] ' l r r i < J , iR a c t c a i n P o 1 1 ' c ' t h v l e n ei n c a r . t o n s
B A T T E R y I , I C T R O I , Y T(E c i d ) ; B a r t c r y
A
E
Fortn nogrovcd
U . S .D E P A R T M E N T F L A I ] O R
O
cAs ( 7 6 6 / l - 9 3 * 9 ) oMB No. d4.R1387
7.?/
and lle;rlth Atlntinirtrarion
Safety
Occupational
EI'A ( $ 6 4 2 - 74 7 )
HAT[RIAL DfiTA
SAFITY SI.lTET
Required under USDL Safety and Health Regulationl for Ship Repairing,
S h i p b u i l d i n ga n d S h i p b r e a k i n { 2 9 C F R 1 9 1 5 , 1 9 1 6 , l 9 l 7 }
. g
CAREFULLY.
READ ALt ATTACHI'IENTS
READ ALL ATTACIil'IENTS
CAREFULLY. SECTTON I
gMERGENCY T鈧琇EPHONE NO.
MANUFACTURER'S NAME
3L2/s62-7290
CORPOMTION
SCHOLLE
Streer,CirT', Srate.ond ZIP CodeJ
AooR Ess (.\,iumber,
2 0 0 I . I . N o r c h A v e n g . e . N . ' r r t h la - k e . I l l i n o i s
I TRAOE NAME AND
NAME ANO SYNONYMS SYNONYMS
CHEMICAL
r\cid - Battery Electrolvte (Acid) lQual Brand & Private Label Brands
Sulfuric
+E,*H'ru'-
Inorganic Acid - Sulfuric Acid HTsoa
SECTION HAZAI'{UUUs IIVbHtsL'IEIV I S
P A I N T S ,P R E S E R V A T I V E S& S O L V E N T S
. ALLOYS .AND METALLIC COATINGS
BASE METAL
PIGt'ENTS
CATALYST
METALLIC COATTNGS
VEHICLE
FILL鈧琑 METAL
SOLVENTS PLUS COATING OA CORE FLUX
ADDITIVES
H A Z A R D O U S M } X T U R E SO F O T H E R L I O U I D S ,S O L I D S .O R G A S E S
B A T T E R Y L E C T R O L Y T( A c i d ) : of
Batterv a hishlv mixture
E E Fluid is corrosive
(li"O) , possessing a specific
( H . , S O) a n d p u r e w a t e r
,
acid
sulfuric travity
( 2 5 V " - 4 O H" S o / . )
7r
ranging from 1.200 + 0.005 ro 1.300 + 0.005 ar BOoF.
ur dav is:
S E C T I O NI I I . P H Y S I C A L A T A
D
BorLrNG potnr (tp.t s P E c l F l cG R A v I T Y { H 2 o ? l }
2o30r @ ggoF
to l. 300
1.200
PERCENT. VOLATILE
(mm H9.)
PRESsURE
VAPOR
loGtSoF aY voLuME (%)
E VA P O R A T I O N R A , I E
V A P O R O E N S T T Y( A l R E l l
+1 (H,0)
(- 1
r l l{ater
SOLUSILITY 'N WATER
laa"A REA,DATTACHEDSPECIFICATIONS CABEFULLY
APPEARANCE oooon_c(rlorless,
Aft clcrudy -
oily slightly
f1uid, to orlorless
S E C T I O NI V . F I R E A N D E X P L O S I O N A Z A R D D A T A
H
(l,t.tnod
POINT
FLASH u!.d) FI.AMMAELE LTMTTS
EXTINGTJISHING T':OtA
rnaterial is use large quantltles
this
If involved in a flre, of water.
FIRE FlcHTlrrG
CIAL PROC鈧琌URES
Lute any spiJled or leaking battery with
electrolyte large amounts of water.
