ROCOL EASYLINE ULTIMATE ALL COLOURS
ChemWatch Material Safety Data Sheet CHEMWATCH 61611
Issue Date: Thu 23-Mar-2000 CD 2001/2 Page 1 of 10
IDENTIFICATION
STATEMENT OF HAZARDOUS NATURE
Not classified as hazardous according to Worksafe Australia criteria.
CONSIDERED A DANGEROUS SUBSTANCE ACCORDING TO DIRECTIVE 67/548/EEC, POINT 4;
AND TO 29 CFP 1910-1200 (USA).
CHEMWATCH HAZARD RATINGS
Flammability:
Toxicity:
Body Contact:
Reactivity:
Chronic:
SCALE: Min/Nil=0 Low=1 Moderate=2 High=3 Extreme=4
PERSONAL PROTECTIVE EQUIPMENT FOR INDUSTRIAL/COMMERCIAL ENVIRONMENTS
Product Name: rocol easyline ultimate all colours
CAS RN No(s): None
UN Number: 1950
Packing Group: None
Dangerous Goods Class: 2.1
Subsidiary Risk: None,
Hazchem Code: 2Y
Poisons Schedule Number: S5
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ROCOL EASYLINE ULTIMATE ALL COLOURS
ChemWatch Material Safety Data Sheet CHEMWATCH 61611
Issue Date: Thu 23-Mar-2000 CD 2001/2 Page 2 of 10
IDENTIFICATION ...
USE
Line marking paint.
Application is by spray atomisation from a hand held aerosol pack.
PHYSICAL DESCRIPTION/PROPERTIES
APPEARANCE
Highly flammable coloured liquid with a sweet odour; does not mix with water.
Supplied in an aerosol pack containing carbon dioxide and flammable dimethyl
ether propellant. Viscosity 25 sec (BS No.4 flow cup).
Boiling Point (deg C): >40 solvent
Melting Point (deg C): <0
Vapour Pressure (kPa): Under Pressure
Specific Gravity: 1.0 approx
Flash Point (deg C): -41 propellant
Lower Explosive Limit (%): Not available.
Upper Explosive Limit (%): Not available.
Solubility in Water (g/L): Immiscible
INGREDIENTS
NAME CAS RN %
ketone solvent 10-30
xylene 1330-20-7 <12.5
resin Not spe
pigments Not spe
carbon dioxide 124-38-9 Not spe
dimethyl ether 115-10-6 10-30
HEALTH HAZARD
ACUTE HEALTH EFFECTS
SWALLOWED
The liquid is discomforting to the gastro-intestinal tract and may be
harmful if swallowed.
Ingestion may result in nausea, pain, vomiting. Vomit entering the lungs
by aspiration may cause potentially lethal chemical pneumonitis.
Considered an unlikely route of entry in commercial/industrial environments.
EYE
The liquid may produce eye discomfort and is capable of causing temporary
impairment of vision and / or transient eye inflammation, ulceration.
The vapour is discomforting to the eyes if exposure is prolonged.
SKIN
The liquid is discomforting to the skin if exposure is prolonged
and may cause drying of the skin, which may lead to dermatitis.
Toxic effects may result from skin absorption.
Open cuts, abraded or irritated skin should not be exposed to this material.
The material may accentuate any pre-existing skin condition.
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ROCOL EASYLINE ULTIMATE ALL COLOURS
ChemWatch Material Safety Data Sheet CHEMWATCH 61611
Issue Date: Thu 23-Mar-2000 CD 2001/2 Page 3 of 10
HEALTH HAZARD ...
INHALED
The vapour is discomforting to the upper respiratory tract.
Inhalation hazard is increased at higher temperatures.
Xylene is a central nervous system depressant.
Inhalation of high concentrations of gas/vapour causes lung irritation
with coughing and nausea, central nervous depression with headache
and dizziness, slowing of reflexes, fatigue and inco-ordination.
Toxic effects are increased by consumption of alcohol.
WARNING:Intentional misuse by concentrating/inhaling contents may be lethal.
