Page 1/6
Material Safety Data Sheet
According to 91/155 EEC
Printing date 16.04.2007 Reviewed on 16.04.2007
1 Identification of substance:
路 Product details: Reagent for water analysis
路 Product name: Phosphate No.1 LR
路 Catalog number: 00513049, (4)513040, (4)513041, 513043
路 Supplier:
Tintometer GmbH
Schleefstra脽e 8-12
D - 44287 Dortmund phone: +49(0)231 94510-0
Made in Germany e-mail: sales@tintometer.de
路 Informing department: Department Laboratory
路 Emergency information:
Poison Center Berlin, Germany
phone: +49(0)30 19240
* 2 Composition/Data on components:
路 Description: Preparation contains anorganic and organic compounds.
路 Dangerous components:
CAS: 7681-38-1 sodium bisulfate ? Xi; R 41 50-60%
@
G
EINECS: 231-665-7
EC Number: 016-046-00-X
CAS: 124-04-9 adipic acid ? Xi; R 36 10-20%
@
G
EINECS: 204-673-3
EC Number: 607-144-00-9
? Xn, ? N; R 20/22-51/53 鈮? 0.1%
CAS: 28300-74-5 potassium antimony(III) oxide tartrate hemihydrate G
@ D
@
EINECS: 234-293-3
EC Number: 051-003-00-9
路 Additional information For the wording of the listed risk phrases refer to section 16.
3 Hazards identification
路 Hazard designation:
G
@
? Xi Irritant
路 Information pertaining to particular dangers for man and environment
The product has to be labelled due to the calculation procedure of the "General Classification guideline for preparations of the
EU" (1999/45/EC) in the latest valid version.
R 41 Risk of serious damage to eyes.
* 4 First aid measures
路 General information Instantly remove any clothing soiled by the product.
路 After inhalation Supply fresh air; consult doctor in case of symptoms.
路 After skin contact Instantly wash with water and soap and rinse thoroughly.
(Contd. on page 2)
GB
DR
Page 2/6
Material Safety Data Sheet
According to 91/155 EEC
Printing date 16.04.2007 Reviewed on 16.04.2007
Product name: Phosphate No.1 LR
(Contd. of page 1)
路 After eye contact
Rinse opened eye for several minutes (at least 10 min) under running water.
Call a doctor immediately.
路 After swallowing
Seek medical treatment.
Rinse out mouth and then drink plenty of water.
路 The following symptoms may occur:
after inhalation:
mucous membrane irritation
coughing
breathing difficulty
after swallowing:
gastric or intestinal trouble
sickness
vomiting
cramps
ataxia (impaired locomotor coordination)
drop in temperature
5 Fire fighting measures
路 Suitable extinguishing agents Use fire fighting measures that suit the environment.
路 Special hazards caused by the material, its products of combustion or resulting gases:
Formation of toxic gases is possible during heating or in case of fire.
Sulphur oxides (SOx)
路 Protective equipment:
Wear self-contained breathing apparatus.
Wear full protective suit.
路 Additional information
Ambient fire may liberate hazardous vapours.
Collect contaminated fire fighting water separately. It must not enter drains.
Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.
* 6 Accidental release measures
路 Person-related safety precautions:
Wear protective equipment. Keep unprotected persons away.
Avoid causing dust.
Use breathing protection against the effects of fumes/dust/aerosol.
路 Measures for environmental protection: Do not allow product to reach sewage system or water bodies.
路 Measures for cleaning/collecting:
Dispose of contaminated material as waste according to item 13.
Collect mechanically.
Ensure adequate ventilation.
* 7 Handling and storage
路 Handling
路 Information about protection against explosions and fires: The product is not flammable
路 Storage
路 Requirements to be met by storerooms and containers: Store in cool location.
路 Information about storage in one common storage facility: Not required.
路 Further information about storage conditions:
Protect from heat and direct sunlight.
Store under dry conditions.
(Contd. on page 3)
GB
DR
Page 3/6
Material Safety Data Sheet
According to 91/155 EEC
Printing date 16.04.2007 Reviewed on 16.04.2007
Product name: Phosphate No.1 LR
(Contd. of page 2)
Protect from humidity and keep away from water.
This product is hygroscopic.
Protect from the effects of light.
* 8 Exposure controls and personal protection
路 Additional information about design of technical systems: No further data; see item 7.
路 Components with limit values that require monitoring at the workplace:
28300-74-5 potassium antimony(III) oxide tartrate hemihydrate
WEL (Great Britain) Long-term value: 0.5 mg/m鲁
as Sb
路 Additional information: The lists that were valid during the compilation were used as basis.
路 Personal protective equipment
路 General protective and hygienic measures
Take off immediately all contaminated clothing
Wash hands during breaks and at the end of the work.
