CSR MATERIAL SAFETY DATA SHEET
n-Propyl Acetate
SECTION 1: IDENTIFICATION OF THE MATERIAL AND SUPPLIER
Product Name: n-Propyl Acetate
Other Names: 1-Propyl acetate, Propyl acetate, 1-Acetoxypropane, Acetic acid-n-propyl ester
Product Codes/Trade Names: Not Applicable
Recommended Use: Flavour and fragrance ingredient; solvent for nitrocellulose resins; component of
lacquers and printing inks.
Applicable In: Australia
Supplier: CSR Distillery Operations Pty Limited (ABN 85 009 660 191)
Address: 664 Lorimer St, Port Melbourne, Victoria 3207
Telephone: 1800 819 618
Email Address: sales.distilleries@csr.com.au
Web Site: www.csrethanol.com.au
Facsimile: 1800 647 260
Emergency Phone Number: 000 Fire Brigade and Police (available in Australia only).
Poisons Information Centre: 13 11 26 (available in Australia only).
This Material Safety Data Sheet (MSDS) is issued by the Supplier in accordance with National standards and guidelines
from the Australian Safety and Compensation Council (ASCC, formerly National Occupational Health and Safety
Commission - NOHSC). The information in it must not be altered, deleted or added to. The Supplier will not accept any
responsibility for any changes made to its MSDS by any other person or organization. The Supplier will issue a new MSDS
when there is a change in product specifications and/or ASCC standards, codes, guidelines, or Regulations.
SECTION 2: HAZARD IDENTIFICATION
STATEMENT OF HAZARDOUS NATURE: Classified as Hazardous according to the criteria of the Australian Safety and
Compensation Council ASCC (formerly NOHSC) Approved Criteria For Classifying Hazardous Substances [NOHSC:1008]
3rd Edition.
n-Propyl Acetate is classified as Dangerous Goods according to the Australian Code for the Transport of Dangerous
Goods by Road and Rail.
Risk Phrases Safety Phrases
R11 - Highly flammable. S7/9 - Keep container tightly closed and in a well
ventilated place
R20/22 - Harmful by inhalation and if swallowed.
S16 - Keep away from sources of ignition - No smoking.
R36/38 - Irritating to eyes and skin.
S23 - Do not breathe vapour.
R66 - Repeated exposure may cause skin dryness and
cracking. S24/25 - Avoid contact with skin and eyes
S29 - Do not empty into drains.
S33 - Take precautionary measures against static
discharges.
S36/37/39 - Wear suitable protective clothing/ gloves and
eye/face protection
CSR MSDS Reference: ETH-SDS-056
Date Issued: April 2008
MSDS for n-Propyl Acetate Page 2 of 8
SECTION 3: COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Name: Synonyms Proportion: CAS Number:
N-Propyl Acetate 100% 109-60-4
SECTION 4: FIRST AID MEASURES
If poisoning occurs contact a doctor or Poisons Information Centre.
Swallowed: If a minor amount has been accidentally swallowed, then, if conscious, rinse mouth with water
and then dilute stomach contents by giving large amounts of water.
Seek medical attention. Do not attempt to induce vomiting or give anything by mouth to an
unconscious person. If person vomits place person on their side in recovery position.
Eyes: Flush eye with flowing water for a minimum of 15 minutes. Seek medical attention promptly if
irritation persists or any loss of vision occurs.
Skin: Contamination of skin may cause minor irritation. With heavier contamination, remove
contaminated clothing. Wash skin with flowing water. Launder contaminated clothing before re-
use.
Inhaled: Remove promptly to fresh air. If there are signs of drunkenness (intoxication or inebriation) or
respiratory irritation, dizziness, nausea or headache occurs, seek immediate medical attention.
Treat unconsciousness by placing the person in the coma position. Apply artificial respiration if
breathing stops.
First Aid Facilities: First aid kits, safety showers, eye wash stations.
Advice to Doctor: Treat symptomatically and as for a narcotic substance.
SECTION 5: FIRE FIGHTING MEASURES
Flammability: Highly flammable liquid. May form explosive mixtures with air. Burns with a
colourless flame. The vapour is heavier than air and may travel along the
ground; distant ignition and flash back are possible.
Run off to sewers and drains may cause explosions. Isolate for at least 800
metres in all directions if tanks or tankers are involved. The use of compressed
air for filling, discharging, mixing or handling is prohibited due to the vapour
hazard.
All vessels must be earthed to avoid generation of static charges when agitating
or transferring solvents. Avoid all ignition sources. Intrinsically safe equipment
is necessary in areas where this chemical is being used.