CHRONIC HEALTH EFFECTS
Principal routes of exposure are by skin contact/absorption and inhalation
of mist/vapours.
Prolonged or continuous skin contact with the liquid may cause defatting
with drying, cracking, irritation and dermatitis following.
Chronic solvent inhalation exposures may result in nervous system impairment
and liver and blood changes. [PATTYS].
Warning: Aerosol containers may present pressure related hazards.
FIRST AID
SWALLOWED
If poisoning occurs, contact a doctor or Poisons Information Centre.
In Australia phone 13 1126; New Zealand 03 4747000.
If swallowed, do NOT induce vomiting. Give a glass of water.
EYE
If this product comes in contact with the eyes:
Immediately hold the eyes open and wash continuously for at least 15
minutes with fresh running water. Ensure irrigation under eyelids by
occasionally lifting the upper and lower lids.
Transport to hospital or doctor without delay. Removal of contact lenses
after an eye injury should only be undertaken by skilled personnel.
SKIN
If solids or aerosol mists are deposited upon the skin:
Wash affected areas thoroughly with water and soap if available.
Remove any adhering solids with industrial skin cleansing cream. DO NOT use
solvents. Seek medical attention in the event of irritation.
INHALED
If fumes or combustion products are inhaled: Remove to fresh air.
Lay patient down. Keep warm and rested.
If breathing is shallow or has stopped, ensure clear airway and apply
resuscitation. Transport to hospital, or doctor.
ADVICE TO DOCTOR
For acute or short term repeated exposures to petroleum distillates or
related hydrocarbons:
1.Primary threat to life, from pure petroleum distillate ingestion and/or
inhalation, is respiratory failure.
2.Patients should be quickly evaluated for signs of respiratory distress
(e.g. cyanosis, tachypnoea, intercostal retraction, obtundation) and given
oxygen. Patients with inadequate tidal volumes or poor arterial blood
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ROCOL EASYLINE ULTIMATE ALL COLOURS
ChemWatch Material Safety Data Sheet CHEMWATCH 61611
Issue Date: Thu 23-Mar-2000 CD 2001/2 Page 4 of 10
HEALTH HAZARD ...
gases (pO2 <50 mm Hg or pCO2 >50 mm Hg) should be intubated.
3.Arrhythmias complicate some hydrocarbon ingestion and/or
inhalation and electrocardiographic evidence of myocardial injury
has been reported; intravenous lines and cardiac monitors should be
established in obviously symptomatic patients. The lungs excrete
inhaled solvents, so that hyperventilation improves clearance
4.A chest x-ray should be taken immediately after stabilisation of
breathing and circulation to document aspiration and detect the
presence of pneumothorax.
5.Epinephrine (adrenalin) is not recommended for treatment of bronchospasm
because of potential myocardial sensitisation to catecholamines.
Inhaled cardioselective bronchodilators (e.g. Alupent, Salbutamol) are
the preferred agents, with aminophylline a second choice.
6.Lavage is indicated in patients who require decontamination; ensure use
of cuffed endotracheal tube in adult patients.
[Ellenhorn and Barceloux: Medical Toxicology].
PRECAUTIONS FOR USE
EXPOSURE STANDARDS
None assigned. Refer to individual constituents.
WARNING:Intentional misuse by concentrating/inhaling contents may be lethal.
EXPOSURE STANDARDS FOR MIXTURE
"Worst Case" computer aided prediction of vapour components/concentrations:
Composite Exposure Standard for Mixture (TWA): 567.5841 mg/m3.
If the breathing zone concentration of ANY of the components listed below is
exceeded, "Worst Case" considerations deem the individual to be over-exposed.
Breathing Zone Mixture
Component ppm mg/m3 Conc.(%)
---------------------------------------------------------- ---------
xylene 38.16 166.9365 12.5
dimethyl ether 209.22 400.6476 30.0
Operations which produce a spray/mist or fume/dust, introduce
non-volatiles to the breathing zone.
