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MaterialSafety Data Sheet
HPLC'Sradf;":W&*
Cfetohexar*e;
Section1 - Chemical Identification
Product
and Company
IISDS Name :.Clrckahexan鈧?, HFLCGm*"
AC610040040
Catalog Numbers: AC610040000,
Hexanaphthalene.
Hexamethylene;
Synonyms: BenzeneHexahydride;Hexahydrobenzene;
Company Identification :
AcrosOrganicsN.V.
One ReagentLane
FairLawn,NJ 07410
For information in ilorth America' call: 800-ACROS-01
For emergencies in the US, call CHEiITREC: 8O0-424-9300
Section2 - Composition,
Informationon Ingredients
L70-82-7
Hazard Symbols: F
Risk Phrases: 11
Section3 - HazardsIdentification
EMERGENCY
OVERVIEW
colorlessliquid. FlashPoint: *20 deg C. Dangef! Aspirationhazardif swallowed.Can enter lungs
Appearance:
and causedamage. May cause respiratoryand digestivetract irritation. May causeeye and skin irritation. May
May cause liver and kidney damage. Highlyflammable.May form
causecentral nervoussystem depression.
peroxides.
explosive
Target Organs: Kidneys,central nervoussystem, liver, cardiovascular system.
Potential Health Effects
Eyel May cause mild eye irritation.
throughthe skin in harmfulamounts.May causeirritationwith burningpain, itchingand
Skin: May be absorbed
redness.
Ingestionl Ingestion of large amounts may cause gastrointestinalirritation. May cause liver and kidney damage.
characterized excitement,followedby headache, dizziness,
by
May causecentral nervoussystem depression,
possibledeath due to
coma and
dlowsiness,and nausea.Advancedstagesmay causecollapse,unconsciousness,
failure. May causevascutarcollapseand damage.Aspirationof material into the lungs may cause
]iratory
lf,鈧琺ical pneumonitis,which may be fatal.
may causecentral nervoussystem effectscharacterized by
Inhalation: Inhalationof high concentrations
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unconsciousness coma. May causerespiratorytract irritation. May be fatal if
and
nausea,headache, dizziness,
exposedto high concentrations.
Chronic: Prolonged rcpeatedskin contact may causedefattingand dermatitis. May cause liver and kidney
or
damage.
Section4 - FirstAid Measures
Eyes: Flusheyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids.
Get medicalaid. Do NOTallow victim to rub or keep eyes closed.
Skin: Flushskin with plenty of soap and water for at least 15 minutes while removingcontaminatedclothingand
shoes.Get medicalaid if irritation developsor persists.Wash clothing before reuse.
and alert, give 2-4 cupfulsof milk or water. Never
Ingestionr Do NOTinducevomiting. If victim is conscious
person.Possible
give anything by mouth to an unconscious aspirationhazard.Get medicalaid immediately.
Inhalation: Removefrom exposureto fresh air immediately.If breathingis difficult,give oxygen. Get medical
aid. Do NOTuse mouth-to-mouthresuscitation. breathinghas ceasedapply artificialrespirationusing oxygen
If
devicesuch as a bag and a mask.
and a suitablemechanical
Notes to Physician: Treat symptomatically and supportively.
Section5 - Fire FightingMeasures
breathingapparatusin pressure-demand,
General Information: As in any fire, wear a self-contained
(approvedor equivalent),and full protectivegear. Vaporsmay form an explosivemixture with air.
MSHA/NIOSH
Vaporscan travel to a sourceof ignitionand flash back. During a fire. irritating and highly toxic gases may be
generatedby thermal decomposition combustion.Extremelyflammable.Materialwill readily ignite at room
or
temperature.Use water spray to keep fire-exposed containerscool. Liquidwill float and may reigniteon the
surfaceof water. Vaporsmay be heavierthan air. They can spreadalong the ground and collectin low or
confinedareas. May polymerizeexplosively when involvedin a fire. Containersmay explodewhen heated.
Extinguishing Media: Water may be ineffective. This material is lighter than water and insolublein water. The
fire could easily be spread by the use of water in an area where the water cannot be contained. Do NOT use
straight streams of water. For large fires, use water spray, fog or regularfoam. For small fires, use dry chemical,
carbondioxide,water spray or regularfoam. Cool containerswith floodingquantitiesof water until well after fire
is out.
