MSDS-031
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MATERIAL SAFETY DATA SHEET
Flexol EPA 40/40
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SECTION 1: IDENTIFICATION OF THE MATERIAL AND SUPPLIER
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Flexol EPA 40/40
Product Name:
LAM Reducer
Other Names:
Recommended Use: General printing industry solvent
Supplier: CSR ETHANOL - CSR Distilleries Operations Pty Limited
ABN: ABN 85 009 660 191
Address: 265 Whitehall Street
Yarraville VIC 3013
Australia
Telephone: +61 2 9372 5888 (Or 1800 807 668 (available in Australia only))
Facsimile: +61 2 9372 5877
000 Fire Brigade and Police (available in Australia only).
Emergency Phone :
Important Notice : This Material Safety Data Sheet (MSDS) is issued by the Supplier in accordance with
the Australian Safety and Compensation Council (ASCC) (formerly the National
Occupational Health & Safety Commission - NOHSC) code and guidelines. As such, the
information in it must not be altered, deleted or added to. The Supplier will issue a new
MSDS when there is a change in product specifications and/or NOHSC
guidelines/regulations. The Supplier will not accept any responsibility for any changes
made to its MSDS by any other person or organisation.
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SECTION 2: HAZARDS INFORMATION
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HAZARDOUS SUBSTANCE - DANGEROUS GOODS
STATEMENT OF HAZARDOUS NATURE: classified as Hazardous according to the criteria of the Australian
Safety and Compensation Council ASCC (formerly NOHSC) Approved Criteria For Classifying Hazardous
Substances [NOHSC:1008] 3rd Edition.
Flexol EPA is classified as a Dangerous Good according to the Australian Code for the Transport of
Dangerous Goods by Road and Rail.
Risk Phrase(s)
R11 - Highly flammable.
R66 - Repeated exposure may cause skin dryness and cracking.
R20/22 - Harmful by inhalation and if swallowed.
R36/38 - Irritating to eyes and skin.
Safety Phrase(s)
S16 - Keep away from sources of ignition - No smoking.
S23 - Do not breathe vapour.
S29 - Do not empty into drains.
S33 - Take precautionary measures against static discharges.
S45 - In case of accident or if you feel unwell seek medical advice immediately (show the label whenever possible).
S7/9 - Keep container tightly closed and in a well ventilated place.
S24/25 - Avoid contact with skin and eyes.
S36/37/39 - Wear suitable protective clothing/ gloves and eye/face protection.
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SECTION 3: COMPOSITION / INFORMATION ON INGREDIENTS
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Chemical Name: Proportion: CAS Number:
Ethyl alcohol (ethanol) < 30% 64-17-5
Ethyl acetate < 50% 141-78-6
Propyl acetate < 50% 109-60-4
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SECTION 4: FIRST AID MEASURES
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If poisoning occurs, contact a doctor or Poisons Information Centre. If there are signs of drunkenness (intoxication
or inebriation) then serious health effects may follow (depending on the amount swallowed or inhaled).
Swallowed: If a minor amount has been accidentally swallowed then, if conscious, give large amounts of water. Do
not allow further work until fitness for duties is established. Do not attempt to induce vomiting or give anything by
mouth to an unconscious person. Seek medical attention.
Eye: Flush eye with running water for a minimum of 15 minutes. Seek medical attention promptly if irritation persists
or any loss of vision occurs.
Skin: Immediately remove contaminated clothing. Wash skin with water. Launder contaminated clothing before re-
use.
Inhaled: Remove promptly to fresh air. If there are signs of drunkenness (intoxication or inebriation) or respiratory
irritation, dizziness, nausea or headache occurs, seek immediate medical attention. Treat unconsciousness by
placing the person in the coma position. Apply artificial respiration if breathing stops.
Notes to doctor: Treat symptomatically and as for a narcotic substance.
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SECTION 5: FIRE FIGHTING MEASURES
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Specific Hazards: Highly flammable liquid. May form flammable mixtures with air. Burns with a colourless flame.
The vapour is heavier than air and may travel along the ground; distant ignition and flash back are possible. Run off
to sewers and drains may cause explosions. Isolate for at least 800 metres in all directions if tanks or tankers are
involved. The use of compressed air for filling, discharging, mixing or handling is prohibited due to the vapour
hazard. All vessels must be earthed to avoid generation of static charges when agitating or transferring solvents.
