Material,,Safety Sheet
Data
Acc#os6eo
O
Section I - Chemica$
Prsduct and CornpanlrXdentification
FfSDS Name+CryS,tru,$$$dt*.$S;M!f,rae
Catalog Numbers: 573250,573253,573268,573268-L,573269,573259-1, 573269-3,
573271,
8P345-500, C489-1,C489-10, C493-3,C/+93-
C489-500, C490-3,C493-10,C493-100.
C490-10,
500,c494,c494-12,C494-2t2, C49425018,C496L2, C495212,573250-1
C494-500,
Synonyms: BlueVitriol
Cornpany trdentification r
FisherScientific
1 Reagent Lane
Fairl-awn.Nl 07410
For information, call : 201-796-7100
Emergency Number: 201-796-7100
For CHEMTREC assistance, calN:800-424-9300
For Internatlonal CHEMTREC assistane, call: 703-527-3887
Sectisn 2 * Compositionn
Information on Ingredfents
fAs# fhenricnl llmle tIilTCS/ETINCS
PGfaGfit
lopoer (II) sulfate oentahvdrate ca.100 unlisted
7758-99-8
Hazard Symbols: XN N
Risk Phrases: 22 36/38 50/53
Sectlon 3 * Hazardslden$fication
I
Appearance: Air Warning! ftarmfulif swallowed.
bluecrystals. sensitive. Causes and
digestive
tract irritationwith possible
burns.Causes and skin irritationand possible
respiratory eye burns.
l-Nyg
roscopic.Possi sensitizer.
ble
Target Organs: Blood,kidneys,liver.
Potential Health Efrects
Eyel Exposure particufates solutionmay causeconjunctivitis,ulceration,and comeal
to or
eye irritationand possible
abnormalities" Causes burns.
Skin: Maycauseskin sensitization, allergicreaction,whichbecomes
an evidentupon re-exposure
skin irritafion and possiblebums. May causeitching eeema.
to this material.Causes
Maycauseseveregastrointestinal
Ingestion: Harmfulif swallowed. tract irritationwith nausea,
vomitingand possible burns.Ingestionof largeamountsof coppersattsmay causebloodystools
jaundiceand coma.Ingestionof coppercompounds
and vomit, low bloodpressure, may Froduce
toxic efFects the kidneyand liver and centralnervousexcitation
systemic to followedby depression.
and perforation the nasalseptumif inhaledin excessive
Inhalation: Maycauseulceration of
quantities. tract irritationwith possible
Causes respiratory burns.
Chronic: Prolonged repeated eye contactmay causeconjunctivitis. Maycauseliver and kidney
or
damage.Maycauseanemiaand other bloodcell abnormalities. wlth Wilson's
Individuals disease
copper.Thus,copperaccumulates varioustissuesand may resultin
in
are unableto metabolize
effecb. !,lay
have resultedin mutagenic
liver, kidney,and braindamage.Laboratory experiments
copperpoisoning man is recognized in
in
causeallergicskin reactionin some individuals.
Chronic
the form of Wilson'sdisease.
Section4 - First Aid Measur鈧瑂
flusheyeswith plentyof waterfor at least15 minutes,occasionally liftingthe
Eyes: Immediately
upperand lowereyelids.Get medical aid.
aid" Flushskin with plentyof soapand waterfor at least 15 rninuteswhile
Skin: Get medical
clothingand shoes.Washclothingbeforereuse.
removingcontaminated
Ingestionl Do NOTinducevomiting.lf victim is conscious atert,give 2-4 cupfulsof milk or
and
person.Get rnedical immediately.
water. Nevergive anythingby mouthto an unconscious aid
from exposure freshair immediately. breathing difficult,give oxygen.
If is
Inhalationr Remove to
has ceased
resuscitation. breathing applyartificial
aid. Do NOTuse mouth-to-mouth If
Get medical
devicesuchas a bag and a mask.
usingoxygenand a suitablemechanical
respiration
witft Wilson'sdisease moresusceptible chroniccopper
to
Notes to Physician: Individuals are
poisoning.
agentshouldbe determined qualified
by
Antidote: The use of d-Penicillamine a chelating
as
medicalpersonnel.
$ection 5 - Fire Fighting Measures
i
i
apparatus presure-
General lnformation: As in any fire, wear a self-contained in
breathing
and full protectivegear. Duringa fire, irritating
(approved equivalent),
demand,MSHA/NIOSH or
and highlytoxic gasesmay be generated thermaldecornposition combustion. is
by or Substance
particlesizeis capable creating
quantityand reduced
noncombustible. materialin sufficient
This of
a dust explosion.
mediamost appropriate the surrounding
for fire. Use
Extinguishing lledia: Useextinguishing
water spray,dry chernical. foam.
carbondioxide,or appropriate
Flash Pointr Not applicahle.
