MSDS for Flexol AC25 Page 1 of 8 MSDS-026
MATERIAL SAFETY DATA SHEET
Flexol AC25
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SECTION 1: IDENTIFICATION OF SUBSTANCE/MIXTURE & SUPPLIER
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Flexol AC25
Product Name:
Denatured Ethanol, RPR 40
Other Names:
Recommended Use: General industrial solvent
Supplier: CSR Distilleries Operations Pty Limited
ABN: ABN 85 009 660 191
Address: 265 Whitehall Street
Yarraville VIC 3013
Australia
Telephone: +61 3 9283 4500 (Or 1800 819 618 (available in Australia only))
Facsimile: 1800 647 260
000 Fire Brigade and Police (available in Australia only).
Emergency Phone :
Important Notice : This Material Safety Data Sheet (MSDS) is issued by the Supplier in accordance with
National Occupational Health & Safety Commission (NOHSC) guidelines. As such, the
information in it must not be altered, deleted or added to. The Supplier will issue a new
MSDS when there is a change in product specifications and/or NOHSC
guidelines/regulations. The Supplier will not accept any responsibility for any changes
made to its MSDS by any other person or organisation.
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SECTION 2: HAZARDS INFORMATION
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HAZARDOUS SUBSTANCE 鈥? DANGEROUS GOODS
DG Class 3
Subsidiary Risk 1: None Allocated
Packaging Group II
Poison Schedule None Scheduled
Risk Phrase(s)
R11 - Highly flammable.
R66 - Repeated exposure may cause skin dryness and cracking.
R20/22 - Harmful by inhalation and if swallowed.
R36/38 - Irritating to eyes and skin.
Safety Phrase(s)
S16 - Keep away from sources of ignition - No smoking.
S23 - Do not breathe vapour.
S29 - Do not empty into drains.
S33 - Take precautionary measures against static discharges.
S45 - In case of accident or if you feel unwell seek medical advice immediately (show the label whenever possible.)
S7/9 - Keep container tightly closed and in a well ventilated place
S24/25 - Avoid contact with skin and eyes
S36/37/39 - Wear suitable protective clothing/ gloves and eye/face protection
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MSDS for Flexol AC25 Page 2 of 8 MSDS-026
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SECTION 3: COMPOSITION / INFORMATION ON INGREDIENTS
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Chemical Name: CAS Number: Proportion:
Ethyl alcohol (ethanol) 64-17-5 75%
Acetone 67-64-1 25%
Water 7732-18-5 0.5% by weight (maximum)
All components in this product are listed on the Australian Inventory of Chemical Substances (AICS).
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SECTION 4: FIRST AID MEASURES
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If there are signs of drunkenness (intoxication or inebriation) then serious health effects may follow (depending on the
amount swallowed or inhaled). Immediate medical attention should be sought and the affected person transferred
and accompanied to the care of a doctor or hospital. Treat unconsciousness by placing the person in the coma
position Apply artificial respiration if breathing stops.
Swallowed: See above. If a minor amount has been accidentally swallowed, then, if conscious, give large amounts
of water. Do not allow further work until fitness for duties is established. Do not attempt to induce vomiting or give
anything by mouth to an unconscious person. Seek medical attention.
Eye: Flush eye with running water for a minimum of 15 minutes,. Seek medical attention promptly if irritation persists
or any loss of vision occurs.
Skin: Immediately remove contaminated clothing. Wash skin with water. Launder contaminated clothing before re-
use.
Inhaled: Remove promptly to fresh air. If there are signs of drunkenness (intoxication or inebriation) or respiratory
irritation, dizziness, nausea or headache occurs, seek immediate medical attention. Treat unconsciousness by
placing the person in the coma position. Apply artificial respiration if breathing stops.
Notes to doctor: Treat symptomatically and as for narcotic substance.
