Material Safety Data Sheet
MSDS ID NO.: 0279MAR019
Revision date: 02/09/2007
1. CHEMICAL PRODUCT AND COMPANY INFORMATION
Product name: Marathon No. 2 Low Sulfur Diesel Dyed 500 ppm Sulfur Max
Synonym: Diesel No. 2 Dyed 500 ppm Sulfur Max; No. 2 Diesel, Non-Road Use, Dyed; No. 2
Diesel Dyed 500 ppm Sulfur Max; No. 2 NR 500 Diesel Dyed; No. 2 Diesel Dyed
(0.05% Sulfur Max)
Chemical Family: Petroleum Hydrocarbon
Formula: Mixture
Manufacturer:
Marathon Petroleum Company LLC
539 South Main Street
Findlay OH 45840
Other information: 419-421-3070
Emergency telephone number: 877-627-5463
2. COMPOSITION/INFORMATION ON INGREDIENTS
No. 2 Diesel is a complex mixture of parafffins, cycloparaffins, olefins, and aromatic hydrocarbons having hydrocarbon
chain lengths predominately in the range of C11 through C20. May contain a trace amount of benzene (<0.01%). Can
contain small amounts of red dye and additives (<0.15%) which are not considered hazardous at the concentrations used.
Product information:
Name CAS Number Weight % ACGIH Exposure OSHA - Vacated Other:
Limits: PELs - Time
Weighted Ave
Marathon No. 2 Diesel 68476-30-2 100 Skin - potential
significant contribution
to overall exposure by
the cutaneous route
= 100 mg/m3 TWA
Component Information:
Name CAS Number Weight % ACGIH Exposure OSHA - Vacated Other:
Limits: PELs - Time
Weighted Ave
Saturated Hydrocarbons Mixture 54-85
Aromatic Hydrocarbons Mixture 15-45
Unsaturated Hydrocarbons Mixture 1-6
Naphthalene 91-20-3 0.01-0.5 Skin - potential = 10 ppm TWA
= 50 mg/m3 TWA
significant contribution
to overall exposure by = 15 ppm STEL
= 75 mg/m3 STEL
the cutaneous route
= 10 ppm TWA
= 15 ppm STEL
Notes: The manufacturer has voluntarily elected to reflect exposure limits contained in
OSHA's 1989 air contaminants standard in its MSDS's, even though certain of those
exposure limits were vacated in 1992.
MSDS ID NO.: 0279MAR019 Product name: Marathon No. 2 Low Sulfur Diesel Page 1 of 10
Dyed 500 ppm Sulfur Max
3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
NO. 2 DIESEL IS A RED COLORED LIQUID. THIS PRODUCT IS CONSIDERED TO BE A COMBUSTIBLE LIQUID PER
THE OSHA HAZARD COMMUNICATION STANDARD AND SHOULD BE KEPT AWAY FROM HEAT, FLAME AND
SOURCES OF IGNITION. NEVER SIPHON THIS PRODUCT BY MOUTH. IF SWALLOWED, THIS PRODUCT MAY
GET SUCKED INTO THE LUNGS (ASPIRATED) AND CAUSE LUNG DAMAGE OR EVEN DEATH. PROLONGED OR
REPEATED SKIN CONTACT CAN CAUSE DEFATTING AND DRYING OF THE SKIN WHICH MAY PRODUCE
SEVERE IRRITATION OR DERMATITIS.
OSHA WARNING LABEL:
WARNING.
COMBUSTIBLE LIQUID.
ASPIRATION (INADVERTENT SUCTION) OF LIQUID INTO THE LUNGS CAN PRODUCE CHEMICAL PNEUMONIA
OR EVEN DEATH.
PRODUCES SKIN IRRITATION UPON PROLONGED OR REPEATED CONTACT.
CONSUMER WARNING LABEL:
A CONSUMER WARNING LABEL IS NOT APPLICABLE FOR THIS PRODUCT.
