 Not Listed particular purpose(s). This MSDS is the most recent
2-Butoxyethanol 111-76-2 MA, NJ, PA received from the product manufacturer or
Secondary alcohol distributor.
ethoxylate 68131-40-8 Not Listed -----------------------------------------------------------
Ethanolamine 141-43-5 MA, NJ, PA COMPAS Code: 29250260
Fragrance NA Not Listed
-----------------------------------------------------------
NA - Not Applicable
-----------------------------------------------------------
CANADA
WHMIS (WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM):
Class D-Division 2B, eye and skin irritant; Class D-
Division 2B, chronic toxic effects. This product has
been classified in accordance with the hazard criteria
of the Canadian Controlled Products Regulations (CPR)
and the MSDS contains all the information required by
the CPR.
-----------------------------------------------------------
16. OTHER INFORMATION
-----------------------------------------------------------
HMIS RATING:
HEALTH * : 3
FLAMMABILITY: 0
REACTIVITY: 0
PERSONAL PROTECTION: -
NFPA RATING:
HEALTH: 2
FIRE: 0
REACTIVITY: 0
SPECIAL: -
MSDS STATUS
Revision #: 6
This MSDS replaces the January 04, 2000 MSDS. Any changes
in information are as follows:
In Section 1: Prepared By Date Prepared [ ] Print
CHEMTREC Phone Number
In Section 3: Potential Health Effects - Skin
Absorption Signs & Symptoms - Inhalation Signs &
Symptoms - Skin
Page 3 of 3
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