d-ALLETHRIN 0213
March 2001
CAS No: 584-79-2 (RS)-3-Allyl-2-methyl-4-oxocyclopent-2-enyl
(1R)-cis-trans-chrysanthemate
RTECS No: GZ1925000
2-Methyl-4-oxo-3-(2-propenyl)-2-cyclopenten-1-yl
UN No: 3352
2,2-dimethyl-3-(2-methyl-1-propenyl)cyclopropanecarboxylate
EC No: 006-025-00-3
C19H26O3
Molecular mass: 302.4
TYPES OF
ACUTE HAZARDS/SYMPTOMS PREVENTION FIRST AID/FIRE FIGHTING
HAZARD/
EXPOSURE
FIRE Combustible. Liquid formulations NO open flames. Powder, AFFF, foam, carbon dioxide.
containing organic solvents may be
flammable.
EXPLOSION In case of fire: keep drums, etc., cool
by spraying with water.
EXPOSURE PREVENT GENERATION OF
MISTS!
Inhalation Cough. Ventilation, local exhaust, or breathing Fresh air, rest. Refer for medical
protection. attention.
Skin Redness. Protective gloves. Remove contaminated clothes.
Rinse and then wash skin with water
and soap.
Eyes Redness. Safety goggles. First rinse with plenty of water for
several minutes (remove contact
lenses if easily possible), then take to
a doctor.
Ingestion Do not eat, drink, or smoke during Rinse mouth. Refer for medical
work. Wash hands before eating. attention.
SPILLAGE DISPOSAL PACKAGING & LABELLING
Personal protection: A/P2 filter respirator for organic Xn Symbol Do not transport with food and
vapour and harmful dust. Do NOT let this chemical N Symbol feedstuffs.
enter the environment. Collect leaking and spilled R: 20/22-50/53
liquid in sealable containers as far as possible. S: (2-)36-60-61
Absorb remaining liquid in sand or inert absorbent and Note: C
remove to safe place. Do NOT wash away into sewer. UN Hazard Class: 6.1
UN Pack Group: III
EMERGENCY RESPONSE SAFE STORAGE
Transport Emergency Card: TEC (R)-61GT6-III Provision to contain effluent from fire extinguishing. Separated from food and
feedstuffs. Keep in a well-ventilated room.
Prepared in the context of cooperation between the International
IPCS Programme on Chemical Safety and the European Commission 漏
IPCS 2005
International
Programme on
SEE IMPORTANT INFORMATION ON THE BACK.
Chemical Safety
0213 d-ALLETHRIN
IMPORTANT DATA
Physical State; Appearance Routes of exposure
VISCOUS LIQUID. The substance can be absorbed into the body by inhalation of its
aerosol and by ingestion.
Chemical dangers
Inhalation risk
The substance decomposes on heating above 400/C producing
irritating fumes. No indication can be given about the rate in which a harmful
concentration in the air is reached on evaporation of this
Occupational exposure limits substance at 20/C.
TLV not established.
Effects of short-term exposure
The substance is irritating to the eyes, the skin and the respiratory
tract.
PHYSICAL PROPERTIES
Relative density (water = 1): 1.01 Flash point: 130/C
Solubility in water: none Octanol/water partition coefficient as log Pow: 4.78
ENVIRONMENTAL DATA
The substance is very toxic to aquatic organisms. Avoid release to the environment in circumstances different to normal use.
NOTES
Carrier solvents used in commercial formulations may change physical and toxicological properties.
Pynamin Forte is a trade name.
Also consult publication Health and Safety Guide No. 24 Allethrins, and Environmental Health Criteria No. 87 Allethrins, of IPCS.
Also consult ICSC 0228 (S-Bioallethrin), 0212 (Allethrin), 0227 (Bioallethrin).
Card has been partly updated in October 2005. See section Emergency Response.
ADDITIONAL INFORMATION
Neither the EC nor the IPCS nor any person acting on behalf of the EC or the IPCS is responsible
LEGAL NOTICE for the use which might be made of this information
漏IPCS 2005
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