MATERIAT, SAFETY DATJ
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04
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Labsafety supply Inc
PRODUCT AND COMPANY IDENTIFICATION
l"
Section
HMIS CODES
PRODUCT NUMBER
2*
Health
4
Flamrnability
20004
0
Reactivity
PRODUCT NAME
Black
C0LORPLACE* Spray Enamel, Flat
EMERGENCY TELEPHONE NO.
MANUFACTURERIS NAME
(2L6) 566-29]-7
by
Distributed
STOTCS INC.
WA],-M.ART
AR 727L5
Bentonville,
INFORMATION TELEPHONE NO.
DATE OF PREPARJATION
(216) s66-2902
27-MAY-03
2 -- COMPOSITION/INFORMATIONON INGREDIENTS
Section
VAPOR PRESSURE
UNITS
INGREDIENT
CAS No.
?byWT
74-98-6 Propane
18
ppm
25A0 750 mm
ACGIH TLV
ppm
1000
OSHA PEL
Butane
106-97-B
L7
800 ppm 760 mm
TLV
ACGIH
800 ppm
OSHA PEL
Hydrocarbon SoIvenL
Lb. Aliphatic
64742-89-8
100 ppm 53 mn
ACGIH TT,V
100 ppm
OSHA PEL
V. M. 5" P. Naphtha
64742-89-8
ppm 12 mm
300
ACGIH TT,V
ppm
300
OSHA PEI,
ppm STEL
400
OSHA PEI,
108-8B-3 Toluene
ppm (skin) 22 mm
ACGII{ TLV fU
ppm (skin)
OSHA PE], 100
ppm (skin) STEL
OSHA PEL 150
Ethylbenzene
100-4L-4
0.1
ppm
100 7.1 mm
ACGIH TLV
ppm STEL
]-25
ACGIH TLV
ppm
l-00
OSHA PEL
ppm STEL
125
OSI]A PEI
111 - 7 6-2 2 -Butoxyethanol
ppm (skin) 0 .88 nrn
2A
ACGIH TLV
ppm (skin)
OSI{A PEIJ zv
67 -64-]- Acet,one
ppm 18 0 rnm
500
ACGIH TIJV
ppm STEL
ACGIH TIIV ,TJU
1 0 0 0 ppm
OSHA PE],
I4807 -96-6 Talc
ACGII{ TI,V mg/m3 as Resp. Dust
1
mg/m3 as Resp. Dust
OSHA PEL
on page 2
Continued
page 2
20004
o Carbon Black
L333-86-4
0.4
mg/m3
3.s
ACGIH TT,V
3.5 ng/m3
OSHA PEL
SCCTiON 3 -- HAZARDS IDEI\XTIFICATION
ROUTESOF EXPOSURE
of vapor or spray mist.
INHAIJATION
EYE or SKIN contact with the product, vapor or spray misL.
EFFECTSOF OVEREXPOSURE
of eyes, skin and upper respiratory system.
Irritatj-on
Extreme overexposure may result
May cause nervous system depression. in
unconsciousness and possibly death.
SIGNS AI{D SYMPTOMS OVEREXPOSURE
OF
nausea, and loss of coordination are indications of
Headache, dizziness,
excessive exposure to vapors or spray mists
or burning sensation may indicate eye or excessive
Redness and itching
skin exposure
MEDICAL CONDITIONS AGGRAVATED EXPOSURE
BY
None generally recognized.
CAT{CERINFORMATION
==:::=::T:::::=3:::::::::=::=::::::l:g==:i=:::::=::=:::::::
Section 4 FIRST AID MEASURES
remove from exposure.
If affected, Restore breathing.
INHAI.,ED:
If
Keep warm and quiet.
Wash affected area thoroughly with soap and water.
ON SKIN:
If
Remove contaminated clothing and launder before re-use.
Flush eyes with large amounts of water for l-5 minutes.
If in EYES:
Get medical attention.
SWALLOWED; Do not induce vomiting.
If
irnmediatelv.
Get medical attention
UEL
POINT LEL
F],ASH
0.9
Propellant ]-2.8
EXTINGUISHINGMEDIA
Carbon Dioxide, Dry Chemical, Foam
UNUSUAIJFfRE AI'ID EXPIJOSIONHAZARDS
Containers may explode when exposed to extreme heat.
to hot surfaces requires special precaut,ions.
Application
During emergrency conditj-ons overexposure Lo decomposition products may
Symptoms may not be inrmediately apparent.
cause a health hazard. Obtain
rnedical attenEion.
