TIIE VALVOLII{ECOI'IPANY
DIVISION OF ASHLAI{D INC.
P,O. BOX 148@8,LEXINGTON, KY 4A51?
(605) 264-7080
pAGE: 1
ALL CtIl'tATE I @W3E
WITII 29 CFR 1gIE.IzEO (THE HAZARD
THIS I'TSDS
COMPTIES COI{I'IUNICATION
STANDARD)
TELEPIIONE:-880-ASHLAND 1-800-27 4-5?63
Z4-H0UREI1ERGENCY 1 0R
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PRODUCT
I{AI'IEI ALt CLII'IATE10t,J3CI
DATA sliEET No: 917A879-813.8A8
PREPARED; @4T13TJ5
SUPERSEDEST @2t1@/95
PRINTDATEI 84/13/95
SECTIONI-PRODUCTIDENTIFICATIBN
GENERAL GENERIC
OR ID: PETROLEUI'I
BASf,D-TUSRICATINS
OIt
DOT HAZARDCLASSIFICATION:NOTREGULATED
SECTION I I_CO}TPONENTS
iF PRESENT,IARC, I{TP ANOOSHACARCII{OGEI{S CHMICALS SUBJECITO THE REPORT-
AND
ING REQUIREI{ENTS SARATITLE III SECTION
OF 313 ARE IDENTIFIED IN THIS SECTION.
SEE DETINIIIOT{PAGEFORCTARIFICATION
s (Bv t,JT)
IlIGREDIENT NOTE
( r)
DETERGENT/DISPERSA}IT
ENGIT{E l0-r5
OIL PACKAGE
PETROLEIJ}ILUBE OIt 85-98 I 1\
\ LT
CAS f,: 6474?-65-@ PEL: 5 l'Ic/113 TLV: 5 l{C/t'13
( .I) I THIS PRODUCT
CONTAINS I'IAXIMU}'I IEE ZINC COMPOUNDS.
A OF ZINC CO},IPOUNNS
ARE REPORTABLE
UNDERSECTION313 OF SARATITTE III
( 2)I PEL/TLV IS FOROIL I'IIST. ACGIHSHORT LII'IIT (STEI) FoR oIL
TERI'I
EXPOSURE
MIST IS IE I'IG1CU}l.
CONIINUED PAGE: 2
ON
Att CLII{ATEI OW3O PAGE:2
SECTIONII1-PHYSICAL DATA
UEASURET'IENT
PROPERTY REFINEI'IENT
5 7 0 . 0 0 DEGF
rOR PRODUCT
BOILING POII{T
?98. B8 DEGC)
76E.EA
I MI{HG
85-90&
VAPOR PRESSURE ) 8,1@ llMHc
FOR COI{PONENT(
6E.OO CIEG F
7 A , A E D E GC)
SPECIFIC VAPORDEN$ITY LIGII?ER THANAIR
SPECIFICGRAVITY ,879
EO.EE BEG F
l 5 . 5 5 DEGC)
PERCENT
VOLATITES NOT APPTICABLE
EVAPORATION
RATE UNAVAILABLE
STATE TIQUID
SEC?IOII IV-FIRE AND EXPTOSION INFOR}IATIOI{
FLASH POINT(COC 438.CI DEGF
? 7 1, 1 n E GC )
EXPIOSIVE
LII'IIT UIIAVAILABTE
EXTTNGUTSHTNG REsutAR
MEDrA: FoAt't cARBoN
oR DroxIDE 0R nRy cHEI'trcAL
HAZARDOUS
DECOI'IpOSITIONPROOUCTSItlAY FORII:, CAREONDIOXIDE ANn CARBON
MONOXIDE, VARIOUS HYDROCARBONS, QXIDES OF SULFUR, NITROCEN AND
gTc.
PgosPH0Rus,
TIREFIGHTING PROCEDURESI WEAR SELF-CONTAINED
A BREATHING APPARATUS WITH A FULL
FACEPIECE OPERATED THE POSITIVE PRESSURE
IN DEI{AND WITH APPR0pRIATE
tIlODE
TURN-OUT GEARAND CHEMICAL RESISTAM PERSONAL PROTECTIVE EQUIP},IENT.
REFERTO THE PERSONAL PROTECTIVE EQUIPI'IENT
SECTION THIS IiISNS.