If the breathing zone concentration of ANY of the components listed below is
exceeded, "Worst Case" considerations deem the individual to be over-exposed.
At the "Composite Exposure Standard for Mixture " (TWA):
Breathing Zone Mixture
Component Conc. mg/m3 Conc.(%)
---------------------------------------------------------- ---------
REPRODUCTIVE HEALTH GUIDELINES
Established occupational exposure limits frequently do not take into
consideration reproductive end points that are clearly below the
thresholds for other toxic effects. Occupational reproductive guidelines
(ORGs) have been suggested as an additional standard. These have been
established after a literature search for reproductive no-observed-adverse
effect-level (NOAEL) and the lowest-observed-adverse-effect-level (LOAEL).
In addition the US EPA's procedures for risk assessment for hazard
identification and dose-response assessment as applied by NIOSH were used
in the creation of such limits. Uncertainty factors (UFs) have also been
incorporated.
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ROCOL EASYLINE ULTIMATE ALL COLOURS
ChemWatch Material Safety Data Sheet CHEMWATCH 61611
Issue Date: Thu 23-Mar-2000 CD 2001/2 Page 5 of 10
PRECAUTIONS FOR USE ...
Ingredient ORG UF Endpoint CR TLV Adequate
xylene 1.5 mg/m3 10 D NA -
carbon dioxide 1800 mg/m3 10 D/R NA -
These exposure guidelines have been derived from a screening level of
risk assessment and should not be construed as unequivocally safe limits.
ORGS represent an 8-hour time-weighted average unless specified otherwise.
CR = Cancer Risk/10000; UF = Uncertainty factor:
TLV believed to be adequate to protect reproductive health:
LOD: Limit of detection
Toxic endpoints have also been identified as:
D = Developmental; R = Reproductive; TC = Transplacental carcinogen
Jankovic J., Drake F.: A Screening Method for Occupational Reproductive
Health Risk:
American Industrial Hygiene Association Journal 57: 641-649 (1996).
INGREDIENT DATA
XYLENE:
TLV TWA: 100 ppm, 434 mg/m3; STEL: 150 ppm, 651 mg/m3 A4
NOTE: This substance has been classified by the ACGIH as A4
NOT classifiable as causing Cancer in humans.
ES TWA: 80 ppm, 350 mg/m3; STEL: 150 ppm, 655 mg/m3 (Under review)
OES TWA: 100 ppm, 441 mg/m3; STEL: 150 ppm, 662 mg/m3 skin
Exposure limits with "skin" notation indicate that vapour and liquid may be
absorbed through intact skin. Absorption by skin may readily exceed vapour
inhalation exposure. Symptoms for skin absorption are the same as for
inhalation. Contact with eyes and mucous membranes may also contribute to
overall exposure and may also invalidate the exposure standard.
IDLH Level: 900 ppm
Odour Threshold Value: 20 ppm (detection), 40 ppm (recognition)
NOTE: Detector tubes for o-xylene, measuring in excess of 10 ppm, are
available commercially. (m-xylene and p-xylene give almost the same
response)
Xylene vapour is an irritant to the eyes, mucous membranes and skin and
causes narcosis at high concentrations. Exposure to doses sufficiently high
to produce intoxication and unconsciousness also produces transient liver
and kidney toxicity. Neurologic impairment is NOT evident amongst
volunteers inhaling up to 400 ppm though complaints of ocular and upper
respiratory tract irritation occur at 200 ppm for 3 to 5 minutes.
Exposure to xylene at or below the recommended TLV-TWA and STEL is thought
to minimise the risk of irritant effects and to produce neither significant
narcosis or chronic injury. An earlier skin notation was deleted because
percutaneous absorption is gradual and protracted and does not
substantially contribute to the dose received by inhalation.