FTRE FIGHT]NG PROCEDURES
SPECTA.T,
Ful-I protective equipment including self-contained breathing apparat,us
should be used
Water spray may be ineffective. If water is used, fog nozzles are
preferable. Water may be used to cool- closed containers bo prevent
pressure build-up and possible autoignition when *rposed to
or *rplosion
extreme heat.
on page 3
Continued
20004 page 3
6 --
SeCIion ACCIDEIITAL RELEASE MEASURES
STEPS TO BE TAKEN IN CASE MATERIAI, IS RELEASED OR SPILLED
Remove all sources of ignition. Ventil-ate the area.
Remove with inert absorbent.
7 --
Section HANDIING AND STORAGE
STORAGECATEGORY
Not Available
PRECAUTIONS TO BE TAKEN IN HAND],ING AND STORAGE
Keep away from heat, sparks, and open flarne. Vapors wiII accumulate
readily and may ignite explosively.
- Do nou
During use and until- all vapors are gone: Keep area ventilated
smoke - Extinguish all flames, pilot and heaters * Turn off stoves,
lights,
electric tools and appliances, and any other sources of ignition.
Consult NFPA Code, Use approved Bonding and Grounding procedures.
Contents under pressure. Do not puncLure, incinerate, or elqpose t,o
temperabure above l-20F. Ileat from sunlight, radiators, stoves, hot water,
and other heat sources could cause container to burst. Do not take
1:::::111I:==f
:!=:::=::=:1:=::3:1=::=::i131:l:======_===
--
Section I EXPOSURE CONTROLS/PERSONALPROTECTION
PRECAUTIONS TO BE TAKEN IN USE
Use only with adequate ventilation.
Avoid contact with skin and eyes. Avoid breathing vapor and spray misE.
Wash hands after using.
only during sanding or abrading of the dried fi1m. If no specifi-c dusts
are listed in SecEion 2, the applicable limits for nuisance dusts are ACGTH
TLV L0 mg,/m3 (total dust), 3 mg/m3 (respirable fract,ion), O S H AP E I J 1 - 5 m g / m 3
(totaL dust), 5 mg/m3 (respirable fraction).
Removal of o1d paint by sanding, scraping or other means may generate
dust, or fumes that contain Lead. Exposure Lo lead dust or fumes may cause
brain damage or other adverse health effects, in children
especially or
pregnant women. Controlling exposure to lead or other hazardous substances
requires Lhe use of proper protective equiprnent, such as a properly fitted
(NIOSH approved) and proper containment and cleanup.
respirator r'or more
information, call E,he National I,ead Information Center at 1-800-424*LEAD
(in US) or contact your local health authority.
VEI\TTIIJATION
Local exhaust pref erable. General exhaust acceptabl-e if the erq>osure to
materials in Section 2 is maintained below applicable exposure limits.
Refer to OSHA St,andards l-9L0.94, l-910.L07, l-91-0.108.
RESPIRATORY PROTECTION
If personal exposure eannob be controlled below applicable limits by
ventilat,ion, wear a properly fitted organic vapor/particulate respirator
approved by NIOSH/MSHA for protection against, materiats in Section 2.
When sanding or abrading the dried film, wear a dust/mist respj-rator
approved by NrOSH/lvlSHA for dust which may be generated from this product,
paint,
underlying or the abrasive.
on page 4
Continued
20004 page 4
===========================================================================
.gROTECTIVE GI,OVES
None required for normal application of aerosol prod.ucts where mj-nimal-
a
Ekin contact is expected. For long or repeated wear chemical
contacE,
gloves.
resistant
EYE PROTECTION
Wear safety with unperforated
spectacles sideshields.
OTHER PRECAUTIONS
Intentional misuse by deliberately concentrating and inhaling the
contents can be harmful or f at,aL.
Section 9 PHYSICAL AND CI{EMICAL PROPERTIES
PRODUCT WEIGHT 6.34 }b/ga1 75e glI
SPECIFIC GRAVITY 0.76
<-18 - l-72 C
<0-343F
BOILING POINT
MELTING POINT Not Availab1e
VOLATIIJE VOLUME 89 Z
EVAPORATION RATE Faster than et.her
VAPOR DENSITY Heavier than air
N.A.