Autoignition Temperature; Not applicable.
Explosion Limits, Lower:Not available.
Upper: Not available.
[{FPARating: (estimated) Health:2; Flammability: Instability: 0
0;
Sect$on - Accldentaf Re$ease
i Measules
6
General Informationr Use properpersonalprotectiveequipmentas indicatedin Section8.
SpillslLeaks: Vacuumor sweepup materialand placeinto a suitabledisposal Cleanup
container.
spllls immediately,obseruingprecaultions the ProtectiveEquipmentsection.Avoid generating
in
Provideventilation.
Place underan inert atmosphere.
dusty conditions.
Section7 - Handtingand Stonage
I
Handling: Washthoroughly after handling.Remove clothingand washbeforereuse.
contaminated
dust generation
Useonly in a well-ventilated area. Minimize and accurnulation. Avoidcontactwith
eyes,skin, and clothing.Keepcontainer tightly closed.Avoidingestion and inhalation. not
Do
Storeprotected
ingestor inhale.Handle underan inert atmosphere" from air.
Storage: Store in a tightly closedcontainer"Store in a cool, dry, well-ventilatedarea away from
substances. not expose air, Store protected
from moisture.Storeunderan inert
to
Do
incompatible
atmosphere.
I
v I Section8-ExposureControls,Personat
Protection
i
with an
storingor utilizingthis materialshouldbe equipped
Engineering Controls: Facilities
keepairbomeconcentrations
ventilationto
facilityand a safetyshower.Useadequate
eyewash
Now.
Expozure Umits
OS}IA - Find PEts
lrlg$l
Chem*cal Hsre AC,G$i
Copper (II) sulfate none listecl
nonelisted
nonelisted
pentahydrate
OStfA Vacated PELsI Copper(II) sulfate pentahydrate:No OSHAVacatedPE[sare listed for this
chemical.
Personal Protective Equipment
Eyes: Wear appropriateprotectiveeyeglasses chemicalsafety gogglesas describedby OSHA's
or
eye and face protection EN166.
Standard
r-egtrlations 29 CFR1910.133 European
in or
Skinl Wear apprqpriateprotectiveglovesto preventskin exposure.
Clothingr Wearappropriateprotectivecfothingto preventskin exposure.
programthat meetsOSHA's CFR51910.134
protection and ANSI
29
Reepirators: A respiratory
wheneverworkplace
Standard 149 must be followed
EN
288.2 requirements European
or
warranta respiratofsuse.
conditiens
.--*-- !
Section I - Physicaland ChernicafProperties i
I
Physical State: Crystals
Appearance: blue
Odor: Odorless
pH: Not available.
Vapor Pressure: 7.3 mm Hg @ 25 deg C
Vapor Density: FIotavailable.
Evaporation R.ateNeg ligible.
:
Viscosi$: ltlot available.
Boiling Point: 150 deg C {dec)
Freezing/Meltlng Pointrl.l0 deg C (dec)
Decomposition Temperature:Not available.
Solubility: Soluhle.
Specific GraviW/ Density:2. 28409/cm3
I{olecular Fonnul a:CuO4S. 2O 5H
Molecular Weight*49.68
---t
Sectlsn 1S - Stability and Reactivity
Chemical Stabili$r Stableat room temperaturein closedcontainersunder normal storageand
handling conditions. sensitive.
Air
rnaterials,dust generation,exposureto
to Avoid: Hightemperatures"incompatible
Conditions
rnoistair or water.
air, exposureto
Incompatibilities with Other tlaterials: Moisture,air, steel, finely powderedmetals,
magnesium, razi nitromethane.
hyd ne,
hydroxylarnine,
Hazardous Decomposition Products: Oxldesof sulfur, irritating and toxic fumes and gases,
oxidesof copper"copperfumes.
Hazardor.s Polymerizatlon: Hasnot hen reported
Section LL * ToxicologicalInfor*ration
RTECS*r
CAS# 7758-99-8:G18900000
rD50lLc50:
cAS# 7758-99-8:
Oral"rat: LD50= 300 mg/kg;
Skin,rat: LD50= >2 gm/kg;
Carcinogenicity:
CAS#7758-99-8:Not listedby ACGIH, IARC,NIOSH, NTP,or OSHA.
Epidemiology: No information available.
Teratogenicity: No information available.
Reproductive Effecb: No informationavailable.
I{eurotoricity: No informationavailable.
