Reorder 17135
No.
Lab Safety SUPPIYlnc.
MSDS Product Name: KODAK DeveloperD-76
MATEI?.IAI, SNITEl'Y DA'IA I]IIF]Ii'I
2 n 0 0 0 0 2/3 1 u { ; A
r/
A p p r o v a l t - l a t e: 0 ) / ? . 5/ L 9 9 B
P r i n f - D a t e : 0 ' )/ ? . 6/ L 9 9 8
[,aqe I
(:tIT:I4I(:AI, INEI.ITIFICATIOT.I
I. PI?()DI'(-]T
AND COMI'ANY
P r " o d r . r < : La n c : I ( O t l A KD e v e l o p e r D - 7 6
N
- To Make 1quarLs (U.s')
f23 0895
C a t - a l o qN u m l > e r : ( s ) :
- To Makq 1 gallon (Ll.S.)
0937
I23
- To Make L guarts (lj.s. )
146 4791
-'i'o Make l/2 gallou (U.S.)
146 4809
- To Make 1 gallon (U.S.)
146 4817
- To Make 10 qallons (U.s. )
)-46 4825
M a n u f . . r e t u r e r / S u t r p l . i . e r : : E A S T M A N O D A KC O M P A N YR o c t r e s t e r " . N e w Y o r k 1 4 6 5 0
K ,
(7L6) '122-5Ir:1'
call
For llme;qenr:yl{c,all-h, SafeLy & Environmenbal Infonnalion,
(800) 242-2424.
o r L o r e q u e s t a n M S D S ,c a l l
information
For other
C o n c e n t r a t e : K A N 4 4 0 5 0 8 ; P C D5 2 3 9 ; C - 0 0 2 ? . 1 0 0
:
Synonym(s)
W o r k i n o s o l u L i o n r C - 0 0 2 7. 1 1 0
COMPOSII'IOII/1.}IFORMA?ION INGREDIEN'fS
ON
2.
Weiqtht S - Component - (CAS Registry No. )
ConcenLrate r
(007'157-83-71
85-90 Sodium sulfite
l { y c i r o q u i n o n e ( 0 0 0 1 2 3- 3 1 * 9 )
4
Sodirrmtet.raborate, pent.ahydrate (0121?9-04-3)
1C
L- )
4- (methylamino)phenol sulfate (000055-55-0)
1-5
Boric anhydride (001303-86-2)
<1
W o r k i n c r s o l u L .i o n :
Wat.er (007'132-18-5)
B5-90
. / 0 0 7 7 5- 8 3 - 7 |
5-10 Sodir:m sul f ite 7
pent.ahydrat.e (012179-04-3)
l-5 Sodium tetraborate,
l ' l y d r o q u i n o n e ( 0 0 0 1 2 3 - 31 - 9 )
<1
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illi.:lAfrJr.ii)i rt,1i, l{.i.,'li()ll
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( / \ r i : I 1 , . Il . l ,l , l I , t I l I j l ;
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,
1 . 1 / r ' /l A l l : ' i , , ( " i / . l y ) : : l l - l l i A l l l : t l ) ( r i I / r l J I l 4 / r l , I r i r ' i ' 1 ,
r)P. flVlhl,l,()W|,lr
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(jri.ril;I.j:l .':l'lll
i I Pil I'l'AT'1()ll
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I'ln'/ (.I\lllll'; hI,Ll:l'.(;lC :lKJl.J IILlA("1'l(til
lllllll lla::;rt i l';rtjtirtr::
r
llr:irl 1ii I J . i i r r r r r r ; r l 'irti' 'rl r
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t ' l l l ' , \ i l . ' r . n , l I ; . i i I ) ' . r r:
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L'
C ' ( n , I ' f A I i . l s :l l y r . l r o , t r l r l c ] n e ( 0 0 0 f 2 3 l i - 9 ) ,
jr sulfar
4-(methylalnjllolphenol
( 0 0 7 ' 1 - /- 8 3 ' - ' / )
( 0 { ) 0 r J 5 5 - ' r ! ' - 0 ) , s o < .i lr . r t ns u l f i t e 5
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'
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o
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! . i . 1i , r r r j l t , l , , ; < j 5 : 1 r 1 r . 1 i r r l . c t r i i r . d f o t ( l ( i r l c l - ( 1 c l r l i c l i , r l ( - (o t l I r " l 1 : o J 1 , - r
y 1
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i:
n r a y n o l b e t l e e ( l c t ( ij f t : r r q i l ) e e l i 1 ) { ; c c ) l t tl . o l s l
(g.
r n a tn r i . r l " i , l ' t . l
jlr tlrtr l1', :l ilt.rit-it
( r ' . r t . , l , r : . r l \ r , r n l , j l i t l . i t . r t t ) . r l t l i t ( . l e ( ! r . l a t { A' l l . t o 1 . . 1 1; l : ( ' ) ,
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l
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f.i.p1r1 rlesi..-rrrat.es otenLial p or
chronic
,
i n t h i s l " 1 S D .n u s t b e ( : ( ) ! l s i ' : i " r e d .
ad(lress; r:af p hancllinq, c
ALL informat.ion
I . ' l R l i , l ,r U l r t . l t : A l j t i l ? t i J ;
4-
rrynu)t.onlii i r:iri. l.), . tjel
t.
