MATERIAL
SAFETYDATA SHEET PROSOCO,
Inc.
PRODUCT
IDENTIFICATION
MANUFACTURER'S NAME PROSOCO, c
In E M E R G E N CT E L E P H O N N U M B E R S :
Y E
8 : 0 0A M - 5 : 0 0P M C S TM o n d a y - F r i d a y :
A N DA D D R E S S : 3741GreenwayCircle 785-865-4200
NON-BUSINESS URSINFOTRAC): (
Lawrence, 66046
KS HO 800-535-5053
PRODUCT
TRADENAME: Sure Klean@600 Detergent
II HAZARDOUSINDREOIENTS
AccrHrLV/rwA oHSA
PEL/rwA
(coMMoNNAME)
CHEMICAL AME
N C A SN O .
|5Pot
(Hydrochloric
Acid)
Hydrogen 5 p p m( C e i l i n g )
Chloride
Solution 5 p p m( C e i l i n g )
7647-01-0 3,0,0,-
withheldas trade secretpursuantto Massachusetts
Percentcontentof hazardousingredients regulations.
III PHYSICAL
DATA
VAPOR
BOILING OINT
P EVAPORATION RATE
PRESSURE VAPORDENSITY
(ButylAcetate= 1)
("F)
(mmHg)
<100
Hydrogen 78 (68'F)
Chloride
Solution 127
150'F
SPECIFIC APPEARANCE AND
SOLUBILITY
GRAVITY IN WATER ODOR
Clearliquid
withslight
113 100%
Sure Klean@ Detergenl
600 pungentodor
ambercolor,
IV FIREAND EXPLOSION
HAZARDDATA
EMERGENCY
OVERVIEW
pungent
odor The vaporand mist fromthis product
Sure Klean@ Detergent a slightly
600 is amber-coloredliquidwith an irritating may
protection Wear splash-proof goggles
causeirritation the respiratory
of tract,wear appropriaterespiratory chemical when handling this
oroduct
(METHOD):
FLASHPOINT None
FLAMMABLE
LIMITS:Unknown
EXTINGUISHING
MEDIA:
Any mediaappropriate surrounding typeof fireinvolving product
for the this
SPECIALFIRE FIGHTING with a full face piece
PROCEDURES:Wear NIOSH/MSHA approved self-contained
breathing apparatus
operated pressure demand otherpositive
pressure
in modeand fullbodyprotective
or clothing
whenfightingfires Watermay be
usedto cool closedcontainers.
UNUSUALFIREAND EXPLOSION gas whichcan form explosive
HAZARDS: Reacts with most metalsto releasehydrogen mixtures
withair Extinguish nearby
all sources ignition
of
-
SureKlean@ Detergent Page1 of 4
600
V HEALTHHAZARDDATA
PRIMARY
ROUTES EXPOSURE:
lnhalation,
OF skin,eyes
INFORMATION: Not listed (OSHA, IARC, NTP) No standardcarcinogenicity
CARCINOGEN studiesfor hydrogen chloridewere
identified.