Avoid all ignition sources. Intrinsically safe equipment is necessary in areas where this chemical is being used.
Extinguishing Media: Use water fog (or if unavailable fine water spray), dry chemical, carbon dioxide or alcohol
stable foam.
Fire Fighting Procedures: Highly flammable liquid. Use water to cool exposed containers. Heating can cause
expansion or decomposition leading to violent rupture of containers. If safe to do so, remove containers from path of
fire. Spills and leaks may be washed away with copious volumes of water, fog or spray. For major fires or where the
atmosphere is either oxygen deficient or contains unacceptable levels of combustion products, fire fighters must
wear self-contained breathing apparatus with full face-mask and protective clothing.
Hazardous Decomposition products: Burning can produce carbon monoxide and/or carbon dioxide.
Hazchem code: 3[Y]E
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SECTION 6: ACCIDENTAL RELEASE MEASURES
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Containment Procedures: In the event of a spillage eliminate all sources of ignition and take measures to prevent
static discharge 鈥? no smoking. Stop and contain the spill for salvage or absorb in inert absorbent material (e.g. soil,
sand, vermiculite) for disposal by an approved method. Prevent run-off into drains and waterways. Clear area of all
personnel not directly involved in the clean up. All personnel involved in the containment and disposal procedures to
wear protective equipment as described in Section 8 to prevent skin and eye contamination and inhalation of
vapours. Use water spray to disperse vapour. Wash the cleaned up area with copious volumes of water to remove
any traces amounts of product. Ethanol mixes completely with water. Spills can be converted to non-flammable
mixtures by dilution with water. Ventilate area well and ensure the atmosphere is safe before personnel return to the
work area. If contamination of sewers or waterways has occurred, advise the local emergency services and relevant
environmental authorities.
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SECTION 7: HANDLING AND STORAGE
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Handling: Use in well ventilated areas away from all ignition sources. Intrinsically safe equipment only must be used
in area where this chemical is being used. The use of compressed air for filling, discharging, mixing or handling is
prohibited due to the vapour hazard. Containers must be earthed to avoid generation of static charges when
agitating or transferring product.
Storage: Store in tightly closed containers in cool, dry, isolated and well ventilated areas away from heat, sources of
ignition and incompatibles. Store away from oxidizing agents. Keep containers closed at all times 鈥? check regularly
for leaks. Do not eat, drink or smoke in areas of use or storage. Observe State Regulations concerning the storage
and handling of Dangerous Goods. Store with all precautions required for handling flammable liquids. The
requirement of Australian Standard AS 1940 should be observed in addition to AS 1020, AS 1076, AS 2380 and AS
3000.
Empty containers retain residue (liquid and/or vapour) and can be dangerous. Do not pressure cut, weld, braze,
solder, drill, grind or expose such containers to heat, flame, sparks, static electricity, or other sources of ignition.
Incompatibilities: Not to be stored with explosives (Class 1), flammable gases in bulk (Class 2.1), poisonous gases
(Class 2.3), spontaneously combustible substances (Class 4.2), oxidizing agents (Class 5.1), organic peroxides
(Class 5.2), radioactive substances (Class 7). Exemptions may apply.
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SECTION 8: EXPOSURE CONTROL / PERSONAL PROTECTION
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Exposure Standards: National Occupational Exposure Standard (NES) Australian Safety and
Compensation Council, ASCC (formerly NOHSC)
Ethanol TWA - 1000 ppm (1880 mg/m3)
STEL - None Allocated
Carcinogen Category - None Allocated
Notices - None Allocated
Ethyl Acetate TWA - 200 ppm (720 mg/m3)
STEL - None Allocated
Carcinogen Category - None Allocated
Notices - None Allocated
Propyl Acetate TWA - 200 ppm (835 mg/m3)
STEL - 250 ppm (1040 mg/m3)
Carcinogen Category - None Allocated
Notices - None Allocated
Exposure Standard (TWA) is the time-weighted average airborne concentration over an eight-hour working day, for
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a five-day working week over an entire working life. According to current knowledge this concentration should
neither impair the health of nor cause undue discomfort to, nearly all workers.
