Code! 8IJG91{4
Date: 03 IIOV 1993
23 I\UG 199t
Printed:
ENGEI,AARD
SAFETY DITA SEEET
I{AIERIAI'
SII,VER SOLUTION 9L44
Product:
Common Name : N/A
Chemical NamE : CHEMICAL MIXTTIRE
: CHEMICAL UTXTURE
Formula
CAS No.: CHEMICAL }TIXTURE
Product
:
Product Use
ENGELHARD CORPORATION, ENGINEERED MATERIALS GROUP
:
Supplier
L WEST CENTRAL AVENUE
:
Address
EAST NEWARK, NJ A7O29
:
St,
City, ZLp
: 1-201-268-7800
Phone
FOR CTEUICAL EUERGENCy CAITITCHEIITREC (2{ EOURS}:
(UBr Canada, Puerto Rico, Virgin Islands)
1-8oo-l2l-930o
L-2O2-483-7 6L6 (Outside. Above Area)
ON INGREDIENTS
T !9t.
CAS NO.
INGREDTEXT
SILVER COMPOUNDS
UETALIO-ORGANIC
90
80
IN TSCA
CYCLOHEXAT{E
15
1-0
LLO-82-7
IIOTES
INGREDIEITT
in
NOTE: The percentage by weight ranges for the hazardous ingredients
this product represent the approximate forrnulation values.
and Section XI for
NOTE: See Section VIII for Exposure Lirnits
Toxicological Information.
ENGEIJtrAND Page 2 Code: Etc9l4rl
UAIERIIIT SIFETI DA||[e SgEE'l[ Date: 03 NOv 1993
EUERGEIICY OVERVIEg
Amber ligrrid
Solvent odor
22 oC
Flash Point.
Repeated excessive exposure may cause liver and kidney darnage.
Prolonged or repeated contact to eyes, skin and
may cause irritation
respiratory tract.
Hatmful if large amounts are swallowed.
gases in a fire
FlammabLe liquid. and corrosive
Product will emit toxic
situation.
ROUITEs OF EITTRI
YES
Eyes? YES YES Inhalation? YES Ingestion?
Skin?
POTEIIIIIAI. EEII.IT EtrFECTg
may cause irritation.
EYE COM[AC[: Prolonged or repeated contact
o nay cause
SKIN CONTA0I causes nild Prolonged contact
irritation.
dermatitis.
and
di-zziness
INHALATION causes the respiratory tract,
irritation of
drowsiness.
and possible
pain
vomiting, loss of
INGESTfON causes irritation, nausea,
consciousness,
CARCINOCENICTEY
NTP? NO IARC? NO OSHA? NO
CARONIC EEAI.,TE EAZARDS
Excessive exposure by any route may cause kidney and liver damage, and
blood disorders. Anesthetic or narcotic effects with nausea and/or
voniting may be obserrred.
The absorption of SILVER compounds into the circulation and the
subsequent deposition of reduced silver in various tissues of the body
nay re-sult in- the production of a generalized greyish pigrmentation of-
the skin and mucous membrane (argyria). Generalized argyria develops
Code: ELG91{{
Page 3
ENGEI.EARI)
Date3 03 NOV 1993
IIIEERIAL SAFETI DATA SEEET
effects
2 to 25 years of exposure. There are no systemic
after
,,3t*r,or'
,dsl\
there is
and n6 physical Once deposited,
iisability.
lvnptons
O
l-i :j :
the pigrruentation
can be elininated;
nLairs by which thi3 silver
per:manent.
ITEDICjAIJ COIIDIAIONS GENENATLT AGCRAVATED BI EXPIOSURE
such as eye, skin,
medical conditions,
Mav adversely affect existing
Iiver andlor kidney ailments.
re3piratoryr-blood,
No?$: See Section VIII for Exposure Lirnits, Section XI for
Inforrnation.
and Section XII for Ecological
Information
Toxicological
flush eyes with plenty water for at least
of
EYE CONTACT: fmnediately
CaII a
with water.
open during this flushing
HoId eyelids
15 minutes.
physician innediately.
