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MATERIAL SAFETY DATA SHEET
SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
COMPANY ADDRESS: EMERGENCY TELEPHONE NUMBERS:
Control Solutions, Inc. (800) 424-9300 (CHEMTREC, transportation and spills)
5903 Genoa-Red Bluff (800) 222-1222 (Poison Control Center)
Pasadena, TX 77507-1041
PRODUCT NAME : Martin鈥檚 Fly-Ban Synergized Pour-On
CHEMICAL FAMILY : Pyrethroid Insecticide
PRODUCT CODE : EPA Reg. No. 53883-74
SECTION 2 - COMPOSITION, INFORMATION OF INGREDIENTS
COMPONENT PERCENTAGE CAS NUMBER OSHA PEL ACIGH TLV
Permethrin 7.40 52645-53-1 Not Listed Not Listed
Piperonyl Butoxide 7.40 51-03-6 Not Listed Not Listed
Petroleum <75% 8052-41-3
distillate(contains
125 mg/M3 125 mg/M3
trimethyl benzene and
525 mg/M3 525 mg/M3
Stoddard Solvent)
SECTION 3 - HAZARDS IDENTIFICATION SUMMARY
(As defined by OSHA Hazard Communication Standard, 29 CFR 1910.1200)
EMERGENCY OVERVIEW: Opaque white liquid with slight odor.
- May be harmful if swallowed, inhaled or absorbed through skin.
- Avoid contact with eyes, skin or clothing.
- Keep out of reach of children.
POTENTIAL HEALTH HAZARDS:
EYE - Mildly irritating to the eyes. Degree of injury will depend on the amount
of material that gets into eye and the speed and thoroughness of the first aid
treatment.
SKIN - Prolonged or repeated skin contact may cause irritation. May cause skin
sensitization, an allergic reaction, which becomes evident on re-exposure to
this material.
INHALATION - May be irritating to respiratory tract.
INGESTATION - May be harmful if swallowed.
ENVIRONMENTAL HAZARDS: Highly toxic to fish, other water organisms and bees.
Keep out of waterways.
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SECTION 4 - FIRST AID MEASURES
FIRST AID
Have the product container or label with you when calling the poison control
center or doctor, or going for treatment.
If inhaled 鈥? Move person to fresh air.
鈥? If person is not breathing, call 911 or an
ambulance, then give artificial respiration,
preferably by mouth-to mouth, if possible.
鈥? Call a poison control center or doctor for
treatment advice.
If on skin 鈥? Take off contaminated clothing.
or 鈥? Rinse skin immediately with plenty of water for
clothing 15-20 minutes.
鈥? Call a poison control center or doctor for
treatment advice.
If in eyes 鈥? Hold eye open and rinse slowly and gently with
water for 15-20 minutes.
鈥? Remove contact lenses, if present, after the
first 5 minutes, then continue rinsing eye.
鈥? Call a poison control center or doctor for
treatment advice.
If 鈥? Immediately call a poison control center or
swallowed doctor.
鈥? Do not induce vomiting unless told to do so by
a poison control center or doctor.
鈥? Do not give any liquid to the person.
鈥? Do not give anything by mouth to an unconscious
person.
Note to Physician: This product may pose an aspiration
pneumonia hazard. Contains petroleum distillate.
Emergency Phone Numbers:
! Transportation or spill, call CHEMTREC 800-424-9300
! Human health, call Poison Control Center at 800-222-1222
SECTION 5 - FIRE FIGHTING MEASURES
FLASHPOINT (method): 185掳 F
FLAMMABLE LIMITS (LFL-UFL): Unknown.
FIRE AND EXPLOSION HAZARD: May release irritating and toxic gases due to thermal
decomposition or combustion.
EXTINGUISHING MEDIA: Use foam, dry chemical, carbon dioxide, or water spray when
fighting fires involving this material.
FIRE FIGHTING INSTRUCTIONS: Evacuate area and fight fire upwind from a safe
distance to avoid hazardous vapors and decomposition products. Dike and collect
water used to fight fire to prevent environmental damage due to run off. Foam
or dry chemical fire extinguishing systems are preferred to prevent
environmental damage from excessive water run off.
FIRE FIGHTING EQUIPMENT: Full fire fighting turn-out gear (Bunker gear).
HAZARDOUS COMBUSTION PRODUCTS: Oxides of hydrogen and carbon.
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SECTION 6 - ACCIDENTAL RELEASE MEASURES
Clean up spills immediately, observing precautions in Section 8 of this
document.
SMALL SPILL: Absorb small spills on paper towels or other inert absorbent.
Place contaminated material in trash for disposal.
LARGE SPILL: Dike large spills using absorbent or impervious material such as
clay or sand. Recover and contain as much free liquid as possible for reuse.