CARBON DIOXIDE:
carbon dioxide gas:
ES TWA: 5000 ppm, 9000 mg/m3; STEL: 30000 ppm, 54000 mg/m3
TLV TWA: 5000 ppm, 9000 mg/m3; STEL: 30000 ppm, 54000 mg/m3
OES TWA: 5000 ppm, 9150 mg/m3; STEL: 15000 ppm, 27400 mg/m3
MAK value: 5000 ppm, 9000 mg/m3
MAK Category IV Peak Limitation: For substances with very weak effects
(ie.) those with MAK value >500 ml/m3 (ppm): Allows excursions of twice the
MAK value for 60 minutes at a time, 3 times per shift.
MAK values, and categories and groups are those recommended within the
Federal Republic of Germany.
IDLH Level: 40000 ppm
NOTE: Detector tubes for carbon dioxide, measuring in excess of 0.01 % vol.,
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ROCOL EASYLINE ULTIMATE ALL COLOURS
ChemWatch Material Safety Data Sheet CHEMWATCH 61611
Issue Date: Thu 23-Mar-2000 CD 2001/2 Page 6 of 10
PRECAUTIONS FOR USE ...
are commercially available. Long-term measurements (4 hrs) may be
conducted to detect concentrations exceeding 250 ppm.
Studies using physically fit males in confined spaces indicate the TLV-TWA
and STEL provides a wide margin of safety against asphyxiation and from
undue metabolic stress, provided normal amounts of oxygen are present in
inhaled air. Lowered oxygen content, increased physical activity and
prolonged exposures each impact on systemic and respiratory effects.
Stimulation of the respiratory centre is produced at 50,000 ppm (5%). The
gas is weakly narcotic at 30,000 ppm giving rise to reduced acuity of
hearing and increasing blood pressure and pulse, Persons exposed at
20,000 ppm for several hours developed headaches and dyspnea on mild
exertion, Acidosis and adrenal cortical exhaustion occurred as a result
of prolonged continuous exposure at 10,000-20,0000 ppm.
Intoxication occurs after a 30 minute exposure at 50,000 ppm whilst
exposure at 70,000-100,000 ppm produces unconsciousness within a few
minutes.
DIMETHYL ETHER:
No exposure limits set by NOHSC or ACGIH.
PROPOSED CHANGE
ES TWA 400 ppm, 760 mg/m3; STEL 500 ppm, 950 mg/m3
CEL TWA: 500 ppm, 942 mg/m3 (compare WEEL TWA)
OES TWA: 400 ppm, 766 mg/m3; STEL: 500 ppm, 958 mg/m3
MAK value: 1000 ppm, 1910 mg/m3
MAK Category IV Peak Limitation: For substances with very weak effects
(ie.) those with MAK value >500 ml/m3 (ppm): Allows excursions of twice the
MAK value for 60 minutes at a time, 3 times per shift.
MAK Group D: Classification as to the effect of the substance on the
developing embryo/ foetus is not yet possible because although
data may indicate a trend, they are not sufficient for a final
evaluation.
MAK values, and categories and groups are those recommended within the
Federal Republic of Germany.
The no-effect-level for dimethyl ether is somewhere between 2000 ppm
(rabbits) and 50,000 ppm (humans) with possible cardiac sensitisation
occurring around 200,000 ppm (dogs). The AIHA has adopted a safety factor
of 100 in respect to the 50,000 ppm level in its recommendation for a
workplace environmental exposure level (WEEL) which is thought to protect
against both narcotic and sensitising effects. This level is consistent
with the TLV-TWA of 400 ppm for diethyl ether and should be easily
achievable using current technologies. The use of the traditionally
allowable excursion of 1.25 to the level of 6.25 ppm is felt to be more
than adequate as an upper safe limit of exposure.
Human data:
50,000 ppm (12 mins): Feelings of mild intoxication.
75,000 ppm (12 mins): As above plus slight lack of attenuation.
82,000 ppm (12 mins): Some incoordination, slight blurring of vision
(30 mins): As above plus analgesia of the face and rushing of
blood to the face.
100,000 ppm (10-20 mins): Narcotic symptoms
(64 mins) : Sickness (assumed to be nausea)
144,000 ppm (36 mins): Unconsciousness
ENGINEERING CONTROLS
General exhaust is adequate under normal operating conditions.