1'r ca I
air
Irrlral,lt-i()n: ll syrnpL(nnaLic, In()veLo freslr
rnedi(:al at-t.|nt ir:n if sympl-oms persist-.
liyerr:
(lon(ienLral:e: I r n r n e ' r l i a t e y f l u s h v . . 'I il r J r Je r r r L y o f a l - ] e a s l , 1 . 5 m i r r r r l . e s.
r^rat--er or
l
I
Gef. mec-lir:al al.t.enl-irrn irrunecliaIeJy.
plenLy
W o r k i n . J s ; o 1 r r t - i c : n :I n u n e c l i a t . e l y f l L r s h ' r i t : l l t.,'aLer-[or al- ]east
of 1"
m i n r t t e s . r l r . r l -m e d i ( j a l a t L e l t l - i o n .
I n u r r e r l i a t . e l y f l u s h v / i t : h p l e l r t - y o f t v a t t e r f o r ' . r t . . lc ' , r s t - 1 5 r n i t r u t e s w l r j .1 e
Ilkjl:
r : e r n o v i . n q < r r r r t - a r n i n a L c dc l t ; t : t r i n q a r r r l s l r o e s . I f s k i r r i . r r .i - t a L i o n o t ' a r l a l l e r q . i r '
rkirr rear:Lion rlevelops, !Jet- nredical at-t-etttion. Wasir c,'onLaminat.:ed -'lot,hinq <
[ ) r ] s rr o y o r t . h o r o u g h l y c l e a n c o n t a m i n a t e c l s h o e s ,
Irefore reusc.
Ingesf ion:
C o n r - : e n l r a f . o L r o N O ' l ' i , n r l l c ev o m i t . i n c f , ( i i v e v i c t - i m a ( - I I a s so f w a f e r . C a l l &
:
l l t r y s i r - : i . a rr . ) r ' l ) ( ) i s o n c o n f . r o l . ( i e n t e r i r n m e c i i a t . . e l y l. l e v n r o i v e . r t t l , t - ] r i n q 1 4 ' t n r l r r t l r
:
r
l ( ) a n r l n r ' ( ) l l s 1:r ) u s f ) e r s o r l.
(
Seek medical attent.ion. Never-
Workilrq i:.)llll:ion: Drink 1-2 cllasses of water.
c 1v e a n y t : l r i n r ; b y r n o u L h h o a n u n r : o n s c i o t - l s p e r s o n .
i
Not-e to Physicians: Absorption of this material inbo t-he bocly leads to the
formation of methernoglobin that, in sufficient concentraLion, causes cyarrosis.
Since reversion of melhemoqlobin to hemoqlobin occurs spontaneously after
Lerrnirration oi r-ixp()sure, nroderat-eclegrees of cyanosis need to be treated only
Thorough
by suppor[ive rneasures such as bed rest and oxygen inhalation.
cleansing of the entire contaminated area of the body, including scalp and
nai1s, is of utmosr- importance. ff cyanosis is severe, inLravenous injection
of methylene blue, one rnilligram per kiloqram of body weiqht, may be of value.
FIRE FIGHTINGMEA'JIJRES
5.
ExLinquishinq l4eclia: IJse appropriate agent. for adjacent fire.
Special Fire-FiqhLing Proceduresl Wear self-contained breathing apparatus ancl
Fire or excessive heat may produce hazardous
protecEi.ve clothing.
< l e c o n p o sI j . o n p r o d r r c t s .
i
H a z a r d o r r s C o m i r r r s l - i o nP r o d u c t s : N o n e ( n o n c o m t r u s t i b l e ) (see also llazardous
DecomposiLion Proclucis s.ection)
Hazards: None
Unusual Fire and Explosion
I{ULUASUMBASUI{IS
6. ACCIDIT.TIAL
ConcenLraLe: Flush lo sewer wilh large amounts of wat.er. OLherwj.se, sweep up
and place in a conlainer for chemical wasle. Clean surface thoroughly to
remove res idual cont.aminaLion.
Working solut.ion: Flush Lo sewer with large amounts of water. Otherwise,
wirh verrniculiE.e or other inert. maLerial, Lhen place in a
absorb spilt
container for chemical waste. Clean surface E,horoughly to remove residual
contaminat ion.