Inhalation: Exposure to high vapor concentrations may produce headache, giddiness, vertigo,
and anesthetic stupor.
Ingestion: Ingestion may result in nausea, vomiting, diarrhea and restlessness. Aspiration
(inadvertent suction) of liquid into the lungs must be avoided as even small quantities
in the lungs can produce chemical pneumonitis, pulmonary edema/hemorrhage and
even death.
Skin contact: Prolonged and repeated liquid contact can cause defatting and drying of the skin and
can lead to irritation and/or dermatitis.
Eye contact: Produces little or no irritation on direct contact with the eye.
Carcinogenic Evaluation:
Product information:
Name IARC NTP ACGIH - OSHA - Select
Carcinogens: Carcinogens: Carcinogens: Carcinogens:
Marathon No. 2 Diesel NE A3 - Confirmed animal
68476-30-2 carcinogen with unknown
relevance to humans (as
total hydrocarbons)
Notes: The International Agency for Research on Cancer (IARC) has determined that there
is inadequate evidence for the carcinogenicity of diesel fuel/fuel oil in humans. IARC
determined that there was limited evidence for the carcinogenicity of marine diesel
fuel in animals. Distillate (light) diesel fuels were not classifiable as to their
carcinogenicity to humans (Group 3A).
IARC has determined that there is sufficient evidence for the carcinogenicity in
experimental animals of diesel engine exhaust and extracts of diesel engine exhaust
particles. IARC determined that there is only limited evidence for the carcinogenicity
in humans of diesel engine exhaust. However, IARC's overall evaluation has resulted
in the IARC designation of diesel engine exhaust as probably carcinogenic to
humans (Group 2A) because of the presence of certain engine exhaust components.
Component Information:
MSDS ID NO.: 0279MAR019 Product name: Marathon No. 2 Low Sulfur Diesel Page 2 of 10
Dyed 500 ppm Sulfur Max
Name IARC NTP ACGIH - OSHA - Select
Carcinogens: Carcinogens: Carcinogens: Carcinogens:
Naphthalene Monograph 82, 2002 Reasonably Anticipated To A4 - Not Classifiable as a Present
91-20-3 Be A Carcinogen Human Carcinogen
Listed
Notes: The International Agency for Research on Cancer (IARC) and the Environmental
Protection Agency (EPA) have determined that naphthalene could be a possible
human carcinogen.
4. FIRST AID MEASURES
Inhalation: If affected, move person to fresh air. If breathing is difficult, administer oxygen. If not
breathing or if no heartbeat, give artificial respiration or cardiopulmonary
resuscitation (CPR). Immediately call a physician. If symptoms or irritation occur with
any exposure, call a physician.
Skin contact: Wash with soap and large amounts of water. Remove contaminated clothing. If
symptoms or irritation occur, call a physician.
Ingestion: If swallowed, do not induce vomiting and do not give liquids. Immediately call a
physician.
Eye contact: Flush eyes with large amounts of tepid water for at least 15 minutes. If symptoms or
irritation occur, call a physician.
Medical conditions aggravated Pre-existing skin conditions and respiratory disorders may be aggravated by
by exposure: exposures to components of this product.
5. FIRE FIGHTING MEASURES
Suitable extinguishing media: For small fires, Class B fire extinguishing media such as
CO2, dry chemical, foam (AFFF/ATC) or water spray can be
used. For large fires, water spray, fog or foam (AFFT/ATC)
can be used. Fire fighting should be attempted only by those
who are adequately trained and equipped with proper
protective equipment.
Specific hazards: This product has been determined to be a combustible liquid
per the OSHA Hazard Communication Standard and should
be handled accordingly. For additional fire related
information, see NFPA 30 or the North American Emergency
Response Guide 128.