Two studies rats were conducted determine hydrogen
on to chloride increased formation nasaltumorsor
if the of
potential formaldehyde both studies
increased carcinogenic
the In the rats were exposed 1O-ppm hydrogen
of to chloride,
6
hoursper day, 5 daysper week One studylasted84 weekswhilethe otherlastedthe animals' lifetime Hydrogenchloridedid
notcausean increase nasaltumors
in and did not increase carcinogenicityformaldehyde
the of
MEDICALCONDITIONS AGGRAVATED BY OVEREXPOSURE: Asthma,bronchitis,
emphysema, and other lung conditions;
and
nose,sinus,or throatconditionsExposures 100 ppm for six hoursa day for 50 days causedonlyslightunrestand
chronic of
guineapigs and pigeons The hemoglobin
irritation the eyes and nose of rabbits,
to contentof the bloodwas also slightly
receiving exposures 33 ppm for six hoursdid not displayany adverse
diminished. Monkeys 20 of effects Higherexposures
(unspecified) caused weightlosswhichparalleled severity exposureBaboons ppm
have the of exposed 500,5000or 10,000
to
alterations any pulmonary parameters daysor 3 months
for 15 minutes not have significant
did in function 3 afterexposureln
longtermoverexposure beenassociated erosion the teeth
humans has with of
very rapidly Causesburns,possible
EFFECTSOF OVEREXPOSURE: Causesseveredamageto eyes and even blindness deep
passagesSwallowing
ulceration skin Breathing mistor dust can causedamage nasaland respiratory
to of to results severe
in
can result deathon penetration vitalareas
damage mucous in
to membranes deeptissue;
and to
severeburnsand permanent
EYE CONTACT:Liquid concentrated
or vaporscan causeeye irritation, damageincluding
blindness
even
aftera shortexposure smallamounts
to
causeburning skin Repeated prolonged
SKIN CONTACT:Liquid concentrated
or vaporscan rapidly withdilutesolutions
of or contact
vaoorscan causeirritation
and concentrated and dermatitis
chloridegas, mist, and vapor can cause irritation respiratory
INHALATION: Hydrogen of tract, with burning,choking, coughing,
headaches, rapidheartbeat 35 ppm can causeirritation the throatand 50-100ppm is nearlyunbearable one hour
of for
and
destruction nasalpassages difficulties occurwith highconcentrations may be delayed in
Inflammation, of and breathing can and
onset Inhalation sufficiently
high concentrations resultin laryngeal edemaor rapidly
of may spasms,laryngeal developing
pulmonary
edema Mistsmay also causebleeding the noseand gums,and ulceration the nasalor oral mucosa 1,000-
of of
2,000ppmcan be fatal
pain,and vomiting
routeof exposureCan causesevereburnsof mouth, may
INGESTION:Unlikely esophagus, stomach Nausea,
and
occur Depending the amountswallowed,holesmay develop the intestinal
in tract,kidneyinflammation,
shockand deathcan
on
occur
E M E R G E N CA N D F I R S T I D P R O C E D U R E S :
Y A
EYE CONTACT: Rinseeyeswith largequantities waterfor at least15 minutes,
holding apartto ensureflushing the entire
of eyelids of
eyesurface Get medical immediately
attention
areawith largequantities waterforat least15 minutes Launder
SKIN CONTACT:Remove contaminatedclothing
and flushexposed of
shoes Get immediate
contaminated
clothing
beforereuse Discardcontaminated medical attention
person freshair. lf breathing preferably
INHALATION: respiration, mouth{o-mouthlf breathing
is
Remove to stops,administer
artificial
give
difficult, oxygen.Get medical
attention immediately