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tloric'
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r'a
L i r r n a i l t a i r l a i r l x r l r r e l e v e l s l r e l o l v l c ( r ( ) n [ l l . ' l l ( l { ' 鈧? ]) i i ' o F l l l . c l
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I
Iimit.s.
(t.y;rica11.y 10 ilj.r ("llatlllcri ir'rl
l,J.rkjtrcl r;e-irrt.ilrr: (i9r1l q(.lr)eral ventilat-iotr
j ( ) l r r a L e s c l t o r r .rl i l r e m a f r ' l t ' - , i l , ( ) ( ' r ) l l ( l i t j.r ' . : ; .
) r < ; , r) r s l t o r r l , . l | 1 r - r i 5 : r . . l V n n t i l . a t
r
r
I t,\t., l i,,rr:
I,.,slil;1t ()ly
jotts
c.io not mail)f-ai.n airl.)orne c()Il(''elil ' aL
cc)ntrols
Conc-.ent-rat-e: Il, enrjineerinq
m u s t - l l e w o . l: r "
an approved respiratol-
lirnit.s,
l , r e l o v r I e c : o n u n e r r c l e (e lx p o s u r e
-
s]1oltld be vrorrt i f llazardous
R e : s 1 . r i- a t . o ] ' t . y 1 ' r e : [ . ) \ l S t ' . . A r e s p i r : a t - o r
no$plrat()l
Lo hc ot have t)Fcn leleased'
r l o c ' o r r r l r o s j t , i < , lrrrr o r l u r : t - s a l e l i k e l y
irle
ancl llea(.'t-ivjty Sect-ion. Jf respil'atols
t:y1ro; Acj.ri rtas. Il..e St.abjlity
us(-(i, n proqrAln $ltoitld be irrst-it,ut.ed to assure compljc-lrlr-'e itll O.!;llA.':t.illl(jar(l w
?.9 (:l:P if)lr).1 ]4.
l e t ' ; c l l . n - if
should
t^Iorkirrg sc-rlur..
j A respirat--or
l t a z a t ' r - l o t t s1 1 , ' a 1 , 1 1 1 J ; r - l 5 i t piro rc l u c t - s a l l e l - i l l e l y t . o l t e o r ' l t a v e l - r e i n nr r t . le ; t : : r , . r l .
, ot
l i r J r r " : A t ; i , l g a s . S e e i : l t . a l r i l i t . y . r n d l ? . e a ( : L i v i t - yS l e c t i , o n . l l
Reslrirat:or'
r e s p i r a t - ( ) l l : ' " t tr ? r l S e ( , 1 ,a J ) r o ( t r a n l s h o r t l e l b e i n s t . i t : r r I e r J ! ( ) . t s s l l l o ( ' ( ) r r u ) ] i A t t r : t ,
w i l . h ( ) S I I A 1 l f - a r r , i . e r r .? C i r R 1 9 1 0 . 1 1 4 .
2l
l;iye ['r'oLer:t ir.rrr
:
( l ( ) n c c n l : r : ; r l ' r r : t ' J { . , ' l rs a f e t : y
t 1 'a l s c , S r ^ / i f i r s i < l e s h i c . l r l s
l (ol qocJqles) arrd a far'r.
l n / t ' ; r ri r l L t I 1 L n , , r ' r ' r - ' r i l r i t ' ;,r:tr r . , i f r r e e r l r : d .
nlrir'l<1.
W o rk i t l ( J l i ( ) l r r t j , ; 1 1 ' b J r ) i ' uI-; a [ ( , 1y ( l l , t t ; s . ' l ] w i t . ] r s i , 1 r , s r l r i o l r . l s r( o r r 1 o t 1jro s , ]
.1
i r i k i r t P r o l - e < : t .i . t - r t i : b l e a r i - n r p e r v i o r . r s :c - ; . l o v t . s a r r c i p r r o t , e c ' l - i . v e r " ' l o r - h i - t r < ;a p r 5 r r o p l . r a t e
[,rr t-lre 1.isk rrf ny[]()srlre,
R e c o m m e n c l e d[ ) o ( ; ( ) r r h - a m i n a t i o n F a c i l i t i e s : E y e ] ^ r a F - ] rw a s h i n g
, facilit.ies, s,rfely
shower
'J. t'l'tYsl.(:AL,
Allt) ct{tiMi(_'ALPP.oPFIR'rIFls
l)hysir:a.l Forrn:
C o n c e r t tr a t e : i , k r l i r - 1
Working so luf.i cln: Lirlu j.cl
Color:
(.:()il('r.nt. (. ! ( l{ { ,,vlr I,t. i
r,1l
Workinq solut"ion: Colorless
Odor:
ConcentraLe: Odorless
-
- Workinq solut-ion: .Sliqht
i i p e r - ' i . f i c G r a v i t - y ( ! , / a t . . e * '- 1 ) :
r
Concenl-rar-e:
Working solut.ir:n: 1.0U-1.09
Vapor Pressure .rt 2OoC(6BoF) :
C ( ) n c e n t r a t e: N e q l i q i b l e
24 rnbar (18 mmHg)
Working solution:
Vapor Density (Air = 1):
ConcenLrate: NoL applicable
Working solution:0.6
Volatile FracLion by WeigliL:
Concentrate : Negligible
Working solut.ion: B5-90 I
troilinq Point:
Concentrate: No[ applicable
W o r k i n g s o l u b i o n : > 1 0 O o C( > 2 l " 2 o F )
Malt-ina DzrinF.