Flash Pointr -20 deg C ( -4.00 deg F)
Autoignition Temperature: 245 deg C ( 473.00 deg F)
Explosion Limits, Lower: 1,3
Upper:8.0
NFPA Rating: (estimated) Health: 1; Flammability: Instability:0
3;
Section6 - Accidental
Release
Measures
,lperal Information: Use proper personalprotectiveequipmentas indicatedin Section8.
Absorbspill with inert material(e.9. vermiculite,
sand or earth), then placein suitablecontainer,
Jlls/Leaks:
Avoid runoff into storm sewersand ditcheswhich lead to waterways.Cleanup spills immediately,observing
precautionsin the ProtectiveEquipment section. Wear a self contained breathing apparatus and appropriate
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oPersona protection.(See Exposure
I Controls,Perconal
Protectionsection).Scoopup with a nonsparkingtool, then
place into a suitablecontainerfor disposal.Removeall sourcesof ignition. Provideventilation.
Section7 - Handlingand Storage
Handling: Wash thoroughlyafter handling.Removecontaminatedclothingand wash before reuse. Use only in a
well-ventilated area. Do not reusethis container.Empty containens retain product residue,(liquid and/or vapor),
and can be dangerous.Keepcontainertightly closed.Avoid contactwith heat, sparksand flame. Do not get on
skin or in eyes. Avoid ingestionand inhalation.Do not pressurize, cut, weld, braze,solder, drill, grind, orexpose
empty containers heat, sparksor open flames.
to
Storage: Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible
substances. Flammables-area.
SectionB - ExposureControls,personalprotection
Engineering Controls: Facilities
storing or utilizingthis materialshould be equippedwith an eyewashfacility
and a safety shower. Use adequategeneralor local exhaustventilationto keep airborneconcentrations below the
issibleexposurelimits.
re Limits
3OOppm TWA; 1050 mg/m3 300 ppm TWA; 1O5Omglm3
lOO ppm TWA
TWA 13OOpDm IDLH TWA
OSHA Vacated PELs: Cyclohexane:300 ppm TWA; 1050 mg/m3 TWA
Personal Protective Equipment
Eyes: Wear appropriate protective eyeglassesor chernicalsafety goggtesas describedby osHA's eye and face
protectionregulationsin 29 cFR 1910.r33 or European standard EN166.
Skin: Wear neoprenegloves,apron, and/or clothing.Wear nitrile-latexgloves,apron, and/or ctothing.
clothingr wear appropriateprotectiveclothingto prevent skin exposure.
Respirators: Followthe OSHArespirator regulationsfound in 29 CFR 1910.134 or EuropeanStandard EN 14g.
Always use a NIOSHor European StandardEN 149 approvedrespiratorwhen necessary.
Section9 - Physical properties
and Chemical
Physical State: Liquid
Appearance: colorless
Odor: sweetishodor - chloroform-like
pH: Not available.
Vapor Pressurel 95 mm Hg
V_aporDensity: 2.90
iate:6. 1 (Butyl acetate=1)
lporation
!'lBcosity: 1.02 cP at 63F.
Boiling Polnt:80.7 deg C
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Freezing/Melting Point:6.5 deg C
Decomposition Temperature; Not available.
Solubility: Practically
insolublein water.
Specifi c Gravity/ Density:O.8 (Water= 1)
Molecula r Formula :CHz(CHz)4CHz
Molecular Weight: 84"084
Section10 - Stabilityand Reactivity
Chemical Stability: Stableat room temperaturein closedcontainercunder normal storageand handling
conditions.Peroxide formation may occur in containersthat have been openedand remain in storage. Normally
stable; however,on long term storage, materialscontainingsimilar functionalgroups form peroxidesof unknown
stability. May form explosive peroxides.
Conditions to Avoid: Incompatible materials, ignition sources,excess heat, oxidizers.
Incornpatibilities with Other lilaterials: Strong oxidizing agents, nitrogen dioxide.
Hazardous Decomposition Products: Carbonmonoxide,irritating and toxic fumes and gases,carbon dioxide,
Hazardous Polymerization: Has not been reported.
Section11 - Toxicological
Information
RTECS#:
CAS# 110-82-7:cU6300000
LD5O/LC5O:
cAS# 110-82-7:
Oral, mouse: LD50 = 813 mgfkg;
Oral, rat: LD50 : 127A5 mg/kg;
Garcinogenicity:
CAS# 110-82-7: Not listed by ACGIH,IARC,NIOSH,NTp, or OSHA.
Epidemiology: No informationavailable.
Teratogenicis: No informationavailabte.
Reproductive Effects: No informatiort available.
