Control Solutions, Inc. "For Chemical Emergency"
Spill, Leak, Fire, Exposure or Accident, Call:
5903 Genoa-Red Bluff, Pasadena, TX 77507-1041
Chemtrec (24 Hours): (800) 424-9300
(281) 892-2500
For Medical Emergency: Call SafetyCall Int鈥檒 (866) 897-8050
MATERIAL SAFETY DATA SHEET
SECTION 1 - PRODUCT IDENTIFICATION
PRODUCT NAME: CHEMICAL NAME (FORMULA):
Martin鈥檚 Clear Pasture (3,5,6 Trichloro-2-Pyridinyl)oxyacetic acid, butoxyethyl ester
CHEMICAL CLASS:
SECTION 2 - HAZARDOUS INGREDIENT INFORMATION
Section 313 of Sara Title III: Ingredients subject to reporting are identified by asterisk (*)
CAS NO. COMPONENT % ACGIH TLV OSHA PEL TWA
064700-56-7 Triclopyr BEE: (3,5,6 Trichloro-2- 61.6% N/D N/D N/D
Pyridinyl)oxyacetic acid, butoxyethyl ester
SECTION 3 - PHYSICAL PROPERTIES
BOILING POINT: MELTING POINT: SPECIFIC GRAVITY: VAPOR PRESSURE:
N/D N/A 1.1 0.1 mm @ 37.8掳C (kerosene)
VAPOR DENSITY (AIR=1): % SOLUBILITY IN WATER: % VOLATILE BY WEIGHT:
>1 Emulsifies N/D
APPEARANCE: ODOR: pH:
Amber liquid Kerosene-like 3.7
SECTION 4 - FIRE AND EXPLOSION HAZARD DATA
FLASH POINT & METHOD: FLAMMABLE LIMITS IN AIR (LFL - UFL):
84.5掳C (TCC) Lower: N/D Upper: N/D
EXTINGUISHING MEDIA:
Water fog, foam, CO2, or dry chemical extinguishing media.
SPECIAL FIRE FIGHTING PROCEDURES:
Firefighters should be equipped with a positive pressure self-contained breathing apparatus and full protective clothing.
UNUSUAL FIRE AND EXPLOSION HAZARDS:
Combustible. Toxic, irritating vapors may be produced if product is involved in fire.
SECTION 5 - REACTIVITY DATA
Stable under normal storage conditions. Combustible.
STABILITY:
Does not occur.
HAZARDOUS POLYMERIZATION:
Nitrogen oxides, hydrogen chloride and phosgene may result under fire conditions.
HAZARDOUS DECOMPOSITION PRODUCTS:
CONDITIONS & MATERIALS TO AVOID: Avoid sources of ignition if temperature is near or above flash point. Avoid acid, base, and
oxidizing material.
SECTION 6 - PROTECTIVE EQUIPMENT & EXPOSURE CONTROL METHODS
RESPIRATORY PROTECTION:
Supplied-air respirators should be worn if large quantities of mist/dust are generated or prolonged exposure possible.
LOCAL EXHAUST: MECHANICAL: SPECIAL: OTHER:
VENTILATION Adequate Acceptable None None
PROTECTIVE GLOVES AND BOOTS: EYE PROTECTION:
Chemical resistant gloves such as barrier laminate, nitrile Chemical goggles recommended.
rubber, neoprene rubber, or viton. Shoes plus socks.
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PRODUCT NAME: Martin鈥檚 Clear Pasture
OTHER PROTECTIVE CLOTHING OR EQUIPMENT: WORK/HYGIENIC PRACTICES:
Long sleeved shirt and long pants. Wash thoroughly with soap and water after handling and
Also recommended are coveralls and chemical resistant before eating, drinking, chewing gum, using tobacco or using
footwear plus socks. the toilet. Remove and wash contaminated clothing and wash
before reuse. Remove PPE immediately after handling this
product. Wash the outside of gloves before removing. If
pesticide gets inside remove immediately; thoroughly wash
and put on clean clothing.
Follow manufacturer鈥檚 instructions for cleaning maintaining
PPE. If no such instructions for washables, use detergent and
hot water. Keep and wash PPE separately from other
laundry.
SECTION 7 - HEALTH HAZARDS
PRIMARY ROUTES OF ENTRY:
Skin, ingestion, and inhalation.
CARCINOGEN: NTP: MUTAGENICITY: TERATOLOGY (BIRTH DEFECTS):
Not listed. Not listed. N/A N/A
SKIN CONTACT:
Harmful if absorbed through skin. Avoid contact with skin and clothing. Prolonged or repeated contact may cause skin
irritation.