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SECTION 5: FIRE FIGHTING MEASURES
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Specific Hazards: Highly flammable liquid. May form flammable mixtures with air. Burns with a colourless flame. The
vapour is heavier than air and may travel along the ground; distant ignition and flash back are possible. Run off to
sewers and drains may cause explosions. Isolate for at least 800 metres in all directions if tanks or tankers are
involved. The use of compressed air for filling, discharging, mixing or handling is prohibited due to the vapour hazard.
All vessels must be earthed to avoid generation of static charges when agitating or transferring solvents. Avoid all
ignition sources. Intrinsically safe equipment is necessary in areas where this chemical is being used.
Extinguishing Media: Use water fog (or if unavailable fine water spray), dry chemical, carbon dioxide or
alcohol stable foam.
Fire Fighting Procedures: Highly flammable liquid. Use water to cool exposed containers. Heating can cause
expansion or decomposition leading to violent rupture of containers. If safe to do so, remove containers from path of
fire. Spills and leaks may be washed away with copious volumes of water, fog or spray. For major fires or where the
atmosphere is either oxygen deficient or contains unacceptable levels of combustion products, firefighters must wear
self-contained breathing apparatus with full face-mask and protective clothing.
Hazardous Decomposition products: Burning can produce carbon monoxide and/or carbon dioxide.
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MSDS for Flexol AC25 Page 3 of 8 MSDS-026
Hazchem code:
2[Y]E
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SECTION 6 : ACCIDENTAL SPILL AND RELEASE MEASURES
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Containment Procedures: In the event of a spillage eliminate all sources of ignition and take measures to prevent
static discharge 鈥? no smoking. Stop and contain the spill for salvage or absorb in inert absorbent material (e.g. soil,
sand, vermiculite) for disposal by an approved method. Prevent run-off into drains and waterways. Clear area of all
personnel not directly involved in the clean up. All personnel involved in the containment and disposal procedures to
wear protective equipment as described in Section 8 to prevent skin and eye contamination and inhalation of
vapours. Use water spray to disperse vapour. Wash the cleaned up area with copious volumes of water to remove
any traces amounts of product. Ethanol mixes completely with water. Spills can be converted to non-flammable
mixtures by dilution with water. Ventilate area well and ensure the atmosphere is safe before personnel return to the
work area. If contamination of sewers or waterways has occurred, advise the local emergency services.
Disposal: Stop and contain the spill for salvage or absorb in inert absorbent material (e.g. soil, sand, vermiculite) for
disposal by an approved method. Prevent run-off into drains and waterways. Dispose of all waste containers and
used drums in accordance with local authority guidelines. Non-returnable containers should be de-gassed prior to
disposal.
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SECTION 7: HANDLING AND STORAGE
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Handling and Storage:
Handling: Use in well ventilated areas away from all ignition sources. Intrinsically safe equipment only must be
used in area where this chemical is being used. The use of compressed air for filling, discharging, mixing or
handling is prohibited due to the vapour hazard. Containers must be earthed to avoid generation of static
charges when agitating or transferring product.
Storage: Store in tightly closed containers in cool, dry, isolated and well ventilated areas away from heat,
sources of ignition and incompatibles. Store away from oxidizing agents. Keep containers closed at all times 鈥?
check regularly for leaks. Do not eat, drink or smoke in areas of use or storage. Observe State Regulations
concerning the storage and handling of Dangerous Goods. Store with all precautions required for handling
flammable liquids. The requirement of Australian Standard AS 1940 should be observed in addition to AS 1020,
AS 1076, AS 2380 and AS 3000.
Empty containers retain residue (liquid and/or vapour) and are dangerous. Do not pressure cut, weld, braze,
solder, drill, grind or expose such containers to heat, flame, sparks, static electricity, or other sources of ignition.
Incompatibilities
Not to be stored with explosives (Class 1), flammable gases in bulk (Class 2.1), poisonous gases (Class 2.3),
spontaneously combustible substances (Class 4.2), oxidizing agents (Class 5.1), organic peroxides (Class 5.2),
radioactive substances (Class 7). Exemptions may apply.