C o l l c e l l L r t - e: l i c - r ta ,v a i l d b l e
a -
Working solulion: Not applicable
Solubi" J. t.y in Wat-er:
i
ConcentraIe : Appreci.able
Working soluLion: Complebe
pl{:
Cloncentrate: Nol applicable
Bs
O.,::;n;:?";:"""''t . a p p l i " c a b l e ,
Concent.rate: No noncombusLible solid
1 jrlijti
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t,,,)t,ittri
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: : l ' i \ l i l l i ' l ' ' 1 . . il l ) I'i l.i'l I'l''a
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l'l r/'fl'1
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l
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i
1I .
() l
I i lf I ( : . t l i l ' l i l Jr 1 ) l l t l t r ' :
{;frIl.:fi I:
('(r't.'.)lli. t ar c
(-laLa' callsc
ltiay
()n arlilTlal
Baserl
slllfate'
'ij()IlLaiIIS (m{lt-hylamino)phenol
4-
:
spleen.
kiclrley,
olClans/Syst-ems: blooc],
OI) Lile follovlirtg
'1(lverse eItr:cts
I J a s e < J ( ) I l a I ) l I n a ] , ( l a t , a t h i s m a t e r i a l c a n p r o c l u . . e n l e t - h e m o g . l o b i r r w l l i t ' ' i r , i riio l l ()l
(-'yanosis' a bltrt'-g7l:ay dis('olol'ii
rirJIf j('i.'nt. (:or.]c'FrnLration, cause$
abilil-1' of the l:l()o(l l-o t'"l lY
t.lre sl"itt ;rtirl lil':-: t'atlrtetl l'1' a 1'p1.lrlr'rlri
ozyq.ll .
(:()1)lilill:r:ii','rlli;rlttilitltt"'1ttF"l44-r;lll;'t:itl<-rt:i1'r::ill':clrrtitlj::l:t;''"lr''f ':
tll(rljr:l)l
i ' 1 { 1 r r ' ; '1 i 1 ;
l l l f i . ) l ' l i i i l i - i r l tO 1
t
i r . 7 r i r , , , i L| t .)il i i i ) - l : t 1 a : t r t l t o , i i r l
{ .}''q11ir'1rl
t ' < l i l t . a r , r , r r t t r . l a r ; , r < l n r - l - l i t r ( ) ! ) . ] t ' , 1 ) ) ; ' l i ; ' c l r : o q r r i ] l O l ] { : ] . i t t r ] ' t . ' e t l l t e 1 l l)'t r I r pla t -o . .]' tl <;' lt| . r ' ' . . r i ; : r l
< i l i1 r
rnalc li-]44 rat'' ]rllt
( ) r a l. i i . t r i l n i r t i : ; t - r a r t . i o i t i t s i r e t ' t l i i o [ c t i ' i l t r i r e
lt
s r ) e ( ] j e s ; O r J . a t - s L r a i r l S t . e s t e d . A l t h o r r g h a l l i n c r e n s e j l l m o l ] o olrl 'i 'c t t ,r lJ e . ] l
jl ii' c lil(rl ()tiri
c
l i e e t t l :e l r o t - t - c d l o l
i | r r k r r r ri . i i r r I : . 1 4 4 ' f e r n a l e r a t . s h a r i 'il a
f in
this
a
i n i r' r i o n i i < : e
'llrere vJas rlo eviclellce of carcinoqc'tricity
slrl)sf.lUonl flt-Ll(1'y'.
l r > l l r l v " l i r r ! ' . l l l l . r l r t i < : . . 1 t ' a - ] a ( ] | n i n : i . s t - ] . a t i o n c l f h y r l t < , q i r i l t cj lr:l ,r cr; 'S a)sI e | c ( : . . . . , , . . ! ] ( : a ( ) i
: c( 1 l
in fcrnale lnice l'y all
1 ; , 1 ' r . ' i l l a ) ( l o r l i ca r : t i v i r - y v / i l s s h o w r l
l t e l F r a t t l r . t l } ' } - l r l a l ' I ) { ] o [ ) l t r s i r . s ; v i l t j . c : i . } ! , , ' L 1 r e p ] i ' l r l a i l j ' | y i l r . r l i t J t l a c l c r l
I : n a \ 1 i ()
. in a s u b s e q t t e t r L s l : r - r t 1 y ' N o s k i t r
t.liis f irrclirr: \.ras not. r:r.r-rr.