INGESTION: conscious, largequantities wateror milk Do not induce
give immediatelyDo notgive
vomiting Get medical
lf of attention
person
anything mouthto an unconscious convulsing
by or
VI REACTIVITY
DATA
STABILITY:Stable
bases(alkali), causeviolent
CONDITIONS AVOID: Contact generating
TO withstrong reaction largeamounts heat
can of
(MATERIALS AVOID): Metals,oxidizing
INCOMPATIBILITY TO agents,nitricacid, chlorates, and cyanides Contactwith
sulfides,
sulfidesreleasespoisonous flammablehydrogensulfide Mercuricsulfate,perchloric acid, carbidesof calcium,cesium,
r u b i d i u m ,c e t y l i d e s c e s i u m n d r u b i d i u m ,h o s p h i d e s c a l c i u m n du r a n i u m ,n d l i t h i u m i l i c i d e
p
a of a a
of a s
Hydrogen Chloride reactwithcyanide,
can forminglethal
concentrations hydrocyanic
of acid Do notenterconfined
spacessuch
as tanksor pitswithout
proper
entryprocedures required 29 CFR 1910146
as by
gas when contacting
HAZARDOUSCOMBUSTION DECOMPOSITION PRODUCTS:Hydrogen hydrogen
OR metals, chloride,
carbon
potential harmin confined poorly
dioxide.Hydrogen generation the highest
gas
monoxide carbon
and has for ventilatedareas
or
whereconcentrations approach
can flammable explosive
or concentrations
VII SPILLOR LEAK PROCEDURES
SPILL' LEAK, WASTE DISPOSALPROCEDURES: Evacuate immediate area where concentratedfumes are present Cleanup
personnel must wear properprotective
equipment Provideadequate ventilation Completely
containspilledmaterial
with dikes,
etc , and preventrunoffintogroundand surfacewatersor intosewers
Dilution waterwilldecrease fumesgenerated
with product Spills
the fromspilled and leaksshouldbe neutralized pouring
by dry
soda ash or lime over the affectedarea Concentrated productshouldbe dilutedwith water beforeaddingneutralizing
agentsto
keepsplattering fumesto a minimum Approximately5 pounds limeare required neutralize gallon thisproduct
and 2 of to one of
Allowpowdered material remainon spill for five to ten minutes
to and flushthoroughly with water Neutralizedmaterial,both
liquid should recovered proper
and solid, be for disposal.
WASTEDISPOSAL METHODS:Recovered solidsor liquids
may be disposed in a permitted
of wastemanagement facility Neutralized
materialsmay be discharged a sanitary
to sewerwith approval the receiving plant TypicalpH rangeof 6-10 is
of treatment
generallyconsideredappropriate discharge Consult
for federal, procedure For
state,and/orlocalauthorities approved
for
additionalinformation
regardinghandling and disposal rinse-water, pleasereviewTechnical "Controlled
of Bulletin2OO-CW
Handling Cleaning
of Wastewater"Emptycontainers mustbe triplerinsed disposal a permitted
before ln landfill Check
sanitary
localrestrictions
VIII SPECIALPROTECTION
INFORMATION
RESPIRATORY PROTECTION:For vapor or mist concentrations
whichexceedor are likelyto exceed5 ppm Threshold LimitValue
(TLV),wear a NIOSH/MSHA approved with acid gas cartridges NIOSH/MSHA
half-mask
respirator approvedsel|contained
(SCBA) pressure
breathing
apparatus or demandsupplied respirator fullfacepieceshouldbe wornwhenconcentrations
air with
exceed50 ppm, A SCBA is recommended NIOSHduringleaksandioremergencies,
by Followall applicable
respirator
use
standards regulations
and
VENTILATION: general
Provide
sufficient and/orlocalexhaust
ventilation maintain
to exposure
belowthe TLV
PROTECTIVE
CLOTHING;
Wearsplashresistant
neoprene PVCrainsuit.