STEL (Short Term Exposure Limit) - the average airborne concentration over a 15 minute period which should not
be exceeded at any time during a normal eight-hour work day.
Sk Notice 鈥? absorption through the skin may be a significant source of exposure.
These Exposure Standards are guides to be used in the control of occupational health hazards. All atmospheric
contamination should be kept to as low a level as is workable. These Exposure Standards should not be used as
fine dividing lines between safe and dangerous concentrations of chemicals. They are not a measure of relative
toxicity.
Engineering Controls:
Ventilation: Local exhaust ventilation and/or mechanical (general) exhaust is recommended where vapours are
likely to be generated. All such equipment must be intrinsically safe.
Special Considerations for Repair And/Or Maintenance of Contaminated Equipment: Empty containers retain
residue (liquid and/or vapour) and can be dangerous. Do not pressure cut, weld, braze, solder, drill, grind or expose
such containers to heat, flame, sparks, static electricity, or other sources of ignition. Vapour is heavier than air 鈥?
prevent concentration in hollows or sumps. Do not enter confined spaces where vapour may have collected. Keep
containers closed when not in use.
Personal Hygiene: Protective clothing (gloves, coveralls, boots, etc.) should be worn to prevent skin contact.
Always wash hands before smoking, eating, drinking or using the toilet. Wash contaminated clothing and other
protective equipment before storing or re-using.
Eye Protection: Avoid eye contact by wearing chemical goggles with side shields or face shield (AS/NZS 1336)
whenever exposed to vapour or mist or if there is a risk of splashing liquid in the eyes. Safety showers with eye-
wash should be provided in all areas where product is handled.
Skin Protection: Avoid skin contact by the use of approved chemical resistant gloves and aprons 鈥? PVC or
Neoprene (AS 2161).
Respiratory Protection: None should be needed under normal circumstances. In high vapour concentrations or
in suspected oxygen deficient atmospheres, such as empty vessels or confined spaces, use air supplied hood. In
other instances where ethanol vapour concentrations are likely to exceed 500 ppm, propyl acetate vapour
concentrations are likely to exceed 100 ppm or propanol vapour concentrations are likely to exceed 100 ppm, an
approved organic vapour respirator (AS/NZS 1715 and 1716) must be worn. Use only respirators that bear the
Australian Standards mark and are fitted and maintained correctly, and kept in clean storage when not in use.
Smoking and Other Dusts: Smoking must be prohibited in all areas where this product is used - see safety
information on flammability.
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SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
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Appearance: Clear colourless liquid
Odour: Slightly ether-like odour
pH, at stated concentration: Not Available
Boiling Point: 78掳C (ethanol)
77.1掳C (Ethyl Acetate)
101.6掳C (propyl acetate)
Melting Point: -117掳C (ethanol)
-83.6掳 (Ethyl Acetate)
-95掳C (propyl acetate)
Vapour pressure: 44 mm Hg at 20掳C (ethanol)
73 mm Hg at 20掳C (ethyl acetate)25 mm Hg at 20掳C (propyl acetate)
Vapour Density: 1.59 (air = 1) (ethanol)
3.0 (air = 1) (ethyl acetate)
3.52 (air = 1) (propyl acetate)
Specific gravity (H2O = 1): Approximately 0.8
Solubility in water: Appreciable
Per cent volatiles: 100%
Flash Point: 13掳C (ethanol)
-4.4掳C (Ethyl Acetate)
14.4 - 21.1掳C (propyl acetate)
Closed cup (ethanol & propyl acetate)
FP Test Method:
Tag open cup (Ethyl Acetate)
Auto Ignition Temperature: 392掳C 鈥? 452掳C
Lower Explosive Limit (LEL): 2 - 3.5%
Upper Explosive Limit (UEL): 8 - 19%
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SECTION 10: STABILITY AND REACTIVITY
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Chemical Stability: Stable.
Hazardous Polymerisation: Will not occur.
Incompatible Materials: Will react with strong oxidizing agents.
Conditions to avoid: Heat, sparks, flame and build-up of static electricity.
