{L h'zt<
fl
ffi iltatrerrrrrilf Ese{f ilirrfl ilrilitisrtsrr*'a,Ifo--(Ei'
Ifl
E'ffi-r-r-' ",^[?Xi!%ii"3'=
AND
fmwt.erys,mmqrtnqffieM CHEMICALS
NATURAL PROCESSED
,ANDSYNTHETIC
154 S. LIVINGSTON AVE., PO. BOX 1O4, LIVINGSTON, NJ O7O39 U.S.A.
TELEPHONE: (2O1) 994-3650 FAX: QOI) 994-3A47
IVIATERIALSAFETY DATA SHEET
'Io Standards.
cornplywith OSI-tA's29 CFR 1910.1200 Bill No. 70 WI.IMISllazardCommunications
an
of Product and Producer
Identity
I.
SECTION
Datellepared: October17,1997
TradeName: Blackbinl,Bamard
CAS NUMBtrR 1332-58-7
Name: BALL CLAY, llydrous AluminumSilicate
Chernical
'I'ELEPIIONE CONTACT
EMERGENCY
NUMBERS
NAME AND ADDI{ESS
PT{ODUCERS
CHEMTREC800424-9300*
973-994-3650
Harnmill & Gillespie,Inc.
FAX
973-994-3847
P. O. Box lM
Livingston,NJ 07039 'To be used onlv io the evcnt of chemical
emergencies invtilving a spill, Ieak, fire
erposurer or accident i[volvilg chcmicalc.
Hazardous Ingredients
SECTION II.
FreeSilica(Quartz)* CASNo. 14808-60-7
Typicallyl0-30%o
Typicallylessrhan2.6Vo CAS No. 13463-67-7
TitaniumDioxide
tBall clayscontaincryslallirresilica. as quartz,up to 30% by dry weiglrl Someof lhis silica is not tine eDough nomatly be coosidered
to respirabla
:r " 1
Physical Data
SECTION III.
2.4 - 2.65
1569-1785"C. Specific Gravity:
tr-usion Range:
Solubility in Water: Negligible Percent Volatile: Below 100oC.
None
Vapor Pressure: NotApplicable 3.5-7.5
PII:
EarLhyodor wben wet, raw color light gray to brown
Odor and Appearance:
Fire and Explosion llata: Non-flammable
SECTION IV.
Health Hazard Data
V.
SECTION
IlespirableCrysurllineQuartz(I'WA-TLV) = 0.1n9/ur3
OSIIA PllL:
Quartz(TWA-TLV) = 0.1m9/m3
ACGIH: Crystallirre
Respirable
& Tridymite(seestability)fftVA-TLV) = 0.05m9m3
Crystobdite
CrystnllincQuartz= 0.05mg/in3
NIOSH TIVA: Respirable
ROUTE O!' DN'[RY: luhalatiorr
'l'ltis
llliAl.l'H IIAZARDS: WAIINING: clay product conudns crystallirrc
silicawhictrInaycause respiratory
disetuc(silicosis) itiltalcdovera prolonged pcriul of lirne. Avoitl breathing
it dust. UseNIOSIVMSIIA approved respirator
wherelLV for crystallinesilica may be exceetlcrl.
IARC MONOGRAPIIVOI-UME 68,1997 concludes dtere sufficient
tlnt is evidence inlrale
Oat silicacauses
crystalline
c:ulcer humans.IARC classi{icatiou:
in GroupI.
I'he NIP, in the Sixth Annuallteporton Carciuogens, 1991, added
has crystalline silica to its list of substances are
tlnt.
"reasonably anticipated becarcinogerr."
to
WARNING: l'ltis productcontainsl'itattiun DioxideOiOr. hrlralation rnaycause darnage respiratory
to system.
Identifiedasa potential carcturogen NIOSII. OSI{A TWA for TiO2 is 15mg/u8.
by
FIITST AID: lCyes: Fluslt thorougltlywith waterfor 10 to 15 rninutes.Contactphysicianif initaion persists.
Ilreathing: If brcatling difliculty develops, relnoveto freshair. If breathing
physician.
L:i**:鈧?
i'i" H*jr+ilrclv
SglcTi{ifxl
cSlstal
freequartzciurchautge
stability: tlall clay is surblcundcrordinarycorxlitions.wlren cxgrscrlto high tclnpcr:rturcs,
healtl hazurlsthanquaru.
whichlravegrcater
g70'c.) or crisobalite(above1470"C.)
stfucture fonn uirJynito(abovc
to
llazardous ltolymerization: Will not occur
Incompatibility (Materials avoitl) - None
to
minilnizing dust. Do ttot
Action to lrc taken in case material is releasedor spilled: Cleanup artdcollect,
respirator.
DusL Wearan approved
recommended or'ILV. Avoicl Breathing
PEL
exceed
slippery'
CAUTION: When wateris applied,productbecornes
Under RCRA (40 CFR
lVaste DisposalMegrod: Follow fe4eral,stae antl local regulations solid wastedisposal.
for
waste.
Part26l) ball clay is not a hazar
Conmrunity Right to Know: California's Proposition lists crystallincsilica as a carcinogen.
65
hygiene. Wasbhandsprior to eating'
slipperywhenwel Usegoul personal
Other precautions: productbecomes
Special Protection Information
SECTION YIII.
method.
Ventilation: Recommended
use
recommended or ILV for shorttirnedurations,
PEL
exceed
Respiratory lrrotection: lf tlust concenlratiors
respirators.
coatings, NIOSH/IvlSllAdust/mist
use
wet
dustrcspimtors.If spraying
NIOSHA4SIIAapprovetl
not
lenses
exist. NIOSH recommends contract
that
Eye l'rotection: Wear tiglrt httiilg goggles high dustcollcentraLiotls
it
be worn whenworking with cryslallinesilica.
zutd/or
engineering
by feasible
otler: l. Dustexgrsurelevelsiu excess appropriate or TLV shoultlbereduced
PEL
of
conlrols.
inistrative
atlm
Practice
package,"standard
obrain copyof thoAS]M E ll32 infonnation
a
2. It is rccolnrnepded theemployer
rhat
Dust''.
to
ExposllrB Quartz
Relating Occupational
to
for Ilealth Requirernents
safework habitswlrcn
training-in
aPproPnltg
penonnet receive
,equilethatexirosed
3. Crovemmeriiregulations
or TLV.
existsfor exceeding PEL
the
workilg with crysialtinesilicawhere0repotential
Special Precautions
SECTION IX.
TLV or PEL.
dust. TWA shouldtrot exceed
Milimize dustgeneration exposure.Do not breathe
and
cryslallinesilica
nCGII.l recommenGpcriulic plrysicalexaminations tlpse employees areexposed respirable
to
wbo
for
PEL.
levelsgreaterlhan504o theTLV or
of
Traceamounts rlioxins havebeendetectexl parrsper trillion (ppt).
in
of
untlerDOT regulations.
Ball clay is not lrazardous
presence tridymite
of
possible
sltouldrecognize
wl19crushantl grintl ceralnichxlies fired lo high temp鈧瑀atures
Manufacturers
thanquartz.
bavegreaterhealthhazards
and/orcrisobalitewhich
ffiornrrlendatiornrccordctlltereinercbelievedtobcaccurate.I-Ialrunill&Gillespie'lnc.makesno
may
tlrcretoanddisclaimsatl liability ftom relianceilrereon. Standards
warralty, eitherexpresse
or
-U.S.iurisdictions.Follow applicableguidelines.
in difll
|