Neurotoxicity: No information available.
lrlutagenicity: DNAdamage; E. coli, 10 umol/L
Other Studies: None.
SectionLZ - Ecological
Information
Ecotoxicity: Fish: FatheadMinnow: LC50 = 117.0 mg/L; 96 Hr.; Static conditionsBluegilfsunfish: LC50 =
34.72 mg/L; 96 Hr.; 25 degreesC flea Daphnia:EC50= 400.00 mg/Lt 48 Hr.; Unspecifedria: phytobacterium
phosphoreum:EC50= 227.A0 mg/Lr 5, 30 minutes; Microtoxtest No data available.
AtmosphericFate: Cyclohexaneis expected to partition to the atmosphere where it will rapidly
Jit"lPental:
with hydroxyl radicals.TERRESTRIAL FATE:If releasedon land, cyclohexanewill be lost through
volatilization and should leach into the ground. Cyclohexaneis resistant to biodegradationbut may biodegrade
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slowly in the presenceof other hydrocarbonsthat are themselves degraded. AQUATICFATE:Volatilizationfrom
water (estimatedhalf-life2 hr in a model river) should be the most importantfate processoccuringin aquatic
systems.
willdegrade by reactionwith photochemically
FATE:In the atmosphere,cyclohexane
Physical: ATMOSPHERIC
producedhydroxyl radicals(half-life 52 hr). The half-lifeis much faster under photochemicalsmog conditions
with half-livesas low as 6 hr being reported.
Other: No experimentaldata are availableon the bioconcentration cyclohexane aquaticorganisms.Using
in
of
regression
the octanoywaterpartition coefficient,3.44, one can estimatea BCFof 242 using a recommended
equation.
Section13 - Disposal
Considerations
waste. US
Chemicalwaste generatorsmust determinewhether a discardedchemicalis classified a hazardous
as
determinationare listed in 40 CFRParts261.3. Additionally,waste generators
EPAguidelines the classification
for
waste regulations ensurecompleteand accurateclassification.
to
must consultstate and local hazardous
RCRA P-Series: None listed.
waste number U056 (Ignitable waste).
RCRA U-Series: CAS# LLO-82-7=
SectionL4 - TransportInformation
a Canada
IATA RID/ADR
US DOT Il'lO
TDG
No
information
Shipptng Name: }CLOHEXANE
available.
Hazard Class: 3
JN1145
UN Number:
Packino Grouo: tI
Section15 - Regulatory
Information
US FEDERAL
TSCA
CAS# 110-82-7 is listed on the TSCAinventory.
Health & Safety R,eporting List
CAs# 110-82-7: EffectiveDate: L2/L9/85; Sunset Date: 12/L9/95
Chemical Test Rules
None of the chemicalsin this productare under a Chemical Test Rule.
Section 12b
slutop ']u1',u.ror'1san[dep @
lw Eooz E
cAs# 110-82-7: 4/!2b'parues?J
TSCA Significant New Use Rule
the chernicals this material
in havea SNURunderTSCA.
ff""
CERCIAHazardous Substancesand corresponding RQs
9fi0t2003
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CAS# 110-82-7: 1000 lb final RQ; 454 kg final RQ
SARA Section 3O2 Extremely Hazardous Substances
None of the chemicalsin this product have a TPQ.
SARA Codes
flammable.
CAS# 110-82-7:acute,chronic,
Section 313
of
(CAS# 110-82-7,9996),which subject to the reportingrequirements
is
This materialcontainsCyclohexane
Section313 of SARATitle III and 40 CFRPart 373.
Clean Air Act:
This materialdoes not containany hazardous pollutants.This materialdoes not containany Class 1 Ozone
air
depletors.This material does not containany Class2 Ozonedepletors.
Clean Water Act:
Substanceunderthe CWA.None of the chemicalsin this productare
CAS# 110-82-7 is listed as a Hazardous
listed as Prioritypollutantsunder the CWA.None of the chemicalsin this productare listed as Toxic Pollutants
underthe CWA.
OSHA:
highly hazardousby OSHA.
None of the chemiEAls this nroduqtare considered
in 'ou[s!lAegeol ulrBau
onuluoc
STATE
CAS# 110-82-7 can be found on the followingstate right to know lists: California,New Jersey,Florida,
uof .au'uoalouusnJ.olueu",Jut
Minnesota,Massachusetts.
