MATERIAL SAFETY DATA SHEET
800-533-6623
Emergency Phone: HAZARD RATING
1 4=EXTREME
Toxicity
800-533-6623
Information Phone:
0 3=HIGH
Fire
973-690-5808
Fax Number:
0 2=MODERATE
Reactivity
N/A 1=SLIGHT
Special
0=INSIGNIFICANT
PRODUCT IDENTIFICATION
RADEX铮? Sb-1000 (GX194)
Product Name:
Granular Titanium Dioxide Product
Chemical Name:
MS-RX-SB1000
MSDS Code:
12/12/07
Effective Date:
1. COMPONENT INFORMATION
No. CAS No. AMT.(%)
1) Titanium Dioxide 13463-67-7 30-90
2) Titanium Hydroxide 20338-08-3 0-30
3) Ethenol, Homopolymer 9002-89-5 0-10
2. PHYSICAL DATA
1855 潞C (3371 潞F)
MELTING POINT:
2500 鈥? 3000 潞C (4532 -5432 潞F)
BOILING POINT:
Not applicable
VAPOR PRESSURE (mm Hg):
Not applicable
VAPOR DENSITY (air=1):
Insoluble
SOLUBILITY IN WATER:
4.26
SPECIFIC GRAVITY (water=1):
< 1 Water
EVAPORATION RATE (Butyl acetate=1):
0% @ 21 潞C (70 潞F)
PERCENT VOLATILITY:
6 鈥? 7 (slurry)
pH (slurry)
Dry, white granules
APPEARANCE:
Odorless
ODOR:
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72 LOCKWOOD STREET, NEWARK, NEW JERSEY 07105
Graver Technologies Product: RADEX Sb1000 (GX194)
MSDS Code: MS-RX-SB1000
Date: 12/12/07
3. EXPOSURE LIMIT INFORMATION
AIRBORNE EXPOSURE LIMITS:
3
Component 1: OSHA Permissible Exposure Limit (PEL) 鈥? 15 mg/m (TWA)
ACGIH Threshold Limit Value (TLV) 鈥? 10 mg/m3 (TWA)
A4 鈥? Not classifiable as a human carcinogen.
Component 2: OSHA PEL and ACGIH TLV do not exist.
4. FIRE AND EXPLOSION HAZARD DATA
FIRE: Not considered to be a fire hazard.
EXPLOSION: Not considered to be an explosion hazard
FIRE FIGHTING EQUIPMENT: Wear full protective clothing and NIOSH approved
self-contained breathing apparatus with full face piece operated in the pressure
demand or other positive pressure mode.
EXTINGUISHING AGENTS: Use any means suitable for extinguishing surrounding
fire.
5. REACTIVITY DATA
STABILITY: Stable under normal handling and storage conditions.
INCOMPATIBILITY: For Titanium Dioxide: A violent reaction with lithium occurs
around 200 潞C (392 潞F) with a flash of light; the temperature can reach 900 潞C. Violent
or incandescent reaction may also occur with other metals such as aluminum, calcium,
magnesium, potassium, sodium, and zinc.
Conditions to Avoid: Dusting and incompatibles.
HAZARDOUS DECOMPOSITION PRODUCTS: No information found.
HAZARDOUS POLYMERIZATION: Will not occur
6. ENVIRONMENTAL AND DISPOSAL INFORMATION
ACTION TO TAKE FOR SPILLS/LEAKS: Sweep up and containerize for reclamation
or disposal. Vacuuming or wet sweeping may be used to avoid dust dispersal.
Ventilate area of leak or spill. Wear appropriate personal protective equipment.
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Graver Technologies Product: RADEX Sb1000 (GX194)
MSDS Code: MS-RX-SB1000
Date: 12/12/07
6. ENVIRONMENTAL AND DISPOSAL INFORMATION (cont.)
DISPOSAL: Whatever cannot be saved for recovery or recycling should be sent to an
appropriate and approved waste disposal facility. Processing, use, or
contamination of this product may change the waste management options. State
and local disposal regulations may differ from federal disposal regulations.
Dispose of container and unused contents in accordance with federal, state, and
local requirements.
7. TOXICOLOGICAL INFORMATION
TOXICOLOGICAL DATA: No LD50/LC50 information found relating to normal routes
of occupational exposure. Investigated as a tumorigen and mutagen.
CARCINOGENICITY: Titanium Dioxide has been classified by the American Congress
of Governmental Industrial Hygienists (ACGIH) as an A4 carcinogen as follows: Not
Classifiable as a Human Carcinogen (1999 TLVs and BEIs,鈥? p. 67). It has been
classified by the International Agency for Research on Cancer (IARC) as group 3 as
follows: Not Classifiable as to its Carcinogenicity to Humans.
8. ECOLOGICAL INFORMATION
ENVIRONMENTAL FATE: No information found.
ENVIRONMENTAL TOXICITY: For Titanium Dioxide, 96 Hour LC50 for fathead
minnows >1,000mg/l
9. HEALTH HAZARD DATA
EYE CONTACT: May mild eye irritation, possible reddening. Flush with water for a
minimum of 15 minutes, lifting upper and lower eyelids occasionally. Consult a
physician if irritation persists.
SKIN CONTACT: Prolonged or repeated exposure may cause skin irritation and
redness. If irritation occurs, wash affected area with soap and water for at least 15
minutes. Remove contaminated clothing and shoes. Wash clothing before reuse.
