MSDS for Flexol PM50 Page 1 of 8 MSDS-039
MATERIAL SAFETY DATA SHEET
Flexol PM50
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SECTION 1: IDENTIFICATION OF SUBSTANCE/MIXTURE & SUPPLIER
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Flexol PM50
Product Name:
Flexol
Other Names:
Recommended Use: General printing industry solvent.
Supplier: CSR Distilleries Operations Pty Limited
ABN: ABN 85 009 660 191
Address: 265 Whitehall Street
Yarraville VIC 3013
Australia
Telephone: +61 3 9283 4500 (Or 1800 819 618 (available in Australia only))
Facsimile: 1800 647 260
Emergency Phone : Working hours (03) 9283 4506 After hours 1800 627 252
Important Notice : This Material Safety Data Sheet (MSDS) is issued by the Supplier in accordance with
National Occupational Health & Safety Commission (NOHSC) guidelines. As such, the
information in it must not be altered, deleted or added to. The Supplier will issue a new
MSDS when there is a change in product specifications and/or NOHSC
guidelines/regulations. The Supplier will not accept any responsibility for any changes
made to its MSDS by any other person or organisation.
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SECTION 2: HAZARDS INFORMATION
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HAZARDOUS SUBSTANCE 鈥? DANGEROUS GOOD
DG Class 3
Subsidiary Risk 1: None Allocated
Packaging Group II
Poison Schedule None Scheduled
Risk Phrase(s)
R11 - Highly flammable.
R66 - Repeated exposure may cause skin dryness and cracking.
R20/22 - Harmful by inhalation and if swallowed.
R36/38 - Irritating to eyes and skin.
Safety Phrase(s)
S7 - Keep container tightly closed.
S16 - Keep away from sources of ignition - No smoking.
S23 - Do not breathe vapour.
S29 - Do not empty into drains.
S33 - Take precautionary measures against static discharges.
S45 - In case of accident or if you feel unwell seek medical advice immediately (show the label whenever possible.)
S24/25 - Avoid contact with skin and eyes
S36/37/39 - Wear suitable protective clothing/ gloves and eye/face protection
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SECTION 3: COMPOSITION / INFORMATION ON INGREDIENTS
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Chemical Name: CAS Number: Proportion:
Ethyl alcohol (ethanol) 64-17-5 50% by volume
Propylene glycol monomethyl ether 107-98-2 50% by volume
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SECTION 4: FIRST AID MEASURES
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If poisoning occurs, contact a doctor or Poisons Information Centre.
Swallowed: If a minor amount has been accidentally swallowed, then if conscious, diluet stomach contents by giving
large amounts of water. Seek medical attention. Do not attempt to induce vomiting or give anything by mouth to an
unconscious person.
Eye: Flush eyes with water for a minimum of 15 minutes. Seek medical attention promptly if irritation persists or any loss
of vision occurs.
Skin: Contamination of skin may cause minor irritation. With heavier contamination, remove contaminated clothing.
Wash skin with flowing water. Launder contaminated clothing before re-use.
Inhaled: Remove promptly to fresh air. If there are signs of drukenness (intoxication or inebriation) or respiratory
irritation, dizziness, nausea or headache occurs, seek immediate medical attention. Treat unconsciousness by placing
the person in the coma position. Apply artificial respiration if breathing stops.
Notes to doctor: Treat symptomatically and as for narcotic substance.
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SECTION 5: FIRE FIGHTING MEASURES
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Specific Hazards:
Highly flammable liquid. May form flammable mixtures with air. Burns with a colourless flame. The vapour is heavier than
air and may travel along the ground; distant ignition and flash back are possible. Run off to sewers and drains may cause
explosions. Isolate for at least 800 metres in all directions if tanks or tankers are involved. The use of compressed air for
filling, discharging, mixing or handling is prohibited due to the vapour hazard. All vessels must be earthed to avoid
generation of static charges when agitating or transferring solvents. Avoid all ignition sources. Intrinsically safe equipment
is necessary in areas where this chemical is being used.
Extinguishing Media:
Use water fog (or if unavailable fine water spray), dry chemical, carbon dioxide or alcohol stable foam.
Fire Fighting Procedures:
Highly flammable liquid. Use water to cool exposed containers. Heating can cause expansion or decomposition leading to
violent rupture of containers. If safe to do so, remove containers from path of fire. Spills and leaks may be washed away
with copious volumes of water, fog or spray. For major fires or where the atmosphere is either oxygen deficient or
contains unacceptable levels of combustion products, firefighters must wear self-contained breathing apparatus with full
face-mask and protective clothing.