Special protective equipment for firefighters: Avoid using straight water streams. Water spray and foam
(AFFF/ATC) must be applied carefully to avoid frothing and
from as far a distance as possible. Avoid excessive water
spray application. Keep surrounding area cool with water
spray from a distance and prevent further ignition of
combustible material. Keep run-off water out of sewers and
water sources.
Flash point: 130-190 F
Autoignition temperature: 637 F
Flammable limits in air - lower (%): 0.7
Flammable limits in air - upper (%): 5.0
NFPA rating: HMIS classification:
Health: 1 Health: 1
Flammability: 2 Flammability: 2
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Dyed 500 ppm Sulfur Max
Reactivity: 1 Reactivity: 1
Other: - Special: *See Section 8 for guidance in selection of
personal protective equipment.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions: Keep public away. Isolate and evacuate area. Shut off source if safe to do so.
Eliminate all ignition sources. Advise authorities and National Response Center (800-
424-8802) if substance has entered a watercourse or sewer. Notify local health and
pollution control agencies, if appropriate. Contain liquid with sand or soil. Recover
and return free product to proper containers. Use suitable absorbent materials such
as vermiculite, sand, or clay to clean up residual liquids.
7. HANDLING AND STORAGE
Handling:
Comply with all applicable EPA, OSHA, NFPA and consistent state and local requirements. Use appropriate grounding
and bonding practices. Store in properly closed containers that are appropriately labeled and in a cool well-ventilated
area. Do not expose to heat, open flames, strong oxidizers or other sources of ignition. Do not cut, drill, grind or weld on
empty containers since they may contain explosive residues.
Avoid repeated and prolonged skin contact. Never siphon this product by mouth. Exercise good personal hygiene
including removal of soiled clothing and prompt washing with soap and water.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
PERSONAL PROTECTIVE EQUIPMENT
Engineering measures: Local or general exhaust required when using at elevated temperatures that
generate vapors or mists.
Respiratory protection: Use approved organic vapor chemical cartridge or supplied air respirators when
material produces vapors that exceed permissible limits or excessive vapors are
generated. Observe respirator protection factor criteria cited in ANSI Z88.2. Self-
contained breathing apparatus should be used for fire fighting.
Skin and body protection: Neoprene, nitrile, polyvinyl alcohol (PVA), polyvinyl chloride and polyurethane gloves
to prevent skin contact.
Eye protection: No special eye protection is normally required. Where splashing is possible, wear
safety glasses with side shields.
Hygiene measures: No special protective clothing is normally required. Select protective clothing
depending on industrial operations. Use mechanical ventilation equipment that is
explosion-proof.
9. PHYSICAL AND CHEMICAL PROPERTIES:
Appearance: Red Liquid
Physical state (Solid/Liquid/Gas): Liquid
Substance type (Pure/Mixture): Mixture
Color: Red
Odor: Slight Hydrocarbon
Molecular weight: 180
pH: Neutral
Boiling point/range (5-95%): 400-640 F
Melting point/range: Not determined.
MSDS ID NO.: 0279MAR019 Product name: Marathon No. 2 Low Sulfur Diesel Page 4 of 10
Dyed 500 ppm Sulfur Max
Decomposition temperature: Not applicable.
Specific gravity: C.A. 0.8
Density: 6.76 lbs/gal
Bulk density: No data available.
Vapor density: 4-5
Vapor pressure: 1-10 mm Hg @ 100 F
Evaporation rate: No data available.
Solubility: Negligible
Solubility in other solvents: No data available.
Partition coefficient (n-octanol/water): No data available.
VOC content(%): 10%
Viscosity: 1.9-3.4 @ 40 C
10. STABILITY AND REACTIVITY
Stability: The material is stable at 70 F, 760 mm pressure.
Polymerization: Will not occur.
Hazardous decomposition products: Combustion produces carbon monoxide, aldehydes,
aromatic and other hydrocarbons.
Materials to avoid: Strong oxidizers such as nitrates, perchlorates, chlorine,
fluorine.