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MSDS for Flexol AC25 Page 4 of 8 MSDS-026
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SECTION 8: EXPOSURE CONTROL AND PERSONAL PROTECTION
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Exposure Standards:
National occupational exposure standards
Ethanol TWA - 1000 ppm (1880 mg/m3)
STEL - None Allocated
Carcinogen Category - None Allocated
Notices - None Allocated
Acetone TWA - 500 ppm (1185 mg/m3)
STEL - 1000 ppm (2375 mg/m3)
Carcinogen Category - None Allocated
Notices - None Allocated
Exposure Standard (TWA) is the time-weighted average airborne concentration over an eight-hour working day,
for a five-day working week over an entire working life. According to current knowledge this concentration should
neither impair the health nor, cause undue discomfort to, nearly all workers.
These Exposure Standards are guides to be used in the control of occupational health hazards. All atmospheric
contamination should be kept to as low a level as is workable. These Exposure Standards should not be used as
fine dividing lines between safe and dangerous concentrations of chemicals. They are not a measure of relative
toxicity.
Engineering Controls:
Ventilation: Local exhaust ventilation and/or mechanical (general) exhaust is recommended where vapours are likely
to be generated. All such equipment must be intrinsically safe.
Special Considerations for Repair And/Or Maintenance of Contaminated Equipment: Empty containers retain
residue (liquid and/or vapour) and are dangerous. Do not pressure cut, weld, braze, solder, drill, grind or expose such
containers to heat, flame, sparks, static electricity, or other sources of ignition. Vapour is heavier than air 鈥? prevent
concentration in hollows or sumps. Do not enter confined spaces where vapour may have collected. Keep containers
closed when not in use.
Personal Hygiene: Protective clothing (gloves, coveralls, boots, etc.) should be worn to prevent skin contact. Always
wash hands before smoking, eating, drinking or using the toilet. Wash contaminated clothing and other protective
equipment before storing or re-using
Eye Protection: Avoid eye contact by wearing chemical goggles with side shields or face shield (AS/NZS 1336)
whenever exposed to vapour or mist or if there is a risk of splashing liquid in the eyes. Safety showers with eye-wash
should be provided in all areas where product is handled.
Skin Protection: Avoid skin contact by the use of approved chemical resistant gloves and aprons 鈥? PVC or
Neoprene (AS 2161).
Respiratory Protection: None should be needed under normal circumstances. In high vapour concentrations, or in
suspected oxygen deficient atmospheres, such as empty vessels or confined spaces, use air supplied hood. In other
instances where ethanol vapour concentrations are likely to exceed 500ppm or acetone vapour concentrations are
likely to exceed 250ppm, an approved organic vapour respirator (AS/NZS 1715 and 1716) must be worn.
Smoking and Other Dusts: Smoking must be prohibited in all areas where this product is used - see safety
information on flammability
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MSDS for Flexol AC25 Page 5 of 8 MSDS-026
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SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
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Appearance: Clear colourless liquid, characteristic odour, burning taste
Odour Detectable at 80 鈥? 100ppm (Ethanol)
pH, at stated concentration
Boiling Point: (oC) 78掳C (ethanol)
Melting Point: (oC) -117掳C (Ethanol)
Vapour pressure: 44 mm Hg @ 20掳C (ethanol)
Specific gravity (H2O = 1) 0.790 - 0.792
Solubility in water: Complete
Evaporation Rate: 253 (n-butyl Acetate = 100) (Ethanol)
560 (n-butyl Acetate = 100) (Acetone)
Vapour Density: 1.59 (air = 1)(ethanol)
2.00 (air = 1)(acetone)
Per cent volatiles: 100%
Flash Point: 13掳C Ethanol
-18掳C (Acetone)
Abel closed cup
FP Test Method:
Autoignition Temperature: 392 - 540掳C
Lower Explosive Limit (LEL): 2.1 - 3.5%
Upper Explosive Limit (UEL): 13 - 19%
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SECTION 10: STABILITY AND REACTIVITY
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Chemical Stability Stable
Hazardous Polymerisation: Will not occur.
Incompatible Materials: Will react with strong oxidizing agents.
