CSR MATERIAL SAFETY DATA SHEET
Special Methylated Spirits - F59, F61 & F62
SECTION 1: IDENTIFICATION OF THE MATERIAL AND SUPPLIER
Product Name: Special Methylated Spirits - F59, F61 & F62
Other Names: Denatured Ethanol, Ethyl Alcohol, Ethanol 鈥? Denatured Export, Special Methylated
Spirits - Export.
Product Codes/Trade Names: 95XXF59, 95XXF61, 95XXF62, 100XXF59, 100XXF61, 100XXF62,
Recommended Use: General industrial solvent for export
Applicable In: Australia
Supplier: CSR Distillery Operations Pty Limited (ABN 85 009 660 191)
Address: Unit 15/21 Sabre Drive, Port Melbourne, Victoria, 3207
Telephone: 1800 819 618
Email Address: sales.distilleries@csr.com.au
Facsimile: 1800 647 260
Emergency Phone Number: 000 Fire Brigade and Police (available in Australia only).
Poisons Information Centre: 13 11 26 (available in Australia only).
This Material Safety Data Sheet (MSDS) is issued by the Supplier in accordance with National standards and guidelines
from the Australian Safety and Compensation Council (ASCC, formerly National Occupational Health and Safety
Commission - NOHSC). The information in it must not be altered, deleted or added to. The Supplier will not accept any
responsibility for any changes made to its MSDS by any other person or organization. The Supplier will issue a new MSDS
when there is a change in product specifications and/or ASCC standards, codes, guidelines, or Regulations.
SECTION 2: HAZARD IDENTIFICATION
STATEMENT OF HAZARDOUS NATURE: Classified as Hazardous according to the criteria of the Australian Safety and
Compensation Council ASCC (formerly NOHSC) Approved Criteria For Classifying Hazardous Substances [NOHSC:1008]
3rd Edition.
Special Methylated Spirits - F59, F61 & F62 is classified as Dangerous Goods according to the Australian Code for the
Transport of Dangerous Goods by Road and Rail.
Risk Phrases Safety Phrases
R11 - Highly flammable. S7/9 - Keep container tightly closed and in a well
ventilated place
R20/22 - Harmful by inhalation and if swallowed.
S16 - Keep away from sources of ignition - No smoking.
R36/38 - Irritating to eyes and skin.
S23 - Do not breathe vapour.
R66 - Repeated exposure may cause skin dryness and
cracking. S24/25 - Avoid contact with skin and eyes
S29 - Do not empty into drains.
S33 - Take precautionary measures against static
discharges.
S36/37/39 - Wear suitable protective clothing/ gloves and
eye/face protection
S45 - In case of accident or if you feel unwell seek
medical advice immediately (show the label whenever
possible.)
CSR MSDS Reference: ETH-SDS-069
Date Issued: 30th January 2008
MSDS for Special Methylated Spirits - F59, F61 & F62 Page 2 of 9
SECTION 3: COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Name: Synonyms Proportion: CAS Number:
Ethyl Alcohol Ethanol 96 - 100% by volume 64-17-5
Diethyl Phthalate DEP (F59, F62) 1 - 1.2% by volume 84-66-2
Dimethyl Phthalate DMP (F62) 1% by volume 131-11-3
SECTION 4: FIRST AID MEASURES
If there are signs of drunkenness (intoxication or inebriation) then serious health effects may follow (depending on the
amount swallowed or inhaled).
Immediate medical attention should be sought and the affected person transferred and accompanied to the care of a
doctor or hospital. Treat unconsciousness by placing the person in the coma position. Apply artificial respiration if
breathing stops.
Swallowed: See above. If a minor amount has been accidentally swallowed, then, if conscious, dilute
stomach contents by giving large amounts of water. Do not allow further work until fitness for
duties is established.
Do not attempt to induce vomiting or give anything by mouth to an unconscious person. Seek
medical attention. If person vomits, place person on their side in recovery position.
Eyes: Flush eye with running water for a minimum of 15 minutes. Seek medical attention promptly if
irritation persists or any loss of vision occurs.
Skin: Remove contaminated clothing. Wash skin with water. Launder contaminated clothing before
re-use.
Inhaled: Remove promptly to fresh air. If there are signs of drunkenness (intoxication or inebriation) or
respiratory irritation, dizziness, nausea or headache occurs, seek immediate medical attention.
