SIGMA CHEMICAL COMPANY
P O S T O F F T C EB O X 1 4 5 0 8
SAINT LOUTS, MISSOURT 3178, USA 6
SGMA-ALpFltCH
ATTN: SAFETY DIRECTOR E M E R G E N CP H O N E1 - 3 1 4 - 7 7 I - 5 7
Y 55
ST CLOUD STATE UNIV
AS I22 DATE 09/A5/02
720 FOURTH AVE S c u S T # I 0 . - 49 ' 4 - 73 8 1 1
SAINT CLOUD MN 56301-4498 PO#: 98II2
MATERIAL SAFETY DATA PAGE
SHEET 1
THIS MSDS IS FOR A COMPONENT CATALOG#:
OF 35-A
- * CHBMICAL..I,DEilTIFICATION-
SECTION l.
C A T A L O G# I 555-8
, T R I C H L O R O A C E T I C C I D S O L U T I O N0 . 4 9 N
NAME: A
SECTION 2. COMPOSITION/TNFORTVTATIONTNGREDTBNTS
ON
7 6-03-g
EC NOz 200-927-2
HAZARDOUSINGREDIENTS
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T R I C H L O R E S S I G S A E U R(E E R M A N ) T R I C H L O R O A C E T I C C I D ( A C G I H ) *
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ACID * TRICHLOROMETHANECARBOXYT]C ACID *
TRICHLOROETHANOIC
S E C T I O N3 .
oNARY
srArEMENrs
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C A U S E SB U R N S .
T A R G E TO N G A N ( S ) :
CENTRAL NERVOUSSYSTEM
I N C A S E O F C O N T A C T I T H E Y E S , R I N S E I M M E D I A T E L YW I T H P L E N T Y O F
W
WATER AND SEEK MEDICAL ADVICE.
WEAR SUITABLE PROTECTTVE CLOTHTNG, GLOVES AND EYEIFACE
PROTECTION.
I N C A S E O F A C C I D E N TO R I F Y O U F E E L U N W E L L , . S E E KM E D I C A L A D V I C E
I M M E D I A T E L Y ( S H O WT H E L A B E L W H S R EP O S S I B L E ) .
S E C T I O N4 . FIRST-AID MEASURES-
WASHOUT MOUTHWITH WATER PROVIDED PERSONIS CONSCIOUS.
IF SWALLOWED,
CALL A PHYglgrAN._
DO NOT INDUCEVOMITING.
IF INHALED, REMOVE O FRESHAIR. IF NOT BREATHING IVE ARTIFICIAL
T G
R E S P I R A T I O N . I F B R E A T H I N GS D I F F I C U L T , G I V E O X Y G E N .
I
IN CASE OF SKIN CONTACT. FLUSH WITH COPIOUS AMOUNTS OF WATER
FOR AT LEAST 15 MINUTES: REMOVECONTAMINATED CLOTHING AND
SHOES. CALL A PHYSICIAN.
IN CASE OF CONTACTWITH EYES, FLUSH WITH COPIOUS AMOUNTS OF WATER
FOR AT LEAST 15 MINUTES. ASSURE ADEQUATE FLUSHING BY SEPARATING
CONTINUED ON NEXT PAGE
170
V/e are to through
Committed the Success of our Customers Science, Technology and Service,
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SIGMA CHEMICAL COMPANY
P O S T O F F T C EB O X 1 4 5 0 8
sArNT LOUTS, MTSSOURT 3178, USA 6
CUST#t 0-494-73811
PO#: 98112
MATERIAL SAFETY DATA SHEET PAGE 2
-3;-;
rHrs MsDsrs FoRa cor'rpoueNT
or-careioc *r-
C A T A L O G# : 665-8
NAME: TRICHLOROACETIC CID SOLUTION0.49 N
A
THE EYELIDS WITH FINGERS. CALL A PHYSICIAN.
SECTION 5. FIRE FIGHTING MEASURES
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cHeMrcALpowDER AppRopRrArE
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SPECIAL FIREFIGHTING PROCEDURES
I'BEETHiNG AND
aeeanaTus PRoTEcTIvE
cLoTHING
To
P R E V E N TC O N T A C T I T H S K I N A N D E Y E S .
W
UNUSUALFIRE AND EXPLOSIONSHAZARDS
E M I T S T O X I C F U M E SU N D E RF I R E C O N D I T I O N S .
_ ACCIDENTAL RELEASE MEASURES-
SECTION 6.
BREATHINGAPPARATUS, RUBBERBOOTS AND HEAVY
WEAB_SELE*C_QNTAINED
RUBBERGLOVES
qgyER-wIrH^pR_{_LluE_gB_sqp4 prcK up, KEEPrN A cLosEDCoN?ATNER
AsH,
AND HOLD FOR WASTE DISPOSAL
AND WASH SPILL SITE AFTER MATERIAL PICKUP IS COMPLETE.