Suitable extinguishing media: Use dry chemical, carbon dioxide or alcohol stable foam. Water may be
ineffective.
Hazards from combustion products: Burning can produce carbon monoxide and/or carbon dioxide.
Special protective precautions and Highly flammable liquid. Use water to cool exposed containers. Heating can
equipment for fire fighters: cause expansion or decomposition leading to violent rupture of containers. If
safe to do so, remove containers from path of fire.
Spills and leaks may be washed away with copious volumes of water, fog or
spray. Spills can be converted to non-flammable mixtures by dilution with
water.
For major fires or where the atmosphere is either oxygen deficient or contains
unacceptable levels of combustion products, firefighters must wear self-
contained breathing apparatus with full face-mask and protective clothing.
HAZCHEM Code: 3[Y]E
CSR SDS Reference: ETH-SDS-056
Date Issued: April 2008
MSDS for n-Propyl Acetate Page 3 of 8
SECTION 6: ACCIDENTAL RELEASE MEASURES
Emergency Procedure: In the event of a spill eliminate all sources of ignition and take measures to
prevent static discharge. No smoking. Use water spray to disperse vapour.
Clear area of all personnel not directly involved in the clean up.
All personnel involved in the containment and disposal procedures to wear
protective equipment as described in Section 8 to prevent skin and eye
contamination and inhalation of vapours.
Ventilate area well and ensure the atmosphere is safe before personnel return
to the work area.
Containment Procedure: Stop and contain the spill for salvage or absorb in inert absorbent material (e.g.
soil, sand, vermiculite) for disposal by an approved method. Prevent run-off into
drains and waterways.
If contamination of sewers or waterways has occurred, advise the local
emergency services.
Clean Up Procedure: Wash the cleaned up area with copious volumes of water to remove any trace
amounts of product. Spills can be converted to non-flammable mixtures by
dilution with water.
Non-returnable containers should be de-gassed prior to disposal. Dispose of all
waste containers and used drums in accordance with local authority guidelines.
SECTION 7: HANDLING AND STORAGE
Handling: Use in well ventilated areas away from all ignition sources. Intrinsically safe
equipment only must be used in area where this chemical is being used.
The use of compressed air for filling, discharging, mixing or handling is
prohibited due to the vapour hazard. Containers must be earthed to avoid
generation of static charges when agitating or transferring product.
Storage: Store in tightly closed containers in cool, dry, isolated and well ventilated areas
away from heat, sources of ignition and incompatibles. Store away from
oxidizing agents. Keep containers closed at all times; check regularly for leaks.
Do not eat, drink or smoke in areas of use or storage. Observe State
Regulations concerning the storage and handling of Dangerous Goods. Store
with all precautions required for handling flammable liquids.
The requirement of Australian Standard AS 1940 should be observed in
addition to AS 1020, AS 1076, AS 2380 and AS 3000.
Empty containers retain residue (liquid and/or vapour) and are dangerous. Do
not pressure cut, weld, braze, solder, drill, grind or expose such containers to
heat, flame, sparks, static electricity, or other sources of ignition.
Incompatibilities: Not to be stored with explosives (Class 1), flammable gases in bulk (Class 2.1),
poisonous gases (Class 2.3), spontaneously combustible substances (Class
4.2), oxidizing agents (Class 5.1), organic peroxides (Class 5.2), radioactive
substances (Class 7).
Exemptions may apply.
CSR SDS Reference: ETH-SDS-056
Date Issued: April 2008
MSDS for n-Propyl Acetate Page 4 of 8
SECTION 8: EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure Standards: National Occupational Exposure Standard (NES) Australian Safety &
Compensation Council, ASCC (formerly NOHSC)
3
TWA - 200 ppm (835 mg/m )
STEL - 250 ppm (1040 mg/m3)
Carcinogen Category - None Allocated
Notices - None Allocated
Notes: All occupational exposures to atmospheric contaminants should be kept to as
low a level as is workable (practicable) and in all cases to below the National
Standard.
TWA (Time Weighted Average): the time-weighted average airborne
concentration over an eight-hour working day, for a five-day working week over
an entire working life. According to current knowledge this concentration should
neither impair the health of, nor cause undue discomfort to, nearly all workers.
STEL (Short Term Exposure Limit): the average airborne concentration over a
15 minute period which should not be exceeded at any time during a normal
eight-hour work day.
Biological Limit Values: No biological limit allocated.
ENGINEERING CONTROLS
Ventilation: Local exhaust ventilation and/or mechanical (general) exhaust is recommended
where vapours are likely to be generated. All such equipment must be
intrinsically safe.
