Material Safety Data Sheet
Revision Date: 06/01/2004 Issue date: 06/01/2004
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product name: FAST CURE MIXER CUPS 1 OZ CAN Item number: 21426_HARDENER
Product type: Epoxy Hardener Region: United States
Company address: Contact Information:
Henkel Corporation Telephone: 860.571.5100
1001 Trout Brook Crossing Emergency telephone: 860.571.5100
Rocky Hill, Connecticut 06067 Internet: www.loctite.com
2. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous components % ACGIH TLV OSHA PEL OTHER
Alumina trihydrate 30-60 None None None
21645-51-2
Polymercaptan hardener 30-60 None None None
Phenol, 2,4,6- 5-10 None None None
tris[(dimethylamino)methyl]
90-72-2
Aromatic plasticizer 5-10 None None None
64741-81-7
Styrene monomer 1-5 20 ppm TWA 100 ppm TWA None
100-42-5 40 ppm STEL 200 ppm Ceiling
6 mg/m3 TWA 10 mg/m3 TWA 3 mg/m3 TWA respirable dust
Silica, amorphous, fumed, 1-5
crystalline-free
112945-52-5
Ethylene glycol 1-5 100 mg/m鲁 Ceiling None None
107-21-1
Benz{a}anthracene 0.1-1 None None None
56-55-3
3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
HMIS:
Physical state: Paste HEALTH: 2
Color: Black FLAMMABILITY: 1
Odor: Mercaptan PHYSICAL HAZARD: 1
Personal Protection: See Section 8
WARNING: CAUSES EYE AND SKIN IRRITATION.
MAY CAUSE ALLERGIC SKIN REACTION.
MAY CAUSE RESPIRATORY TRACT IRRITATION.
Relevant routes of exposure: Eye contact, Ingestion, Inhalation, Skin contact
Potential Health Effects
Item number: 21426_HARDENER Product name: FAST CURE MIXER CUPS 1 OZ CAN
1 of 5
Inhalation: May cause respiratory tract irritation. May cause irritation to nose and throat. Vapors may cause
headaches, nausea, dizziness and respiratory tract irritation. Shortness of breath.
Skin contact: Allergic skin reaction. Moderate skin irritation. Itching. Redness.
Eye contact: Moderate eye irritation. Redness. Tissue damage.
Ingestion: Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea. Nausea. Vomiting.
Existing conditions aggravated by Skin disorders. Skin allergies. Respiratory disorders. Eye disorders.
exposure:
See Section 11 for additional toxicological information.
4. FIRST AID MEASURES
Inhalation: Remove to fresh air. If symptoms develop and persist, get medical attention.
Skin contact: Immediately flush skin with plenty of water (using soap, if available). Remove contaminated clothing
and shoes. Get medical attention if symptoms occur.
Eye contact: Immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention.
Ingestion: DO NOT induce vomiting unless directed to do so by medical personnel. Keep individual calm. Get
medical attention if symptoms develop and persist.
Notes to physician: None.
5. FIRE-FIGHTING MEASURES
Flash point: Greater than 93潞C (200潞F) Tagliabue closed cup
Autoignition temperature: Not available
Flammable/Explosive limits-lower %: Not available
Flammable/Explosive limits-upper %: Not available
Extinguishing media: Foam, dry chemical or carbon dioxide.
Special fire fighting procedures: Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear.
Unusual fire or explosion hazards: Closed containers may rupture (due to build up of pressure) when exposed to extreme heat.
Hazardous combustion products: Oxides of carbon. Irritating organic fragments.
6. ACCIDENTAL RELEASE MEASURES
Environmental precautions: Prevent product from entering drains or open waters.
Clean-up methods: Remove all ignition sources. Immediately contact emergency personnel. Scrape up as much material
as possible. Clean residue with soap and water. Store in a closed container until ready for disposal.
Item number: 21426_HARDENER Product name: FAST CURE MIXER CUPS 1 OZ CAN
2 of 5
7. HANDLING AND STORAGE
Handling: Keep away from heat, spark and flame. Do not breathe mist or vapors. Keep container closed. Avoid
contact with eyes, skin and clothing. Wash thoroughly after handling.
Storage: Store in original container until ready to use. Keep in a cool, well ventilated area away from heat,
sparks and open flame. Keep container tightly closed until ready for use.
Incompatible products: Refer to Section 10.
For information on product shelf life contact Henkel Customer Service at (800) 243-4874.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Engineering controls: Use local exhaust ventilation to maintain airborne concentrations below established exposure limits.
Respiratory protection: Use a NIOSH approved air-purifying respirator if the potential to exceed established exposure limits
exists.
Skin protection: Chemical resistant, impermeable gloves.
Eye/face protection: Chemical splash goggles or safety glasses with side shields.