Treat unconsciousness by placing the person in the coma position. Apply artificial respiration if
breathing stops.
First Aid Facilities: First Aid Kits, Safety showers, eye wash stations.
Advice to Doctor: Treat as for excess consumption of alcoholic drink. Supportive, hospital or even intensive care
may be required. Advice on emergency treatment of alcohol poisoning (Ethyl alcohol, ethanol)
is to be found in standard texts on Emergency Medicine.
SECTION 5: FIRE FIGHTING MEASURES
Flammability: Highly flammable liquid. May form flammable mixtures with air. Burns with a
colourless flame. The vapour is heavier than air and may travel along the
ground; distant ignition and flash back are possible.
Run off to sewers and drains may cause explosions. Isolate for at least 800
metres in all directions if tanks or tankers are involved. The use of compressed
air for filling, discharging, mixing or handling is prohibited due to the vapour
hazard.
All vessels must be earthed to avoid generation of static charges when agitating
or transferring solvents. Avoid all ignition sources. Intrinsically safe equipment is
necessary in areas where this chemical is being used.
Suitable extinguishing media: Use water fog (or if unavailable fine water spray), dry chemical, carbon dioxide
or alcohol stable foam.
Hazards from combustion products: Burning can produce carbon monoxide and/or carbon dioxide.
CSR SDS Reference: ETH-SDS-069
Date Issued: 30th January 2008
MSDS for Special Methylated Spirits - F59, F61 & F62 Page 3 of 9
Special protective precautions and Highly flammable liquid. Use water to cool exposed containers. Heating can
equipment for fire fighters: cause expansion or decomposition leading to violent rupture of containers. If
safe to do so, remove containers from path of fire.
Spills and leaks may be washed away with copious volumes of water, fog or
spray.
For major fires or where the atmosphere is either oxygen deficient or contains
unacceptable levels of combustion products, firefighters must wear self-
contained breathing apparatus with full face-mask and protective clothing.
HAZCHEM Code: 2[Y]E
SECTION 6: ACCIDENTAL RELEASE MEASURES
Emergency Procedure: In the event of a spill eliminate all sources of ignition and take measures to
prevent static discharge. No smoking. Use water spray to disperse vapour.
Clear area of all personnel not directly involved in the clean up.
All personnel involved in the containment and disposal procedures to wear
protective equipment as described in Section 8 to prevent skin and eye
contamination and inhalation of vapours.
Ventilate area well and ensure the atmosphere is safe before personnel return
to the work area.
Containment Procedure: Stop and contain the spill for salvage or absorb in inert absorbent material (e.g.
soil, sand, vermiculite) for disposal by an approved method. Prevent run-off into
drains and waterways.
If contamination of sewers or waterways has occurred, advise the local
emergency services.
Clean Up Procedure: Wash the cleaned up area with copious volumes of water to remove any trace
amounts of product. Ethanol mix completely with water. Spills can be converted
to non-flammable mixtures by dilution with water.
Non-returnable containers should be de-gassed prior to disposal. Dispose of all
waste containers and used drums in accordance with local authority guidelines.
SECTION 7: HANDLING AND STORAGE
Handling: Use in well ventilated areas away from all ignition sources. Intrinsically safe
equipment only must be used in area where this chemical is being used.
The use of compressed air for filling, discharging, mixing or handling is
prohibited due to the vapour hazard. Containers must be earthed to avoid
generation of static charges when agitating or transferring product.
Storage: Store in tightly closed containers in cool, dry, isolated and well ventilated areas
away from heat, sources of ignition and incompatibles. Store away from
oxidizing agents. Keep containers closed at all times 鈥? check regularly for leaks.
Do not eat, drink or smoke in areas of use or storage. Observe State
Regulations concerning the storage and handling of Dangerous Goods. Store
with all precautions required for handling flammable liquids.
The requirement of Australian Standard AS 1940 should be observed in
addition to AS 1020, AS 1076, AS 2380 and AS 3000.
Empty containers retain residue (liquid and/or vapour) and are dangerous. Do
not pressure cut, weld, braze, solder, drill, grind or expose such containers to
heat, flame, sparks, static electricity, or other sources of ignition.