SKIN CONTACT: Flush area with water while removing contaminatbd
Do not
Follow by washing with soap and water.
and shoes.
clothing
get
persists,
or shoes until If irritation
reuse clothing cleaned.
unless ordered by the
Do not apply oils or ointments
nedical atten鈧琲on.
physician.
give
difficult,
Remove to fresh air. ff breathing is
INIIALATION:
a physician.
oxygen. Call
INGESTION: Irnnediately give two glasses of ivater and calL a physician,
emergency room, or poison control center for a way to j.nduce
hospital
Never give anything by mouth to an unconscious person.
vomiting.
F1ash Pointz 22 oC
Not Determined
Auto-Ignition:
LEL: Not Detemined
UEL: Not Deternined
NFPE EIZERD CIJASSITICArION
Reactivity: o
Health: 2 Flarnmable: 3
ENCEIJEAND Page a Code! f,lc91aa
UAAERIAIT SA3E:IY Dat6s 03 t{ov 1993
DA!!A SEEET
AUTS EAZAND CLASSIFICAIIION
Health: 2t Flanmable: 3 Reactivity: 0
* Indicates the possibility of chronic health effects. See
Chronic Health H-azards in Section III for nore information.
ggINC I.IEDIA
EXTXTTGUI
Use waterspray, carbon dioxide, dry chenical or foan.
SPBCIAIT FIRE 3IGETIIIC PROCEDITRES
positive-pressure
Wear NIOSH/MSIIA approved self-contained breathing
'and
prolbctive
apparatus btothing is specified in 29 CFR L9L0.l-56.
UITUSUAL FIRA I}ID EXPIOSXON trAZANDg
gases
F1anmable Product emit and corrosive a fire
liquid. will toxic in
situation.
Contain spillage, soak up with inert and scoop into container
absorbent
for disposal. of the National Response Center
Notification
(800/424-8802) nay be required. Refer to EPA, DOT and applicable state
and local regulations for current response infonnation.
prevention,
It is recornnended that each user establish a spitl control
and counter:measure plan (SPCC). procedures
Such plan should include
to proper storage,
applicable control and clean-up of spills, including
(see Section XI: Disposal
reuse or disposal as appropriate
Considerations) .
**NOTE** In the event of an accidental release of this material, the
above procedures proper exposure
should be followed. Additionally
and personal protection equipment should be used (see Section
controls
- Exposure Control/Personal
VIII Protection) and disposal of the
naterial should be in accordance with Section XI Disposal
Considerations.
AANDLING.AI{D STORAGE
Store in tightly closed container.
Store in a cool, dry location.
Wash thoroughly after handling.
Codes gLGgl{4
Page 5
ENGEIIEARD
Date: 03 NOV 1993
DATA SAEET
SIFBTY
I{ATERIAII
.,,:.\
or smoke in work area.
drink,
Do not eat,
adequate ventilation.
Use only with
vapors or mists.
Do not breathe
use.
Wash hands and face after
EXPOSI'RA LruITg
TLV-ACGIE
INGREDIEIIT PEIr-OgEA
I{ETALIO-ORGAI.IIC SILVER COMPOUNDS
None Established
None Established
CAS NO.: fN TSCA
CYCIPHEXANE
300 ppn 300 ppn
CAS NO.: LLO-82-7
as 8-hour Time:Weighted
a1l values are reported
Unless otherwise noted,
Averages (fWAs) and total dust (particulates A11 ACGIH TLVs
only).
Eo 29 CFR Part L910
All OSHA PELs refer
to the L992-93 Standards.
refer
Final Rule, January L9, L989.
