CHEMTREC Transporation
Emergency Phone: 800-424-
9300
Material Safety Pittsburgh Poison Control
Center
Health Emergency No.: 412-
Data Sheet 681-6669
NOTE: The CHEMTREC Transportation
Emergency Phone is to be used only in the
event of chemical emergencies involving a
spill, leak, fire, exposure or accident involving
chemicals
Section 1 - Chemical Product / Company Information
A-788 SPLASH ZONE COMPOUND
Revision Date: 09/02/2005
Product Name:
PART B
Identification
PLMSDS 0969B5NL Supercedes : 09/02/2005
Number:
Epoxy Polyamide - FOR INDUSTRIAL
Product
USE ONLY
Use/Class:
Regulatory, Department
Preparer:
Manufacturer: Carboline Company
350 Hanley Industrial Ct.
St. Louis, MO 63144
Section 2 - Composition / Information On Ingredients
Chemical Name CAS Number Weight % Less Than ACGIH TLV-TWA ACGIH TLV-STEL OSHA PEL-TWA OSHA-CEIL
TALC 014807-96-6 40.0 N/E N/E N/E N/E
MICROCRYSTALLINE 014808-60-7 30.0 0.05 MG/M3 N/E 0.1 MG/M3 N/E
SILICA (respirable) (respirable)
TRIS-2,4,6- 90-72-2 5.0 NE N/E NE NE
(DIMETHYLAMINOMETHYL)
PHENOL
TRIETHYLENETETRAMINE 112-24-3 5.0 NE N/E NE NE
Section 3 - Hazards Identification
Emergency Overview: Contains SILICA which can cause cancer. Risk of Cancer depends on duration and level
of exposure.
Effects Of Overexposure - Eye Contact: Can cause eye burns.
Effects Of Overexposure - Skin Contact: Can cause skin burns. May be harmful if absorbed through the skin.
Can cause allergic skin reaction.
Effects Of Overexposure - Inhalation: May cause nose and throat irritation. May cause lung irritation. May
cause allergic respiratory reaction, effects may be permanent.
Effects Of Overexposure - Ingestion: May be harmful if swallowed.
Effects Of Overexposure - Chronic Hazards: Crystalline silica is known to cause silicosis, a noncancerous
lung disease. Exposure is by route of inhalation. If material is in a liquid matrix it is unlikely to be inhaled.
Primary Route(s) Of Entry: Skin Contact, Skin Absorption, Inhalation, Ingestion, Eye Contact
Medical Conditions Prone to Aggravation by Exposure: If sensitized to amines, epoxies, or other chemicals
do not use. See a physician if a medical condition exists.
Section 4 - First Aid Measures
First Aid - Eye Contact: If material gets into eyes, flush with water immediately for 15 minutes. Consult a
physician.
First Aid - Skin Contact: In case of contact, wash skin immediately with soap and water.
First Aid - Inhalation: If inhaled, remove to fresh air. Administer oxygen if necessary. Consult a physician if
symptoms persist or exposure was severe.
First Aid - Ingestion: If swallowed do not induce vomiting. Seek immediate medical attention.
Section 5 - Fire Fighting Measures
Flash Point, F: 201F (93C) Lower Explosive Limit, %: N/A
Upper Explosive Limit, %: N/A
(Setaflash)
Extinguishing Media: Carbon Dioxide, Dry Chemical, Foam, Water Fog
Unusual Fire And Explosion Hazards: This product contains less than 1% volatile components. The amount of
vapors that could accumulate are minimal. However, vapors are heavier than air and could travel long distances,
ignite, and flashback. Eliminate all ignition sources. Keep away from sparks, open flames, and heat sources. All
electrical equipment and installations should be made and grounded in accordance with the National Electrical
Code. In areas where explosion hazards exist, workers should be required to use nonferrous tools and to wear
conductive and non-sparking shoes.
Special Firefighting Procedures: Evacuate hazard area of unprotected personnel. Use a NIOSH approved self-
contained breathing unit and complete body protection. Cool surrounding containers with water in case of fire
exposure.
Section 6 - Accidental Release Measures
Steps To Be Taken If Material Is Released Or Spilled: Eliminate all ignition sources. Handling equipment must
be grounded to prevent sparking. Evacuate the area of unprotected personnel. Wear appropriate personal
protection clothing and equipment. Follow exposure controls/personal protection guidelines in Section 8. Contain
and soak up residual with an aborbent (clay or sand). Take up absorbant material and seal tightly for proper
disposal. Dispose of in accordance with local, state and federal regulations. Refer to Section 15 for SARA Title III
and CERCLA information. Use self-contained breathing apperatus and chemically protective clothing. Wear
suitable protective clothing, gloves and eye/face protection. Evacuate personnel to safe areas.
Section 7 - Handling And Storage
Handling: Do not get in eyes, on skin, or on clothing. Keep container tightly closed when not in use. Wear
personal protection equipment. Do not breathe vapors. Wash thoroughly after handling. If pouring or transferring
materials, ground all containers and tools. Do not weld, heat, cut or drill on full or empty containers. Use only in
accordance with Carboline application instructions, container label and Product Data Sheet. Avoid breathing
vapors or spray mist.
Storage: Keep away from heat, sparks, open flames and oxidizing agents. Keep containers closed. Store in a
cool, dry place with adequate ventilation.
Section 8 - Exposure Controls / Personal Protection
Engineering Controls: Use explosion-proof ventilation when required to keep below health exposure guidelines
and Lower Explosion Limit (LEL).