Incompatibilities: Not to be stored with explosives (Class 1), flammable gases in bulk (Class 2.1),
poisonous gases (Class 2.3), spontaneously combustible substances (Class
CSR SDS Reference: ETH-SDS-069
Date Issued: 30th January 2008
MSDS for Special Methylated Spirits - F59, F61 & F62 Page 4 of 9
4.2), oxidizing agents (Class 5.1), organic peroxides (Class 5.2), radioactive
substances (Class 7).
Exemptions may apply.
SECTION 8: EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure Standards: National Occupational Exposure Standard (NES) Australian Safety &
Compensation Council, ASCC (formerly NOHSC)
Ethanol:
TWA - 1000 ppm (1880 mg/m3)
STEL - None Allocated
Carcinogen Category - None Allocated
Notices - None Allocated
DEP/DMP:
TWA - 5 mg/m3
STEL - None Allocated
Carcinogen Category - None Allocated
Notices - None Allocated
Notes: All occupational exposures to atmospheric contaminants should be kept to as
low a level as is workable (practicable) and in all cases to below the National
Standard.
These Exposure Standards are guides to be used in the control of occupational
health hazards.
These Exposure Standards should not be used as fine dividing lines between
safe and dangerous concentrations of chemicals. They are not a measure of
relative toxicity.
TWA (Time Weighted Average): the time-weighted average airborne
concentration over an eight-hour working day, for a five-day working week over
an entire working life. According to current knowledge this concentration
should neither impair the health of, nor cause undue discomfort to, nearly all
workers.STEL (Short Term Exposure Limit): the average airborne
concentration over a 15 minute period which should not be exceeded at any
time during a normal eight-hour work day.
Biological Limit Values: N/A
ENGINEERING CONTROLS
Ventilation: Local exhaust ventilation and/or mechanical (general) exhaust is recommended
where vapours are likely to be generated. All such equipment must be
intrinsically safe.
Special Consideration for Empty containers retain residue (liquid and/or vapour) and are dangerous. Do
Repair &/or Maintenance of not pressure cut, weld, braze, solder, drill, grind or expose such containers to
Contaminated Equipment: heat, flame, sparks, static electricity, or other sources of ignition.
Vapour is heavier than air 鈥? prevent concentration in hollows or sumps. Do not
enter confined spaces where vapour may have collected. Keep containers
CSR SDS Reference: ETH-SDS-069
Date Issued: 30th January 2008
MSDS for Special Methylated Spirits - F59, F61 & F62 Page 5 of 9
closed when not in use.
PERSONAL PROTECTION
Personal Hygiene Protective clothing (gloves, coveralls, boots, etc.) should be worn to prevent
skin contact. Always wash hands before smoking, eating, drinking or using the
toilet.
Wash contaminated clothing and other protective equipment before storing or
re-using.
Skin Protection: Avoid skin contact by the use of approved chemical resistant gloves and aprons
鈥? PVC or Neoprene (AS 2161).
Eye Protection: Avoid eye contact by wearing chemical goggles with side shields or face shield
(AS/NZS 1336) whenever exposed to vapour or mist or if there is a risk of
splashing liquid in the eyes.
Safety showers with eye-wash should be provided in all areas where product is
handled.
Respiratory Protection: None should be needed if engineering, storage and handling controls are
adequate to ensure that atmospheric contamination is kept below the National
Standard.
Where vapour concentrations are likely to approach or exceed the National
Standard, an approved organic vapour respirator (AS/NZS 1715 and 1716)
must be worn.
In high vapour concentrations, or in suspected oxygen deficient atmospheres,
such as empty vessels or confined spaces, use air supplied hood.
Thermal Protection: None should be needed under normal circumstances.
Smoking & Other Dusts Smoking must be prohibited in all areas where ethanol is used - see safety
information on flammability.
