SafetyDataSheet
Material
gryo ate
Ammonium bdaft,:$olution4. ror'fihospfi
mol
an_c_9f*11s1 - ChemicafProductand CompanyIdentification
Section 1
MSDSName: Arnmonium
Catalog Numbers: LCffZ*gi Lgfl:ns
Synonyms:
Company Identifi cation :
LabchemInc.
200 William Pitt Way
Pittsburgh,PA 15238
For information" call: 412-826-5230
For CHEMTR.EC assistance, call: 800-424-9300
For International CHEMTRECassistance, call : 7 A3-527-3887
Section2 - Composition,
Informationon Ingredients
iv
ErrrEcs/ErJl{cs
cA:s# Perccnt
Chemical llame
1336-21-6 Ammoniumhydroxide 0.25 215-647-6
Water 23L-79r-2
7732-18-5 balance
13106-75-B 235-031-3
{mmonium molybdate 4.8
G[.f lfl,?'#"o:i"#ilHJl':*
Section 3 - Hazardsldentification
EMERGENCYOVERVIEW
Appearance:colorless.CautiOn! May cause eye and skin irritation.
Target 0rgans: None known.
Potential Health Effects
Eye: Causesredness, pain, and irritation.
Skin: Causesrednessand pain.
Ingestion: Low human toxicity, high animal toxicity with kidney damage.
fnhalation: Transitory irritation of throat and lungs.
Chronic: May causedermatitisand conjunctivitis.
Section4 - FirstAid Measures
i
t
!
Eyes: Flusheyes with plenty of water for at least 15 minutes,occasionally lifting the upper and lower lids
until no evidenceof chemical remains. Get medical aid at once.
Get medical aid. Immediately flush skin with plen$ of soap and water for at least 15 minutes while
lSkin:
Uremoving contaminated clothingand shoes.Removecontaminatedclothingand shoes.
Ingestion: Get medicalaid at once. Give conscious victim large quantitiesof water to dilute acid. Give
oxygen if respiration is depressed.Induce vomiting (touch finger to back of throat) keeping head lower
than hips (prevent aspirationinto lungs). Medicalperconnelmay use gastric lavageor emesisto remove
poison; give activatedcharcoal.
Inhalation: Give artificial respiration if necessary.Get medical aid. Keep victim warm, at rest. Move
victim to fresh air.
to Physician: Treatsymptomatically suppottively.
and
On*""
Section - Firefighting
Measures
5 I
fire and explosionhazardwhen exposedto heat or flame. Move
General Information: Negligible
possible,avoid breathingvapors or dust.
containerif
Extinguishing Media: For small frres, use dry chemical,carbondioxide,water spray or alcohol-resistant
foam.
"-***--**-.i
Section - Accfdentaf
6 Refease
Measures I
.l
I
General Information: Useproperpersonal protectiveequipment indicated Section
in
as 8.
sand,fuller'seafth)and placein plastic
(vermiculite,
Spills,/Leaks:
Absorb spillswith absorbent bagsfor
laterdisposal.
Areamay be washed downwith water.
Section7 - Handlingand Storage
Handling: Wash thoroughlyafter handling.Avoid breathingdust, vapor, mist, or gas.
Storage: Store capped at room temperature. Protectfrorn heat and incompatibles.
*.-.*****'__ !
SectionB - ExposureControls, PersonalProtection I
I
EngineeringControls: Provide
localexhaust general
or dilutionventilation.
Erposure Limits
l{ros}t
Chemical Name OSHA - Final FEls
ACGXH
Ammoniumhydroxide rone listed nonelisted none listed
Water rone listed none listed none listed
Ammonium molybdate rone listed none listed none listed
OSHA Vacated PELs: Ammonium hydroxide: No OSHAVacated PELsare listed for this chemical. Water:
No OSHAVacated PELsare listed for this chemical. Ammonium motybdate: No OSHAVacated pELsare
listed for this chemical.