Conditions to avoid: Excessive heat, sources of ignition and open flames.
11. TOXICOLOGICAL INFORMATION
Acute toxicity:
Product information:
Name CAS Number Inhalation: Dermal: Oral:
Marathon No. 2 Diesel 68476-30-2 No data available No data available No data available
MSDS ID NO.: 0279MAR019 Product name: Marathon No. 2 Low Sulfur Diesel Page 5 of 10
Dyed 500 ppm Sulfur Max
Lifetime skin painting studies in animals with similar distillate fuels have produced weak to moderate carcinogenic activity
following prolonged and repeated exposure. Similar middle distillates, when tested at nonirritating dose levels, did not
show any significant carcinogenic activity indicating that this tumorigenic response is likely related to chronic irritation and
not to dose. Repeated dermal application has produced severe irritation and systemic toxicity in subacute toxicity studies.
Some components of this product, have been shown to produce a species specific, sex hormonal dependent kidney
lesion in male rats from repeated oral or inhalation exposure. Subsequent research has shown that the kidney damage
develops via the formation of a alpha-2碌-globulin, a mechanism unique to the male rat. Humans do not form alpha-2碌-
globulin, therefore, the kidney effects resulting from this mechanism are not relevant in humans. Some components of
this product were found to be positive in a few mutagenicity tests while negative in the majority of others. The exact
relationship between these results and human health is not known.
Summary of health effect data on distillate fuel components:
This product may contain >0.1% naphthalene. Exposure to naphthalene at 30 ppm for two years caused lung tumors in
female mice. Male mice with the same exposure did not develop tumors. Exposure to 10-60 ppm naphthalene for 2 years
caused tumors in the tissue lining of the nose and respiratory tract in male and female rats. Oral administration of 133-
267 mg/kg/day of naphthalene in mice for up to 90 days did not produce mortality, systemic toxicity, adversely affect
organ or body weight or produce changes in blood. Repeated oral administration of naphthalene produced an anemia in
dogs. Repeated intraperitoneal doses of naphthalene produced lung damage in mice. Repeated high doses of
naphthalene has caused the formation of cataracts and retinotoxicity in the eyes of rats and rabbits due to accumulation
of 1,2-naphthoquinone, a toxic metabolite. Effects in human eyes is uncertain and not well documented. Pregnant rats
administered intraperitoneal doses of naphthalene during gestation gave birth to offspring that had delayed heart and
bone development. Pregnant mice given near lethal doses of naphthalene showed no significant maternal toxicity and a
reduction in the number of pups per litter, but no gross abnormalities in offspring. Suppressed spermatogenesis and
progeny development have been reported in mice, rats and guinea pigs after exposure to high concentrations of
naphthalene in their drinking water. Certain groups or individuals, i.e., infants, Semites, Arabs, Asians and Blacks, with a
certain blood enzyme deficiency (glucose-6-phosphate dehydrogenase) are particularly susceptible to hemolytic agents
and can rapidly develop hemolytic anemia and systemic poisoning from ingestion or inhalation of naphthalene.
Summary of health effect information on diesel engine exhaust:
Chronic inhalation studies of whole diesel engine exhaust in mice and rats produced a significant increase in lung tumors.
Combustion of kerosine and/or diesel fuels produces gases and particulates which include carbon monoxide, carbon
dioxide, oxides of nitrogen and/or sulfur and hydrocarbons. Significant exposure to carbon monoxide vapors decreases
the oxygen carrying capacity of the blood and may cause tissue hypoxia via formation of carboxyhemoglobin.