clermal ':1rpli..at ion of li1'rli iillll()l)')'
1 r - 1 r ( )tr. r . c l i r r r r | ir . r - f o l r l o r v j n c t r . l c > t t g - t . r l t n
'l'itertllort-',ttt'o1r1'1st-icrosjl)ollsesilt'rvetroLI-:eottc'tlltltistt:ttt-aclos'()ut(r()f
ba<':t-erial
glellerelly rreqat-ive
or sex. lly
exp()srtr.e, species, (! r)1'omosome
the clasLoqenicity
f or
ilrr..lLitge,cril,y t-est-s; tirere is evi
jr]
'l'liel Ieleviincc (': Llre
i.tlone i.tt vivo ar]cl in viL]o'
l)reakacle) oI Iryrlr:oqtl j: ;ttclr'''al-'
in preclict-ilir't llrtntattr isk
< : l r r o r n o s o l r r n lc f f e c : t . s i n t e s L a l l i r n a l f )
.
Ittlrirlat iott:
f11 tliltlt.dc|. \.l]tl-l
Airborne
C t l n < , e r i t ' . r a t ' , t . ' :i , i a , r : t n I t r ] i f . i r r l r a l e < ] .
st-r()ngacjds;OI.If}reat-ed,sulfit-esmaylj.be]:ate,su]furclj"
i l , r l f r r r ' , l i r r . l i r l o r - J l : : j . r ; . i r . ri t . a l . i r t q l r l t . l t e r e s l - r il.a f . o : y l . r a ( : t l. S r ' . r n ta s t 1 i l n t l
c ,
( ) t i t i : I, r l r r i r n : : i i ti , " ' r . . i r r r l i " v i r ' l r r a i s n r ; r y e x l l ) e r i c n c r : r l i f f i r . r r l . t b ; e a t _ l ; i t t < I.
W o t k i n r t : : , r l ' t f i o t t : [ i x ; ; r r c L o r i l - r ; b e a 1 r ) r . /h a z a r t . ] f o r r e c o r r u r e l t ( l e d l r a n r lf . i - r t q .
( ' n l i l i l l ' i r . . l1 l r r r f t o t t < l a l i r l s { r l i f l r r . n lo r l , : l l l f r j l n s 1 ' 1 n 11 i l r e r a t . . J s l l l f u l
i ,
1 1 o x j . r l , ) r 1 . l : i . I i r l l , f r , r r : , ' il o x i , ] e I t a s ; i r ; j r r - i r - a f - j n c r t c r t . . l r e r - e s l r i r a l - ( ) r - y f r a , . . t .
i
. ' . - n t n pt s r.fl t t t l n ti.r " s r r t h y P e t s e n s i t . i v r - i r r , .i1 i c h . t a l s r n a . , 'r ' x p e r i e r l c r l i l i f f i c r r l l '
. v
trr,,,tllrinrl.
l'i;'t':r
:
C()ncefrt-l'al-o: (l/luit鈧?)sbrrrnr,;. Aii l-rorrrer:lrlsf irr. it-aLin
W o r k i r r g s r - . l l r r l : i o n :C a u s e s i r r . i t a L r r : n .
5 l ki n :
C o l l c e n t . r ' a t : { : . :( : a u s e s i r r i t - a t - i o n , l'Iay cause allerqi( skin rea(:tiorr Iraset.l
I u u n a r r o x l r o r i F I ) { : o . M n y r : a u s o s k i n , l n p . i q m e n l a L i ( ) r r.
s()lrrtiorr: (iauses iriitat-ion. M a y c a u s e a l .l n r u i c
h/'rr inq skin
k reacr.iorl
baserl on llulnalr ey.perience.
Incres t. t
1 - i 1 1 1 1 ' lpn t1c : l l a r r n I r . r i i f s v r n ]l o w o t l. l l o m e a $ t h r n a ti c s o r s r r . l .ift e - s e n s i t i v e
1t
i r r , l i v i c l ' r a 1 s m a y e x p e r i e n c e w h e e z i n g , c h e s t t i g h t n e s s , s t . o m a c hu p s e t ,
hives, faint-ness, weakness and diarrhea. May cause burns of t:he
qast ro i nL er:l-. inal tr"act i f sv,ra lowecl . I
W o r k i l r q s o l r r l i o n : M a y l : e h a r n r I r r I i f s r v a l l o w e <.l S r : r n e s t : h m a t . i c s o r
a
srrl.fil:e-sens;t-ive indiviclurals may experience wheez-ing, chest tight-ness,
i
$ L o r n a ( : lu p : i e t - , h i . v e s , f a i n L n e s s , w e a k n e s s a n d d i a r r h e a . M a y
r caLrse
i r : r i . L a t -i o n o f L h e q a s t r r ) i n t - e s r i n a l t r " a c L .