Mutagenicity: DNAInhibition:Human,Lymphcyte = 76 umofL"; Unscheduled Synthesis:
Dl,lA
turnor = 300 mg/kg.; Micronucleus
Rat, Liver = 31 umoUL"; Rat,Ascites
Analysis:
Cytogenetic
mouse= 5 mglkg,
Test: Intraperitoneal,
Otlrer Studies: No informationavailable.
- - - -- -
-- i, I
1 Section t2 - EcolqgicalInforrnaticn I
i
trout: LC50= 0.1-2"5mg/L; 96 Hr; Unspecified fish: LC50
Ecotorlcityl Fish:Rainbow Harlequin
a
v =0.1-2.5 mg/L; 96 Hr; UnspeifiedGoldfish:LC50= 0.1-2-5mglL; 96 Hr; Unspecified flea
Daphnia:EC50= A.24 rng/L;48 Hr; Unspecified soil, coppersulfateis partly washed
In downto
lowerlevels,partly boundby soil components, partly oxidatively
and transformed. Copperhas a
strongaffinityfor hydrousiron and manganese oxides,clays,carbonate minerals,and organic
matter"Sorptionto thesematerials... suspended the water column& in the bed sediments,
in
results in relativeenrichmentof the solid phaseand reductionin di*solvedlevels.
Environmental: Copperis accumulated plantsand animals,but it doesnot appearto
by
frorn plantsto anirnals.
This lackof biomagnification commonwith heavy
biomagnify appears
metals.In air, copperaerosols general)havea residence time of 2 to 10 daysin an unpolluted
{in
atmosphere 0.1 to > 4 days in polluted,urbanar鈧琣s.
and
procesfor copper
Physical: No evidencewas found to indicatethat there is any biotransforrnation
compounds which would have a significantbearingon the fate of copperin aquaticenvironments.
Other: None.
- --_-*]
Section13 - D eonst
wa$e generators must determinewhethera discarded
Chemical chemical classified a
is as
guidelines the classification
hazardouswaste.US EPA for determination listedin 40 CFRParts
are
wastegenerators
261.3.Additionally, must consultstate and localhazardouswasteregulations
to
ensurecompleteand accurateclassification.
RCRAP-Series: Nonelisted.
RCRAU-Series: ltlonelisted.
o $ection 14 - Transport Inforrnation
Canada
us D{tr IHO
nID/ADR
IATA TDG
i*oT
CUPRIC
1EGUIATED
Shipping tlame: :OR DOMESTIC SULFATE
TRANSPORT
noN 9.2
Hazard Clasc:
uNg109
FSo002
UN Number:
Par.fttng @oupi ff
REGULATED
Additional Info: UMIT sKG
Section 15 * RegulatoryInforunatlon
US FEDERAL
TSCA
CAS#7758-99-8 is not on the TSCAInventory"It is a hydrate and exemptfrom TSCAInventory
requirements ).
{4OCFR720.3(uX2)
Healilr & Safety Reporting List
Noneof the chemicals sn the Health& Safety R.eporting List.
are
Rules
Chemical Tst
Noneof the chernicals this productare undera ChemicalTest
in Rule.
Section tZb
Noneof the chernicals listed under TSCASection12b.
are
TSCASlgnificant New Use Rule
Noneof the chemicals this materialhavea SNUR
in underTSCA.
SARA
Section 3O2 (RQ)
Noneof the chemicals this materialhavean RQ.
in
Section 3O2 {TPQ)
Noneof the chernicals this producthavea TPQ.
in
SARA Codes
CAS# 7758-99-8:acute,chronic.
Section 313
Copper(II) sulfatepentahydrate (CAS#7758-99-
This materialcontains {listedas Copper),100o/o,
8) which is subjectto the reportingrequirements Section313 of SARA Title III and 40 CFRPart
of
373.
Clean Air Actr
This materialdoesnot containany hazardous poflutants. This materialdoesnot contalnany
air
Class1 Ozonedepletors.This materialdoes not containany Class2 Ozonedepletors.
Clean }llater Act:
Noneof the chemicals this productare listedas llazardous
in underthe CWA.Noneof
Substances
the chemicals this productare listedas PriorityFollutants
in underthe CWA.ltloneof the chemicals
in this productare listecl ToxicFolfutants
as underthe CWA.
OSHA:
Noneof the chemicals this productare considered
in highlyhazardous OSHA.
by
STATE
CAS#7758鈧?9-8 is not presenton state listsfrom CA,PA,MN,MA,FL,or NJ.