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Clear colourless liquid
Odour: Characteristic alcohol odour. Ethanol odour detectable at 80 - 100 ppm
pH, at stated concentration: Not Available
Vapour pressure: 44 mm Hg @ 20掳C (Ethanol)
Vapour Density: 1.59 (air = 1) (Ethanol)
Boiling Point/range (掳C): 78掳C (Ethanol)
Freezing/Melting Point (掳C): -117掳C (Ethanol)
Solubility: Complete (Ethanol)
Specific Gravity (H2O = 1): 0.79-0.81 (Water =1) (Ethanol)
FLAMMABLE MATERIALS
Flash Point: 13掳C (Ethanol)
Flash Point Method: Abel closed cup
Flammable (Explosive) Limit - 19% (Ethanol)
Upper:
Flammable (Explosive) Limit - 3.5% (Ethanol)
Lower:
CSR SDS Reference: ETH-SDS-069
Date Issued: 30th January 2008
MSDS for Special Methylated Spirits - F59, F61 & F62 Page 6 of 9
Autoignition Temperature: 392掳C (Ethanol)
ADDITIONAL PROPERTIES
Evaporation Rate 253 (n-Butyl Acetate = 100) (Ethanol)
Molecular Weight Not Applicable
Volatile Organic Compounds Not Applicable
Content (VOC)
(as specified by the Green
Building Council of Australia)
% Volatiles 100%
SECTION 10: STABILITY AND REACTIVITY
Chemical Stability: Stable
Incompatible Materials: Will react with strong oxidizing agents
Conditions to avoid: Heat, sparks, flame and build-up of static electricity.
Hazardous Decomposition Burning can produce carbon monoxide and/or carbon dioxide.
Products:
Hazardous Reactions: Hazardous polymerisation will not occur.
SECTION 11: TOXICOLOGICAL INFORMATION
Toxicological Data:
LD50/oral/rat: 7060 mg/kg (literature data) (Ethanol)
LC50/inhalation/rat: 38 mg/l/10 h (literature data) (Ethanol)
Health effects information is based on reported effects in use from overseas and Australian reports.
ASCC (NOHSC) does not classify ethanol as a carcinogen. IARC has evaluated ethanol IARC has evaluated ethanol as a
carcinogen on the basis of effects of drinking alcoholic beverages, but there is no known carcinogenic risk from
occupational exposures. There is extensive toxicological and epidemiological information on the health effects of ingesting
alcoholic drinks containing ethanol.
Effects: Acute
Swallowed: Accidental swallowing is unlikely in the industrial setting. Swallowing ethanol can cause
drunkenness or harmful central nervous system effects. The deliberate ingestion of ethanol
is a known occupational risk.
As little as 50-100ml intake in a shift in a 70kg worker may cause inebriation to the point
where safety is impaired. Effects of a small intake may include excitation, euphoria,
headache, dizziness, drowsiness, blurred vision, and fatigue.
A blood alcohol level in excess of 0.05g\100ml is regarded as likely to impair functioning for
tasks such as operating machinery.
Eyes: Vapours may irritate the eyes. Liquid and mists may severely irritate or damage the eyes.
Skin: Contact with skin may result in slight irritation and redness.
Inhaled: Vapour is moderately irritating to mucous membranes and respiratory tract. Inhalation of
the vapour may result in drunkenness, (see effects of swallowing above) or headache,
nausea, incoordination, narcosis (sleepiness) and vomiting.
Early signs or Symptoms may occur at airborne levels of 1000 to 5000 ppm.
CSR SDS Reference: ETH-SDS-069
Date Issued: 30th January 2008
MSDS for Special Methylated Spirits - F59, F61 & F62 Page 7 of 9
Effects: Chronic
Nasal and eye irritation may occur at concentrations below the exposure standard.
Long term exposure by swallowing or repeated inhalation may cause degenerative changes in the liver, kidneys,
gastrointestinal tract and heart muscle.
Prolonged or repeated contact and heavy skin contamination may cause skin drying and cracking and/or dermatitis with
redness, itching, and swelling. This may lead to secondary infection.
Ongoing or repeated exposures at High concentrations may cause central nervous symptoms similar to acute
"swallowed鈥? above. Deliberate inhalation of the vapour is a known occupational risk.
Exposure to ethanol in the work setting adds to any intake from alcoholic drinks and any health effects caused by the
total intake of alcohol.
Additional Notes
In work areas where exposures in excess of the occupational exposure limits occur, then the following may apply:
Persons with pre-existing liver impairment, skin and respiratory disorders may be at an increased risk.
Ethanol may cause adverse reproductive effects. Absorption of some drugs may be affected causing adverse health
effects. Ingestion by pregnant women may cause serious effects in their newborn babies called 鈥渇oetal alcohol
syndrome鈥?.