V-E-!.ITI.!A!E_ABEA
EVACUATE AREA
- HANDLING AND STORAGE-
SECTION 7.
R E F E R T O S E C---- N 8 .
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SAFETY SHOWER AND EYE BATH.
USE ONLY IN A CHEMICAL FT'MEHOOD.
WASH CONTAMINATED CLOTHING BEFOREREUSE.
DISCARD CONTAMINATED SHOES.
WASH THOROUGHLY AFTER HANDLING.
DO NOT BREATHE VAPOR.
DO NOT GET IN EYES, ON SKIN, ON CLOTHING.
A V O I D , P R O L O N G E O R -R E P E A T E D ' X P O S U R E .
D E
NI OSH/MSHA_APPROVED RESPIRATOR.
BLE CHEMr
courPATr CAL-RESrSTANT GLOVES .
C H E M I C A LS A E E T Y G O G G L E S .
(8-INCH MINIMUM)
FACESHIELD .
KEEP TIGHTLY CLOSED
STORE IN A COOL DRY PLACE.
SECTION 9. PHYSICAL AND CHEMICALPROPERTIES
APPEARANCEAND ODOR
L I Q U ID .
-STABILITY AND REACTIVITY
SECTION10.
S T A B IL I T Y
CONTINUED ON NEXT PAGE
T7I
SIGMA CHEMICAL COMPANY
GMA-ALDFIICH P O S T O F F T C EB O X 1 4 5 0 8
sArNT LOUTS, MISSOURI53178, USA
CUST#: 0-494-7 3811
PO#: 98II2
MATERIAL PAGE 3
SAFETY DATA SHEET
T H I S M S D S I S FOR A COMPONENT CATALOG#t 35-A
OF
CATALOG # : 555-8
ACID SOLUTION
T R IS H L OROACETIC 0.49 N
NAME:
STABLE.
I NCOMPATI LI TI ES
BI
STRONGOXIDI ZING AGENTS
HAZARDOUSCOMBUSTION DECOMPOSITIONFRODUCTS
OR
CARBONMONOXIDE, CARBONDIOXIDE
HYDROGENCHLORIDEGAS
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WILL NOT OCCUR.
S E C T I O Nl l .
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ACUTE EFFECTS
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MA'-BE HAnUT'uIIF ABSORBED THE sKIN.
THROUGH
MATERIAL IS EXTREMELY"DE$TRUCTIVE TI{E TISSUE OF THE MUCOUS
TO MEI'{BRANES
AND UPPER RESPIRATORYT=RAC?.
MAY BE HARMFUL IF IN!{ tED; .:
MAY BE HARMFULIF SWALLOWED.
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oF
DESEBUCIIyE
A N D U P P E RR E S P I R A T O R Y R A C T , E Y E S A N D S K I N .
T
INHALATION MAY RESULT IN SPASM. INFLAMMATIONAND EDEMAOF THE
LARYNX AND BRONCHI. CHEMICAL PNET'MONITISAND PULMONARY EDEMA.
SYMPTOMS EXPOSURE MAY INCLUDE BURNING SENSATION, COUGHING,
OF
LARYNGITIS, SHORTNESS OF BREATH, HEADACHE, NAUSEA AND
!YH.E.EZINq,
VOMITING
C A N C A U S EC N S D E P R E S S I O N .
TO THE BEST OF OUR KNOWLEDGE, THE CHEMICAL. PHYSICAL, AND
TOXICOLOGICALPROPERTIESHAVE NOT BEEN THOROUGHLY INVESTIGATED.
CHRONIC EFFECTS . :
T A R G E TO R G A N ( S ) :
CENTRAL NERVOUSSYSTEM
THIS PRODUC.i"iS 5R"C6.I.irerNs A COMPONENT THAT IS NoT cLAssIFIABLE As
T 9 r _ T Sq A R q I N Q G E N I C T T Y A S E DO N r T S r A R C , A C G T H , N T p O R E p A
B
CLASSIFICATION.
R T E C S# : A J 7 8 7 5 0 0 0
ACETIC ACID, TRTCHLORO-
IRRITATION DATA
SKN-RBT 2IO UG MLD XEURAO DDC-1715
M
EYE-RBT 35OO UGI5S SEV XEURAo MDDC-1715
TOXICITY DATA
SCU-MUS LD50 1270 MG/KG NI rRDN 5,879 ,1982
TARGET ORGANDATA
PATERNALEFFECTS (SPERMATOGENESIS)
ONLY SELECTEDREGISTRY OF TOXIC EFFECTS OF CHEMICAL SUBSTANCES
CONTINUEDON NEXT PAGE
t72
We are Committed to the Srccess our Customers
of through Science, Technology and Seruice.