Allow absorbed material to solidify, and scrape up for disposal. After removal,
flush contaminated area thoroughly with water. This material is a water
pollutant and should be prevented from contaminating soil or from entering
sewage and drainage systems and bodies of water.
SECTION 7 - HANDLING AND STORAGE
KEEP OUT OF REACH OF CHILDREN!
HANDLING: Use only in a well-ventilated area.
STORAGE: Keep container closed when not in use. Keep away from food, feed and
drinking water. Store in a cool dry area away from heat or open flame. Store
above 32 degrees Fahrenheit.
SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
EXPOSURE LIMITS (8 HOUR TWA): (Refer to Section 3)
ENGINEERING CONTROLS: Proper ventilation is required when handling or using this
product. Facilities storing or utilizing this material should be equipped with
an eyewash facility and a safety shower.
PERSONAL PROTECTIVE EQUIPMENT:
EYE PROTECTION - Safety glasses
CLOTHING - Long-sleeved shirt and long pants, Shoes plus socks
GLOVES - Waterproof gloves
USER SAFETY RECOMMENDATIONS:
1. Wash hands before eating, drinking, chewing gum, using tobacco or using the
toilet.
2. Remove clothing immediately if pesticide gets inside. Then wash thoroughly
and put on clean clothing.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL DESCRIPTION: Pale amber liquid.
ODOR: Slight aromatic.
DENSITY: 0.86(7.2lb/gl)
pH: 4.5 - 5.0
% VOLATILE: Unknown.
WATER SOLUBILITY: Miscible.
SECTION 10 - STABILITY AND REACTIVITY
CHEMICAL STABILITY: Stable, however may decompose if heated.
CONDITIONS TO AVOID: Avoid temperatures above 150掳F.
INCOMPATIBILITY WITH OTHER MATERIALS: Alkaline and acidic conditions and
materials,
Oxidizing materials.
HAZARDOUS DECOMPOSITION PRODUCTS: Oxides of hydrogen and carbon.
HAZARDOUS POLYMERIZATION: Product will not undergo polymerization.
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SECTION 11 - TOXICOLOGICAL INFORMATION
ACUTE TOXICITY:
Oral LD50 (rat) - > 5,000 mg/Kg
Dermal LD50 (rat) - > 2,000 mg/Kg
Inhalation LC50 (rat) - > 4.0 mg/L
Eye Irritation (rabbit) - moderate
Skin Irritation (rabbit) - slight
Sensitization (guinea pig) - potential
CARCINOGEN STATUS:
OSHA - Not listed.
NTP - Not listed.
IARC - Not listed.
SECTION 12 - ECOLOGICAL INFORMATION
ENVIRONMENTAL SUMMARY: This product is extremely toxic to fish. Do not
apply directly to water. Do not contaminate water when disposing of
wastes.
BEE TOXICITY: Highly toxic.
SECTION 13 - DISPOSAL CONSIDERATIONS
Do not contaminate water, food or feed by storage or disposal.
WASTE: Pesticide wastes are toxic. Dispose of in accordance with applicable
Federal, state and local laws and regulations.
CONTAINER: Do not reuse container. Wrap container in several layers of
newspaper and discard in trash.
SECTION 14 - TRANSPORT INFORMATION
DOT SHIPPING DESCRIPTION:
DOT HAZARD CLASS:
UN NUMBER:
DOT PACKING GROUP:
DOT PRIMARY/SECONDARY LABEL:
DOT PRIMARY/SECONDARY PLACARD:
DOT EMERGENCY RESPONSE GUIDE #:
SECTION 15 - REGULATORY INFORMATION
FIFRA: All pesticides are governed under the Federal Insecticide, Fungicide,
and Rodenticide Act. The regulatory information presented below is pertinent
only when this product is handled outside of the normal use and application as a
pesticide.
OSHA HAZARD COMMUNICATION STANDARD STATUS:
CERCLA REPORTABLE QUANTITY:
SARA TITLE III STATUS:
302 Extremely Hazardous Substance -
311/312 Hazard Categories -
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313 Toxic Chemicals -
CALIFORNIA PROP 65 STATUS:
SECTION 16 - OTHER INFORMATION
DISCLAIMER: The information presented herein is based on available data from
reliable sources and is correct to the best of Control Solutions, Inc.'s
knowledge. Control Solutions, Inc. makes no warranty, express or implied,
regarding the accuracy of the data or the results obtained from the use of this
product. Nothing herein may be construed as recommending any practice or any
product in violation of any law or regulations. The user is solely responsible
for determining the suitability of any material or product for a specific
purpose and for adopting any appropriate safety precautions. We disclaim all
liability for injury or damage stemming from any improper use of the material or
product described herein.
REVISED DATE: 12-13-04
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