1"2. ECOLOGICALTIJFORMATION
Ttris envirorunental effecLs summaryis writLen to assist in
In[roduction:
whictr mi.gltt occur duritru
addressing emerqencies created l-ry an ac-'ciden[a1 spill
tire slripmenL ()f t:.his mat-erial, and, in general, it is not meant to acldress
di.scharges to s.rniLary sewers or publically owned treatment works.
S u m m a r y : D a t - - af o r L i r e m a j o r c o m p o n e n L s o f t h i s m a t e r i a l i r a v e b e e n u s e d t o
est.imate the environrnental impact of Lhis material. However, this material,
icsel f , h.rs not been resced for environmental ef f ect.s.
It is expect-ed t-o have the followinq properties: a moderate bioclremical oxygen
demand and may cause oxyqen deplet.ion in aqueous systems, a high pot,eneial to
affecL some aquar-ic organisms, a high potential to affect- secondary waste
poLential to af fect bhe germinat ion
L.reat.menl rnicrobial rnet-abolism, a moderaLe
a r r ( l / o r e a r l y q r ( ) b r L ho f s o r n e p l a n t s , a l o w p o L e n t i a l t o p e r s i s [ in t-ire
environrnenL, a l()w potential wirlr a large
r-o bioconcenbrate. Af ter dilution
anourlt of vrater, followed by secondary wasEe treabmenl,, this material is not.
expecl-ecl t-o cau$e adverse environmental ef fects.
'l
1 . D IIiI-'OIlt\i, ('illlil f l)[t]AT'l.OtJ:';
r:t lr.r'.r1
I l . i s r : l i a r q e , i . t o ; 1t . r n e n t - , 9 ; r - 1 i s ; r o s a l n r a l , | i e : ; t - t l . r -c l . r o i r a ! : - i o n a . l . , s I a t , e .
ej
l n w f . l ; l r r : l r l o j : r ' i . J l l v / i f l r l ; i r , , t , ' ; I r r o r r t r lt o l - 1 1 ' n 1 . 6 , 1 1i 'l.t t ' n t t n t r . r f . i e rc ' t r t l fi t i l l c t ; '
S l
c o t t L a i n e r i s e r t q . rife t l .
l e L a i . l t ) r ( ) 1 l r t 1 t ,t e s i . ( 1 1 1 e , f o 1 1 o r , . r , L a b e l v , ' a r n i r t c l s e v e n a l t e r
't,tr.Atl.; ,r)t{t' i ilr'()ptlA.i' tof t
t
I4 .
- F < : t ' t . t . ' a t t s J r on t i o r t i t t f o t t r t a t .i o t t t e ( t a l ( l i t t r ]t l r i s 1 r t o t l r t r ' l ' a l I t . l r e K c x l a k
t
tt
( ? 1 6 ) ' / 2 i . ? . 4 ) A [ ' r e [ w e e t t8 a . n t . a n t ]
W o r l < l v ' r i r l e ' l ' t a n s p - l r : r l " a Ii . o n ] l a z r n a l " l f < r l .i.. , i n e :
'f
ime) , l4onrlay t-hrotrgir liri daY.