Air Contaminants:
by the U.s. Circuit Court
of the JuIy 7, L992 decision
NOTE: As a result
of Appeals (AFL-CIO v. OSHA) to vacate the L989 PBLs, OSHA will no
to the pre-1989 PELs.
these new }inits
Ionger enforce and will return
to List the more prot-ective 1989
however, will continue
nng6lhard,
Ievels.
RESPIRAIORY PROTECTION
A NIOSH/MSIIA-approved respirator as necessary.
VEITTILETION
ventilation as necessary to control any air
local exhaust
General;
their PELs or TLVs during the use of this
contaninants to within
product
PROTBCIIrVE EQUTPUEIIT
Safety glasses (with side shields).
gloves should be worn.
resistant
Chenical
as necessary to prevent
Body protection skin contact.
PERAONNEITSAUPITIIIC PROCEDURE
For CYCLOIIEXAIIE; Refer to NIOSH Manual of Analytical 3rd
Methods,
Edition, Volume 2, Method 1500.
Page 6 Coder EtG9l{l
ENGBI.f,AND
Date: 03 llov 1993
I{IIERIEL SATETI DATA SAEET
.':;l:iii.:.i.!.r.!i,iril.ri:ii:iii]lll.liiil.:ii.iil,:i.:.:.:.:l:l.rir:..l.l.l:,ri::il:::t::::t::::.gECf
lott,:il'].It.i.:i.:.,:if.E:
Boiling Point: Not Determined
Specific Gravity (HrO=L)z L.24 g/cc
Melting Point: Not Deternined
Vapor Pressure (nn Hg) : Not Detemined
Vapor Density (Air=l) : Not Determined
Evaporation Rate (Butyl Acetate-l): Not, Detemined
t Solubility In Water: Insoluble
Appearance: Amber liquid
Odor: Solvent odor
pH: Not Determined
Stabillty: Generally considered stable.
Avoidr None expected
(ttateri.als
ntCOt{PefIBILITY to Avoid)
Strong acids, oxidizing agents, alkali.
strong strong
EAZIRDOUSDECOI{POSIrIOU OR BY-PRODUCTS'
produce oxides of carbon,
Thermal decomposition will oxides of sulfur,
and metal oxide funes.
Pollmerization: is not expected to occur.
Pollmerization
Avoidl Not applicable. .
,rNaoBttAt[troN
cEEltIcAr. t{Al{E t nt. LD50 LC50
METALIO-ORGANICSILVER COMPOUNDS
Not Available
CAS NO.: IN TSCA 80 90 Not Available
CYCIOHE)(AI.IE
10 L5 81,3 mg/kg MOUSE, Not
CAS NO.3 L10-82-7 Determined
oral
Code: ULG91{,I
Page 7
ENGEI',AARD
IIA'ITERIA& gAFETY DATA ggEET Date: 03 NOV 1993
f;"r
infor:nation.
for additional
VfIf and Xff
lff,
See Sections
NOTE:
ECOTOXICIlTT
No data available.
EMTIRONI,TEXTEI FATE
No data avai.lable.
US EPA Waste Number: D001
DO11
will determine
Federal, state and local disposal laws and regulations
the proper waste disposal/recycling/reclamation procedure. All waste
hazards
should be reviewed to determine the applicable
naterials
(testing may be necessary) . Disposal requirements are dependent on the
and will vary by location and the type of disposal
hazard classification
selected.
**NOTE** Chemical additions, processing or otherwise altering this
presented above
material may make the waste management infornation
inaccurate or othenrise inappropriate.
incomplete,
may varyt all waste must be disposed/regycLed/re-
As local regulations
clained in accordance with federal, state, and local environmental
control regulations.
INTERIIAIXONAL
UN Nunber: UN1993
ENGBI,EIRD Page 8 IILG91{{
Code:
ITATERXII. SAFETT DIiTA 8f,EET 03 lrov 1993
Date:
I'IIITED 8!ETES
EPA Waste Number: DO01
DOL1
DOT Classificationc 3 Flamnable and combustible licruid
DOT Proper Shipping Name: Flamnable Liquid, n.o.s.