$ r r i l e X P LV e f O N H A Z A R O S
- OSit
NUSUAL iraf
-
on:Flarrunabl e-bul reJCtIVe conbustible materlals.
Capabl e of igniting
P.AGE 1I (Continued on r:ver* ride)
{ DBO-l 523 Form 0Sl'1A.20
'.:.
':,
1. i
.
DATA
HEALTHHAZARD
V
SECTION
does not c
el"ectrolvte
Batte
S E C T ION I . REACTIVITY
DATA
V
-{if TO AVOID
CONDITIONS
Coniact wirh @
STA3ILITY UNSTA9LE
srABLe | 1007"
r - l i . : r C 4 3 l SI u J L
f NCOr,r2ATA9rLlTY
end alr ots-t"i"
aii 'et"i"
'itt
i;;;;GAi;i"
D=cotrPosrTroN PRooucrs
xaienccus
coNotTloNs To AVolo
MAY OCCUR
HAZARDOUS
POLY'!IE ETZATION
u/'LL NOT OCCUR
S E C T I O N I I . S P I L LO R L E A K P R O C E D U R E S
V
::a::: : : =e u: e : ;s e o
= : a ;: o:R; ;S P;Ix "L E D
: : ;; L
s*
h
;;h ;;;i';. ;?i;;;;a-'LJ;-sr;i' Pia"rY"r'"te''
sawdust? or .an):other conbustibles'
Do not use cloth'
sand or ashes.
of soda and dilqqg with water.
ffi;"i'i;";?'"iifi-t?Sarbonare
S E C T I O N I I I . S F E C I A LP R O T E C T I O NN F O R M A T I O N
I
V
-Iocau
Exueusr SPECIAL
i/g11111-3,TtON Datisfactory
I
OTHEST
rriciexrceu lGencral)
l eve enorecrlo&
:ty Coggles
lChemical$afr ,
.
-
Rubhel-G-lSyes -
鈧琎UIPilENT
PEOT鈧珻TtV;
OTHER
Cl ove$
rer ,, ,
niiUtlcr Arrron. ll;rCc'
SPECIAL RECAUTIONS
P
S E C T I O NI X
pescAuTlor.s ANo SToRING
B: TAKE.N lN HANoLlN,c
ro
Jffi6'"ir.,-'l"ooi.]-ary'iiace.'-fqrrv'iri.oCeciea_ rro"* rnoistqre and sgverg t{e.ather. Avoid
r l l h a n d l i n-_ a n d s t o r a g e p r o c e d u r e s t h a r m a y r e s u l t i n s p i l l s ' l e a k s ' p u n c t u r e s .
g
a___________
srorq ln areas where an unlimlted water surrplv ls avallable.
;"Jfi,ti.,"";ii:';fili.t
Form OSHA-?O
PAGE 12}
Rrv. Mry 72
ct o I ti.:&)
a
IJ3il-4.r!
contact with
are the basls of proper first aid for
Tlrese gcneral rules
sulfuric acid:
since delay ean result in
First aid nrust be started inrnediately,
serious injury.
thc
no Tnatter how sltght
Call a physician as soon as possible,
inJury appc'ars to be.
'
Alf contaminated clothing must be removed immediately, FLush
areas of the body with copious guantities of water until all
affected
traces of sulfuric acid are removed.
Do not neutralize the acid with urild alkaline solutions until all
amounts of
areas of contact have been thoroughly washed with plentiful
running lrater
In.case of severe or extensive burns, shock slnnptons -- rapid
pulse, svreating, collapse -- might aPpear at any time, I{hen they do,
place the patient on his back and keep ltim wBrm, not hoE, unlil a
Do not give anything by moutlr to an unconsciotls
physician arrives.
patient. :
acid:
sulfurlc
In ease of eye contact with
of running water for 15
Wash the eyes with copious quantities
the eye lids apart to rnake sure the **ater washes all
m{nutes. Hold
Do not use hot ltater.
tissues of the surface of the eyes and lids.
must be called inunediately.