5 pr,n. (I'l;rrtpt tl St,.lndard
iOt'l
I 5 . Rfi(ltll,A'l()PY IIJi:OP.l4AT
- l4at r.r i.a 1 (:: ) krto',rt I o t.tr,ir s l , r f , e r r r f t ' : a i i f o r n i ; , r fqr q:1t11,;g'arl('.lt-:
( Ikrtte
l . { . 1r o ( l l t c t j \ f ( j
- M a t . n r i . r I ( r : ) l ' . t t o ' , v r 1 . , . rf . l t r " f i t . r f . c r > f t ' a l i f C r f n i n fArrl:e AclVorse )
t t.r
rrf fer:l-s;: lli'rrtp
' C a r c i n o q e r r i c i l - y t J l a s s i f i c a L i o r r ( r : o r n l n r t e n t sL ' ) r e s e n t a t 0 . 1 t s o r n l o r e ) :
* I n f - e r n a t -j . o n a 1 A g e n c y f o r R e s e a r c h o n C a n c e r ( I A R C ) : N o n e
- A m e r i r - ' a n( l o n f e r e n c e o f G o v e r n m e n t a l I n d u s L r i a l I l y g i e n i s t s ( A C G I I I ) : N o n e
- Nat.ional Toxicoloqly Program (NTP): None
- O r : c ' r . r [ r ; r t . i . r . : nclj , r f e l , y e r r r r il l e a l t " h A r l r n i n i s l - r a t j o t r ( O : i ] i A ): ] J o t t c
.l
- Chemical (s) sr-rbjer:tto the reporting reqtrirements of Sect.ion 313 or Tit. le
I I I o f [ h e S r r p e r f u n d A m e n d m e n t sa n d R e a u t h o r i z a t i o n A c L ( S A R A ] o f 1 9 8 6 a n d
40 CFR ParL 172: ilych:oquinone
16. OTTIERI}J}"'OI]MATJ.ON
U S / C a l r a < l i . r t rL a l . , ,Il S t - . a l - e n r e n : s
L
ConcentraLe:
(-'OlffAItis: tlyclroquinone (000121-31-9); 4- (methylarnino)phenol sulface
-7
( 0 0 0 0 5 5 - ' l 5 -0 ) , s r : d i t . r m r r l f i L e ( 0 0 ' 1 7 5 " 1 - 8 3 )
s
I
t)AtJr;nP.
CAUSBSEYE BI.IRNS
MAY (..AIJ.SE BASEDON ANIMAL DA'I'A
BLOODDISORDERS
MAY CATISECYANOSIS BASEDON ANIMAL DATA
HARMFULIF INHALED OR SWALLOWED
DUST IRRITAT]NG TO THE EYES AND RESPIRATORY TRACT
CAUSljs !;KI}.I IRITI'I'A'fION
MAY LIBERATE SULFURDIOXIDE
SKIN REACTION
MAY CA{JSEAI-,LERGIC
Do ncl[ get in eyes and avoid contacL wiLh skirr artrl clot.hinq.
Avoitl breattring dust.
l J s e w i t h a c l e c 4 r a I e v e n t j . 1 a bi o n .
Wash lhoror"rqhly after handling.
a glass
tlive victim of
do NOT induce vomit.ing.
PIRST AID: If swallowed,
j
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;;.r1'1r 1 i ,, iJtri /,tl i(rri.: ,1
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1 Uj
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l)iI
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l : r ' : i r , " r l r t i, i i l
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trl
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lr'1 i()ll
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l
(\.'l\'(1{'l)
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11r'r,r1 II
jl r l a l , c ( l
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irrt.til.,r.'p()r1t
t:l,r/(.:t(,,
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r .,;rr'l) ol
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j()Il:: il: i)'ltn
l;uf ciy
i'l'it{'I ial
()r rll;rr tllrt il sat('ty
1 1 , ;1 1 6 1 l r . t t t , - l 1 t ' lllci'ar-ll-
j l l r r . l : t , ( 1 , ' 1 ' ; l ) : : ) r ; r . . r e 1 , , , r ' , l rl ' ( ) . ' I i 1 a t t r l L l t r , r ' r 5 t O ( . ) ( l
j
i
t }rir:
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Salet. l' Diit-;i $ireet
l ' < . : r a < l r i1 i . 6 r r ; r l i r r { a ; r r n a L i o r r , s o e r I ' l a t - e ti a L
t
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t - l } a r . l1 t t r r . L l r ; t to f
r'r)IlL;riners qI{1at.l
/vl,iir.ir.rrr.rl lr;r:arrl prir.-.alrticxrs fot
Lirtuicl clr-! J1(,llncls f solic'l :
o
1 a ! r q : 1r * i r r n i l t r ] s
lollorr
r , 1 n 1 j; .t q r l c o n I a i l e r s relairr lir'o(irrct: resiLhre.
si'c.
ptni)tii'cl'
nven nlLel. .,'.)Iltairtet' is
i r ' , ' I ; t t t t i i r r ) ) r i t i : l t r :. rr r. l l . i ( i i r :
( ' ( r i i , l ' A I l l : : :l i . , 'l,1 , . 1 r i q1 r . 1 1 1 0 t, t l l ) , . 1. i I . ( l ) , 4 - ( l r i i : l
rr \1
'i\
( r ) { r ( l i ) l ' . ' , ' . 1 , { r ( ) \ t j : r i l:l r } l i i i , ' ( r i ( l ' i " ' :, ' " " ' ' ] .