Packing Group: IfI
CAITADA
PIN Nunber: ItN1993
TDG Class: 3 Flammable and cornbustible liguid
EC
DGL: Not Determined
Ug FBDBRAI. REGUI.ATTONS
TSCA: IN TSCA
SERA 311 IITD 312 EAZARD CATEGORIES
fUI{EDIATE (Acute) Health Hazard: YES
DEIAYED (Chronic) Health Hazard: YES
FIRE Hazard: YES
-
REA TIVITY Hazard: NO
-
Sudden Release of PRESSURE: NO
SARI SECTIOX 313 IIOTIFICATION
This product (or chenicats)
contains a toxic chemical subject t,o the
reporting requirements of Section 313 of Title of the- Superfund
Iff
Amendnents and Reauthorization Act of L986 and 40 CFR Part 372.
CEEtlIClIl lllltE CAS Number t Wt.
II{ETALI,O-ORGANIC SILVER COMPOUNDS
IN TSCA 80 90
CYCIOHEXANE
LLO-82-7 1_O L5
ozoNB DEPLETING SUBSTANeES (ODS)
This product neither contains nor is manufactured with an ozone
depleting substance subject to the labelling requirements of the Clean
Air Act Amendnents 1990 and 40 CFR Part 82.
C;
Code: ELG9144
Pags 9
ENGEI.EARD
Date: 03 NOV 1993
IIAIERIAL SAFEIY DATA SEBET
COtlPOUltDg (VOC)
ORGllnC
VOLIIrI.E
Not Determined
U8 STATE NECUI..ArIONS
CoUPOUND (CARB) : Not Determinbd
oRGN[Ic
VOLATILE
CEIIADIIT{ REGUIJATIONS
DSL,/NDSL: Not Detemined
Not Determined
wHMIs Classification:
EUROPEAII REGITLA:IION8
EfNECS! Not Deternined
OTEER REGUI.ArIONS
AICS: Not Determined
Deternined
l,tITI: Not
REVISIONA
Number: 3
Revision
This II{SDShas been revised in section(s):
the following
II: COMPOSITION/INFORMATIONoN INGREDIENTS
SECTION
III: HAZARDS IDENTITTCATION
SECTION
IV: FIRST AID MEASI'RES
SECTION
V: FIRE-FIGHTING I.TEASURES
SECTION
VIIf: EXPOSURE CONTROLS/PERSONALPROTECTION
SEetfON
IX: PHYSTCAL AND CHEI,TICALPROPERTIES
SECTION
XI:
SECTION TOXICOLOGICAL INFORMATION
XTII: DTSPOSAL CONSIDERATIONS
SECTION
XIV:
SECTION TRANSPORT INFORMATION
XV: REGUI,ATORYINFORMATION
SECTION
PREPARATXOII IIIFORUATIOII
Prepared By: Corporate Group
Environment, Health & Safety
I
Phone Number: See Section
in this Material Safety Data Sheet should be provided to
The information
all who will use, handle, store, transport, or otherwise be exposed to
this product. has been prepared for the guidance of
This information
and managenent and for persons working
plant engineering, operations,
Codes nLG9144
ETTGEI,EAND Page 10
Date: 03 NOV 1993
UATERIAI. SAFE.|[Y DAII SBEET
:, with or handling this product. The information presented in the MSDS is
'' prenised upon pioper handling and anticipated uies and is for the
We believe this
material vithout chenical additions/alterations.
as of the date of publication,
to be reliable and up-to-date
information
if this Material Safety
but make no warranty that it is. Additionally,
Data Sheet is more than three years old, please contact the supplier at
the phone number listed in Section I to nake cbrtain that this sheet is
curr-ent. Copyright Engelhard Corporation. License granted to'make
unLinited copies for internal use only. End of MSDS
|