Special Consideration for Empty containers retain residue (liquid and/or vapour) and are dangerous. Do
Repair &/or Maintenance of not pressure cut, weld, braze, solder, drill, grind or expose such containers to
Contaminated Equipment: heat, flame, sparks, static electricity, or other sources of ignition.
Vapour is heavier than air 鈥? prevent concentration in hollows or sumps. Do not
enter confined spaces where vapour may have collected. Keep containers
closed when not in use.
PERSONAL PROTECTION
Personal Hygiene Protective clothing (gloves, coveralls, boots, etc.) should be worn to prevent
skin contact. Always wash hands before smoking, eating, drinking or using the
toilet.
Wash contaminated clothing and other protective equipment before storing or
re-using.
Skin Protection: Avoid skin contact by the use of approved chemical resistant gloves and aprons
鈥? PVC or Neoprene (AS 2161).
Eye Protection: Avoid eye contact by wearing chemical goggles with side shields or face shield
(AS/NZS 1336) whenever exposed to vapour or mist or if there is a risk of
splashing liquid in the eyes.
Safety showers with eye-wash should be provided in all areas where product is
handled.
Respiratory Protection: None should be needed if engineering, storage and handling controls are
adequate to ensure that atmospheric contamination is kept below the National
Standard.
Where vapour concentrations are likely to approach or exceed the National
Standard, an approved organic vapour respirator (AS/NZS 1715 and 1716)
must be worn.
In high vapour concentrations, or in suspected oxygen deficient atmospheres,
such as empty vessels or confined spaces, use air supplied hood.
Thermal Protection: None should be needed under normal circumstances.
Smoking & Other Dusts Smoking must be prohibited in all areas where this product is used - see safety
information on flammability.
CSR SDS Reference: ETH-SDS-056
Date Issued: April 2008
MSDS for n-Propyl Acetate Page 5 of 8
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Clear colourless liquid
Odour: Strong, slightly fruity odour. Detectable at approximately 20 ppm
pH, at stated concentration: Not Available
Vapour pressure: 25 mm Hg at 20掳C
Vapour Density: 3.52 (air = 1)
Boiling Point/range (掳C): 101.6掳C
Freezing/Melting Point (掳C): -95掳C
Solubility: Moderate - 18.9 g/L at 20掳C
Specific Gravity (H2O = 1): 0.89 at 20/20掳C
FLAMMABLE MATERIALS
Flash Point: 14.4 - 21.1掳C
Flash Point Method: tag open cup
Flammable (Explosive) Limit - 8
Upper:
Flammable (Explosive) Limit - 2
Lower:
Autoignition Temperature: 457掳C
ADDITIONAL PROPERTIES
Evaporation Rate: 275 (n-Butyl Acetate = 100)
Molecular Weight: Not Applicable
Volatile Organic Compounds 100%
Content (VOC):
(as specified by the Green
Building Council of Australia)
% Volatiles: 100%
SECTION 10: STABILITY AND REACTIVITY
Chemical Stability: Stable
Incompatible Materials: Will react with strong oxidizing agents.
Conditions to avoid: Heat, sparks, flame and build-up of static electricity.
Hazardous Decomposition Burning can produce carbon monoxide and/or carbon dioxide.
Products:
Hazardous Reactions: Hazardous polymerisation will not occur.
CSR SDS Reference: ETH-SDS-056
Date Issued: April 2008
MSDS for n-Propyl Acetate Page 6 of 8
SECTION 11: TOXICOLOGICAL INFORMATION
Toxicological Data:
Acute toxicity (Propyl Acetate): LD50/oral/rat: 8700 mg/kg
LD50/dermal/rat: 17760 mg/kg
Health effects information is based on reported effects in use from overseas and Australian reports.
Effects: Acute
Swallowed: Unlikely under normal occupational exposures but swallowing the product may cause nausea,
vomiting, diarrhoea, abdominal discomfort, pain and stomach cramps.
Eyes: Liquid and mists may severely irritate or damage the eyes. The vapour may be mildly irritating.
Skin: Contact with skin may result in mild irritation.
Inhaled: Vapours in high concentrations may cause minor irritation of the upper respiratory tract.
Effects: Chronic
Prolonged or repeated contact and heavy skin contamination may cause skin drying and cracking and/or dermatitis with
redness, itching, and swelling. This may lead to secondary infection.
Inhalation of higher concentrations can cause drowsiness, headaches and vomiting.