12. ECOLOGICAL INFORMATION
Ecotoxicity effects: Product can cause fouling of shoreline and may be harmful to aquatic life in low
concentrations. The 96 hour LL50 values for an accomadated fraction (WAF) of fuel
oil ranged from 3.2 to 65 mg/l in fish and 2-210 mg/l in invertebrates. EL50 values for
inhibition of algal growth ranged from 1.8 to 2.9 mg/l for No. 2 fuel oil and from 10 to
78 mg/l for diesel fuel. This product does not concentrate or accumulate in the food
chain. If released to soil and water, this product is expected to biodegrade under
both aerobic and anaerobic conditions.
13. DISPOSAL CONSIDERATIONS
Cleanup Considerations: This product as produced is not specifically listed as an EPA
RCRA hazardous waste according to federal regulations (40
CFR 261). However, when discarded or disposed of, it may
meet the criteria of an "characteristic" hazardous waste. This
material could become a hazardous waste if mixed or
contaminated with a hazardous waste or other substance(s).
It is the responsibility of the user to determine if disposal
material is hazardous according to federal, state and local
regulations.
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Dyed 500 ppm Sulfur Max
14. TRANSPORT INFORMATION
49 CFR 172.101:
DOT:
Transport Information: This material when transported via US commerce would be regulated by DOT
Regulations.
Proper shipping name: Fuel Oil, No. 2
UN/Identification No: NA 1993
Hazard Class: 3
Packing group: III
DOT reportable quantity (lbs): Not applicable.
TDG (Canada):
Proper shipping name: Fuel Oil, No. 2
UN/Identification No: NA 1993
Hazard Class: 3
Packing group: III
Regulated substances: Not applicable.
15. REGULATORY INFORMATION
Federal Regulatory Information:
US TSCA Chemical Inventory Section 8(b): This product and/or its components are listed on the TSCA
Chemical Inventory.
OSHA Hazard Communication Standard: This product has been evaluated and determined to be
hazardous as defined in OSHA's Hazard Communication
Standard.
EPA Superfund Amendment & Reauthorization Act (SARA):
SARA Section 302: This product contains the following component(s) that have been listed on EPA's
Extremely Hazardous Substance (EHS) List:
Name CERCLA/SARA - Section 302 Extremely Hazardous Substances and TPQs
Saturated Hydrocarbons NA
Aromatic Hydrocarbons NA
Unsaturated Hydrocarbons NA
Naphthalene NA
SARA Section 304: This product contains the following component(s) identified either as an EHS or a
CERCLA Hazardous substance which in case of a spill or release may be subject to
SARA reporting requirements:
Name CERCLA/SARA - Hazardous Substances and their Reportable Quantities
Saturated Hydrocarbons NA
Aromatic Hydrocarbons NA
Unsaturated Hydrocarbons NA
Naphthalene = 0.454 kg final RQ
= 1 lb final RQ
= 100 lb final RQ
= 45.4 kg final RQ
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SARA Section 311/312: The following EPA hazard categories apply to this product:
Acute Health Hazard
Fire Hazard
Chronic Health Hazard
SARA Section 313: This product contains the following component(s) that may be subject to reporting on
the Toxic Release Inventory (TRI) From R:
Name CERCLA/SARA 313 Emission reporting:
Saturated Hydrocarbons None
Aromatic Hydrocarbons None
Unsaturated Hydrocarbons None
Naphthalene = 0.1 % de minimis concentration
State and Community Right-To-Know Regulations:
The following component(s) of this material are identified on the regulatory lists below:
Saturated Hydrocarbons
Louisiana Right-To-Know: Not Listed
California Proposition 65: Not Listed
New Jersey Right-To-Know: Not Listed.
Pennsylvania Right-To-Know: Not Listed.
Massachusetts Right-To Know: Not Listed.
Florida substance List: Not Listed.
Rhode Island Right-To-Know: Not Listed
Michigan critical materials register list: Not Listed.