RiskLevel:Noneof the chemicals this productare listed.
in
No
California Significant
European I International Regulations
European Labeling in A-oldanae with EC Directives
Hazard Sfmbols:
XNN
Risk Phrases:
R 22 Harrnfulif swallowed.
R 36/38 lrritating to eyes and skin.
R 50/53 Verytoxic to aquaticorganisms; may cause
long-termadverse effectsin the aquaticenvironment.
Safety Phrases:
S 22 Do not breathedust.
S 60 This materialand/or its containerrnust be
waste"
disposed as hazardous
of
S 61 Avoid releaseto the environment.Referto
speciali nstnrctions/Safety
data sheets.
WGK tWater Danger/Protection)
CAS#7758-99-8:2
Canada - DSN./I{DSL
Noneof the chemicalsin this productare listed on the DSLor NDSLlist. Canada - WHtrtIS
This producthas a WHMIS classification DlB, D2A.
of
Canadian Ingredient Disclosule List
CAS#7758-99-8{listedas Copper)is listedon the Canadian IngredientDisclosurel-ist.
Exposure l-imits
CAS#7758-99-8:OEL-ARAB Republic Egypt:TWA mg(Cu)/m3(turne)
of 0.1
OEL-AUSTMUA:TWA mg(Cu)/m3(turne)OEL-AUSTRAUA:TWA
0.2 1 rng(Cu)/m3
(dust) OEL-BEI-GIUM:TWA mg(Cu)/m3(fume) OEL-BELGIUM:TWA
0.2 1 mgtCu
(dust) OEL-DEIIMARKTTWAmg(Cu)/m3(tume) OEL-DENi.IARK:TWA
0.1 1m
)/m3
g(Cu)/m3(dust) OEL-FINI,AND:TWA mg(Cu)/m3ttume) OEL-FINLAND
0.2 :TWA
1 mg(Cu)/m3OEL-FINLAND:TWA 1 mg(Cu)/m3(dust) OEL-FMNCE:TWA m 0.2
g(Cu)/rn3{furne)OEL-FRANCE:TWA 1 mg(Cu)/m3;STEL rng(Cu)/rn3 (dust OE
2
(fume) OEL-GERMANY:TWA
L-GERMANY:TWA Mg(Cu)Irn3
0"1. 1 mg{Cu}Im3OEL-G
(dust) OEL-HUNGARY:TWA mg(Cu)lm3;STEL
ERMANY:TWA 1 mg(Cu)/m3 0.2 0.a
mg(Cu)lrn3(dust) OEL.INDIA:TWA mg(Cu)lm3(fume)OEL-THE
0,2 NETHERLA
NDS:TWA mg(Cu)/m3(furne)OEL-THE
02 NETHERI-ANDS:TWA 1 mg(Cu)/m3(dust
PHIUPPINES:TWA mg{Cu)/m3(tume)lAN9 OEL-POLAND:TWA
1.0
) OEL-THE 0
.1 rng(Cu)/m3(furne)OEL-RUSSIA:STEI- ppm (1 mg(Cu)/m3){dust) lANg
0.5
OEL-SWEDEN:TWA mg(Cullm3 (resp.dust) OEI--S\MEDEN:TWAmg(Crr)
0.2 0"2
/m3 (fume) OEL-SWEDEIII:TWA 1 mg(Cu)/rn3(total dust) OEL-SWITZERLAND:T
WA 0.1 mg(Cullm3;STEL mg(Cu)/m3(fume) OEL-SWITZERIAND:TWA
0.2 1 mg(C
u)/m3;STeL1 mg(Cu)/m3OEL-THAILAND:TWA mg(Cu)/m3{tume) OEL-THA
0.1
II-AND:TWA mg{Cu)/m3OEL-U
1
SecElon!8 * Addit$enalInf0rmafi$n
I I
I
MSDS Creation Ilate 7&9/1999
Revision #2 Dats 8t'0?20fr)
Ttle infonnation a&ovc is bc{rrgnedts De aac&rate and replresents tbe besf inftrrmation anrrently available to us, fbrever, we make
o
no warraw af merchanbbility ar any othar watrantyn 鈧?,ryrw ar iwpfid, with NW b sadr infartn*tian" erd we sssr,tma no
liability testtlting kotn iE u*. Users sfiould nreke their own inv鈧瑂firgaffoos b detet'nine the sttabiliry of fhe lnbrmation for their
partianlar pelrpses. In fio event s;fto,tl fistpr &e liaHe far any claims, iosses, or darnages of any third grty w for l& profi& ar any
qecial, itdit&, incidental,,cor?se.4s.enttai or exemplary darnagReghaw*ever arisinE eysn if ffsfier fias ben advi*d of the
poxibility of such damages.
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