INGESTION:
Harmful if swallowed. Low toxicity if swallowed. Small amounts swallowed during normal handling operations are not likely
to cause injury. Larger amounts may cause injury. Aspiration into the lungs may occur during ingestion or vomiting causing
lung damage or even death due to pneumonia.
INHALATION:
Harmful if inhaled. Avoid breathing vapor or spray mist. Excessive exposure may cause irritation to upper respiratory tract
(nose and throat).
EYE CONTACT:
Avoid contact with eyes. Causes moderate eye irritation.
ALLERGIC SKIN REACTIONS (Dilute Mix):
Prolonged or frequently repeated skin contact may cause allergic skin reaction in some individuals.
SECTION 8 - EMERGENCY & FIRST AID PROCEDURES
SKIN CONTACT:
Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Call a poison control center or
doctor for treatment advice.
INGESTION:
Immediately call a poison control center or doctor. DO NOT induce vomiting un less told to by a poison control center or
doctor. DO NOT give any liquid to the person. DO NOT give anything to an unconscious person.
INHALATION:
Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably by
mouth-to-mouth, if possible. Call a poison control center or doctor for further treatment advice.
EYE CONTACT:
Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after first 5
minutes, then continue rinsing eye. Call a poison control center or doctor for treatment advice.
NOTES TO PHYSICIAN:
Contains petroleum distillate 鈥? vomiting may cause aspiration pneumonia.
SECTION 9 - SPILL, LEAK & DISPOSAL INFORMATION
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED:
In case of large scale spill, avoid contact, isolate area and keep out animals and unprotected persons. Call CHEMTREC (800
424-9300). In case of small spill, wear personal protective equipment as specified on the label.
WASTE DISPOSAL METHOD:
Wastes resulting from the use of this product (that cannot be used according to label instructions) may be disposed of on site or
at an approved waste disposal facility. If these wastes cannot be disposed to label instructions, contact the state agency
responsible for pesticide regulation to the Hazardous Waste representative at the nearest EPA Regional Office for guidance.
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PRODUCT NAME: Martin鈥檚 Clear Pasture
SECTION 10 鈥? ECOLOGICAL INFORMATION
SUMMARY OF EFFECTS:
This pesticide is toxic to fish. Do not apply directly to water, to areas where surface water is present, or to intertidal areas
below the mean high water mark. Do not contaminate water when cleaning equipment or disposing of equipment washwaters.
FISH TOXICITY (Technical):
96 hour LC50, Rainbow Trout NA
INVERTEBRATE (Technical):
48 hour LC50, Daphnia magna NA
MOVEMENT & PARTITIONING: Log Pow is 4.09
Log octanol/water partition coefficient.
This chemical has properties and characteristics associated
with chemicals detected in groundwater. The use of this
chemical in areas where soils are permeable, particularly
where the water table is shallow, may result in groundwater
contamination.
SECTION 11 - SHIPPING DATA
DOT PROPER SHIPPING NAME:
Non-Bulk packages shipped by Air, Land, or Water:
Not Regulated
Bulk packages shipped by Land:
COMBUSTIBLE LIQUID, N.O. S. (contains KEROSENE)/COMBUSTIBLE LIQUID/NA 1993/PGIII
NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) RATINGS:
Health 2
Flammability 2
Reactivity 0
Additional Labeling: None
SECTION 12 - SPECIAL INSTRUCTIONS
SPECIAL INSTRUCTIONS:
Avoid contamination of food. Store above 28掳F.
SECTION 13 - OTHER INFORMATION/PRECAUTIONS
TSCA STATUS:
N/A
SARA TITLE 3: SECTION 311/312 CATEGORIZATIONS (40CFR 370):
An immediate health hazard
A delayed health hazard
A fire hazard
SARA TITLE 3: SECTION 313 INFORMATION (40CFR 372):
N/A
CALIFORNIA PROPOSITION 65:
N/A
CERCLA REPORTABLE QUANTITY:
N/A
COMMON ABBREVIATIONS THAT MAY HAVE BEEN USED: N/A = NOT APPLICABLE N/D = NOT DETERMINED NA = NOT AVAILABLE
The information provided on this Material Safety Data Sheet is furnished without warranty, expressed or implied, except that
it is accurate to the best knowledge of Control Solutions, Inc. The data on this sheet relates only to the specific material
designated herein. Control Solutions, Inc. assumes no legal responsibility for the accuracy or completeness of this data, nor for
use or reliance upon this data.
DATE: 072606
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