Hazardous Decomposition products:
Burning can produce carbon monoxide and/or carbon dioxide
Hazchem code: 3[Y]E
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MSDS for Flexol PM50 Page 3 of 8 MSDS-039
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SECTION 6 : ACCIDENTAL SPILL AND RELEASE MEASURES
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Containment Procedures:
In the event of a spillage eliminate all sources of ignition and take measures to prevent static discharge 鈥? no smoking.
Stop and contain the spill for salvage or absorb in inert absorbent material (e.g. soil, sand, vermiculite) for disposal by an
approved method. Prevent run-off into drains and waterways. Clear area of all personnel not directly involved in the
clean up. All personnel involved in the containment and disposal procedures to wear protective equipment as described
in Section 8 to prevent skin and eye contamination and inhalation of vapours. Use water spray to disperse vapour. Wash
the cleaned up area with copious volumes of water to remove any traces amounts of product. Ethanol mixes completely
with water. Spills can be converted to non-flammable mixtures by dilution with water. Ventilate area well and ensure the
atmosphere is safe before personnel return to the work area. If contamination of sewers or waterways has occurred,
advise the local emergency services.
Disposal:
Stop and contain the spill for salvage or absorb in inert absorbent material (e.g. soil, sand, vermiculite) for disposal by an
approved method. Prevent run-off into drains and waterways. Dispose of all waste containers and used drums in
accordance with local authority guidelines. Non-returnable containers should be de-gassed prior to disposal.
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SECTION 7: HANDLING AND STORAGE
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Handling and Storage:
Handling:
Use in well ventilated areas away from all ignition sources. Intrinsically safe equipment only must be used in area where
this chemical is being used. The use of compressed air for filling, discharging, mixing or handling is prohibited due to the
vapour hazard. Containers must be earthed to avoid generation of static charges when agitating or transferring product.
Storage:
Store in tightly closed containers in cool, dry, isolated and well ventilated areas away from heat, sources of ignition and
incompatibles. Store away from oxidizing agents. Keep containers closed at all times 鈥? check regularly for leaks. Do not
eat, drink or smoke in areas of use or storage. Observe State Regulations concerning the storage and handling of
Dangerous Goods. Store with all precautions required for handling flammable liquids. The requirement of Australian
Standard AS 1940 should be observed in addition to AS 1020, AS 1076, AS 2380 and AS 3000.
Empty containers retain residue (liquid and/or vapour and can be dangerous. Do not pressure cut, weld, braze, solder,
drill, grind or expose such containers to heat, flame, sparks, static electricity, or other sources of ignition.
Incompatibilities
Not to be stored with explosives (Class 1), flammable gases in bulk (Class 2.1), poisonous gases (Class 2.3),
spontaneously combustible substances (Class 4.2), oxidizing agents (Class 5.1), organic peroxides (Class 5.2),
radioactive substances (Class 7). Exemptions may apply.
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SECTION 8: EXPOSURE CONTROL AND PERSONAL PROTECTION
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Exposure Standards: National Occupational Health & Safety Commission NOHSC Worksafe Australia occupational
exposure standards
Ethanol TWA - 1000 ppm (1880 mg/m3)
STEL - None Allocated
Carcinogen Category - None Allocated
Notices - None Allocated
PGMME TWA - 100 ppm (369 mg/m3)
STEL - 150 ppm (553 mg/m3)
Carcinogen Category - None Allocated
Notices - None Allocated
PGMME = Propylene glycol monomethyl ether
As published by National Occupational Health and Safety Commission.
Exposure Standard (TWA) is the time-weighted average airborne concentration over an eight-hour working day, for a five-
day working week over an entire working life. According to current knowledge this concentration should neither impair the
health or, not cause undue discomfort to, nearly all workers.
STEL (Short Term Exposure Limit) - the average airborne concentration over a 15 minute period which should not be
exceeded at any time during a normal eight-hour work day.
These Exposure Standards are guides to be used in the control of occupational health hazards. All atmospheric
contamination should be kept to as low a level as is workable. These Exposure Standards should not be used as fine
dividing lines between safe and dangerous concentrations of chemicals. They are not a measure of relative toxicity.
Engineering Controls:
Ventilation: Local exhaust ventilation and/or mechanical (general) exhaust is recommended where vapours are likely to
be generated. All such equipment must be intrinsically safe.
Special Considerations for Repair And/Or Maintenance of Contaminated Equipment: Empty containers retain
residue (liquid and/or vapour) and can be dangerous. Do not pressure cut, weld, braze, solder, drill, grind or expose such
containers to heat, flame, sparks, static electricity, or other sources of ignition. Vapour is heavier than air 鈥? prevent
concentration in hollows or sumps. Do not enter confined spaces where vapour may have collected. Keep containers
closed when not in use.