A physician, preferably an eye specialist,
should be
If he does not arrive within 15 minutes, eye irrigation
After the first irrigatiotr,
resumed for a second 15-minute period.
r$ro or three drops of 0.57" pontocaine solution or egually effective
aqueous topical anesLhetic IItElybe placed in the eyes by a qualified
aid man, Do not use any other solution or ointment.
first
acid has been taken internally, call a physician iuune-
ff sulfuric
Do not give anything by mouth to
Do not induce vomiting.
diately.
an uneonscious patient.
If the patient is conscious, have him wash out his mouth with copious
Then have him drink milk, preferably mixed with
quantities of lrater,
have
of eggs. If milk and egg whites are not available,
the whites
patient drink as much wacer as possible.
the
A n y a c c i d e n t a l c o n f a c t w i t h s u l f u r i c a c i d , w l r e L l r e re x t e r n a l o r J n t c r n a l
should bc dcscribed to tlre physician in detail at Llre time that hc is
He should be given Ehe exact location of the patient.
caLled.
Reupve to fresh air.
-) and repeated breathlng of vapors.
A'void repeat.ed conLact with skin
IlAJ:ljlillrJif|lN!:J-L- IJt'!]':RNJU:r-oN4I:.-.1.r',1':!J
tJ-Q4.l'I.QU.l
"o the
sha1l be a solution of sulplttrric acid in pure ltatcr at
Electrolyte
The capacity and
required by the procuring agency,
sfecifi"-gravity
gravity
plrformance reqi,irements tlrough are based on the eLectrolyre
batteries are
ff f.265 +.005 regardloss of the gravity at which the
used in sErvice.
sulphuric acid used in preparing this electrolyte
The first-class
conform to the reqr.rirements of the latest issue of Federal Speci-
sha.ll
fications O-S-801-b.
shall conform
dry-charged batteries
used for filling
Electrolyre
stated in this B.C,I. Yearbook, which is quoted
as
to the specification
below:
covers sulphuric acid eiectrolyte
Scope: This specification
a.
for use in dry-clrarged storage batteries within a specific
gravity range of f .ioo to 1.300 sp. Gr. at B0or Q6-7ac)-
shall
Requircments: This speclfic gravity of tlrc electrolyte
b.
be as ordered wiEh a tolerance of plus or minus .003.
speclflc graviLy shal1 be determined by a hydrometer cali-
( 2 6 . 7 u C ./ 2 0 . 7 " C . ) .
brared ar B0or/80'F.
o gravity
specific
coincide with
I h e H 2 S O 4c o n t e n t s h a l l
(plus or minus .L27,).
not exeeed Lhe mav-imum
shall
in the electrolyte
Irryurities
shown in the table below:
llmits
llaximum Limit Per Cent
ImpuritY
To pass test defined in Federal
Organic Matter
Specification O-S-801-b, 4-14-65
.075
Flxed residue
.o03
Iron (fe)
r 0015
Sulfurous Acid (SOZ)
.00004
Arsenic (As)
.00004
Antimony (Sb)
.000007
Manganese (l-'In)
.0002
(t'l0g)
Nltrates
.0004
Asmoniun (Ntl4)
.004
Chloride (CI)
.o025
Copper (Cu)
.0015
Zlnc (Zn)
.0007
Selentum (Se)
.0000/+
Nickel (Ni)
1o pass test defined in Federal
(et)
Platinun
Specification O-S-801-b, 4'14-65
t
t'
DEPART]'MNTOF TRANSPORTATION
}IA7-ART}OU },lAT[RI ALS
S ra
SPTC }:I CAI'IONS
I
PACKAG1NC
(acid) and alkaline corrosive battery fluJc
$ fZf.ZSZ Electrolyte .