Pennsylvania, itreurfxreluo:t
california No significantRisk Level: None of the chemiclilsin thif;rggd;tr?,q3if
l5|r".*
"r"u,Jn"
e*s 3&鈧??i.*,a K *3 鈧?3es
*$a* **
f,gropea n/ Internationa I Regulations
Labeling in Accordance with EC Directives
]oeean
Fazard Symbols: ST'TI$ :lunouv telol
F
T :rtilluenb
Risk Phrases: -lf,H
CI3V '\UOIVUOS\fi CIO ralllr uelr
ClSSOghll flltOg
R 11 Highly flammabgso3lM
97,666ALE(.鈧? lraqunN ru"rl
:6uplpueg
Safety Phrases:
ST'9$ t EulddrqS
S 16 Keepaway from sourcesof ignition - No sn
:lunoruv
smoking. 00'9$
S 33 Take precautionary measuresagainststatic
'uof,'eu!luoerourqsru鈧?)ueurlur peluoS asea;d'uollf,esuerl:no{ uo sllelepJoJ
discharges.
S 9 Keep qontainer in a well-ventilated pla'stlroqsuollf,esuells!t{l roJ ldlalal lleua ue eNef,eJ lll^ no^
-lVdAVd,,
',,NVWJN* se lllq rno{ uo;eadde llrA uolpesupJlpJeg llpels slrll
ol lues uaaqseLlSI'IT$ Jo lueujAedV
WGK (Water Danger/Protectii*l$f,'aulluoaroulqsnr@)uPursl'x
C A S # 1 1 0 - 8 2 - 7 :1 g 3x**axAv4
&isglR;.el'lsga"t
Canada - DSLIIIDSL
CAS# 110-82-7 is listed on Canada'sDSL List.
&L&See$*{*}s {}pffi$'$ $?*A
Canada - WHMIS w
WHMIS:Not available.
Canadian Ingredient Disclosure List
CAS# LL0-82-7 is listed on the CanadianIngredient Disclosure List.
ExposureLimits i-# # 3 " # {J* $tuf &-fiS 鈧?,AS E"B Ate A$* eT*
e4S J ffi
#
CAS# 110-82-7:OEL-AUSTRAUA:TWA ppm (1050 mg/m3) OEL-AUSTRIA:T j
300
WA 300 ppm (1050 mg/m3) OEL-BELGIUM:TWA ppm (1030 mg/m3) OEL-DEN
300
300 ppm (1050 mg/m3) OEL-FINLAND:TWA ppm (1050 mg/m3);ST
300
fl-ARK:TWA
ppm (1315 mglm3) OEL-FRANCE:TWA ppm (1050 mg/m3);STEL375
300
JS7S
lpm (1300 mglm3) OEL-GERMANY:TWA ppm (1050 mg/m3) OEL-HUNGARY:TW
300
A 500 mg/m3;STEL1000 mglm3 OEL-JAPAN:TWA ppm (520 mg/m3) OEL-TH
150
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3
E NETHERLANDS:TWA ppm (1050 mg/m3) JAN9OEL-THE PHILIPPINES:TWA
300
150
00 ppm (1050 mg/m3) JANpOEL-POLAND:TWA mg/m3 OEL-RUSSIA:TWA
80
370 ppm (1
ppm;STEL mg/m3 OEL-SWEDEN:TWA ppm (1000 mg/m3);STEL
300
B0
300 mg/m3) OEL-SWITZERLAND:TWA ppm (1050 mg/m3);STEL600 ppm OEL
300
-TURKEY:TWA ppm (1050 mg/m3) OEL-UNITED KINGDOM:TWA ppm;STEL
100
300
checkACGIHTLV OEL
JORDAN,KOREA
350 ppm OELIII BULGARIA,COLOMBIA,
ACGITLV
ChCCK
VIETNAM
SINGAPORE,
IN NEWZEALAND,
Section16 - Additional
Information
l'fSDS Creation Date: 6/O41t999
Revision #3 Dater 3/L8/2OO3
The information above is beJieved to fu acc.trafle and represents the bssf infunation atrrently availaile to us. Hawever, we make no wawanty of
merchantability or any other warra$ty, express or i*lplie.d, uritk reqed to such informatbn, and we ass{rnte rw liability resultirry from iB u*. Users
should make their own investigatiotrs to determine the suitability 6 the information for their particular purpass- In no event shall fisher be liable for
any claims, losws, or dan'tages of any third Wrty or for lost 9r&8. or any rycial, indirect, irrcidental, @n*quentia.l or exemplary damages,
lwwsoever arising, even if Fisher has been adrri*d af the poxibility of such damages.
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