MSDS for Liquid One Shot Page 1 of 5 MSDS-048
MATERIAL SAFETY DATA SHEET
Liquid One Shot
(LOS, LOS Mid N, LOS High N, LOS + P)
SECTION 1: IDENTIFICATION OF THE MATERIAL AND SUPPLIER
Product Name: Liquid One Shot
Other Names: LOS, LOS Mid N, LOS High N, LOS + P
Recommended Use: As a complete fertiliser for all crops, but mainly sugar cane; applied by spraying.
Supplier: CSR Distilleries Operations Pty Ltd
ABN: 85 009 660 191
Address: Bruce Highway
Sarina QLD 4737
Australia
Telephone: +61 7 4940 9822
Facsimile: +61 7 4956 2147
Emergency Phone: Working hours: +61 7 4940 9822; After Hours: 1800 627 252
Important Notice: This Material Safety Data Sheet (MSDS) is issued by the Supplier in accordance with the Australian
Safety and Compensation Council ASCC (formerly National Occupational Health and Safety
Commission - NOHSC) Code and guidelines. As such, information in it must not be altered, deleted
or added to. The Supplier will issue a new MSDS when there is a change in product specifications,
and/or regulatory requirements. The Supplier will not accept any responsibility for any changes
made to its MSDS by any other persons or organisations.
SECTION 2: HAZARDS IDENTIFICATION
NON-HAZARDOUS 鈥? NON-DANGEROUS GOOD
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name Proportion CAS Number
Nitrogen as urea 3.5 鈥? 8.5% w/v 57-13-6
Potassium Up to 3% w/v 7440-09-7
Nitrogen 0.75% w/v 7727-37-9
Phosphorus < 1% w/v 7723-14-0
< 1% w/v
Calcium 7440-70-2
< 1% w/v
Magnesium 7439-95-4
< 1% w/v
Sulphur 7704-34-9
Water 40 鈥? 50% w/v 7732-18-5
Carbohydrates 20 鈥? 25% w/v -
Ash 10 鈥? 15% w/v -
Glycerol 3 鈥? 6% w/v 56-81-5
Liquid One Shot is a by-product of sugar cane milling and contains vegetable matter with traces of potassium, sodium, nitrogen,
calcium, magnesium, phosphorus and sulphur. Sulphuric acid is added to increase the sulphur content and breaks down into
water, sulphur and may form sulphates in the final product.
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MSDS for Liquid One Shot Page 2 of 5 MSDS-048
SECTION 4: FIRST AID MEASURES
Swallowed: Unlikely in the industrial setting. Give water to drink to dilute stomach contents. Do not induce vomiting.
Eye: Flush thoroughly with flowing water for at least 15 minutes. If symptoms/irritation persist, seek medical attention.
Skin: Wash with soap and water.
Inhaled: Remove to fresh air.
Notes to Doctor: Treat symptomatically.
SECTION 5: FIRE FIGHTING MEASURES
Product will not burn. No specific requirements.
SECTION 6: ACCIDENTAL RELEASE MEASURES
Containment Procedures:
Disposal: Large spills - hose down but avoid this product getting into drains, sewers and waterways because of high BOD load
and low pH. Bund and pump into suitable drum for reuse.
SECTION 7: HANDLING & STORAGE
Transported by bulk tanker. No special precautions.
Incompatibilities: None
SECTION 8: EXPOSURE CONTROL / PERSONAL PROTECTION
Exposure Standards:
None assigned by ASCC (formerly NOHSC) Australia
CSR Distilleries recommendation: Keep exposure to aerosols and mists as low as practicable and avoid skin contact.
Engineering Controls:
All work with Liquid One Shot should be carried out in such a way as to minimise skin contact with the product and avoid
generation of liquid aerosol (mist) where persons can inhale it.
Eye Protection:
Goggles or safety glasses (AS 1336 and AS/NZS 1337) and a face shield should be worn if there is a risk of splash.
Skin Protection:
Wear loose comfortable clothing. Wear PVC or rubber gloves AS 2161. Wash work clothes regularly.
Respiratory Protection:
If an aerosol or mist is generated, wear a respirator for acid gases conforming to AS/NZS 1715 and 1716.