(acid) may not,L" oroor 47 percenr strength (39o lia
(a) nleccrolyre
lt.ria must be packaged ;'r
or *it rl.irr" corrosive baEtery
Electrolyte o r ! r ' 1 iL 鈧? f Y
a bag to contain the electrolyte
(packaging utilicing
follows
by air):
fluid is not ar.rthorized for rransPortation
o f t h i s s u b c h a p t c :) '
Spei. 128 or l2C (SE fZa.205 or .L78.206
(6)
polyethylene or other electro-
Fibbrboard boxes with inside corrtainers'of
having secure closures r::apable
lyte acid resj.siant nonfragile materials
without leakage and
of withstanding conditions incident to CransPortation
nature they must be contained
unless conLainers arc rigid or semi-rigid in
thlckness of polyetlrylene or
in other strong i'side containersl minimum
otlrermaterialsslrallbenotlessEhan'0:993-inch-forany.filmsheetfor
inch for- single-wal1 containers;
multiWal1 confainers or not less than O'006
shal1 be packed in one outside box
not ruore than 12 such inside containers Inside
in $ f23.401(c) shall i'rot be required'
a'd the nrarking pt"""tiU"a
containersshall.bepackedtopreventmovemenEwitlrin'|:11(see
Dry srorage batteries
5 5 f Z g , Z A S - 3 4 : r r r d 1 7 i J . 2 0 6 - 1 9o i t l r i s s r r b c h a p t e r ) '
S d n t eo u t t s i d e b o x w l t e t t a d e -
in lhe
or baftery charger device may be packcd of this
from other insiie containers (se9-3 ffg '2O5-33
guarely separared
not exceed 65 potrnds'
package shall
subclraptcr); gr(lss weight of completcd
inside conLainers the gross weiglrt
pa"t*a i-n individ.ral
except when acid is
closed as for shipnrent' rn'ith
s h a l l b e n o t o v e r 7 5 p o u n d s . c o n ' p 1 e t e- p a c k a g e , as cornraodity
with liquid of sane sPecific gravity
inside containers filied 2 drops from a
I rmrst be capable oi withstanding at least
i.-i"-"rripp"d,
without leakage from or rupture of
height of 4 feet onto solid concrete
inside containers.
C o r r u g a t e tI f i b e r b o a r d
tQ tta o^E ^r *Li - o,rl'alrenr
(14) Spec. 128 (g 178'2AS 9f elis subchapter)'
as_defined in 5 178.205-37 of this subchapter'
boxes wirh pf""ti.'taBp
shal1 not be required'
I'Iarking ptu".tit.,od in-$ 172'312(a)
suitable
g rza .205-37 Special boxl authorized polyethylene or otlter
or alkaline corrosive
(acid)
bags for pa"tagrng oi electrolyte
plasric excepl as
(i) gox must comPly with this specification
fluid. onfy.
battery styl"e and sra)'have
of slotted
Box nrr,:stbe one-piece construction
follows: closure Part'
size to provide access to an inside
die-cut areas of minirnum other suitable
bai made of pol.yethylene _or
Box must conEain one multiwa11 coming into contact
size a'd eafacity to te capab1e of
of sufficient
plastic Each ply of the
tile-box when filled.
surfaces'of
with all 0f the interior Joints
film not -less than 0'003 inch rhick'
bag musc be formed from virgin
l/B-inch wide'
must be heat sealed and not less than
st yltr' ot -t:g*l ar slottcd -
Boxt:s nttrs bc cctrter :poti al. sl ot Led
t
(b)
E t y l e . I f a , ' y n , c r a l i s t . r s e < l i n E l r c b o x c o n s t r r r c t i o r t , f u l l l i t r c r sa n ds o lp r g c t t r b e ' m r r s L
a di tc a
Any 'retal closurc for
and boEto* puiu-'ute requircd. bag' Dis-
so as to prevent coniact with the polyethylene
be installed
Maximum volumetric capacity
sealed'.