Respiratory Protection: Use only with ventilation to keep levels below exposure guidelines listed in Section 2.
User should test and monitor exposure levels to ensure all personnel are below guidelines. If not sure, or not able
to monitor, use MSHA/NISOH approved supplied air respirator. Follow all current OSHA requirements for
respirator use.
Skin Protection: Recommend impervious gloves and clothing to avoid skin contact. If material penetrates to skin,
change gloves and clothing. The use of protective creams may be beneficial to certain individuals. Protective
creams should be applied before exposure.
Eye Protection: Recommend safety glasses with side shields or chemical goggles to avoid eye contact.
Other protective equipment: Eye wash and safety showers should be readily available.
Hygienic Practices: Wash with soap and water before eating, drinking, smoking, applying cosmetics, or using
toilet facilities. Use of a hand cleaner is recommended. Launder contaminated clothing before reuse. Leather
shoes can absorb and allow hazardous materials to pass through. Check shoes carefully after soaking before
reuse.
Section 9 - Physical And Chemical Properties
N/A - N/A Heavier than Air
Boiling Range: Vapor Density:
Slight Amine N/D
Odor: Odor Threshold:
Viscous Liquid Slower Than Ether
Appearance: Evaporation Rate:
N/D
Solubility in H2O:
N/D 1.68
Freeze Point: Specific Gravity:
N/D N/D
Vapor Pressure: PH:
Liquid
Physical State:
(See section 16 for abbreviation legend)
Section 10 - Stability And Reactivity
Conditions To Avoid: Heat, sparks and open flames.
Incompatibility: Avoid contact with strong oxidizing agents.
Hazardous Decomposition Products: Carbon monoxide, nitrogen oxides, and unidentified organic compounds.
Consider all smoke and fumes from burning material as very hazardous. Welding, cutting or abrasive grinding can
create smoke and fumes. Do not breathe any fumes or smoke from these operations.
Hazardous Polymerization: Will not occur under normal conditions.
Stability: This product is stable under normal storage conditions.
Section 11 - Toxicological Information
Product LD50: N/D Product LC50: N/D
Chemical Name CAS Number LD50 LC50
TALC 014807-96-6 NOT AVAILABLE NOT AVAILABLE
MICROCRYSTALLINE SILICA 014808-60-7 NOT AVAILABLE NOT AVAILABLE
TRIS-2,4,6- (DIMETHYLAMINOMETHYL) 90-72-2 2169 MG/KG ORAL NOT AVAILABLE
PHENOL
TRIETHYLENETETRAMINE 112-24-3 2500MG/KG RAT,ORAL,805 MG/KG DERMAL NOT AVAILABLE
Section 12 - Ecological Information
Ecological Information: No data
Section 13 - Disposal Information
Disposal Information: Dispose of in accordance with State, Local, and Federal Environmental regulations.
Responsibility for proper waste disposal is with the owner of the waste.
Section 14 - Transportation Information
DOT Proper Shipping Name: Not Regulated Packing Group: N/A
N/A Hazard Subclass: N/A
DOT Technical Name:
None N/A
DOT Hazard Class: Resp. Guide
Page:
N/A
DOT UN/NA Number:
Section 15 - Regulatory Information
CERCLA - SARA HAZARD CATEGORY
This product has been reviewed according to the EPA Hazard Categories promulgated under Sections 311and
312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under
applicable definitions, to meet the following categories:
IMMEDIATE HEALTH HAZARD, CHRONIC HEALTH HAZARD
SARA SECTION 313
This product contains the following substances subject to the reporting requirements of Section 313 of Title III of
the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
No Section 313 Substances exist in this product
TOXIC SUBSTANCES CONTROL ACT
All components of this product are listed on the TSCA inventory.
This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if
exported from the United States:
No TSCA 12(B) Substances exist in this product
U.S. STATE REGULATIONS AS FOLLOWS:
NEW JERSEY RIGHT-TO-KNOW
The following materials are non-hazardous, but are among the top five components in this product.
Chemical Name CAS Number
TRADE SECRET TRADE SECRET
PENNSYLVANIA RIGHT-TO-KNOW
The following non-hazardous ingredients are present in the product at greater than 3%.
Chemical Name CAS Number
TRADE SECRET TRADE SECRET
CALIFORNIA PROPOSITION 65
Warning: The following ingredients present in the product are known to the state of California to cause
Cancer:
Chemical Name CAS Number
MICROCRYSTALLINE SILICA 014808-60-7
Warning: The following ingredients present in the product are known to the state of California to cause
birth defects, or other reproductive hazards:
No California Proposition 65 Reproductive Toxins exist
INTERNATIONAL REGULATIONS AS FOLLOWS:
CANADIAN WHMIS
This MSDS has been prepared in compliance with Controlled Product Regulations except for the use of the 16
headings.
CANADIAN WHMIS CLASS: D2A D2B
Section 16 - Other Information
HMIS Ratings
Health: 3 Flammability: 1 Reactivity: 0 Personal Protection: X
VOLATILE ORGANIC COMPOUNDS, GR/LTR MIXED (UNTHINNED): 0
REASON FOR REVISION: Changed to 16 Section Format.
Legend: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined
The information contained herein is, to the best of our knowledge and belief accurate. However, since the
conditions of handling and use are beyond our control, we make no guarantee of results, and assume no liability
for damages incurred by use of this material. It is the responsibility of the user to comply with all applicable
federal, state, and local laws and regulations
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