Personal Protective Equipment
Eyes: Do not wear contact lenseswhen working with chemicals. eye wash fountain should be available
An
in the immediate work area. Wear splash-proofsafety goggles.
Skin: Wear appropriate protective gloves to prevent skin exposure.
Clothing: Protectivegarments not normally required.
Respirators: Not required for normal use.
Section9 - Physlcaland ChemicalPruperties
Physical State: Clearliquid
Appearance: colorless
Odor: ammonia-like
pH: Not available.
Vapor Pressure: < ether
Vapor Density: Not available.
Evaporation Rate:Not available.
Viscosityr Not available.
Boiling Pointr Not available.
Jreezing f Melting Point:Not available.
Decomposition Temperature:Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
NFPA Rating: Not published.
Explosion Limits, Lower:Not available.
Upper: Not available.
Solubility: Soluble.
Specifi c Gravity/Density: > 1
Molecular Formula:Not available.
Molecular Weight:Not available.
Section 10 - Stability and Reactivity
stability: stable undernormaltemperatures pressures.
and
lchemical
Vconditions to Avoid: Hightemperatures, incompatible materials.
Incompatibilities with Other Materials: Not available.
Hazardous Decomposition Products: Oxidesof nitrogen,irritatingand toxic gases,ammonia.
Hazardous Polymerization: Not available.
Section 11 - Toxicologicat
Information
RTECS#:
CAS# 1336-21-6 unlisted.
CAS# 7732-L8-5unlisted.
CAS# 13106-76-8 unlisted.
LDSO/LCSO:
cAs# 1336-21-6:
Oral,rat: LD50= 350 mglkg;
cAS# 7732-t8-5:
Oral,rat: LD50= >90 mVkg;
cAS# 13106-76-8:
lnhafation, LC50=>1930mg/m3/4H;
rat:
Oral,rat: LD50= 3883mg/kg;
lCarcinogenicity:
11lq:-21-6:Not listedby ACGIH,
IARC,NTOSH, NTp,or OSHA.
ITl9f CAS#7732-t8-5: Not listedby
-
ACGIH,IARC,NIOSH, NTP,or OSHA. CAS#13106-76-8:Not listedby ACGIH,
IARC,NIOSH, NTp,oi
OSHA.
Epidemiology:Ammonium molybdate a severe
is eye,skin,mucousmembrane ritant.Ammonium
ir
-
hydroxide concentration less than 1olo no t consideredhazardousin this solution.
Teratogenicity: No data available.
Reproductive Effests: No data available.
No data available.
lNeurotoxicity:
No data available.
]lutagenicity:
-
Other Studies: No data available.
Section tZ - Ecological
Infcrmation
No informationavailable.
Section - Disposal
13 Considerations
Chemicalwaste generators must determine whether a discardedchemical is classifiedas a hazardous
waste. US EPAguidelines the classification
for determinationare listed in 40 CFRParts261.3. Additionally,
waste generators must consult state and local hazardouswaste regulationsto ensure complete and
accurate classification.
RCRA P-Series: None listed.
RCRA U-Serie: None listed.
Section 14 - Transport Information
Canada
US DOT IATA Ihto
ffiD/ADR
TDG
No
No information
Shipping Name: information
available.
available.
Hazard Class:
UN Number:
Packing Group:
Section 15 = RegulatoryInformatlon
US FEDERAL
TSCA
CAS#1336-21-6 listedon the TSCA
is inventory.
CAS#7732-18-5is listedon the TSCA inventory.
CAS#13106-76-8 listedon the TSCA
is inventory.
llealth & Safety Reporting List
Noneof the chemicals on the Health SafetyReporting
are & List.
Chemicaf Test Rules
Noneof the chemicals this product undera chemical
in are rest Rule.
Section 12b
Noneof the chemicals listedunderTSCA
are Section12b.
Significant t{ew Use Rute
ffSCa
vNone of the chemicals this material
in havea SNUR underTSCA.
