tyco Adhesives Material Safety Data Sheet
SECTION I - IDENTIFICATION
铮?
PRODUCT NAME: POLYKEN铮? 1027 AEROSOL PRIMER
SHIPPING NAME: Consumer Commodity
DOT ID NO.: N/A
HAZARD CLASS: ORM-D
EMERGENCY TELEPHONE NUMBER: CHEMTREC 1-800-424-9300
OTHER TECHNICAL/HEALTH/SAFETY INFORMATION: 617-861-3200
SECTION II - HAZARDOUS INGREDIENTS/IDENTITY INFORMATION
CAS REG. NO. NIOSH NO. AMOUNT
75-09-02 PA8050000 approx. 55%
METHYLENE
CHLORIDE
64742-89-8 DE3030000 Approx. 15%
VM&P NAPHTHA
108-88-3 X95250000 Approx. 3%
TOLUENE
74-98-6 TX22750000 Approx. 27%
PROPANE
SECTION III - PHYSICAL/CHEMICAL INFORMATION
BOILING POINT: NA VAPOR DENSITY (Air = 1): >1
pH: Neutral VAPOR PRESSURE: 80 psig (70掳F)
SPECIFIC GRAVITY: >1.0 WATER SOLUBILITY: Negligible
FREEZING POINT: NA EVAPORATION RATE (BuAc=1): <1
VISCOSITY: 56 cP VOC: 4.9 lbs/gal
APPEARANCE AND ODOR: Black, viscous liquid with odor of hydrocarbon solvents. Odor
threshold 10-15 ppm for Toluene, <300 ppm for VM&P Naphtha, 214 ppm for Methylene
Chloride.
SECTION IV - FIRE & EXPLOSION HAZARD DATA
tyco Adhesives
15 Hampshire Street, Mansfield, MA 02048 (508) 261-6200
FLASH POINT: propellant : -156掳 F (API established)
AUTOIGNITION TEMPERATURE: Approximately 480掳 F (VM&P Naphtha)
LEL: 1.8 % UEL: 9.5%
EXTINGUISHING MEDIA: Foam, CO2, Dry Chemical, water fog or spray.
SPECIAL FIRE FIGHTING PROCEDURES: If only water is available, use spray and not a direct
hose stream. Isolate hazard area and do not permit unnecessary personnel to enter. Avoid
breathing fumes or vapors. Wear full protective clothing, including NIOSH approved self
contained breathing apparatus. Cool surrounding areas and exposed containers with water.
UNUSUAL FIRE & EXPLOSION HAZARDS: Do not spray near open flames. At elevated
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temperatures (>120 F) containers may vent, rupture or burst. Aerosol container; do not expose to
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temperature above 120 F.
SECTION V - REACTIVITY DATA
STABILITY: Stable under most conditions. Avoid high temperatures, sparks, open flame.
INCOMPATIBILITY (Materials to avoid): Strong oxidizing agents such as liquid chlorine, pure
oxygen, sodium hypochlorite, and calcium hypochlorite.
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide and complex organic
hydrocarbons may be formed upon combustion.
HAZARDOUS POLYMERIZATION: Will not occur.
SECTION VI - HEALTH HAZARD DATA
THRESHOLD LIMIT VALUE: Not determined for mixture; 25ppm for Methylene Chloride; 300
ppm for VM&P Naphtha; 100 ppm for Toluene; 1000ppm for Propane.
COMPONENTS LISTED AS KNOWN OR POTENTIAL CARCINOGENS: Methylene Chloride
per OSHA Std. 29CFR Part 1910.1200
HEALTH HAZARDS: Intentional misuse use by deliberately concentrating and inhaling the
contents may be harmful or fatal. Reports have associated repeated and prolonged
occupational exposure to solvents with permanent brain and nervous system damage. In
confined areas, vapors in high concentrations are anesthetic. Over exposure may result in light
headedness, staggering gait, giddiness and possible nausea. Irritation to skin and respiratory
tract. Methylene chloride is listed as a potential carcinogen by IARC. Methylene chloride has
been shown to cause cancer in certain laboratory animals. Methylene chloride is not believed to
pose a measurable carcinogenic risk when handled as directed.
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: Respiratory ailments
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ACUTE EFFECTS OF OVEREXPOSURE:
INHALATION: May be irritating to mucous membranes. Inhalation of vapors may lead to
giddiness, dizziness, nausea, and loss of consciousness.
SKIN CONTACT: May be mildly irritating to the skin. Prolonged or repeated exposure may
result in defatting of skin, possibly leading to dermatitis.