Personal Hygene: Protective clothing (gloves, coveralls, boots, etc.) should be worn to prevent skin contact. Always
wash hands before smoking, eating, drinking or using the toilet. Wash contaminated clothing and other protective
equipment before storing or re-using
Eye Protection: Avoid eye contact by wearing chemical goggles with side shields or face shield (AS/NZS 1336)
whenever exposed to vapour or mist or if there is a risk of splashing liquid in the eyes. Safety showers with eye-wash
should be provided in all areas where product is handled.
Skin Protection: Avoid skin contact by the use of approved chemical resistant gloves and aprons 鈥? PVC or Neoprene
(AS 2161).
Respiratory Protection: None should be needed under normal circumstances. In high vapour concentrations, or in
suspected oxygen deficient atmospheres, such as empty vessels or confined spaces, use air supplied hood. In other
instances where vapour concentrations are likely to exceed 50%TWA, an approved organic vapour respirator (AS/NZS
1715 and 1716) must be worn.
Smoking and Other Dusts: Smoking must be prohibited in all areas where ethanol is used - see safety information on
flammability.
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SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
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Appearance: Clear colourless liquid
Odour Characteristic alcohol odour.
pH, at stated concentration Not Available
Boiling Point: (oC) 78掳C (ethanol)
117 - 125掳C (PGMME)
Melting Point: (oC) -117掳C (ethanol)
-96掳C (PGMME)
Vapour pressure: 44 mm Hg at 20掳C (ethanol)
Specific gravity (H2O = 1) 0.79-0.81 (Water =1)
Solubility in water: Complete
Evaporation Rate: 253 (n-Butyl Acetate = 100) (ethanol)
66 (n-Butyl Acetate = 100) (PGMME)
Vapour Density: 1.59 (air = 1) (ethanol)
3.6 (air = 1) (PGMME)
Per cent volatiles: 100%
Flash Point: 13掳C (ethanol)
32掳C (PGMME)
Abel closed cup (ethanol)
FP Test Method:
Setaflash (PGMME)
Autoignition Temperature: 392掳C (ethanol)
270掳C (PGMME)
Lower Explosive Limit (LEL): 3.5% (ethanol)
Upper Explosive Limit (UEL): 19% (ethanol)
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SECTION 10: STABILITY AND REACTIVITY
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Chemical Stability: Stable
Hazardous Polymerisation: will not occur
Incompatible Materials: Will react with strong oxidizing agents
Conditions to avoid: Heat, sparks, flame and build-up of static electricity.
Hazardous Decomposition products: Burning can produce carbon monoxide and/or carbon dioxide
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SECTION 11: TOXICOLOGICAL AND EPIDEMIOLOGICAL DATA
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Acute Effects:
Acute Oral Toxicity LD50 (rat): 6000 mg/kg
Acute Skin Toxicity LD50 (rabbit): 11000 mg/kg
Swallowed: Accidental swallowing is unlikely in the industrial setting. PGMME toxicity is low. The oral LD50 (rabbit) is
6000 mg/kg. Swallowing ethanol containing products can cause drunkenness or harmful central nervous system effects.
The deliberate ingestion of ethanol containing products is a known occupational risk, and as little as 50-100ml intake in a
shift in a 70kg worker may cause inebriation to the point where safety is impaired. Effects of a small intake may include
excitation, euphoria, headache, dizziness, drowsiness, blurred vision, and fatigue. Drinking a large amount may lead to
severe acute intoxication, tremors, convulsions, loss of consciousness, coma, respiratory arrest and death. .Aspiration
into lungs may cause pneumonitis.
Eye: Liquid and eye mists may irritate the eyes. The vapour is mildly irritating at high concentrations.
Skin: Contact with skin may result in slight irritation. Prolonged or repeated contact and heavy skin contamination may
cause skin drying and cracking and/or dermatitis with redness, itching and swelling. This may lead to possible secondary
infection.
Inhaled: Vapours in high concentrations may cause irritation of the upper respiratory tract. Higher concentrations can
cause drowsiness, headaches and vomiting. May also produce central nervous system depression, which can lead to
loss of co-ordination, impaired judgement and, if exposure is prolonged, unconsciousness.
Chronic (Long term effects): No information about long term exposure is reported. However, by analogy with other
similar substances, repeated and excessive over-exposure may damage some organs such as the liver and kidneys.
There may be a risk of these in humans following prolonged and repeated high exposures. Signs and symptoms of
excessive exposure may be anaesthetic or narcotic effects (drunkenness).
