ALLYL GLYCIDYL ETHER 0096
March 1996
CAS No: 106-92-3 ((2-Propenyloxy)methyl)oxirane
Allyl 2,3-epoxypropyl ether
RTECS No: RR0875000
1-(Allyloxy)-2,3-epoxypropane
UN No: 2219
C6H10O2
EC No: 603-038-00-1
Molecular mass: 114.2
TYPES OF
ACUTE HAZARDS/SYMPTOMS PREVENTION FIRST AID/FIRE FIGHTING
HAZARD/
EXPOSURE
FIRE Flammable. NO open flames, NO sparks, and NO Powder, AFFF, foam, carbon dioxide.
smoking.
EXPLOSION Above 48/C explosive vapour/air Above 48/C use a closed system, In case of fire: keep drums, etc., cool
mixtures may be formed. ventilation, and explosion-proof by spraying with water.
electrical equipment.
EXPOSURE AVOID ALL CONTACT!
Inhalation Burning sensation. Shortness of Ventilation, local exhaust, or breathing Fresh air, rest. Artificial respiration
breath. Headache. Drowsiness. protection. may be needed. Refer for medical
Dullness. Nausea. Vomiting. attention.
Skin MAY BE ABSORBED! Dry skin. Protective gloves. Protective clothing. Remove contaminated clothes.
Redness. Pain. Blisters. Rinse and then wash skin with water
and soap. Refer for medical
attention.
Eyes Redness. Pain. Blurred vision. Safety goggles or face shield. First rinse with plenty of water for
Severe deep burns. several minutes (remove contact
lenses if easily possible), then take to
a doctor.
Ingestion Burning sensation. Headache. Do not eat, drink, or smoke during Rinse mouth. Give plenty of water to
Dullness. Drowsiness. Nausea. work. drink. Refer for medical attention.
Vomiting.
SPILLAGE DISPOSAL PACKAGING & LABELLING
Ventilation. Collect leaking and spilled liquid in Xn Symbol
sealable containers as far as possible. Wash away R:
remainder with plenty of water. Personal protection: 10-20/22-37/38-40-41-43-52/53-62-68
self-contained breathing apparatus. S: (2-)24/25-26-36/37/39-61
UN Hazard Class: 3
UN Subsidiary Risks: 6.1
UN Pack Group: III
EMERGENCY RESPONSE SAFE STORAGE
Transport Emergency Card: TEC (R)-30S2219 Fireproof. Separated from strong oxidants, strong bases, strong acids. Cool.
Keep in the dark.
Prepared in the context of cooperation between the International
IPCS Programme on Chemical Safety and the European Commission 漏
IPCS 2005
International
Programme on
SEE IMPORTANT INFORMATION ON THE BACK.
Chemical Safety
0096 ALLYL GLYCIDYL ETHER
IMPORTANT DATA
Physical State; Appearance Routes of exposure
COLOURLESS LIQUID, WITH CHARACTERISTIC ODOUR. The substance can be absorbed into the body by inhalation and
through the skin, and by ingestion.
Chemical dangers
Inhalation risk
The substance can presumably form explosive peroxides. The
substance may polymerize readily. The substance decomposes A harmful contamination of the air can be reached rather quickly
on burning producing toxic gases. Reacts violently with strong on evaporation of this substance at 20/C.
oxidants, acids and bases.
Effects of short-term exposure
Occupational exposure limits Corrosive. The substance is corrosive to the eyes, the skin and
TLV: 1 ppm as TWA; A4 (not classifiable as a human carcinogen); the respiratory tract. Inhalation of the vapour may cause lung
(ACGIH 2004). oedema (see Notes). Acute exposure may cause central nervous
MAK: skin absorption (H); sensitization of skin (Sh); Carcinogen system depression. Exposure could cause lowering of
category: 2; (DFG 2004). consciousness. Medical observation is indicated.
Effects of long-term or repeated exposure
Repeated or prolonged contact with skin may cause dermatitis.
Repeated or prolonged contact may cause skin sensitization. May
cause genetic damage in humans. Does cause serious
reproductive toxicity in humans.
PHYSICAL PROPERTIES
Boiling point: 154/C Relative vapour density (air = 1): 3.9
Melting point: -100/C Relative density of the vapour/air-mixture at 20/C (air = 1): 1.02
Relative density (water = 1): 0.97 Flash point: 48/C o.c.
Solubility in water, g/100 ml: 14 Auto-ignition temperature: see Notes
Vapour pressure, kPa at 25/C: 0.63 Explosive limits, vol% in air: see Notes
ENVIRONMENTAL DATA
NOTES
Auto-ignition temperature is unknown in literature.
Explosive limits are unknown in literature, although the substance is combustible and has a flash point < 61/C.
Use of alcoholic beverages enhances the harmful effect.
Depending on the degree of exposure, periodic medical examination is suggested.
The symptoms of lung oedema often do not become manifest until a few hours have passed and they are aggravated by physical effort.
Rest and medical observation are therefore essential.
The odour warning when the exposure limit value is exceeded is insufficient.
Check for peroxides prior to distillation; eliminate if found.
Card has been partly updated in October 2005. See sections Occupational Exposure Limits, EU classification, Emergency Response.
ADDITIONAL INFORMATION
Neither the EC nor the IPCS nor any person acting on behalf of the EC or the IPCS is responsible
LEGAL NOTICE for the use which might be made of this information
漏IPCS 2005
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