If risk of overexposure exists, wear SAA approved respirator.
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ROCOL EASYLINE ULTIMATE ALL COLOURS
ChemWatch Material Safety Data Sheet CHEMWATCH 61611
Issue Date: Thu 23-Mar-2000 CD 2001/2 Page 7 of 10
PRECAUTIONS FOR USE ...
Correct fit is essential to obtain adequate protection.
Provide adequate ventilation in warehouse or closed storage areas.
PERSONAL PROTECTION
EYE
No special equipment for minor exposure i.e. when handling small quantities.
OTHERWISE: Safety glasses with side shields.
Contact lenses pose a special hazard; soft lenses may absorb irritants and
all lenses concentrate them.
HANDS/FEET
No special equipment needed when handling small quantities.
OTHERWISE: Wear general protective gloves, eg. light weight rubber gloves.
Or as required: Wear chemical protective gloves, eg. PVC.
Wear safety footwear.
OTHER
No special equipment needed when handling small quantities.
OTHERWISE: Overalls. Skin cleansing cream. Eyewash unit.
Do not spray on hot surfaces.
RESPIRATOR
Respiratory protection may be required when ANY "Worst Case" vapour-phase
concentration is exceeded (see Computer Prediction in "Exposure Standards")
Protection Half-Face Full-Face Spray/ Mist
Factor (Min) Respirator Respirator Spatter
---------------------------------------------------------------------------
10 x ES Air-line* AX -2 AX -2 ^
- AX -PAPR-2 AX -PAPR-2 ^
20 x ES - AX -3 AX -3 ^
20+ x ES - Air-line** Air-line** ^
* - Continuous-flow; ** - Continuous-flow or positive pressure demand
^ - Full-face.
The local concentration of material, quantity and conditions of use determine
the type of personal protective equipment required. For further information,
consult site specific CHEMWATCH data (if available), or your Occupational
Health and Safety Advisor.
SAFE HANDLING
STORAGE AND TRANSPORT
SUITABLE CONTAINER
Aerosol dispenser. Check that containers are clearly labelled.
STORAGE INCOMPATIBILITY
Avoid storage with oxidisers.
STORAGE REQUIREMENTS
1: Store in original containers in approved flame-proof area.
2. DO NOT store in pits, depressions, basements or areas where vapours
may be trapped.
3: No smoking, naked lights, heat or ignition sources.
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ChemWatch Material Safety Data Sheet CHEMWATCH 61611
Issue Date: Thu 23-Mar-2000 CD 2001/2 Page 8 of 10
SAFE HANDLING ...
4: Keep containers securely sealed. Contents under pressure.
5: Store away from incompatible materials.
6: Store in a cool, dry, well ventilated area in an upright position.
7: Avoid storage at temperatures higher than 40 deg C.
8: Protect containers against physical damage and check regularly for
leaks.
9: Observe manufacturer's storing and handling recommendations.
TRANSPORTATION
Class 2.1 - Flammable gases shall not be loaded in the same vehicle or
packed in the same freight container with:
Class 1 - Explosives;
Class 3 - Flammable liquids (where both flammable liquids and flammable
gases are in bulk);
Class 4.1 - Flammable solids;
Class 4.2 - Spontaneously combustible substances;
Class 4.3 - Dangerous when wet substances;
Class 5.1 - Oxidising agents;
Class 5.2 - Organic peroxides;
Class 7 - Radioactive substances.
SPILLS AND DISPOSAL
MINOR SPILLS
1: Clean up all spills immediately.
2: Avoid breathing vapours and contact with skin and eyes.
3: Wear protective clothing, impervious gloves and safety glasses.
4: Shut off all possible sources of ignition and increase ventilation.
5: Wipe up.
6: If safe, damaged cans should be placed in a container outdoors, away
from ignition sources, until pressure has dissipated.
7: Undamaged cans should be gathered and stowed safely.
MAJOR SPILLS
1: Clear area of personnel and move upwind.