Hazardous Decomposition products: Burning can produce carbon monoxide and/or carbon dioxide.
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SECTION 11: TOXICOLOGICAL INFORMATION
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Acute toxicity (ethanol): LD50/oral/rat: 7060 mg/kg (literature data)
LC50/inhalation/rat: 38 mg/l/10 h (literature data)
Acute toxicity (Ethyl Acetate): LD50/oral/rat: 8700 mg/kg
LD50/dermal/rat: 17760 mg/kg
Acute toxicity (propyl acetate) LD50/oral/rat: 8700 mg/kg
LD50/dermal/rat: 17760 mg/kg
Acute Effects:
Inhalation at levels at or exceeding the Occupational Exposure limits or any deliberate ingestion is known to lead to
health effects that may be obvious or lead to impaired functioning and consequent safety risks in the industrial
setting. A blood alcohol level in excess of 0.05g\100ml is regarded as likely to impair functioning for tasks such as
operating machinery.
Swallowed: Accidental swallowing is unlikely in the industrial setting. Swallowing ethanol can cause drunkenness
or harmful central nervous system effects. The deliberate ingestion of ethanol is a known occupational risk, and as
little as 50-100ml intake in a shift in a 70kg worker may cause inebriation to the point where safety is impaired. This
is unlikely with this product which contains acetates as the main ingredients. Effects of a small intake may include
excitation, euphoria, headache, dizziness, drowsiness, blurred vision, nausea and fatigue. Drinking a large amount
may lead to severe acute intoxication tremors, convulsions, loss of consciousness, coma, respiratory arrest and
death. Aspiration into lungs may cause pneumonitis.
Eye: Vapours may irritate the eyes. Liquid and mists may severely irritate the eyes.
Skin: Contact with skin may result in slight irritation and redness. Prolonged or repeated contact and heavy skin
contamination may cause skin drying and cracking and/or dermatitis with redness, itching, and swelling. This may
lead to possible secondary infection.
Inhaled: Vapour is moderately irritating to mucous membranes and respiratory tract. Inhalation of the vapour may
result in drunkenness, (see effects of swallowing above) or headache, nausea, incoordination, narcosis (sleepiness)
and vomiting. Early signs or symptoms may occur at airborne levels of 1000 to 5000 ppm. Ongoing or repeated
exposures at high concentrations may cause central nervous symptoms similar to 鈥淪wallowed鈥? above. Deliberate
inhalation of the vapour is a known occupational risk.
Chronic - Long Term Effects:
Long term exposure by swallowing or repeated inhalation, may cause degenerative changes in the liver, kidneys and
other organs. Exposure to ethanol in the work setting adds to any intake from alcoholic drinks and any health effects
caused by the total intake of alcohol.
Special toxic effects: In work areas where exposures in excess of the occupational exposure limits occur, then the
following may apply: Persons with pre-existing liver impairment, skin and respiratory disorders may be at an
increased risk. Ethanol may cause adverse reproductive effects. Absorption of some drugs may be affected
causing adverse health effects. Ingestion by pregnant women may cause serious effects in their newborn babies
called 鈥渇oetal alcohol syndrome鈥?. The Australian Safety and Compensation Council, ASCC (formerly NOHSC) does
not classify any of the ingredients as carcinogens. IARC has evaluated ethanol as a carcinogen on the basis of
effects of drinking alcoholic beverages, but there is no known carcinogenic risk from occupational exposures. There
is extensive toxicological and epidemiological information on the health effects of ingesting alcoholic drinks
containing ethanol. Any occupational exposures will add to overall exposures from ingestion of alcoholic drinks any
health effects that result from such exposures.
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SECTION 12: ECOLOGICAL INFORMATION
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Ecotoxicity (ethanol): Toxicity to fish (acute): LC0/Golden ide/: >1000 mg/l/48 h
Toxicity to daphnia: EC50/Daphnia magna/: >1000 mg/l/24 h
Ecotoxicity (ethyl acetate, propyl acetate): Toxicity to fish (acute): LC50/Fathead minnow/: 56 - 64
mg/l/96 h Toxicity to daphnia: EC50/Daphnia magna/: 318 mg/l/24 h
Persistence and degradability (ethanol): Degree of elimination: 94% Evaluation: biodegradable
Persistence and degradability (ethyl acetate, propyl acetate): Degree of elimination: >60%
Evaluation: readily biodegradable.