OF
WATER FOAI'I
OR I'IAY CAUSE FROTHING WHICHCAN BE VIOTENTAND POSSIBTY
ENDANCER LIFE OF THE FIREFIGHTER.
THE
DEI{SESI,IOKE
MAY BE GENERATED h'IIILE BURNINS.
SPECIALFIRE & EXPLOSION HAZARDS: NEVER USE WELDING CIIITING TORCH OR
OR ON
NEARDRIJI{(EVENE},IPTY) BECAUSE PRoDucT {gVE$ JusT RESIDUE)cAN IGNITE
EXPLOSIVELY.
NFPACODES: HEALTH- 1 FLAI'IMABIIITY- 1 REACTIVITY- E
CONTINUED PAGE: 3
ON
ALL CLIIIATE l Otd3E PAGE: 3
SECTIONV-HEALTHHAZARD
NATA
PERI'IISSIBLE
EXPOSURE
LIMIT: NOTESTABLISHED PRO$UC?. SEE SECTION
FOR II.
EFFECTS ACUTEOVEREXPOSUREI
OT
EYES - EXPOSURE NOT EXPECTED CAUSE
IS TO EYE IRRITATION OR INJURY.
SKIN - EXPOSURE CAUSE
I'IAY I'IILO SKIN IRRITATIOI{. PROTONGED REPEATED
OR
EXPOSURE DRY THE SKIN, SY}IPTOT{S INCLUDE
MAY I{AY REDNESS, EURNING,DRYIICC
ANDCRACKING, ANDSKIN BURNS. PRE-EXISTING SKIN DISORDERS BE}IAY
AGGRAVATED EXPOSURE THIS }IATERIAL,
BY TO
_
BREATHING EXPOSURE POSSISIE UNDER
IS CERTAINCONDITIONS I{ANDLI}IG
OF ANO USE
{8.G,/ DURING HEATINC, SPRIYING, OR STIRRING),
SYI'IPTOHSARE MORE TYPICAIIY SEENAT AIR CONCENTRATIONS EXCEEDI!{G THE
RECBI{I'IEI{DEDEXPOSURE LII{ITS. SYI'IpTOI{S EXPOSURE
OF I'IAY INCLUDEI
-IRRITATIO}I (NOSE,THROAT, RESPIRATORY TRACT)- PRE-EXISTING IUNG
DISOROERS, E.G, ASTHI'IA*LIKE CONDIrIONS,I'IAY BE AGGRAVATED EXPOSURE
EY TO
THIS },IATERIAL,
-
SWATTOWINGSINGTEDOSEORALTOXICITY IS LOr,t, SWALLOWII{G SMALTAt'tOtINTS
DURINGNORMAL ITANDLING NO? LIKELY TO CAUSEHARI'IFUL
IS EFFECTS; S?IALLOIiINC
LARGEAI'IOUI{fS}lAY BE I{AR}IFUL.
SYMPTOMS }IAY INCLUDEI
-GASTROII{TESTINAI, _
IBRITATION (I{AUSEA,VOI'IITING, OIARRHEA)
-ABDOI'IINAL PAIN-
FIRST AID:
IF ON $KIT{: RE{OVECONTAMINATED CLOTHII{G. WASH EXPOSED AREAWITH soAP ANo
WATER, IF SY}TPTO}IS PIRSIS?, SEEKIIISDICALATTENTION. LAUNDER CLOTHING
BEFORE REUSE,
IF IN EYES: IF SYMPTOI-ISDEVELOP, }!OVE INOIVIOVALAWAY FROM EXPOSURE AND INTO
FRESH AIR. FLUSHEYESGEI|TLYWITH TTIATER WIIILE HOLDINGEYELI0S APART, IF
SYMPTOI'ISPERSISTOR THEREIS ANY VISUAL DIFFICULTY, SEEKTTEDICAL
ATTENTlON.
IF SWATLOWEDI NOT INDUCE
DO VOI'IITING. THIS I'IATERIALIS AN ASpIRATIONHAZARD,
IF INDIVIDUAL IS DROWSY UNCONSCIOUS,
OR PLACEON ttTT SIDE I'ITH THE HEAD
NOWN. SEEK}'TEDICAL ATTENTION. IF POSSIBLE, DO NOT TEAVSINDIVIDUAL
UNATTENNED.