SECTION 12: ECOLOGICAL INFORMATION
Eco-toxicity: (Ethanol)
Toxicity to fish (acute): LC0/Golden ide/: >1000 mg/l/48 h
Toxicity to daphnia: EC50/Daphnia magna/: >1000 mg/l/24 h
Persistence and (Ethanol):
Degradability: Degree of elimination: 94%
Evaluation: biodegradable
Mobility: No data available
SECTION 13: DISPOSAL CONSIDERATIONS
Suitable for incineration by approved agent under controlled conditions if permitted by local authorities, otherwise
disposal must be in accordance with local waste authority requirements.
Product must be contained and not disposed to sewerage systems, drains or waterways. Advise flammable nature.
Empty containers must be decontaminated by rinsing with water.
SECTION 14: TRANSPORT INFORMATION
Proper Shipping ETHANOL
Name:
UN number: 1170
DG Class: 3
Subsidiary Risk 1: None Allocated
Packaging Group: II
HAZCHEM code: 2[Y]E
Marine Pollutant: No
Special Precautions Refer to incompatibilities in section 7 and stability and reactivity information in section 10.
for User:
CSR SDS Reference: ETH-SDS-069
Date Issued: 30th January 2008
MSDS for Special Methylated Spirits - F59, F61 & F62 Page 8 of 9
ADDITIONAL TRANSPORT REQUIREMENTS:
Nil
SECTION 15: REGULATORY INFORMATION
Poisons Schedule: Not scheduled.
SECTION 16: OTHER INFORMATION
For further information on this product, please contact:
CSR Distilleries Operations Pty Limited (ABN 85 009 660 191)
265 Whitehall Street, Yarraville, Victoria, 3013, Australia.
Phone: (03) 9676 7200 or 1800 819 618 (available in Australia only).
Fax: (03) 9676 7220 or 1800 647 260 (available in Australia only). [Enter contact phone]
ADDITIONAL INFORMATION
Australian Standards References:
AS 1020 The Control of undesirable static electricity.
AS 1076 Code of Practice for selection, installation and maintenance of electrical apparatus and
associated equipment for use in explosive atmospheres (other than mining applications) 鈥?
Parts 1 to 13.
AS/NZS 1336 Recommended Practices for Occupational Eye Protection
AS/NZS 1715 Selection, Use and Maintenance of Respiratory Protective Devices
AS/NZS 1716 Respiratory Protective Devices
AS 1940 The Storage and Handling of Flammable and Combustible Liquids.
AS 2161 Industrial Safety Gloves and Mittens (excluding electrical and medical gloves)
AS 2380 Electrical equipment for explosive atmospheres 鈥? Explosion Protection Techniques (Parts 1
to 9).
AS 3000 Electrical installations (known as the Australian/New Zealand Wiring Rules).
Other References:
[Enter additional references here]
NOHSC:2011(2003) National Code of Practice for the Preparation of Material Safety Data Sheets 2nd Edition, April
2003, National Occupational Health and Safety Commission.
NOHSC; 2012 National Code of Practice for the Labelling of Workplace Substances, March 1994, Australian
(1994) Government Publishing Service, Canberra.
NES National Occupational Exposure Standards for workplace Atmospheric Contaminants (NES)
Australian Safety and Compensation Council, ASCC (Formerly NOHSC) 1995 as amended.
ADG Code 6th Australian Dangerous Goods Code 6th Edition
Edition
AUTHORISATION
Reason for Issue: 5 yearly review & new CSR format
Authorised by: CSR Ltd. Group Manager OHS
CSR SDS Reference: ETH-SDS-069
Date Issued: 30th January 2008
MSDS for Special Methylated Spirits - F59, F61 & F62 Page 9 of 9
Date of Issue: 30th January 2008
Expiry Date: January 2013
Whilst the information contained in this document is based on data which, to the best of our knowledge, was accurate and
reliable at the time of preparation, no responsibility can be accepted by us for errors and omissions. The provision of this
information should not be construed as a recommendation to use any of our products in violation of any patent rights or in
breach of any statute or regulation. Users are advised to make their own determination as to the suitability of this
information in relation to their particular purposes and specific circumstances. Since the information contained in this
document may be applied under conditions beyond our control, no responsibility can be accepted by us for any loss or
damage caused by any person acting or refraining from action as a result of this information.
END OF MSDS
CSR SDS Reference: ETH-SDS-069
Date Issued: 30th January 2008
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