Mobility in soil: No direct data available. Product is highly volatile.
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SECTION 13: DISPOSAL CONSIDERATIONS
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Suitable for incineration by approved agent under controlled conditions if permitted by local authorities, otherwise
disposal must be in accordance with local waste and environmental authority requirements. Product must be
contained and not disposed to sewerage systems, drains or waterways. Advise flammable nature. Empty
containers must be decontaminated by rinsing with water.
Dispose of all waste containers and used drums in accordance with local authority guidelines. Non-returnable
containers should be de-gassed prior to disposal.
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SECTION 14: TRANSPORTATION INFORMATION
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Transport Requirements:
UN number: 1993
DG Class: 3
Subsidiary Risk 1: None Allocated
Packaging Group II
Hazchem code: 3[Y]E
Incompatibilities: Not to be stored with explosives (Class 1), flammable gases in bulk (Class 2.1),
poisonous gases (Class 2.3), spontaneously combustible substances (Class 4.2),
oxidizing agents (Class 5.1), organic peroxides (Class 5.2), radioactive substances
(Class 7). Exemptions may apply.
Road and Rail Transport (Australian Dangerous Goods Code):
UN Number: 1993
Proper Shipping Name: FLAMMABLE LIQUID, N.O.S. (ETHANOL, ETHYL ACETATE AND PROPYL ACETATE)
DG Class: 3 Flammable Liquid
Hazchem Code: 3[Y]E
Packing Group: II
Marine Transport (International Maritime Dangerous Goods Code):
UN Number: 1993
Proper Shipping Name: FLAMMABLE LIQUID, N.O.S. (ETHANOL, ETHYL ACETATE AND PROPYL ACETATE)
DGClass: 3 Flammable Liquid
Packing Group: II
Marine Pollutant: No
Air Transport (International Air Transport Association Dangerous Goods Regulations):
UN Number: 1993
Proper Shipping Name: FLAMMABLE LIQUID, N.O.S. (ETHANOL, ETHYL ACETATE AND PROPYL ACETATE)
DG Class: 3 Flammable Liquid
Packing Group: II
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SECTION 15: REGULATORY INFORMATION
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Poisons Schedule: Not Scheduled
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SECTION 16: OTHER INFORMATION
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Emergency Contact Number: Poisons Information Centre 13 11 26
Further Information can be obtained from:
CSR Distilleries Operations Pty Limited (ABN 85 009 660 191), 265 Whitehall Street, Yarraville VIC 3013,
Australia. Phone +61 2 9372 5888 or 1800 807 668 (available in Australia only). Fax +61 2 9372 5877
Additional Information
Australian Standards References:
AS 1020 The Control of undesirable static electricity.
AS 1076 Code of Practice for selection, installation and maintenance of electrical apparatus and
associated equipment for use in explosive atmospheres (other than mining applications) 鈥? Parts
1 to 13.
AS/NZS 1336 Recommended Practices for Occupational Eye Protection.
AS/NZS 1715 Selection, Use and Maintenance of Respiratory Protective Devices.
AS/NZS 1716 Respiratory Protective Devices.
AS 1940 The Storage and Handling of Flammable and Combustible Liquids.
AS 2161 Industrial Safety Gloves and Mittens (excluding electrical and medical gloves).
AS 2380 Electrical equipment for explosive atmospheres 鈥? Explosion Protection Techniques (Parts 1 to 9).
AS 3000 Electrical installations (known as the Australian/New Zealand Wiring Rules).
This MSDS was correct at the time it was prepared (see below for the date). The Supplier, as part of its Health and
Safety Programme, updates MSDSs when its ongoing review process indicates a need for a change to be made.
You should make sure that the MSDS you are reading and relying on is current. You can do this by contacting the
Supplier at the above address.
Issue Date: 08/2008
MSDS Revision Summary
Supersedes Issue Date: 02/2007
Reasons for Issue: Updated emergency phone number only. Full review required by 02/2012
CSR MSDS No.: MSDS-031
Expiry Date: 02/2012
END of MSDS
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