SOIJUBILITY IN WATER
VOI-.,ATILE ORGANIC COMPOUNDS(VOC Theoretical)
Vo1atile Weight 59.83 ? Less Water and Federally Exempt Solvents
SecLion ]-O STABILITY AND REACTIVITY
STABII,ITY SIable
^IONDITIONS TO AVOID
None known
U
TNCOMPATIB TIJTTY
None known.
HAZARDOUS DECOMPOSITION PRODUCTS
By fire: Carbon Dioxide, Carbon Monoxide
HAZARDOUS POLYMERIZATION
WitI not occur
================================-==
Section 11 TOXICOLOGICAL INFORMATION
CHRONICHEATTH HAZARDS
Ethylbenzene is classified by IARC as possibly earcinogenic to humans
(2B) based on inadequat,e evidence in humans and sufficient evidence in
laboratory animals. Lifetime inhalation exposure of rats and mice to high
ethylbenzene concentrations resulted in increases in certain types of
cancer, including kidney tumors in rats and lung and Liver tumbrs in mice.
These effects were not observed in animals e>qlosed to lower concentrations.
There is no evidence that ethylbenzene causes cancer in humans.
Carbon Black is cl-assified by IARC as possibl-y carcinogenic to humans
(group 28) based on experimental animal data, however, there is
insufficient evidence in humans for its carcinogenicity.
_ Prolonged overexlposure to solvent ingredienEs in Section 2 may cause
adverse effects to the liver, urinary, blood forming, cardiovascular and
reproductive svstems.
Reports have associated repeated and prolonged overexposure to solvents
With permanent. brain and nervous system 3.amage.
o ont.inued on page 5
20004 page 5
===========================================================================
|-I'OXICOLOGY DATA
, CAS No. Ingredient Name
V
74-98 - 6 Propane
LCsO RAT 4HR Not Available
LDsO RAT Not Available
105-97-8 Butane
LC50 RAT 4HR Not Available
LD50 RAT Not Avai_Iable
647 42- 8 9- B Lt. Aliphatic llydrocarbon Solvent
1,C50 RAT 4HR Not Available
LDsO RAT Not Available
64742-89-8 V. M. & P. Naphtha
RAT
LCsO 4HR Not Available
LD5O RAT Not Available
1-08-88-3 Toluene
LCsO RAT ppm
4HR 4000
LDsO RAT s000 mg/kg
i . 0 0- 4 L - 4 Ethylbenzene
LCsO RAT 4HR Not Available
LD5O RAT 3s00 mg/kg
2 -Butoxyethanol
L1"L-76-2
LCsO RAT 4HR Not Available
LDsO RAT 470 mg/kg
67-64-1 Acetone
LCSO RAT Not Available
4HR
LD5O RAT s800 mg/kg
TaIc
l_4807-96-6
LCsO RAT 4HR Not Available
LDsO FAT Not, Available
Carbon Black
1333-86-4
RAT
LCsO 4HR Not Available
LD5O RAT Not Available
ECOTOX COLOGI CAL INFORMATION
I
No data available.
===========================================================================
1-3 -- DISPOSAL CONSIDERATIONS
SecIioN
WASTEDISPOSAL METHOD
Waste from this product may be hazardous as defined under the Resource
Conservation and Recovery Act (RCRA) 40 CFR 251-.
waste must be tested for ignitability to determine the applicable EPA
hazardous waste numbers.
Do not incinerate. Depressurize container. Dispose of in accordance
with Federal, State/Provincial, and T,oca1 regulations regarding pollution.
].4 TRANSPORT
SecLion INFORMATION
No daE,a available.
Continued
20004 page 6
CAS No. CHEMICAL/COMPOUND ? by WT k Element
108-88-3 Toluene L2
l - 00 - 4 1 - 4 'n1
Ethylbenzene U.I
Glycol Ethers z
CALIFORNIA PROPOSITION 65
WARNING: This product known to the State of
contains chemicals
California to causE cancer and birth or other reproductive
defects harm.
TSCA CERTIFIEATION
A11 chemicals product
in this are list,ed, or are exempt from listing,
on the TSCA fnventory.
-:-:::======]=============-========================================
16 _- OTHER INFORMATION
Seclion
This product has been classified in accordance with the hazard criteria
of the CPR and. the MSDS contains aII of the information required by the
CPR.
The above informat.ion pertains to this produet. as currently formulated,
and is based on the information available lt this time. Addilion of
reducers or other additives to this product may substantially alter the
and hazards of the product. Since conditions of use are
llcmposition
our control, we make no warranties, express or implied, and assume
Itrtside
in connection with any use of this j-nformation.
no liabirity
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