2: Alert Fire Brigade and tell them location and nature of hazard.
3: May be violently or explosively reactive.
4: Wear breathing apparatus plus protective gloves.
5: Prevent, by any means available, spillage from entering drains or
water course.
6: No smoking, naked lights or ignition sources.
7: Increase ventilation.
8: Stop leak if safe to do so.
9: Water spray or fog may be used to disperse / absorb vapour.
10:Absorb or cover spill with sand, earth, inert materials or vermiculite.
11:If safe, damaged cans should be placed in a container outdoors, away
from ignition sources, until pressure has dissipated.
12:Undamaged cans should be gathered and stowed safely.
13:Collect residues and seal in labelled drums for disposal.
DISPOSAL
Consult State Land Waste Management Authority for disposal.
Discharge contents of damaged aerosol cans at an approved site.
Allow small quantities to evaporate.
DO NOT incinerate or puncture aerosol cans.
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ROCOL EASYLINE ULTIMATE ALL COLOURS
ChemWatch Material Safety Data Sheet CHEMWATCH 61611
Issue Date: Thu 23-Mar-2000 CD 2001/2 Page 9 of 10
SAFE HANDLING ...
Bury residues and emptied aerosol cans at an approved site.
FIRE FIGHTERS' REPORT
EXTINGUISHING MEDIA
Water spray or fog. Foam. Dry chemical powder.
BCF (where regulations permit).
Carbon dioxide.
FIRE FIGHTING
1: Alert Fire Brigade and tell them location and nature of hazard.
2: May be violently or explosively reactive.
3: Wear breathing apparatus plus protective gloves.
4: Prevent, by any means available, spillage from entering drains or
water course.
5: If safe, switch off electrical equipment until vapour fire hazard
removed.
6: Use water delivered as a fine spray to control fire and cool adjacent
area.
7: Do not approach containers suspected to be hot.
8: Cool fire exposed containers with water spray from a protected location.
9: If safe to do so, remove containers from path of fire.
10:Equipment should be thoroughly decontaminated after use.
When any large container (including road and rail tankers) is involved in a fire,
consider evacuation by 100 metres in all directions.
FIRE/EXPLOSION HAZARD
1: Liquid and vapour are highly flammable.
2: Severe fire hazard when exposed to heat or flame.
3: Vapour forms an explosive mixture with air.
4: Severe explosion hazard, in the form of vapour, when exposed to flame or
spark.
5: Vapour may travel a considerable distance to source of ignition.
6: Heating may cause expansion or decomposition with violent container
rupture.
7: Aerosol cans may explode on exposure to naked flames.
8: Rupturing containers may rocket and scatter burning materials.
9: Hazards may not be restricted to pressure effects.
10:May emit acrid, poisonous or corrosive fumes.
11:On combustion, may emit toxic fumes of carbon monoxide (CO).
Other combustion products include carbon dioxide (CO2).
FIRE INCOMPATIBILITY
Avoid contact with oxidising agents.
HAZCHEM
2Y
CONTACT POINT
COMPANY CONTACT
(02) 9757 8800
AUSTRALIAN POISONS INFORMATION CENTRE
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ROCOL EASYLINE ULTIMATE ALL COLOURS
ChemWatch Material Safety Data Sheet CHEMWATCH 61611
Issue Date: Thu 23-Mar-2000 CD 2001/2 Page 10 of 10
CONTACT POINT ...
24 HOUR SERVICE: 13 11 26
POLICE, FIRE BRIGADE OR AMBULANCE: 000
NEW ZEALAND POISONS INFORMATION CENTRE
24 HOUR SERVICE: (03) 4747 000
NZ EMERGENCY SERVICES: 111
End of Report
Issue Date: Thu 23-Mar-2000
Print Date: Mon 25-Jun-2001
This document is copyright. Apart from any fair dealing for the purposes
of private study, research, review or criticism, as permitted under the
Copyright Act, no part may be reproduced by any process without written
permission from CHEMWATCH. TEL (+61 3) 9572 4700
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