IF BREATHED: SYMPTOMS
IF DEVELOP,II'IMEDIATELY MOVEINDIVIDUAL AWAY FROM
EXPOSURE AND INTO FRESttAIR, SEEK IIIHEDIATE}IEDICAI ATTENTION; KEEP
PERSON WARI'I
AND QUIET. IT PERSON NOT BREATHII{G,
IS BI$IN ARTIFICIAL
RESPIRATIOI{. IF SREATIIING DIFFICUTT, AD}IINISTER
IS OXYGEN.
EFFECTS CHRONIC
OF OVEREXPOSURE:
NONE CURRENTLYKNOWNFOR THE PRODUCT.
USED }IOTOR OIL IIAS EEEN SHOI9NTO CAUSE SXIN CANCER IN TABORATORYANII{ALS
CONTINUALLYEXPOSEDBY REPEATEDAPPTICATIONS,AVO]D PROIOI{GEDOR REPEATED
SKIN CONTACT.
CONTII{UED PAGI: 4
ON
PAGEr
4
AtL CIII'IATE I OW3E
SECTION VI -REACTIVITY DATA
HAZARUOUSPOTYI'IERIZATION:
CANNOT OCCUR
STAEILITY: $TABLE
INCOMPATIBITITYTAVOID COI{TACT
vtITHr, STROT{G
OXIDIUINS AGENTS
SECTION VII-SPILL OR LEAK PROCEDURES
STEPS TO BE TAKEN IN CASE IIATERIAI IS RELEASEOOR SPIIIED:
S}TALI SPILL: ABSORB tlQUID ON VER}IICULITE, FTOOR ABSORBENT OTHER
OR ABSORBENT
I{ATERIAt.
LARGESPILL: PREVEI{T RUN-OFF?O SEWSRS/ STREAMS OT1IER BODIES OF IIATER, IF
OR
RUN-OFF CICCURS, NO?ITY PROPERA{.TTHORITIES REQUIRED,
AS ?HAT A SPILL HAS
OCCURED.
PERSONS NOT {.'EARII{GPNOTEC?IVEEQUIPI'IENT
SHOULD EXCTUDED FROI{AREA OF
BE
SPILL UNTIL CLEAN-UP HAS BEENCOI'IPLETED.
STOPSPILL AT SOURCE, DIKE AREA
OF SPItt TO PREVENT SPREADING,PtIMPTIQUID TO SATVAGE TAI{K. REMAINING
LIQUID I'IAY 8E TAITEN ON SAND, CLAY, EARTHI FLOOR
UP ABSORBENT, OTHER
OR
ABSORBENT }IATERIAI AI{O SHOVETEOINTO CONTAINERS.
WASTEDISPOSAL
HETHOO:
SI{AIL SPIttI DISPOSEOF IN ACCORDANCS
WITH Att tOCAt, STATEAN! FEDERAL
REGULATIONS.
LARGESPrLL: DISPOSE OF rN ACCORDAT{CE ALL APPLTCAELE
WrTH tOCAt, STATEAND
FEDERAL REGULATIONS,
SECTIONVIII-PROTECTIVE EQUIPI'IENT BE USED
TO
RESPIRATORY PBOTECTION: NOT REQUIRED UNDER NORI'IAL
COI{DITIONSOF USE. HSUEVER,
IF OIt MISTS ARE GENERATED ABOVE RECOI'IMENDED
PEL/TLV OF 5 }1GIM3, THENA
NIOSH/}'ISIIA
AP}ROVEO RESPIRATOR ADVISEDIN ABSENCE PROPER
IS OF
CONTSOI, (SEE YOURINDUSTRIAL
EIWIRONI'IENTAL HYGIENIST).
VENTIIATION: NOT REQUIRED UI{DERNORI,TAL CONDITIONS USE. IIolltEvER, IF UI{USUAI
OF
OPERATING COIIDITIONS (CENERAL
EXIST, THXNPROVIDE SUFFICIENTMECHANICAT
ANDIORLOCATEXI{AUST) VENTITATION }IAINTAIN NXPOSURE PEt/TtV (S).
TO BELO{d
PROTECTIVE GLOVES:NOT NORt'tALLy REOUIRED, HOWEVER, WEAR RESISTANT GLOVES SUCH
AS NITRILE RUBBER PREVENT
TO IRRITATION WHICXI'IAY RESUTT FROI'I
PROTOI{GED
OR REPEATED SKIN CONTACT WITH PRODUCT.