Not listed as mutagenic or carcinogenic. Exposure to Ethanol-containing product in the work setting add to any
intake from alcoholic drinks and any health effects caused by total intake of alcohol.
Special toxic effects:
Inhalation at levels at or exceeding the Occupational Exposure limits or any deliberate ingestion is known to lead to
health effects which may be evident in themselves, or lead to impaired functioning and consequent safety risks in the
industrial setting. A blood alcohol (ethanol) in excess of 0.05g/100mL is regarded as likely to impair functioning for
tasks such as operating machinery.
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SECTION 12: ECOLOGICAL INFORMATION
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Ecotoxicity (ethanol)
Toxicity to fish (acute): LC0/Golden ide/: >1000 mg/l/48 h
Toxicity to daphnia: EC50/Daphnia magna/: >1000 mg/l/24 h
Persistence and degradability (ethanol):
Degree of elimination: 94%
Evaluation: biodegradable
Mobility in soil:
No data available
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SECTION 13: DISPOSAL CONSIDERATIONS
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Suitable for incineration by approved agent under controlled conditions if permitted by local authorities, otherwise
disposal must be in accordance with local waste authority requirements. Product must be contained and not disposed to
sewerage systems, drains or waterways. Advise flammable nature. Empty containers must be decontaminated by rinsing
with water.
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SECTION 14: TRANSPORTATION INFORMATION
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Transport Requirements:
UN number: 1993
Class 3
Subsidiary Risk 1: None Allocated
Packaging Group II
Hazchem code: 3[Y]E
Incompatibilities:
Not to be stored with explosives (Class 1), flammable gases in bulk (Class 2.1), poisonous gases (Class 2.3),
spontaneously combustible substances (Class 4.2), oxidizing agents (Class 5.1), organic peroxides (Class 5.2),
radioactive substances (Class 7). Exemptions may apply.
Road and Rail Transport (Australian Dangerous Goods Code):
UN Number: 1993
Proper Shipping Name: FLAMMABLE LIQUID N.O.S (ETHANOL & PROPYLENE GLYCOL MONOMETHYL
ETHER)
Class: 3
Hazchem Code: 3[Y]E
Packing Group: II
Marine Transport (International Maritime Dangerous Goods Code):
UN Number: 1993
Proper Shipping Name: FLAMMABLE LIQUID N.O.S (ETHANOL & PROPYLENE GLYCOL MONOMETHYL
ETHER)
Class: 3
Packing Group: II
Marine Pollutant: No
Air Transport (International Air Transport Association Dangerous Goods Regulations):
UN Number: 1993
Proper Shipping Name: FLAMMABLE LIQUID N.O.S (ETHANOL & PROPYLENE GLYCOL MONOMETHYL
ETHER)
Class: 3
Packing Group: II
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SECTION 15: REGULATORY INFORMATION
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Regulatory Information:
Classification: Hazardous according to criteria of NOHSC.
Dangerous Good according to criteria of the Australian Dangerous Goods Code.
Poisons Schedule: Not Scheduled
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SECTION 16: OTHER INFORMATION AND CONTACT POINT
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Further Information can be obtained from:
CSR Distilleries Operations Pty Limited (ABN 85 009 660 191), 265 Whitehall Street, Yarraville VIC 3013, Australia.
Phone +61 3 9283 4500 or 1800 819 618 (available in Australia only). Fax 1800 647 260
Additional Information
Australian Standards References:
AS 1020 The Control of undesirable static electricity.
AS 1076 Code of Practice for selection, installation and maintenance of electrical apparatus and associated
equipment for use in explosive atmospheres (other than mining applications) 鈥? Parts 1 to 13.
AS/NZS 1336 Recommended Practices for Occupational Eye Protection.
AS/NZS 1715 Selection, Use and Maintenance of Respiratory Protective Devices.
AS/NZS 1716 Respiratory Protective Devices.
AS 1940 The Storage and Handling of Flammable and Combustible Liquids.
AS 2161 Industrial Safety Gloves and Mittens (excluding electrical and medical gloves).
AS 2380 Electrical equipment for explosive atmospheres 鈥? Explosion Protection Techniques (Parts 1 to 9).
AS 3000 Electrical installations (known as the Australian/New Zealand Wiring Rules).
This MSDS was correct at the time it was prepared (see below for the date). The Supplier, as part of its Health and
Safety Programme, updates MSDSs when its ongoing review process indicates a need for a change to be made. You
should make sure that the MSDS you are reading and relying on is current. You can do this by contacting the Supplier at
the above address.
MSDS Revision Summary
Supersedes Issue Date: N/A
Reasons for Issue: Correct error in subsidiary risk field.
CSR MSDS No.: MSDS-039
Issue Date: 02/2004
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