3-CHLOROANILINE 0130
April 2000
1-Amino-3-chlorobenzene
CAS No: 108-42-9
3-Chlorobenzeneamine
RTECS No: BX0350000
Orange GC base
UN No: 2019
m-Chloroaniline
EC No: 612-010-00-8
C6H6ClN / (C6H4)Cl(NH2)
Molecular mass: 127.6
TYPES OF
ACUTE HAZARDS/SYMPTOMS PREVENTION FIRST AID/FIRE FIGHTING
HAZARD/
EXPOSURE
Combustible. Gives off irritating or NO open flames. Powder, AFFF, foam, carbon
FIRE
toxic fumes (or gases) in a fire. dioxide.
EXPLOSION
EXPOSURE PREVENT GENERATION OF
MISTS!
Blue lips or finger nails. Blue skin. Ventilation, local exhaust, or Fresh air, rest. Artificial respiration
Inhalation
Dizziness. Headache. Shortness of breathing protection. may be needed. Refer for medical
breath. Nausea. Vomiting. attention.
Convulsions. Weakness.
Confusion. Unconsciousness.
MAY BE ABSORBED! Redness. Protective gloves. Protective Remove contaminated clothes.
Skin
Burning sensation. (Further see clothing. Rinse and then wash skin with water
Inhalation). and soap. Refer for medical
attention.
Redness. Pain. Safety goggles or face shield. First rinse with plenty of water for
Eyes
several minutes (remove contact
lenses if easily possible), then take
to a doctor.
Abdominal pain. (Further see Do not eat, drink, or smoke during Rinse mouth. Give plenty of water to
Ingestion
Inhalation). work. Wash hands before eating. drink. Refer for medical attention.
SPILLAGE DISPOSAL PACKAGING & LABELLING
Collect leaking and spilled liquid in sealable T Symbol Do not transport with food and
containers as far as possible. Absorb remaining N Symbol feedstuffs.
liquid in sand or inert absorbent and remove to safe R: 23/24/25-33-50/53
place. Do NOT let this chemical enter the S: (1/2-)28-36/37-45-60-61
environment. Chemical protection suit including Note: C
self-contained breathing apparatus. UN Hazard Class: 6.1
UN Pack Group: II
EMERGENCY RESPONSE SAFE STORAGE
Transport Emergency Card: TEC (R)-61S2019 Separated from food and feedstuffs. Keep in the dark. Well closed.
IPCS Prepared in the context of cooperation between the International
Programme on Chemical Safety and the European Commission 漏
International IPCS 2005
Programme on
Chemical Safety SEE IMPORTANT INFORMATION ON THE BACK.
0130 3-CHLOROANILINE
IMPORTANT DATA
Physical State; Appearance Routes of exposure
LIGHT YELLOW LIQUID, WITH CHARACTERISTIC ODOUR. The substance can be absorbed into the body by inhalation,
TURNS DARK ON EXPOSURE TO AIR. through the skin and by ingestion.
Chemical dangers Inhalation risk
The substance decomposes on burning producing toxic fumes No indication can be given about the rate in which a harmful
including nitrogen oxides, hydrogen chloride - see ICSC0163. concentration in the air is reached on evaporation of this
substance at 20/C.
Occupational exposure limits
Effects of short-term exposure
TLV not established.
MAK: IIb (not established but data is available); skin absorption The substance is irritating to the eyes and the skin. The
(H); sensitization of skin (Sh); (DFG 2004). substance may cause effects on the blood, resulting in the
formation of methaemoglobin. Medical observation is indicated.
The effects may be delayed.
Effects of long-term or repeated exposure
The substance may have effects on the blood, resulting in the
formation of methaemoglobin.
PHYSICAL PROPERTIES
Boiling point (decomposes): 230/C Relative vapour density (air = 1): 4.4
Melting point: -10/C Relative density of the vapour/air-mixture at 20/C (air = 1): 1.00
Relative density (water = 1): 1.216 Flash point: 118/C c.c.
Solubility in water, g/100 ml at 20/C: 0.6 Auto-ignition temperature: >540/C
Vapour pressure, Pa at 20/C: 9 Octanol/water partition coefficient as log Pow: 1.9
ENVIRONMENTAL DATA
The substance is toxic to aquatic organisms.
NOTES
Stabilized with 0.1% Hydrazine hydrate.
Depending on the degree of exposure, periodic medical examination is suggested.
Specific treatment is necessary in case of poisoning with this substance; the appropriate means with instructions must be available.
Card has been partly updated in April 2005. See sections Occupational Exposure Limits, Emergency Response.
ADDITIONAL INFORMATION
Neither the EC nor the IPCS nor any person acting on behalf of the EC or the IPCS is responsible
LEGAL NOTICE
漏IPCS 2005
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