1
t^l^Ilr'tll'(;" I
( : n i r : ; i . 1 . : ;; l i i l l n l l l ) l l Y t ' , l l ' l i ' l l ' l ' i r ' l ( r l i
i
(
l"1A]' iln liA.tr.l'{l"lil,If Sl^lf\i.,1,()l'Jtll)
M 1 r ' / r ' n 1 1 . 1 J/;i'l , t , l . l f i ( ; l ( ' : i t ( T t i t ' . f A ( ; l ' I ( ) l ' l
A . r o i rj l r r .t ' a t l r i t t t l t r r is t - ( ) l - 1 / i l r ) ( ) 'r
(
A v o i r . l ( ' ( ) r i li L , t - ' . ' / i t , l l( r \ / ( ) c , l l l : i t l , t i l l i l l e i t l t i r r < '1
'iotl.
l l : : r : , . . r1i' 1 , ' 1 1 1 . r | 1 , 'e t v o l l i - i l u r t
' t
l / ; r s : ] t t - . h o r ' o t t r r ] 1 i 1 ri t - < l l i r ' i t r t l l i t r c t '
a
] J c ' r r e ' t ( l i v { i n r l y f - } i i r t t r ' lr 1 r m i ) t l t ' l l
i r l ' . , r 1 ' l ' A . l l ) : J l r ; 1 ' l a .llo v , r . t l, s r r ( : : l : I l i e c i i ( " : t . i r t r ' l r ' r i c : c "
i)L (.:()llLiii"t', jltuttt''ilat el)' i lrrl;lt c)'(r':l ill)(l
L r . r . r i r l l n ( . ' ( . ) i l : . 1 r . ' ! - o lrr.cs t1 l t - . r t l 1 t t e i t l r e
.
tt
1.5 rnintrLc:svrilile relnovincl
skjn vrit-h plenLy of lvat.er-f<,1- aL least
( - l e l - :l n e d i c a l a f t e n f i o r t i f s y t t t l : L o l l l F io ( : ( : U l '
arlrl sl)oes.
( . ( ) l l t - A m r i) a t - e ( J I l t ; t l t i n q
.
( ) l f l t O f < l l - t < 1 1 t 1 1r' ' ' ' r l t
cj
jntitiilq i)efor鈧瑀 It)rlljc' I')eStt-oir
t r { , . r s l r : p r r f . a t in t . l l , F ( l t . :
p
( ' ( ) n ta n i I r , l t - e ( l s l l ( ) e s '
j
(--)l J dl"cr] .
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I..r-.elrc.rr.rtr.r
t.lrir;
{}'lsDS) f or
M a l < ' r " j a l ' 5 a fe L ) ' I r a t - n s h e c t
I ; - r > ra c l d i t ' i o t t ; r . i . r n f o t - t n a t - i o n . s e r :
rn;it-eriaI.
( ' ( ) l ) t - a r l t r ) lI i ' l t t ? , r l, ' r l .I t ; r n . l r t a . l l r r t t r : l
l r , r ; a t r . l l ) r c ( . ' i r r l t - - i r - , r rl ro; t
Arlrlil. i,rn,rI
t,
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Iir|tirl,,r
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, ' 1 1r1 1t r . r ' l r ' o r l l l i n r . r : l
1 t r.t;tilr rvntttitt,t:
lal'r'l
pyo11 .1f'f r:; r:orti,ailtr:l' is e n r p l :i r : r 1 .
'l'lr,r irrl.oltn.rl i()n r:orrl-airrer-hert:in f ruttir;hecl rvif.lrotrt !'rar"t:ant-y f an]'kiIl(1.
o
is
l
orily aFl .1 sllfrplenlpnt. t.o ot-hel inf otntat iolr
tlsers slrqu lrl L-()rrsii(ler t-hese clala
y arrti
c{al.herr:rl lry Ifrorn and mu:qt-nlake irrrl{]pondont- r.leterntjnatiorts of s\tila})iIit
ci()nrpleLeness oI in[or.mat-i<:n from a].1 soulces to assttre proper use and di.':pr'lsal
of entployees ar]d cr,tsLomers attd
6l t:[ese rnal-eri.als arrJ l-fre safet-y and health
t - l i o J i r : ( ) t t e ( ' i1 . r r r r f I l r e e n v i l o n r r r e r r t . . ' l ' l r e i r r f o r m a t i o n re1,.il-irl!l Lo t.he wor-kjltrl
o
is for gl-lidance p\rrposes on1y, and is based on correct mixittql anr] Lts(:
sollrti<:n
j.ons.
of Lhe pro(lucL r-lcrcordinq to ilrstruct
(.lr)rtr.:erlt-rat,e:R-2S-'3, F-f-), C-.0
,
Wfl:R-1., S-2, f {), C-0
lMunbgr ScrvisciI
I,S-rrUUuil
tSlrgU
llo.$c-| liind I LrgrLu-eir
rvcbnuslcr rhissircprcscnls pr,,hl.u,..
if nny
Cl()nlilct
Kodirk(irtrtpatty.lt)t"tll-l99tJ l)livacyPracticcl.
and
Cgfrfrislf O liaslrrntrr
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