Massachusetts Extraordinarily Hazardous Not Listed
Substances:
California - Regulated Carcinogens: Not Listed
Pennsylvania RTK - Special Hazardous Not Listed
Substances:
New Jersey - Special Hazardous Substances: Not Listed
New Jersey - Environmental Hazardous Not Listed
Substances List:
Illinois - Toxic Air Contaminants Not Listed
New York - Reporting of Releases Part 597 - Not Listed
List of Hazardous Substances:
Aromatic Hydrocarbons
Louisiana Right-To-Know: Not Listed
California Proposition 65: Not Listed
New Jersey Right-To-Know: Not Listed.
Pennsylvania Right-To-Know: Not Listed.
Massachusetts Right-To Know: Not Listed.
Florida substance List: Not Listed.
Rhode Island Right-To-Know: Not Listed
Michigan critical materials register list: Not Listed.
Massachusetts Extraordinarily Hazardous Not Listed
Substances:
California - Regulated Carcinogens: Not Listed
Pennsylvania RTK - Special Hazardous Not Listed
Substances:
New Jersey - Special Hazardous Substances: Not Listed
New Jersey - Environmental Hazardous Not Listed
Substances List:
Illinois - Toxic Air Contaminants Not Listed
New York - Reporting of Releases Part 597 - Not Listed
List of Hazardous Substances:
Unsaturated Hydrocarbons
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Dyed 500 ppm Sulfur Max
Louisiana Right-To-Know: Not Listed
California Proposition 65: Not Listed
New Jersey Right-To-Know: Not Listed.
Pennsylvania Right-To-Know: Not Listed.
Massachusetts Right-To Know: Not Listed.
Florida substance List: Not Listed.
Rhode Island Right-To-Know: Not Listed
Michigan critical materials register list: Not Listed.
Massachusetts Extraordinarily Hazardous Not Listed
Substances:
California - Regulated Carcinogens: Not Listed
Pennsylvania RTK - Special Hazardous Not Listed
Substances:
New Jersey - Special Hazardous Substances: Not Listed
New Jersey - Environmental Hazardous Not Listed
Substances List:
Illinois - Toxic Air Contaminants Not Listed
New York - Reporting of Releases Part 597 - Not Listed
List of Hazardous Substances:
Naphthalene
Louisiana Right-To-Know: Not Listed
California Proposition 65: Listed
New Jersey Right-To-Know: Listed
Pennsylvania Right-To-Know: Listed
Massachusetts Right-To Know: Listed
Florida substance List: Not Listed.
Rhode Island Right-To-Know: Listed
Michigan critical materials register list: Not Listed.
Massachusetts Extraordinarily Hazardous Not Listed
Substances:
California - Regulated Carcinogens: Not Listed
Pennsylvania RTK - Special Hazardous Not Listed
Substances:
New Jersey - Special Hazardous Substances: Not Listed
New Jersey - Environmental Hazardous Listed
Substances List:
Illinois - Toxic Air Contaminants Listed
New York - Reporting of Releases Part 597 - Listed
List of Hazardous Substances:
Canadian Regulatory Information:
Canada DSL/NDSL Inventory: This product and/or its components are listed either on the Domestic Substances List
(DSL) or are exempt.
Name Canada - WHMIS: Classifications of Substances: Canada - WHMIS: Ingredient Disclosure:
Naphthalene B4, D2A 1%
16. OTHER INFORMATION
Additional Information: No data available.
Prepared by: Craig M. Parker Manager, Toxicology and Product Safety
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Dyed 500 ppm Sulfur Max
The information and recommendations contained herein are based upon tests believed to be reliable. However,
Marathon Petroleum Company LLC (MPC) does not guarantee their accuracy or completeness nor shall any of this
information constitute a warranty, whether expressed or implied, as to the safety of the goods, the merchantability of the
goods, or the fitness of the goods for a particular purpose. Adjustment to conform to actual conditions of usage maybe
required. MPC assumes no responsibility for results obtained or for incidental or consequential damages, including lost
profits arising from the use of these data. No warranty against infringement of any patent, copyright or trademark is made
or implied.
End of Safety Data Sheet
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