Page 1/6
Material Safety Data Sheet
According to 91/155 EEC
Printing date 17.12.2004 Reviewed on 17.12.2004
* 1 Identification of substance:
路 Product details: Reagent for water analysis
路 Product name: DPD 1 Reagent
路 Catalog number: 471020, 471021, 471026
路 Supplier:
Tintometer GmbH
Schleefstra脽e 8a-12
D - 44287 Dortmund phone: +49(0)231 94510-0
Made in Germany
路 Informing department: Department Laboratory
路 Emergency information:
Poison Center Berlin, Germany
phone: +49(0)30 19240
* 2 Composition/Data on components:
路 Chemical characterization
路 Description: Mixture of the substances listed below with harmless additions.
路 Dangerous components:
CAS: 7664-93-9 sulphuric acid C; R 35 10-20%
EINECS: 231-639-5
EC Number: 016-020-00-8
CAS: 6283-63-2 N,N-diethylbenzene-1,4-diammonium sulphate Xn; R 20/21/22-36 鈮? 2.5%
EINECS: 228-500-6
路 Additional information For the wording of the listed risk phrases refer to section 16.
* 3 Hazards identification
路 Hazard designation:
Xi Irritant
路 Information pertaining to particular dangers for man and environment
The product has to be labelled due to the calculation procedure of the "General Classification guideline for preparations of the
EU" in the latest valid version.
R 36/38 Irritating to eyes and skin.
路 Classification system
The classification is in line with current EC lists. It is expanded, however, by information from technical literature and by
information furnished by supplier companies.
* 4 First aid measures
路 General information Instantly remove any clothing soiled by the product.
路 After inhalation Supply fresh air and call for doctor for safety reasons.
路 After skin contact Instantly wash with water and soap and rinse thoroughly.
(Contd. on page 2)
GB
DR
Page 2/6
Material Safety Data Sheet
According to 91/155 EEC
Printing date 17.12.2004 Reviewed on 17.12.2004
Product name: DPD 1 Reagent
(Contd. of page 1)
路 After eye contact
Rinse opened eye for several minutes under running water.
Call a doctor immediately.
路 After swallowing
Seek medical treatment.
Rinse out mouth and then drink plenty of water.
路 The following symptoms may occur:
after inhalation:
coughing
mucous membrane irritation
breathing difficulty
After swallowing of large amounts:
Danger of gastric perforation.
* 5 Fire fighting measures
路 Suitable extinguishing agents
CO2, extinguishing powder or water jet. Fight larger fires with water jet or alcohol-resistant foam.
路 Special hazards caused by the material, its products of combustion or resulting gases:
Formation of toxic gases is possible during heating or in case of fire.
nitrous gases
Sulphur oxides (SOx)
路 Protective equipment: Wear self-contained breathing apparatus.
路 Additional information
Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.
Collect contaminated fire fighting water separately. It must not enter drains.
* 6 Accidental release measures
路 Person-related safety precautions:
Wear protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
路 Measures for environmental protection: Do not allow product to reach sewage system or water bodies.
路 Measures for cleaning/collecting:
Ensure adequate ventilation.
Neutralize with diluted sodium hydroxide solution or by throwing on lime sand, lime or sodium carbonate.
Absorb with liquid-binding material (sand, diatomite, universal binders).
* 7 Handling and storage
路 Handling
路 Information for safe handling: Keep away from heat and direct sunlight.
路 Information about protection against explosions and fires:
Protect from heat.
The product is not flammable
路 Storage
路 Requirements to be met by storerooms and containers: Store in cool location.
路 Information about storage in one common storage facility: Store away from metals.
路 Further information about storage conditions:
Keep container tightly sealed.
Store under dry conditions.
路 Storage class Not required.
GB
(Contd. on page 3)
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Page 3/6
Material Safety Data Sheet
According to 91/155 EEC
Printing date 17.12.2004 Reviewed on 17.12.2004
Product name: DPD 1 Reagent
(Contd. of page 2)
* 8 Exposure controls and personal protection
路 Additional information about design of technical systems: No further data; see item 7.
路 Components with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace.
路 Additional information: The lists that were valid during the compilation were used as basis.
路 Personal protective equipment
路 General protective and hygienic measures
Keep away from foodstuffs, beverages and food.
Take off immediately all contaminated clothing
Wash hands during breaks and at the end of the work.
Do not inhale gases / fumes / aerosols.
Avoid contact with the eyes and skin.
Do not eat, drink or smoke while working.
路 Breathing equipment: Use breathing protection against the effects of fumes/dust/aerosol.
路 Recommended filter device for short term use: Filter B
路 Protection of hands:
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Preventive skin protection by use of skin-protecting agents is recommended.
After use of gloves apply skin-cleaning agents and skin cosmetics.
路 Material of gloves
Natural rubber, NR
PVC or PE gloves
nitrile rubber, NBR
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from
manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not
be calculated in advance and has therefore to be checked prior to the application.
Recommended thickness of the material: 鈮? 0.11 mm
路 Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed.
Wert f眉r die Permeation: Level = 6 ( 480 min )
路 Eye protection: Tightly sealed safety glasses.
路 Body protection: Light weight protective clothing
* 9 Physical and chemical properties:
Fluid
路 Form:
Colourless
路 Colour:
Odourless
路 Odour:
路 Melting point/Melting range: Not determined
路 Boiling point/Boiling range: 100掳C
Not applicable
路 Flash point:
Product is not selfigniting.