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SIGMA CHEMICAL COMPANY
P O S T O F F T C EB O X 1 4 5 0 8
s A r N T L O U I S , M I S S O U R T5 3 1 7 8 , U S A
CUST#: 0-494-73811
PO#: 98112
MATERIAL SAFETY DA TA SHEET PAGE
T H I S M S D S I S FOR A COMPONENT
OF CATALOG #: 35 - A
CATALOG # : 655:8
NAME: T R ] C H L O R O A C E T IA C I D S O L U T I O N0 . 4 9 N
C
(nrecs DATA IS PRESENTED
) HERE. SEE ACTUAL ENTRY IN RTECS FOR
COMPLETE I N F O R M A T I O N .
ACGIH TLV-CONFIRMED NIMAL CARCINOGEN A OTLVS* TLVIBEI,1999
ACGIH TLV-TWA 1 PPM DTLVS* TLVIBEI.1999
IARC CANCER EVIEW:ANIMAL IMITED EVIDENCE
R L I M E I ' { D T6 3 , 2 9 I . 1 9 9 5
I A B g q A N q E B B V I E w : H U L { A NI N A D E-Q U A T E V I D E N C E I M E l @ ! 6 3 | 2 9 _ ! ; 1 9 9 5
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I A R C C A N C E RR E V I E W T G R O U3 P I M E I I I D T5 3 ' . 2 9 1 ; 1 9 9 5
E P A F I F R A 1 9 8 8 P E S T I C I D E S U B J E C TT O R E G I S T R A T I O NO R R E - R E G I S T R A T I O N
F E R E A C5 4 , 7 7 4 0 , 1 9 8 9
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O E L - B E L G I U M :T W A I P P M ( 5 . 7 I " I G / M 3 ) , J A N 1 9 9 3
OEL-DENMARK: TWA 1 MG,/M3, JAN1999
O E L - F R A N C E :V M E 1 P P M ' ( 5 ' M G / M 3 ) , J A N 1 9 9 9
OEL-GERMANYI O MAK ESTABLISHED, JAN1999
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0.75 PpM(s-MGTftrs) JAN1999
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O E L - S W I T Z E R L A N DM A K - W 1 ' P P M ( 7 M G / r 4 3 ) . J A N 1 9 9 9
:
O E L - U N I T E D K I N G D O M :L T E L I P P M ( 5 M c l M 3 ) , J A N 1 9 9 3
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N O H SI 9 7 4 t H Z D 8 I 5 5 0 t N I S 8 ; T N F 1 3 5 3 ; N O S 1 3 ; T N E 1 3 9 4 5
NOES 19832 HZD 81550i NIS 9i TNF 1562i NOS 2Ii TNE 35I24r TFE 15821
E P A G E N E T O XP R O G R A M 9 8 8 , I N C O N C L U S I v E : H I S T I D I N E R E V E R S I O N - A M E S E S T
1 T
CONTINUED ON NEXT PAGE
173
SIGMA CHEMICAL COMPANY
P O S T O F F T C EB O X 1 4 5 0 8
GMA.ALDFIICH s A r N T L O U T S , M I S S O U R T5 3 1 7 8 , U S A
CUST# 0-494-7 3811
r
PO#: 98112
PAGE
DATA SHEET
SAFETY
MATERIAL
35-A
T H I S M S D S I S F O R A COMPONENT CATALOG#:
OF
665-8
C A T A L O G# :
Acr D sotur loN 0.49 N
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NAME:
E P A T S C A S E C T I O N 8 ( B ) C H E M I C A LI N V E N T O R Y
E P A T S C A E E C T I Q T . I - 9 ( D )U N P U B L I S H E D E A L T H / S A F E T Y T U D I E S
H S
ON EPA IRIS DATABASE
(rscars) oare Sase, JANUARy
Ei;a-ri;cA-'iEst-3frilfii5sroH 2001
- OTHER
sEcTroN15. lNrOnUerION-
THE ABovE TNFoRMATTbN BELTEvED BE coRREcr sur bons Nor puRpoRTTo
To
Is
BE AtL INCLUSIVE AND SHALL BE USED...ONLY A GUIDE...SIGMA SHALL NOT BE
AS
HELD LIABLE FOR ANY DAMAGERESULTING FROMHANDLING OR FROM CONTACTWITH
THE ABOVE PRODUCT.SEE REVERSESIDE OF INVOICE OR PACKING SLIP FOR
A D D I T I O N A L T E R M SA N D C O N D I T I O N SO F S A L E .
C O P Y R I G H T 9 9 9 S I G M A - A L D R I C HC O .
1
LICENSE GRANTEDTO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.
MATERIAL WAS SHIPPED TO THIS ADDRESS:
ST CLOUD STATE UNIV
JOHN SEIFERT HAH 1I1
2Il- llTH ST S
SAINT CLOUD MN 55301
774
We are Committed to the Silccess of our Customers throrgh Science, TechnoLogy and Ser utce.
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