Page 1/6
Material Safety Data Sheet
According to 91/155 EEC
Printing date 01.12.2004 Reviewed on 01.12.2004
* 1 Identification of substance:
路 Product details: Reagent for water analysis
路 Product name: Sulfide No.2
路 Catalog number: 502940
路 Supplier:
Tintometer GmbH
Schleefstra脽e 8a-12
D - 44287 Dortmund phone: +49(0)231 94510-0
Made in Germany
路 Informing department: Department Laboratory
路 Emergency information:
Poison Center Berlin, Germany
phone: +49(0)30 19240
* 2 Composition/Data on components:
路 Chemical characterization
路 Description: Mixture of the substances listed below with harmless additions.
路 Dangerous components:
CAS: 10034-88-5 sodium hydrogensulphate Xi; R 41 60-70%
EINECS: 231-665-7
EC Number: 016-046-00-X
CAS: 124-04-9 adipic acid Xi; R 36 10-20%
EINECS: 204-673-3
EC Number: 607-144-00-9
路 Additional information For the wording of the listed risk phrases refer to section 16.
* 3 Hazards identification
路 Hazard designation:
Xi Irritant
路 Information pertaining to particular dangers for man and environment
The product has to be labelled due to the calculation procedure of the "General Classification guideline for preparations of the
EU" in the latest valid version.
R 41 Risk of serious damage to eyes.
路 Classification system
The classification is in line with current EC lists. It is expanded, however, by information from technical literature and by
information furnished by supplier companies.
* 4 First aid measures
路 General information Instantly remove any clothing soiled by the product.
路 After inhalation Supply fresh air and call for doctor for safety reasons.
(Contd. on page 2)
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Page 2/6
Material Safety Data Sheet
According to 91/155 EEC
Printing date 01.12.2004 Reviewed on 01.12.2004
Product name: Sulfide No.2
(Contd. of page 1)
路 After skin contact
Instantly rinse with water.
If skin irritation continues, consult a doctor.
路 After eye contact
Rinse opened eye for several minutes under running water.
Call a doctor immediately.
路 After swallowing
Rinse out mouth and then drink plenty of water.
Do not induce vomiting; instantly call for medical help.
路 The following symptoms may occur:
after absorption:
allergic reactions
after inhalation:
breathing difficulty
mucous membrane irritation
after swallowing:
gastric or intestinal trouble
路 Danger Danger of gastric perforation.
* 5 Fire fighting measures
路 Suitable extinguishing agents
Water
Foam
Use fire fighting measures that suit the environment.
路 Special hazards caused by the material, its products of combustion or resulting gases:
Formation of toxic gases is possible during heating or in case of fire.
Sulphur oxides (SOx)
路 Protective equipment:
Wear full protective suit.
Wear self-contained breathing apparatus.
路 Additional information
Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.
Collect contaminated fire fighting water separately. It must not enter drains.
* 6 Accidental release measures
路 Person-related safety precautions:
Wear protective equipment. Keep unprotected persons away.
Use breathing protection against the effects of fumes/dust/aerosol.
路 Measures for environmental protection:
Do not allow product to reach sewage system or water bodies.
Inform respective authorities in case product reaches water or sewage system.
路 Measures for cleaning/collecting:
Dispose of contaminated material as waste according to item 13.
Collect mechanically.
Ensure adequate ventilation.
* 7 Handling and storage
路 Handling
路 Information for safe handling:
Prevent formation of dust.
Keep containers tightly sealed.
(Contd. on page 3)
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Page 3/6
Material Safety Data Sheet
According to 91/155 EEC
Printing date 01.12.2004 Reviewed on 01.12.2004
Product name: Sulfide No.2
(Contd. of page 2)
路 Information about protection against explosions and fires:
Protect from heat.
The product is not flammable
路 Storage
路 Requirements to be met by storerooms and containers: Store in cool location.
路 Information about storage in one common storage facility: Store away from metals.
路 Further information about storage conditions:
Store under dry conditions.
Protect from humidity and keep away from water.
路 Storage class Not required.
* 8 Exposure controls and personal protection
路 Additional information about design of technical systems: No further data; see item 7.
路 Components with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace.
路 Additional information: The lists that were valid during the compilation were used as basis.
路 Personal protective equipment
路 General protective and hygienic measures
Take off immediately all contaminated clothing
Wash hands during breaks and at the end of the work.
Avoid contact with the eyes.
Do not eat, drink or smoke while working.
路 Breathing equipment: Use breathing protection against the effects of fumes/dust/aerosol.
路 Recommended filter device for short term use: Filter P1
路 Protection of hands:
Preventive skin protection by use of skin-protecting agents is recommended.
After use of gloves apply skin-cleaning agents and skin cosmetics.
路 Material of gloves
nitrile rubber, NBR
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from
manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not
be calculated in advance and has therefore to be checked prior to the application.
Recommended thickness of the material: 鈮? 0.1 mm
路 Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed.
Wert f眉r die Permeation: Level = 6 ( 480 min )
路 Eye protection: Tightly sealed safety glasses.
路 Body protection: Protective work clothing.
* 9 Physical and chemical properties:
Tablets
路 Form:
White
路 Colour:
Odourless
路 Odour:
路 Melting point/Melting range: Not determined
路 Boiling point/Boiling range: Not applicable
Not applicable
路 Flash point:
Product is not selfigniting.
路 Self-inflammability:
Product is not explosive.