路 Self-inflammability:
Product is not explosive.
路 Danger of explosion:
23.0 hPa
路 Vapour pressure at 20掳C:
1.095 g/cm鲁
路 Density at 20掳C
路 Solubility in / Miscibility with
Fully miscible
Water:
0.1
路 pH-value at 20掳C:
路 Solvent content:
0.0 %
Organic solvents:
< 90 %
Water:
(Contd. on page 4)
GB
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Material Safety Data Sheet
According to 91/155 EEC
Printing date 17.12.2004 Reviewed on 17.12.2004
Product name: DPD 1 Reagent
(Contd. of page 3)
>1%
路 Solids content:
* 10 Stability and reactivity
路 Thermal decomposition / conditions to be avoided: To avoid thermal decomposition do not overheat.
路 Materials to be avoided:
ammonia
alkalis
acids
metals
combustible substances
organic solvents
路 Dangerous reactions
Corrosive action on metals
Reacts with metals forming hydrogen
Reacts with organic substances
路 Dangerous products of decomposition:
nitrous gases
Sulphur oxides (SOx)
see chapter 5
* 11 Toxicological information
路 Acute toxicity: Quantitative data on the toxicity of the preparation are not available.
路 LD/LC50 values that are relevant for classification:
7664-93-9 sulphuric acid
Oral LD50 2140 (25%) mg/kg (rat)
Inhalative LC 50 510 (pure) mg/m鲁/2h (rat)
6283-63-2 N,N-diethylbenzene-1,4-diammonium sulphate
Oral LD50 497 mg/kg (rat)
路 Primary irritant effect:
路 on the skin: Irritant to skin and mucous membranes.
路 on the eye: Irritant effect.
路 Sensitization: No sensitizing effect known.
路 Additional toxicological information:
The product shows the following dangers according to the calculation method of the General EC Classification Guidelines for
Preparations as issued in the latest version:
Irritant
* 12 Ecological information:
路 Information about elimination (persistence and degradability):
路 Other information: Quantitative data on the ecological effect of this product are not available.
路 Ecotoxical effects:
路 Acquatic toxicity:
7664-93-9 sulphuric acid
Daphnia EC50 29 mg/l/24h (Daphnia magna)
路 Remark:
Forms corrosive mixtures with water even if diluted.
Toxic for algae
路 Remark: neutralization possible
(Contd. on page 5)
GB
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Material Safety Data Sheet
According to 91/155 EEC
Printing date 17.12.2004 Reviewed on 17.12.2004
Product name: DPD 1 Reagent
(Contd. of page 4)
路 General notes:
Water hazard class 2 (German Regulation) (Self-assessment): hazardous for water.
Do not allow product to reach ground water, water bodies or sewage system.
Rinse off of bigger amounts into drains or the aquatic environment may lead to decreased pH-values. A low pH-value harms
aquatic organisms.
* 13 Disposal considerations
路 Product:
路 Recommendation Hand over to disposers of hazardous waste.
路 European waste catalogue
16 05 06 laboratory chemicals, consisting of or containing dangerous substances, including mixtures of laboratory chemicals
路 Uncleaned packagings:
路 Recommendation: Disposal must be made according to official regulations.
路 Recommended cleaning agent: Water, if necessary with cleaning agent.
* 14 Transport information
路 Land transport ADR/RID (cross-border)
路 ADR/RID-GGVS/E Class: 8 (C1) Corrosive substances.
80
路 Kemler Number:
3264
路 UN-Number:
III
路 Packaging group:
8
路 Label
3264 CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. (SULPHURIC ACID)
路 Designation of goods:
路 Maritime transport IMDG:
8
路 IMDG Class:
3264
路 UN Number:
8
路 Label
III
路 Packaging group:
F-A,S-B
路 EMS Number:
No
路 Marine pollutant:
CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. (SULPHURIC ACID)
路 Correct technical name:
路 Air transport ICAO-TI and IATA-DGR:
8
路 ICAO/IATA Class:
3264
路 UN/ID Number:
8
路 Label
III
路 Packaging group:
(Contd. on page 6)
GB
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Page 6/6
Material Safety Data Sheet
According to 91/155 EEC
Printing date 17.12.2004 Reviewed on 17.12.2004
Product name: DPD 1 Reagent
(Contd. of page 5)
CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. (SULPHURIC ACID)
路 Correct technical name:
* 15 Regulatory information
路 Designation according to EC guidelines:
The product has been classified and labelled in accordance with EC Directives / Ordinance on Hazardous Materials (GefStoffV)
路 Code letter and hazard designation of product:
Xi Irritant
路 Risk phrases:
36/38 Irritating to eyes and skin.
路 Safety phrases:
20 When using do not eat or drink.
23 Do not breathe fumes/aerosol.
25 Avoid contact with eyes.
26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
27/28 After contact with skin, take off immediately all contaminated clothing, and wash immediately with plenty of water.
36/37/39 Wear suitable protective clothing, gloves and eye/face protection.
45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
60 This material and its container must be disposed of as hazardous waste.
16 Other information
These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product features
and shall not establish a legally valid contractual relationship.
路 Relevant R-phrases
20/21/22 Harmful by inhalation, in contact with skin and if swallowed.
35 Causes severe burns.
36 Irritating to eyes.
路 Department issuing data specification sheet: Technical Department
路 * Data compared to the previous version altered.
GB
DR
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