EYE CONTACT: Short-term exposure may lead to irritation. NOTE: Wearing contact lenses
is not recommended when using this product.
INGESTION: Ingestion of the liquid may lead to vomiting.
CHRONIC EFFECTS OF OVEREXPOSURE: unknown
EMERGENCY & FIRST AID PROCEDURES:
INHALATION: Move affected person to fresh air and provide oxygen if breathing is
difficult. Give artificial respiration if necessary. Seek medical advice.
SKIN CONTACT: Flush with water, then wash affected area with soap and water. Remove
contaminated clothing immediately and launder before reuse. If irritation
develops, seek medical advice.
EYE CONTACT: Flush with water for at least 15 minutes and seek medical advice.
INGESTION: DO NOT INDUCE VOMITING! If vomiting occurs spontaneously, keep
head below hips to prevent aspiration of liquid into lungs. Seek medical
advice.
TOXICITY INFORMATION:
Methylene Chloride ihl-hmn Tclo 500 ppm/ 8 hr
ivn-mus LD50 1500-2000 mg/kg
Toluene ihl-hmn Tclo 200 ppm/ 8 hr
ivn-mus LD50 5320 mg/kg
VMP & Naptha ihl-hmn Tclo 600 ppm/ 8 hr
ivn-mus LC50 >5000 mg/kg
SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND USE
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: DANGER!
FLAMMABLE! Eliminate all ignition sources. Handling equipment must be grounded to prevent
sparking.
LARGE SPILLS: Isolate the hazard area and keep unnecessary personnel away. Wear NIOSH-
approved protective clothing and self-contained breathing apparatus. Ventilate area. Confine free
liquid by diking and remove liquid with explosion-proof vacuum truck or pump to chemical storage
vessel. Soak up residue with inert absorbent material such as clay or sand; place in leak-free
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container, label as to contents, and hold for proper disposal. Dispose of spill material according to
applicable regulations. DO NOT ALLOW MATERIAL TO ENTER SEWERS OR WATER
COURSES LEADING TO SURFACE WATERS.
SMALL SPILLS: Take up with inert absorbent materials and place in non-leaking containers;
label as to contents; seal tightly for proper disposal.
WASTE DISPOSAL: Dispose of material according to RCRA regulations. Do not puncture,
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incinerate, burn or store above 120 F. Exposure to heat or prolonged exposure to sun may cause
can to burst. Discard empty can in accordance with local regulations. Do not place in home trash
compactor.
PRECAUTIONS FOR HANDLING AND STORING: Contents of can under pressure. Do not store
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near areas that may exceed 120 F. Avoid inhalation of vapors and excessive or repeated skin
contact.
SECTION VIII - CONTROL MEASURES
VENTILATION REQUIREMENT: Local or mechanical explosion-proof.
RESPIRATORY PROTECTION: If exposure exceeds, or there is a possibility that it may exceed
OSHA exposure limits use NIOSH-approved respirators. At extreme exposure levels, use self-
contained breathing apparatus.
PROTECTIVE GLOVES: Chemically impervious.
EYE PROTECTION: Goggles.
OTHER PROTECTIVE EQUIPMENT: Chemical impervious clothing to prevent skin contact.
SECTION IX - SPECIAL PRECAUTIONS
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: Do not handle or store near
heat, sparks, flame or strong oxidizers. Adequate ventilation required. Avoid breathing vapors;
avoid prolonged or repeated skin contact.
NOTE: FLAMMABLE LIQUID LABEL REQUIRED!
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SECTION X - REGULATORY INFORMATION
SARA (313) Chemicals:
This product contains toxic chemicals which are subject to the reporting requirements of Section
313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part
372.
Dichloromethane CAS # 75-09-2 55%
U.S. Department of Labor NFPA Rating:
Toxicity = 3 Reactivity = 0 FIRE = 3 Special = A
DATE OF ISSUE: February 18, 1998 SUPERSEDES: April 2, 1991
The information presented herein was prepared at TYCO ADHESIVES (R&D Laboratory, 17
Hartwell Avenue, Lexington, MA 02173, 781-861-3200 by qualified technical personnel, and to
our knowledge it is true and accurate. The information and recommendations are furnished for
this product with the understanding that the purchaser will independently determine the suitability
of the product for his purposes. The data do not constitute a warranty, expressed or implied,
statutory or otherwise, nor are they a representation for which TYCO ADHESIVES assumes legal
responsibility. The data are submitted for the user鈥檚 information and consideration only. Any use
of this product must be determined by the user to be in accordance with the applicable federal,
state and local laws and regulations.
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