SARA
Section 3O2 (RQ)
final RQ= 1000pounds (454 kg)
CAS#1336-21-6:
Section 3O2 (TPQ)
Noneof the chemicals this producthavea TPQ.
in
-SARA Codes
# L336-2L-6: CAS# 13106-76-8:
acute,chronic. acute.
GnS
Section 313
No chemicals reportable
are underSection 313.
Clean Air Act:
any hazardous pollutants.
Thismaterial doesnot contain air Thismaterial doesnot containany Class1
This doesnot contain
depletors" material
Ozone any Class Ozone
2 depletorc.
Clean Water Act:
Noneof the chemicals this product
CAS#1336-21-6 listedas a Hazardous
is Substance underthe CWA. in
are listedas Priority Noneof the chemicals this product listedas Toxic
Pollutantsunderthe CWA" in are
Pollutantsunderthe CWA.
OSHA:
Noneof the chemicals this product considered
in are highlyhazardous OSHA.
by
STATE
CAS#1336-21-6 can be foundon the followingstate right to knowlists: California,
NewJersey,
nsylvania,
Pen Massach usetts.
CAS#7732-L8-5is not presenton state listsfrom CA, PA,MN,MA,FL,or NJ.
CAS#13106-76-8 be foundon the following
can state rightto knowlists:NewJersey.
California Significant Level:Noneof the chemicals this product listed.
No Risk in are
European/International Regulations
European l-aheling in Accordance with EC Directives
Hazard Symbols:
Not available.
Risk Phrases:
Safety Phrases:
lWG K ( Water Danger/ Protection)
r336-zt-6:
Z
!cns*
CAS# 7732-L8-5: No information available.
CAS# 13106-76-8:1
Canada
CAS# 1336-21-6 is listed on Canada'sDSL List. CAS# 1336-21-6 is listed on Canada'sDSL List. CAS#
7732-18'5 is listed on Canada'sDSL Ust. CAS# 7732-L8-5 is tisted on Canada'sDSL List. CAS# 13106-
76-8 is listed on Canada'sDSL List. CAS# L3LO6-76-Bis listed on Canada'sDSL List.
WHMIS:Not available.
CAS# 1336-21-6 is listed on Canada's IngredientDisclosureList.
CAS# 7732-18-5 is not listed on Canada'sIngredient DisclosureList.
CAS# 13106-76-8is listed on Canada's IngredientDisclosureList.
Exposure Lirnits
CAS# L3tO6-76-8: OEL-AUSTRAUA:TWA mg(Mo)/m3 OEL-BELGIUM:TWA mg
5 5
(Mo)/m3 OEL-DENMARK:TWA 5 mg(Mo)/m3 OEL-FINLAND:TWAmg(Mo)/m3 OEL
5
-FRANCE:TWA mg(Mo)/m3;STEL mg(Mo)/m3 JANSOEL-GERMANY:TWA
5 10 5 mg(M
o)/m3 OEL-THE NETHERLANDS:TWA 5 mg(Mo)/m3 OEL-THE PHILIPPINES:TWA 5
mg(Mo)/m3 OEL-SWITZERLAND :TWA 5 mg(Mo)lm3 OEL-TURKEY:TWA mg(Mo)/m3
5
KINGDOM:TWA mg(Mo)/m3;5TEL10 mglm3 OELIN BULGARIA,
OEL-UNITED 5 C
KOREA
OLOMBIA,JOR.DAN. checKACGIHTLV OEL IN NEWZEAISND, SINGAPORE.
VIETNAMcheck ACGI TLV
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IMSDS Creation Date: tt/t9/t997
-Revision #1 Datet t2/06/2000
In{armation in this NSDS is from available published surces and E fulieved to be a@lrate. No warranty, express or implied, is made and
l-abChem tnc. assumes no liability resulting ftom the use of, this IUSDS. The user must deteftnine suitability 6 this information for his
application
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