Thoroughly clean shoes before reuse. Consult a physician if irritation persists.
SKIN ABSORPTION: Skin absorption is unlikely due to physical properties.
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Graver Technologies Product: RADEX Sb1000 (GX194)
MSDS Code: MS-RX-SB1000
Date: 12/12/07
9. HEALTH HAZARD DATA (cont.)
INGESTION: Single dose oral LD50 has not been determined. Single dose oral toxicity
is believed to be low. No hazards anticipated from ingestion incidental to industrial
exposure. Not expected to require first aid measures. If large amounts are
swallowed, give water to drink and call a physician.
INHALATION: Vapors are unlikely due to physical properties. Avoid breathing dust. If
inhaled, remove to fresh air. Get medical attention for any breathing difficulty.
CHRONIC EXPOSURE: Long-term exposure to titanium dioxide dust may result in
mild fibrosis (scarring of the lungs).
PRE-EXISTING CONDITIONS: Persons with pre-existing lung disease may be more
susceptible to the effects of this substance.
10. PERSONAL PROTECTION MEASURES
EXPOSURE GUIDELINES: None established.
VENTILATION: A system of local and/or general exhaust is recommended to keep
employee exposures below the Airborne Exposure Limits. Local exhaust
ventilation is generally preferred because it can control the emissions of the
contaminant at its source, preventing dispersion of it into the general work area.
Refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended
Practices, most recent edition, for details.
RESPIRATORY PROTECTION: If the exposure limit is exceeded, a half-face dust/mist
respirator may be worn for up to ten times the exposure limit or the maximum use
concentration specified by the appropriate regulatory agency or respirator supplier,
whichever is lowest. A full-face piece dust/mist respirator may be worn up to 50
times the exposure limit, or the maximum use concentration specified by the
appropriate regulatory agency, or respirator supplier, whichever is lower. For
emergencies or instances where the exposure levels are not known, use a full-face
piece positive-pressure, air-supplied respirator.
WARNING: Air purifying respirators do not protect workers in oxygen-deficient
atmospheres.
EYE PROTECTION: Use chemical safety goggles and/or full face shield where dusting
or splashing of solutions is possible.
SKIN & HAND PROTECTION: Avoid skin contact. When using this substance, use
skin protection (clean body-covering clothing) and protective gloves for the hands.
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Graver Technologies Product: RADEX Sb1000 (GX194)
MSDS Code: MS-RX-SB1000
Date: 12/12/07
10. PERSONAL PROTECTION MEASURES (cont.)
OTHER PROTECTIVE EQUIPMENT: Facilities storing or utilizing this material should
be equipped with an eyewash fountain or quick-drench facility.
11. STORAGE AND HANDLING INFORMATION
STORAGE CONDITIONS: Keep in a tightly closed container. Store in a cool, dry,
ventilated area.
HANDLING PROCEDURES: Protect against physical damage. Containers of this
material may be hazardous when empty since they retain product residues (dust,
solids); observe all warnings and precautions listed for the product.
12. REGULATORY INFORMATION
WORKPLACE CLASSIFICATIONS: This product is considered non-hazardous under
OSHA Hazard Communication Standard (29CFR 1910.1200).
This product is not a 鈥楥ontrolled Product鈥? under the Canadian Workplace
Hazardous Materials Information System (WHMIS).
TRANSPORTATION CLASSIFICATIONS: US DOT Hazard Class - Non-regulated
EMERGENCY PLANNING & COMMUNITY RIGHT-TO-KNOW (SARA TITLE 3):
Section 311/312 Categorizations (40CFR 370) Acute: Yes Chronic: Yes
Fire: No Pressure: No Reactivity: No (Pure/Solid)
Section 313 Information (40CFR 372) This product does not contain a
chemical which is listed in Section 313 above de minimis concentrations.
CERCLA Information (40CFR 302.4) Releases of this material to air, land, or
water are not reportable to the National Response Center under the
Comprehensive Environmental Response, Compensation, and Liability Act
(CERCLA) or to state and local emergency planning committee under the
Superfund Amendments and Reauthorization Act (SARA Title III Section 304).
RCRA Information When a decision is made to discard this material as
supplied, it does not meet RCRA鈥檚 characteristic definition of ignitability,
corrosivity, or reactivity, and is not listed in 40CFR 261.33. The toxicity
characteristic (TC), however, has not been evaluated by the Toxicity Characteristic
Leaching Procedure (TCLP).
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Graver Technologies Product: RADEX Sb1000 (GX194)
MSDS Code: MS-RX-SB1000
Date: 12/12/07
12. REGULATORY INFORMATION (cont.)
Chemical Control Law Status All components of this product are listed or are
excluded from listing on the U.S. Toxic Substance Control Act (TSCA) Chemical
Substance Inventory.
RADEX铮? is a trademark of Graver Technologies
Abbreviations:
ACGIH - American Conference of Governmental Industrial Hygienists
OSHA - Occupational Safety and Health Administration
TLV - Threshold limit Value
TWA - Time Weighted Average
The above information contained herein relates to the specific material identified. Graver Technologies
believes that such information is accurate and reliable as of the date of this material safety data sheet, but
no representation, guarantee or warranty, express or implied, is made as to the accuracy, reliability, or
completeness of the information. Graver Technologies urges persons receiving this information to make
their own determination as to the information鈥檚 suitability and completeness for their particular application.
Consult Graver Technologies for further information.
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