路 Danger of explosion:
1.885 g/cm鲁
路 Density at 20掳C
(Contd. on page 4)
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Page 4/6
Material Safety Data Sheet
According to 91/155 EEC
Printing date 01.12.2004 Reviewed on 01.12.2004
Product name: Sulfide No.2
(Contd. of page 3)
路 Solubility in / Miscibility with
Soluble
Water:
1.7
路 pH-value (11.1 g/l) at 20掳C:
路 Solvent content:
0.0 %
Organic solvents:
100.0 %
路 Solids content:
* 10 Stability and reactivity
路 Thermal decomposition / conditions to be avoided: strong heating
路 Materials to be avoided:
metals
alcohols
路 Dangerous reactions
Corrosive action on metals
Corrodes aluminium
Liberates acid in contact with water or alcohol.
路 Dangerous products of decomposition:
Sulphur oxides (SOx)
see chapter 5
* 11 Toxicological information
路 Acute toxicity: Quantitative data on the toxicity of the preparation are not available.
路 LD/LC50 values that are relevant for classification:
10043-35-3 boric acid, crude natural, containing not more than 85 per cent of H3BO3 calculated on the dry weight
Oral LD50 2660 mg/kg (rat)
Dermal LD50 > 2000 mg/kg (rat)
124-04-9 adipic acid
Oral LD50 5700 mg/kg (rat)
路 Primary irritant effect:
路 on the skin: Irritant to skin and mucous membranes.
路 on the eye: Strong irritant with the danger of severe eye injury.
路 Sensitization: Sensitizing effect by skin contact is possible by prolonged exposure.
路 Additional toxicological information:
The product shows the following dangers according to the calculation method of the General EC Classification Guidelines for
Preparations as issued in the latest version:
Irritant
* 12 Ecological information:
路 Information about elimination (persistence and degradability):
路 Other information: Quantitative data on the ecological effect of this product are not available.
路 Behaviour in environmental systems:
10043-35-3 boric acid, crude natural, containing not more than 85 per cent of H3BO3 calculated on the dry weight
log P(o/w) 0.76 (25掳C) (.)
124-04-9 adipic acid
log P(o/w) 0.093 (25掳C) (.)
(Contd. on page 5)
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Page 5/6
Material Safety Data Sheet
According to 91/155 EEC
Printing date 01.12.2004 Reviewed on 01.12.2004
Product name: Sulfide No.2
(Contd. of page 4)
路 Ecotoxical effects:
路 Acquatic toxicity:
10043-35-3 boric acid, crude natural, containing not more than 85 per cent of H3BO3 calculated on the dry weight
EC50 133 mg/l/48h (Daphnia magna)
124-04-9 adipic acid
EC50 86 mg/l/48h (Daphnia magna)
LC50 511 mg/l/48h (Leuciscus idus)
97 mg/l/96h (Pimephales promelas)
路 Additional ecological information:
路 BSB5-value:
124-04-9 adipic acid
BSB5 0.598 g/g (-)
路 General notes:
Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for water.
Do not allow undiluted product or large quantities of it to reach ground water, water bodies or sewage system.
Must not reach sewage water or drainage ditch undiluted or unneutralized.
Rinse off of bigger amounts into drains or the aquatic environment may lead to decreased pH-values. A low pH-value harms
aquatic organisms. In the dilution of the use-level the pH-value is considerably increased, so that after the use of the product the
aqueous waste, emptied into drains, is only low water-dangerous.
* 13 Disposal considerations
路 Product:
路 Recommendation
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
Hand over to disposers of hazardous waste.
路 European waste catalogue
16 05 06 laboratory chemicals, consisting of or containing dangerous substances, including mixtures of laboratory chemicals
路 Uncleaned packagings:
路 Recommendation: Disposal must be made according to official regulations.
路 Recommended cleaning agent: Water, if necessary with cleaning agent.
* 14 Transport information
路 Land transport ADR/RID (cross-border)
路 ADR/RID-GGVS/E Class: 8 (C2) Corrosive substances.
80
路 Kemler Number:
3260
路 UN-Number:
III
路 Packaging group:
8
路 Label
2923 CORROSIVE SOLID, TOXIC, N.O.S. (sodium hydrogensulphate, potassium dichromate)
路 Designation of goods:
(Contd. on page 6)
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Page 6/6
Material Safety Data Sheet
According to 91/155 EEC
Printing date 01.12.2004 Reviewed on 01.12.2004
Product name: Sulfide No.2
(Contd. of page 5)
路 Maritime transport IMDG:
8
路 IMDG Class:
3260
路 UN Number:
8
路 Label
III
路 Packaging group:
F-A,S-B
路 EMS Number:
No
路 Marine pollutant:
CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S. (sodium hydrogensulphate)
路 Correct technical name:
路 Air transport ICAO-TI and IATA-DGR:
8
路 ICAO/IATA Class:
3260
路 UN/ID Number:
8
路 Label
III
路 Packaging group:
CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S. (sodium hydrogensulphate)
路 Correct technical name:
* 15 Regulatory information
路 Designation according to EC guidelines:
The product has been classified and labelled in accordance with EC Directives / Ordinance on Hazardous Materials (GefStoffV)
路 Code letter and hazard designation of product:
Xi Irritant
路 Risk phrases:
41 Risk of serious damage to eyes.
路 Safety phrases:
24 Avoid contact with skin.
26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
39 Wear eye/face protection.
60 This material and its container must be disposed of as hazardous waste.
路 Special designation of certain preparations:
Contains potassium dichromate, potassium chromate. May produce an allergic reaction.
16 Other information
These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product features
and shall not establish a legally valid contractual relationship.
路 Relevant R-phrases
36 Irritating to eyes.
41 Risk of serious damage to eyes.
路 Department issuing data specification sheet: Technical Department
路 * Data compared to the previous version altered.
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