See Section 2 for exposure limits.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical state: Paste
Color: Black
Odor: Mercaptan
Vapor pressure: Nil
pH: Not applicable
Boiling point/range: Greater than 149掳C (300掳F)
Melting point/range: Not available
Specific gravity: 1.40
Vapor density: Not available
Evaporation rate: Not available
Solubility in water: Slightly soluble
Partition coefficient (n-octanol/water): Not available
VOC content: 14.3%; 200 grams/liter 0.038% (value for resin and hardener together)
10. STABILITY AND REACTIVITY
Stability: Stable
Hazardous polymerization: Will not occur.
Hazardous decomposition products: None
Incompatability: Strong acids. Strong bases. Strong oxidizers.
Conditions to avoid: Excessive heat. Storage with incompatible materials.
11. TOXICOLOGICAL INFORMATION
Carcinogen Status
Item number: 21426_HARDENER Product name: FAST CURE MIXER CUPS 1 OZ CAN
3 of 5
Hazardous components NTP Carcinogen IARC Carcinogen OSHA Carcinogen
Alumina trihydrate No No No
21645-51-2
Polymercaptan hardener No No No
Phenol, 2,4,6- No No No
tris[(dimethylamino)methyl]
90-72-2
Aromatic plasticizer No No No
64741-81-7
Styrene monomer No Group 2B No
100-42-5
Silica, amorphous, fumed, No No No
crystalline-free
112945-52-5
Ethylene glycol No No No
107-21-1
Benz{a}anthracene Suspect Carcinogen Group 2A No
56-55-3
Literature Referenced Target Organ & Other Health Effects
Hazardous components Health Effects/Target Organs
Alumina trihydrate Irritant, Lung, Respiratory
21645-51-2
Polymercaptan hardener No data
Phenol, 2,4,6- Allergen, Irritant
tris[(dimethylamino)methyl]
90-72-2
Aromatic plasticizer No Target Organs
64741-81-7
Styrene monomer Blood, Ear, Eyes, Irritant, Liver, Mutagen, Nervous System, Some evidence of carcinogenicity
100-42-5
Silica, amorphous, fumed, Nuisance dust
crystalline-free
112945-52-5
Ethylene glycol Blood, Bone Marrow, Central nervous system, Developmental, Eyes, Irritant, Kidney, Liver, Metabolic
107-21-1
Benz{a}anthracene Blood, Immune system, Irritant, Liver, Mutagen, Respiratory, Skin, Some evidence of carcinogenicity
56-55-3
12. ECOLOGICAL INFORMATION
Ecological information: Not available
13. DISPOSAL CONSIDERATIONS
Information provided is for unused product only.
Recommended method of disposal: Dispose according to EPA and local governmental regulations.
EPA hazardous waste number: Not a RCRA hazardous waste.
14. TRANSPORT INFORMATION
The shipping classifications in this section are for non-bulk packaging only (unless otherwise specified). Shipping classiciation may be
different for bulk packaging.
U.S. Department of Transportation Ground (49 CFR):
Proper shipping name: Not regulated
Hazard class or division: None
Identification number: None
Packing group: None
International Air Transportation (ICAO/IATA):
Proper shipping name: Not regulated
Hazard class or division: None
Item number: 21426_HARDENER Product name: FAST CURE MIXER CUPS 1 OZ CAN
4 of 5
Identification number: None
Packing group: None
WaterTransportation (IMO/IMDG):
Proper shipping name: Not regulated
Hazard class or division: None
Identification number: None
Packing group: None
Marine pollutant: None known
15. REGULATORY INFORMATION
United States Regulatory Information
TSCA 8 (b) Inventory Status: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory.
TSCA 12 (b) Export Notification: None.
CERCLA/SARA Section 302 EHS: None above reporting de minimus.
CERCLA/SARA Section 311/312: Immediate Health Hazard
CERCLA/SARA 313: Ethylene glycol (CAS# 107-21-1) . Styrene monomer (CAS# 100-42-5) .
California Proposition 65: This product contains a chemical known to the State of California to cause cancer. 1,4-Dioxane (CAS#
123-91-1). Acetaldehyde (CAS# 75-07-0). Ethylene oxide (CAS# 75-21-8). Benz{a}anthracene (56-55-
3). Formaldehyde (CAS# 50-00-0). Benzene (CAS# 71-43-2).
Canada Regulatory Information
CEPA DSL/NDSL Status: Contains one or more components listed on the Non-Domestic Substances list.
WHMIS hazard class: D.2.B
16. OTHER INFORMATION
This material safety data sheet contains changes from the previous version in sections: Revised to new format.
Prepared by: Gary Pierson, Health and Regulatory Affairs Specialist
DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation
does not assume responsibility for any results obtained by persons over whose methods Henkel Corporation has no control. It is the
user's responsibility to determine the suitability of Henkel's products or any production methods mentioned herein for a particular
purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be
involved in the handling and use of any of Henkel Corporation's products. In light of the foregoing, Henkel Corporation specifically
disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale
or use of Henkel Corporation's products. Henkel Corporation further disclaims any liability for consequential or incidental damages of
any kind, including lost profits.
Item number: 21426_HARDENER Product name: FAST CURE MIXER CUPS 1 OZ CAN
5 of 5
|