EYE PRCITECTIONI REQUIRED
NOT UNOER NORI'IAL CO}TDITIO}IS usE. IIO!''EVER,
oF IF
MISTING OR SPLASHING COT{DITIONS EXISTT T}TEN SAFETYGLASSES CHE}IICAL
OR
SPTASH GOGGLES ADVISED.
ARE
OTIIERPROTEC?IVE EQUIPMENTI NORI'TAL
!{ORKCTOTHING COVERING ARMS AND LEGs,
CO$TINUED PAGE; 5
ON
ALL CLII'IATEI OW3O PAGEr 5
SECTIONIX-SPECIAL PRECAUTIONS OTHER
OR COI,I}IENTS
COI{TAII{ERS TIIIS }TATERIAL
OF i{HENH'IPTIED,SINCE${PTIED
I'IAY 8E HAZARDOUS
(VApOR,LrQUrD, AND/OR
C0NTAINERS RETAINPROOUCT RESIDUES SOLID), ALL
HAZARD PRECAUTIOUS GIVEN IN THE DATA SHEETT,IUST OBSERVED,
BX
THE INFORMATION ACCUI{ULATEDHEREINIS BETIEVEDT! BE ACCURATE BUT IS NOT
WARRANTED EE WHETHER
TO ORICINATING I{ITI TIIE COMPAI{Y NOT. RECIPIENTS
OR
ARE ADVISEDTO CONFIRI{IN ADVA}-ICE NEEDTHAT THE INFORI'IATION
OF IS
CURRENT, APPLICAELE,AIID SUITABLETO TI{EIR CIRCUI{STANCES.
SECTIONX-LABEL II{FOR}IA?IOII
CAUTION!
I{AY CAUSESLIGHT EYE IRRITATION.
PROLO!{CED REPEATED
OR CONTACT MAYCAUSE SKIN DISORDERS,
INHALATION OIt }1IS? I'IAYCAUSE
OF RESPIRATORY IRRITATION.
SWALLOWING CAUSESTO}IACH
I.IAY CRAI'IPS
ANB DIARRHEA.
HANDLING STORAGEI
&
AVOIN COI{TACTWITII EYESAI{D SKII{. WEAR SAFETYGTASSES SOGGLES,
OR
RESISTANTGLOVES,AND OTHER APPROPRIATE PROTECTIVE EQUIPI'IENT
ESSET{1IAI
FOR YOUROPERATIOT. KEEP WORKPTACE AIRSORITE CONCEI{TRATIONS
BELOI{LEGAL
AND RECOUI4ENDEDLII'IITS. USE NIOSH-APPROVEDRESPIRATOR EXPOSED OIL
IF TO
I{IST. OO NOT TRA{STER UNLABELED
TO CONTAINER. DO NOT USE CUTTINGOR
}'ELDINGT0RCIIoN THIS CDNTAINER EMPTY) BEFORIUsE, REvIHlt
,
TEVEN
MATERIATSAFETYDATA SHEETFOR I'IOREDETAITED INFOR}IATION,INCLUDII{G
CHRONIC IiEALTHETFECTS.
FIR$T AID:
EYES: FLUSHTI{OROUGHIY WITI{ WATER. GET I'IEDICALATTENTION IRRITATION
IF
PERSISTS.
SKIN: WASH EXPOSEDAREASWITH SOAPAND WATER.GET MEDICALATTENTION SKIN
IF
DISORDERS DEVELOP.
INHALATION: IF AFFECTED OIL }1IST, REI'IOVE FRESH
BY To AIR,
INGESTION:DO NOT INDUCEVOI,TITING.CAtt A PEYSICIANoR PoISoN coNTRoL
CENTER I}IMEDIATELY,
CHRONICINFORI{ATION;
OVEREXPOSURE CURRENTLYUNKNOWN THE PRODUCT. CAUTIONT USEDI'TOTOR
FOR OIL
HAS SEEN SHOWN CAUSXSKIN CANCER CERTAINLABORATORY
TO IN ANII'IAIS
CONTINUALLY EXPOSED USEDMOTOR
TO OIL BY REPEATED
APPLICATIONS. AVOID
PRoLoNGEo REPEATED coNTAcr ro sKDf. CONTAINS:pETRotEUuorl AND
oR
PROPRIETARY ENGINEOIL ADDITIVES.
)t** COIIIPONENTS ***
APPEAR IN SECTION JI
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