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MSDS for Liquid One Shot Page 3 of 5 MSDS-048
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Brown - Black liquid
Odour: Mild molasses odour
pH, at stated concentration: 3.3-4.0
Boiling Point: 100掳C
Melting Point: Not determined
Vapour pressure: Not applicable - does not vapourise
Specific gravity: (H2O = 1) ~ 1.17
Solubility in water: Nutrients soluble in water, mixture partly soluble
Bulk Density: 1200 kg/cubic metre (40 Brix)
Flash Point: Not applicable
Autoignition Temperature: Does not auto-ignite
Appearance: Brown - Black liquid
Odour: Mild molasses odour
pH, at stated concentration: 3.3-4.0
Boiling Point: 100掳C
Melting Point: Not determined
Vapour pressure: Not applicable - does not vapourise
SECTION 10: STABILITY AND REACTIVITY
Product is stable and will not polymerize.
Chemical Stability:
SECTION 11: TOXICOLOGICAL INFORMATION
The health effects listed below are related to the acid pH of the product (3.3 - 4.0) and potential for mild irritation of skin and
mucous membranes.
Swallowed: Unlikely under normal conditions of use, but could cause abdominal discomfort and nausea, and throat irritation.
Eye: Can irritate the eyes and cause watering and redness.
Skin: Can cause skin irritation if in repeated or prolonged contact with the skin.
Inhaled: Can be temporarily irritating to the respiratory system if aerosol mist breathed in.
Chronic: Can be temporarily irritating to the respiratory system if aerosol mist breathed in.
SECTION 12: ECOLOGICAL INFORMATION
Ecotoxicity: Product is biodegradable and has no significant ecotoxicity.
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MSDS for Liquid One Shot Page 4 of 5 MSDS-048
SECTION 13: DISPOSAL CONSIDERATIONS
Large spills-hose down but avoid this product getting into drains, sewers and waterways because of high BOD load and low pH.
Bund and pump into suitable drum for reuse.
SECTION 14: TRANSPORTATION INFORMATION
Transport Requirements:
UN number: Not applicable
Class: Not applicable
Subsidiary Risk: Not applicable
Packaging Group: Not applicable
Hazchem code: Not applicable
Not applicable
EPG Incompatibilities:
Road and Rail Transport (Australian Dangerous Goods Code):
UN number: Not applicable
Proper Shipping Name: Not applicable
Class: Not applicable
Packing Group: Not applicable
Hazchem Code: Not applicable
Marine Transport (International Maritime Dangerous Goods Code):
UN number: Not applicable
Proper Shipping Name: Not applicable
Class: Not applicable
Packing Group: Not applicable
Marine Pollutant: Not applicable
Air Transport (International Air Transport Association Dangerous Goods Regulations):
UN number: Not applicable
Proper Shipping Name: Not applicable
Class: Not applicable
Packing Group: Not applicable
SECTION 15: REGULATORY INFORMATION
LOS is classified as non-Dangerous Goods.
Poisons Schedule: Not scheduled
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MSDS for Liquid One Shot Page 5 of 5 MSDS-048
SECTION 16: OTHER INFORMATION
Further Information can be obtained from:
CSR Distilleries Operations Pty Limited (ABN 85 009 660 191)
Bruce Highway, Sarina QLD 4737, Australia.
Phone +61 7 4940 9822; Fax +61 7 4956 2147 or Poisons Information Centre 13 11 26
Additional Information and reference documents
National Code of Practice for the Preparation of Material Safety Data Sheets 2nd Edition [NOHSC:2011(2003)], April 2003,
National Code Of Practice For The Labelling Of Workplace Substances [NOHSC:2012(1994)], March 1994, Australian
Government Publishing Service, Canberra.
List Of Designated Hazardous Substances [NOHSC:10005(1999)] April 1999 National Occupational Health and Safety
Commission, Sydney
National Code of Practice for the Control of Workplace Hazardous Substances [NOHSC:2007(1994)]; (Australian States have
similar Codes of Practice in each State).
This MSDS was correct at the time it was prepared (see below for the date). The Supplier, as part of its Health and Safety Programme, updates
MSDSs when its ongoing review process indicates a need for a change to be made. You should make sure that the MSDS you are reading and
relying on is current. You can do this by contacting the Supplier at the above address.
Issue Date: May 2006
MSDS Revision Summary
Supercedes Issue Date: 09/05
Reasons for Issue: Updated to include LOS + P
CSR MSDS No.: MSDS-048
END of MSDS
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