charge tubes rm.rst be piugged or heat
5 gallons (nominal) '
must not exceed
fiber-
of 6 qr'rarts (nomlnal) or less'
For boxes h a v i n g c a p a c i t i e s
(f) for construction'
least 200-pound test ls r e q u i i e d
boarcl of at
-2-
It'
'o excess of 6 quarrs, fiberbcrard of
(2) For boxes havlng capaclcles in
Pads are required for regular slotted
least 350-pound Lest is reqtrired.
at
of at leasr 35O-potrndtest or other
style boxes and mtrst be of fiberboard
Protec cion.
material tlraE will provide equi,valent
(c) Reprcsentative samples of completeLy assembled boxes with aLl parts
closed as for shipment, ;must be capable of withstanding the following tests
No one box shall be expected to
wlthout lcakage or serious damage to boxes.
more than one of the following tests:
withstand
.(1) Box with inside container filLed to shipping capacity with a solu-
tion vhich is cornpatible with the plastic bags nust be dropped twice from
a height of 4 feet ontcr concrece, one drop to be made with the box posi-.
tioped so as to strike flat on the box bottom, the other drop to be frade
strike flat on the Largest face,
so box will
to shipping capaci.ty with a solu-
Box rvith inside conLainer filled
(2)
tion which is corpatible with tbe plastic bags, and renains liquid at
goF. or lower shall be dropped once from a hcight of 4 feet onto conerete,
when container and conLents are ac or below OoF, Box shall be positioned
so as to strike flat on the box botEom.
as prescribed in paragraph (c)
Box with inside eontainer filled
(3)
(1)-of tfiis secrion shall be capable of withstanding a vibration test by
table anchorcd in such a manner Lltat
placing tlre container on the vibration
be restricted and only vertical motion al1owed.
froiiuonta] moticn shall
Tf
" fh e t e s t s h a t l b e p e r f o r m e d f o r o n e h o u r u s i n g a n a m p l i t u d e o f o n e i n e h a t
a freguency that causes the test container to be raised from the floor of
the table to such a degree that.a piece of paper or flat straP or tape can
be passed beLween the tabLe and the container.
Tesrs to be condueted by or for each plant assembling and filling
(d)
start of production and must be repeated at inter-
boxes at the initial
of four nronths thereaf rer; init-ia1 tests must bc wit.nesscd by a
vals
Samples last tested musL be
of the Btrreau of Expl"osives.
representative
subsequen[ tests are
date of test and urust be retained until
dafed with
boxes with liners may be shipped to a central point for
Empty
condueted.
and testing in which cases the Bureau of Explosives
assembling, filling
.
must be advised of test location.
:o
"e
CERTIFICATIOT'I
QUAL ACrD PACKACIS
Scholle Corporation, I Net,ada corporation rvith principal
offices at 200 11. North Avenue, Northlahe, 11linois, hereby certified
and wal-rants that its Qual Acid Packages have been tested in accor-
dance witlr the proccdures established under the United Slates Federal
Govcrmnenr "Poison Prevention Packaging Act of 1970".
Said protocol tests were conducted by the llomeArts Grrild
report is on file in the offices
Research Ccnt"er, and tlre official
of the Fcderal Governmentrs Consumer ProducL Safecy Cclurmission.
to alty customcr
- Copics of the protocal tcst report are availablc
the company on request to tbe Scholle Corporation'
of
-
I
- and warranted that Qual /rcid Packages
It is ftrrther certified
successfully.exceeded al-1 mininum requirements of Ehe test, wiEh bolh
Closure r.ritlrin
as a Child-Resjs[ant
children and a'du1ts, and qualifies
the mearrirrgof the Poison Preventiorr Paclcaging Act of 1970.
hereby.
are expressed or implied
No other warranties
January L979.
Lst day of
this
CERTIFIED to,
Corporation
Seholle
By:
lLu0v*
P. J. Petersen
Presldent
|