May also produce central nervous system depression, which can lead to loss of co-ordination, impaired judgement and, if
exposure is prolonged, unconsciousness. Similar products have been implicated in substance abuse (sniffing).
Additional Notes
Not listed as being a sensitiser.
Not listed as mutagenic or carcinogenic.
There is limited information suggesting that repeated and excessive over-exposure to this product may damage the liver
and kidneys.
SECTION 12: ECOLOGICAL INFORMATION
Eco-toxicity: Toxicity to fish (acute): LC50/Fathead minnow/: 56 - 64 mg/l/96 h
Toxicity to daphnia: EC50/Daphnia magna/: 318 mg/l/24 h
Persistence and Degree of elimination: >60%
Degradability: Evaluation: biodegradable
Mobility: No data available.
SECTION 13: DISPOSAL CONSIDERATIONS
Suitable for incineration by approved agent under controlled conditions if permitted by local authorities, otherwise
disposal must be in accordance with local waste authority requirements.
Product must be contained and not disposed to sewerage systems, drains or waterways. Advise flammable nature.
Empty containers must be decontaminated by rinsing with water.
CSR SDS Reference: ETH-SDS-056
Date Issued: April 2008
MSDS for n-Propyl Acetate Page 7 of 8
SECTION 14: TRANSPORT INFORMATION
Proper Shipping N-PROPYL ACETATE
Name:
UN number: 1276
DG Class: 3
Subsidiary Risk 1: None Allocated
Packaging Group: II
HAZCHEM code: 3[Y]E
Marine Pollutant: No
Special Precautions Refer to incompatibilities in section 7 and stability and reactivity information in section 10.
for User:
ADDITIONAL TRANSPORT REQUIREMENTS:
Nil
SECTION 15: REGULATORY INFORMATION
Poisons Schedule: Not Scheduled
SECTION 16: OTHER INFORMATION
For further information on this product, please contact:
CSR Distilleries Operations Pty Limited (ABN 85 009 660 191)
664 Lorimer St, Port Melbourne, Victoria 3207
Phone: (03) 9676 7200 or 1800 819 618 (available in Australia only)
Fax: (03) 9676 7220 or 1800 647 260 (available in Australia only)
ADDITIONAL INFORMATION
Australian Standards References:
AS 1020 The Control of Undesirable Static Electricity
AS 1076 Code of Practice for selection, installation and maintenance of electrical apparatus and
associated equipment for use in explosive atmospheres (other than mining applications) 鈥?
Parts 1 to 13
AS/NZS 1336 Recommended Practices for Occupational Eye Protection
AS/NZS 1715 Selection, Use and Maintenance of Respiratory Protective Devices
AS/NZS 1716 Respiratory Protective Devices
AS 1940 The Storage and Handling of Flammable and Combustible Liquids
AS 2161 Industrial Safety Gloves and Mittens (excluding electrical and medical gloves)
AS 2380 Electrical equipment for explosive atmospheres 鈥? Explosion Protection Techniques (Parts 1 to
9)
AS 3000 Electrical installations (known as the Australian/New Zealand Wiring Rules)
CSR SDS Reference: ETH-SDS-056
Date Issued: April 2008
MSDS for n-Propyl Acetate Page 8 of 8
Other References:
NOHSC:2011(2003) National Code of Practice for the Preparation of Material Safety Data Sheets 2nd Edition, April
2003, National Occupational Health and Safety Commission.
NOHSC:2012 (1994) National Code of Practice for the Labelling of Workplace Substances, March 1994, Australian
Government Publishing Service, Canberra.
NES National Occupational Exposure Standards for workplace Atmospheric Contaminants (NES)
Australian Safety and Compensation Council, ASCC (Formerly NOHSC) 1995 as amended.
Australian Dangerous Goods Code 6th Edition.
ADG Code
AUTHORISATION
Reason for Issue: 5 yearly review & new CSR format
Authorised by: Operations Manager - Yarraville Distillery
Date of Issue: April 2008
Expiry Date: April 2013
Whilst the information contained in this document is based on data which, to the best of our knowledge, was accurate and
reliable at the time of preparation, no responsibility can be accepted by us for errors and omissions. The provision of this
information should not be construed as a recommendation to use any of our products in violation of any patent rights or in
breach of any statute or regulation. Users are advised to make their own determination as to the suitability of this
information in relation to their particular purposes and specific circumstances. Since the information contained in this
document may be applied under conditions beyond our control, no responsibility can be accepted by us for any loss or
damage caused by any person acting or refraining from action as a result of this information.
END OF MSDS
CSR SDS Reference: ETH-SDS-056
Date Issued: April 2008
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