or
PROTECTIVE
GLOVES:Nitrile
rubber
type,neoprene PVCwithacceptable resistance
or acid
EYE PROTECTION: splashgogglesandiorfull face shield(8 inch minimum) compliance
Chemical in with OSHAregulationsDo not
wear contactlensesbecausethey may contribute the severity an eye injury
to of
OTHERPROTECTIVE
EQUIPMENT:
Acid-resistant
rubber
boots,
headgear Eyewash safety
and shower
IX SPECIALPRECAUTIONS
WORK PRACTICES: workpractices
Proper and planningshouldbe utilized avoidcontact passersby, non-masonry
to with workers, and
surfaces Brushon or apply at the lowestpractical pressure Do not atomizeduringapplication Application equipment,
' scaffolding,swingstagesand support systems mustbe constructed acidresistant
of materials Useonlyweilmaintainedstaging
and scaffolding is equipped
that with steelcable. This product attacknylon,cottonand hemp roping Use polypropylene
will
ropesand safetylines Dilution shouldbe of polypropylene HDPEconstructionBeware wind
and applicationequipment or of
drift. Wind-drift may be diminished pre-rinsing low pressure
hazards by with waterbeforepressure pedestrian
washing Divert
trafficaround workareas Seethe Product Datasheetand labelfor specific
precautions be takenduringuse Smoking,
to eating
anddrinking should discouraged
be during useof thisproduct Washhandsafterhandling use
the or
This product is only to be used as suppliedand specified. Do not alter,mix with chlorine-type
bleaches otherchemicals,
or
product
or dilute except specified the labeland Product
as on DataSheet
PRECAUTIONS BE TAKENlN HANDLING
TO AND STORAGE:Useproper (seesection
safety equipment Vllt)whenhandling Storein
a cool,well-ventilated
area Separate fromoxidizing nitricacid,alkalis,
agents, chlorates,
sulfides, (seesection
etc Vl) Do not
removeproductlabel. Material must be properly
dilutedfor application labeledand storedin acid-resistant
containerswith
steel,polypropylene polyethylene
rubber-lined or construction
Addition acidiccleaner water releases
of to heat,whichcan resultin violentboilingand spattering Always add cleanerto
waterslowly and in small amounts. Neveruse hot water. Neveradd water to acidic cleaners.
Containers this material
of may be hazardous when emptied,sinceemptiedcontainers
retainproductresidues
(vapor,
liquid,
precautions
and/or
solid) All hazard givenin thrsdatasheetmustbe observed
OTHERPRECAUTIONS: notget in eyes,on skinor on clothing Can causesevere
Do in1ury blindnessAvoidbreathing or vapor.
or mist
Provide
ventilation
sufficient limitemployee
to exposure
belowOSHApermissible limit Do nottakeinternallyWashthoroughly
afterhandling
X REGULATORYINFORMATION
SHIPPING:Thisproduct "Corrosiveliquid,acidic, inorganic,n.o.s.(Hydrochloric
carries shipping
the description acid),8, UN3264,
ll" for shipping ground, and oceantransport The product
by meetsapplicable whenshipped the
air DOT and UN standards in
packaging, sizemay be limited air transport Someparcel
factory
original, although
unopened for shipping
container companies
may limitcontainersizes
NATIONAL
MOTORFREIGHT
CLASSIFICATION:
44157 Sub 3 RateClass: 85
SARA 313 REPORTABLE:
NAME
CHEMICAL CAS UPPERBOUND
CONCENTRATION BY WEIGHT
%
Hydrogen
Chloride 7647-01-0 30%
This productcontainsno chemicalslisted under California's
CALIFORNIA
PROPOSITION
65: Proposition65.
XI OTHER
MSDSStatus: Dateof Revision: February 2005
8,
For ProductManufactured
After: February,
2005
National
Changes: Updated MotorFreight
Classification,
Section
X
Item#: 10020
ApprovedBy: Regulatory
Department
DISCLAIMER:
The information contained the Material
on SafetyDataSheethas beencompiled from data considered accurate This data is
believed be reliable,but it must be pointedout that valuesfor certainproperties
to are known to vary from sourceto source.
PROSOCO, expresslydisclaimsany warrantyexpressor impliedas well as any liabilityfor any injuryor loss arising
Inc.
from the use of this informationor the materialsdescribed. Thisdata is not to be construed absolutely
as complete since
when particular
additionaldata may be desirable conditions circumstances
or exist lt is the responsibility the user to
of
determine best precautions necessary the safe handlingand use of this productfor his uniqueapplication This data
the for
relatesonlyto the specific material
designated is not to be usedin combination any othermaterial Manyfederal
and with and
pertaindirectly indirectly the product's use and disposal containers unused
stateregulations or to end material.lt is the
of and
purchaser'sresponsibility familiarize
to himself regulations
withall applicable
DATEOF PREPARATION; Februarv 2005
8.
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