Conditions to avoid: Heat, sparks, flame and build-up of static electricity.
Hazardous Decomposition products: Burning can produce carbon monoxide and/or carbon dioxide.
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SECTION 11: TOXICOLOGICAL AND EPIDEMIOLOGICAL DATA
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Swallowed: Accidental swallowing is unlikely in the industrial setting. Swallowing ethanol or products with high
ethanol content can cause drunkenness or harmful central nervous system effects. The deliberate ingestion of
ethanol is a known occupational risk, and as little as 50-100ml intake in a shift in a 70kg worker may cause inebriation
to the point where safety is impaired. Effects of a small intake may include excitation, euphoria, headache, dizziness,
drowsiness, blurred vision, and fatigue. Drinking a large amount may lead to Severe acute intoxication, tremors,
convulsions, loss of consciousness, coma, respiratory arrest and death. Aspiration into lungs may cause pneumonitis.
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MSDS for Flexol AC25 Page 6 of 8 MSDS-026
Eye: Vapours may irritate the eyes. Liquid and mists may severely irritate or damage the eyes.
Skin: Contact with skin may result in slight irritation and redness. Prolonged or repeated contact and heavy skin
contamination may cause skin drying and cracking and/or dermatitis with redness, itching, and swelling. This may
lead to possible secondary infection.
Inhaled: Vapour is moderately irritating to mucous membranes and respiratory tract. Inhalation of the vapour may
result in drunkenness, (see effects of swallowing above) or headache, nausea, incoordination, narcosis (sleepiness)
and vomiting. Early signs or Symptoms may occur at airborne levels of 1000 to 5000 ppm. Ongoing or repeated
exposures at High concentrations may cause central nervous symptoms similar to 鈥渟wallowed鈥? above. Deliberate
inhalation of the vapour is a known occupational risk.
Chronic: Long term exposure by swallowing or repeated inhalation, may cause degenerative changes in the liver,
kidneys, gastrointestinal tract and heart muscle.
Note: Nasal and eye irritation may occur at concentrations below the exposure standard.
Special toxic effects: In work areas where exposures in excess of the occupational exposure limits occur, then the
following may apply: Persons with pre-existing liver impairment, skin and respiratory disorders may be at an
increased risk . Ethanol may cause adverse reproductive effects. Absorption of some drugs may be affected causing
adverse health effects. Ingestion by pregnant women may cause serious effects in their newborn babies called
鈥渇oetal alcohol syndrome鈥?. The National Occupational Health & Safety Commission in Australia (NOHSC) does not
classify ethanol as a carcinogen. IARC has evaluated ethanol as a carcinogen on the basis of effects of drinking
alcoholic beverages, but there is no known carcinogenic risk from occupational exposures. There is extensive
toxicological and epidemiological information on the health effects of ingesting alcoholic drinks containing ethanol.
Any occupational exposures will add to overall exposures from ingestion of alcoholic drinks any health effects that
result from such exposures.
Acute Effects:
Acute toxicity: Inhalation at levels at or exceeding the Occupational Exposure limits or any deliberate ingestion is
known to lead to health effects which may be evident in themselves, or lead to impaired functioning and consequent
safety risks in the industrial setting. A blood alcohol level in excess of 0.05g\100ml is regarded as likely to impair
functioning for tasks such as operating machinery
LD50/oral/rat: 7060 mg/kg (literature data)
LC50/inhalation/rat: 38 mg/l/10 h (literature data)
Long Term Effects: Exposure to ethanol in the work setting adds to any intake from alcoholic drinks and any health
effects caused by the total intake of alcohol. Product is not regarded as being carcinogenic or mutagenic.
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SECTION 12: ECOLOGICAL INFORMATION
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Ecotoxicity:
Ecotoxicity (ethanol):
Toxicity to fish (acute): LC0/Golden ide/: >1000 mg/l/48 h
Toxicity to daphnia: EC50/Daphnia magna/: >1000 mg/l/24 h
Persistence and degradability (ethanol):
Degree of elimination: 94%
Evaluation: biodegradable
Mobility in soil (ethanol):
No data available.
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MSDS for Flexol AC25 Page 7 of 8 MSDS-026
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SECTION 13: DISPOSAL CONSIDERATIONS
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Suitable for incineration by approved agent under controlled conditions if permitted by local authorities, otherwise
disposal must be in accordance with local waste authority requirements. Product must be contained and not
disposed to sewerage systems, drains or waterways. Advise flammable nature. Empty containers must be
decontaminated by rinsing with water
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SECTION 14: TRANSPORTATION INFORMATION
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Transport Requirements:
UN number: 1993
Class 3
Subsidiary Risk 1: None Allocated
Packaging Group II
Hazchem code: 2[Y]E
EPG
Incompatibilities: Not to be stored with explosives (Class 1), flammable gases in bulk (Class 2.1),
poisonous gases (Class 2.3), spontaneously combustible substances (Class 4.2), oxidizing agents (Class 5.1),
organic peroxides (Class 5.2), radioactive substances (Class 7). Exemptions may apply.
Road and Rail Transport (Australian Dangerous Goods Code):
UN Number: 1993
Proper Shipping Name: FLAMMABLE LIQUID, N.O.S. (ETHANOL AND ACETONE)
Class: 3 Flammable Liquid
Hazchem Code: 2[Y]E
Packing Group: II
Marine Transport (International Maritime Dangerous Goods Code):
UN Number: 1993
Proper Shipping Name: FLAMMABLE LIQUID, N.O.S. (ETHANOL AND ACETONE)
Class: 3 Flammable Liquid
Packing Group: II
Marine Pollutant: No
Air Transport (International Air Transport Association Dangerous Goods Regulations):
UN Number: 1993
Proper Shipping Name: FLAMMABLE LIQUID, N.O.S. (ETHANOL AND ACETONE)
Class: 3 Flammable Liquid
Packing Group: II
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SECTION 15: REGULATORY INFORMATION
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Regulatory Information:
Classification: Hazardous according to criteria of NOHSC.
Dangerous Good according to criteria of the Australian Dangerous Goods
Code.
Poisons Schedule: Not Scheduled.
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MSDS for Flexol AC25 Page 8 of 8 MSDS-026
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SECTION 16: OTHER INFORMATION AND CONTACT POINT
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Further Information can be obtained from:
CSR Distilleries Operations Pty Limited (ABN 85 009 660 191), 265 Whitehall Street, Yarraville VIC 3013,
Australia. Phone +61 3 9283 4500 or 1800 819 618 (available in Australia only). Fax 1800 647 260
Additional Information
Australian Standards References:
AS 1020 The Control of undesirable static electricity.
AS 1076 Code of Practice for selection, installation and maintenance of electrical apparatus and
associated equipment for use in explosive atmospheres (other than mining applications) 鈥?
Parts 1 to 13.
AS/NZS 1336 Recommended Practices for Occupational Eye Protection.
AS/NZS 1715 Selection, Use and Maintenance of Respiratory Protective Devices.
AS/NZS 1716 Respiratory Protective Devices.
AS 1940 The Storage and Handling of Flammable and Combustible Liquids.
AS 2161 Industrial Safety Gloves and Mittens (excluding electrical and medical gloves).
AS 2380 Electrical equipment for explosive atmospheres 鈥? Explosion Protection Techniques
(Parts 1 to 9).
AS 3000 Electrical installations (known as the Australian/New Zealand Wiring Rules).
This MSDS was correct at the time it was prepared (see below for the date). The Supplier, as part of its Health and
Safety Programme, updates MSDS鈥檚 when its ongoing review process indicates a need for a change to be made.
You should make sure that the MSDS you are reading and relying on is current. You can do this by contacting the
Supplier at the above address.
Issue Date: 08/2008
MSDS Revision Summary
Supersedes Issue Date: 10/2003
Reasons for Issue: Updated emergency phone number only. Full review required by 10/2008.
CSR MSDS No.: MSDS-026
Expiry Date: 10/2008
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