Avoid contact with the eyes.
Do not eat, drink or smoke while working.
路 Breathing equipment: Use breathing protection against the effects of fumes/dust/aerosol.
路 Recommended filter device for short term use: Filter P2
路 Protection of hands:
Preventive skin protection by use of skin-protecting agents is recommended.
After use of gloves apply skin-cleaning agents and skin cosmetics.
路 Material of gloves
nitrile rubber, NBR
Recommended thickness of the material: 鈮? 0.11 mm
路 Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed.
Value for the permeation: Level 鈮? 6 (480 min)
路 Eye protection: Tightly sealed safety glasses.
路 Body protection: Protective work clothing.
* 9 Physical and chemical properties:
Tablets
路 Form:
White
路 Colour:
Odourless
路 Odour:
路 Melting point/Melting range: Not determined
路 Boiling point/Boiling range: 265掳C
> 100掳C
路 Flash point:
Product is not explosive.
路 Danger of explosion:
1.815 g/cm鲁
路 Density at 20掳C
路 Solubility in / Miscibility with
Soluble
Water:
1.13
路 pH-value (4.75 g/l) at 20掳C:
路 Solvent content:
0.0 %
Organic solvents:
(Contd. on page 4)
GB
DR
Page 4/6
Material Safety Data Sheet
According to 91/155 EEC
Printing date 16.04.2007 Reviewed on 16.04.2007
Product name: Phosphate No.1 LR
(Contd. of page 3)
100.0 %
路 Solids content:
10 Stability and reactivity
路 Thermal decomposition / conditions to be avoided: To avoid thermal decomposition do not overheat.
路 Materials to be avoided:
alkalis
metals
alcohols
oxidizing agents
路 Dangerous reactions
Reacts with alcohols
Reacts with certain metals
Forms hydrogen in aqueous solution with metals
Liberates acid in contact with water or alcohol.
路 Dangerous products of decomposition:
Sulphur oxides (SOx)
see chapter 5
* 11 Toxicological information
路 Acute toxicity: Quantitative data on the toxicity of the preparation are not available.
路 LD/LC50 values that are relevant for classification:
10043-35-3 boric acid, crude natural, containing not more than 85 per cent of H3BO3 calculated on the dry weight
Oral LD50 2660 mg/kg (rat)
Dermal LD50 > 2000 mg/kg (rat)
124-04-9 adipic acid
Oral LD50 5700 mg/kg (rat)
50-81-7 ascorbic acid
Oral LD50 11900 mg/kg (rat)
路 Primary irritant effect:
路 on the skin: Irritant to skin and mucous membranes.
路 on the eye: Strong irritant with the danger of severe eye injury.
路 Sensitization: No sensitizing effect known.
路 Subacute to chronic toxicity:
CAS-No. 10043-35-3:
MERCK: Sensitization test (guinea pig): negative (OECD 406)
CAS-No. 124-04-9:
Sensitization test (guinea pig): negative (IUCLID)
路 Additional toxicological information:
The product shows the following dangers according to the calculation method of the General EC Classification Guidelines for
Preparations as issued in the latest version:
Irritant
* 12 Ecological information:
路 Information about elimination (persistence and degradability):
路 Other information:
Quantitative data on the ecological effect of this product are not available.
The following statements refer to the individual components.
CAS-No. 124-04-9: 100% / 28 d
(Contd. on page 5)
GB
DR
Page 5/6
Material Safety Data Sheet
According to 91/155 EEC
Printing date 16.04.2007 Reviewed on 16.04.2007
Product name: Phosphate No.1 LR
(Contd. of page 4)
路 Behaviour in environmental systems:
10043-35-3 boric acid, crude natural, containing not more than 85 per cent of H3BO3 calculated on the dry weight
log P(o/w) 0.76 (25掳C) (.)
124-04-9 adipic acid
log P(o/w) 0.093 (25掳C) (.)
50-81-7 ascorbic acid
log P(o/w) -2.15 (.)
路 Ecotoxical effects:
路 Acquatic toxicity:
10043-35-3 boric acid, crude natural, containing not more than 85 per cent of H3BO3 calculated on the dry weight
EC50 133 mg/l/48h (Daphnia magna)
LC50 5600 mg/l/96h (Gambusia affinis)
124-04-9 adipic acid
EC50 86 mg/l/48h (Daphnia magna)
LC50 511 mg/l/48h (Leuciscus idus)
97 mg/l/96h (Pimephales promelas)
50-81-7 ascorbic acid
LC50 33000 (Merck) mg/l/48h (Leuciscus idus)
1020 mg/l/96h (Oncorhynchus mykiss)
路 Remark:
Harmful effect due to pH shift.
Toxic for fish:
sulphates > 7 g/l
Forms corrosive mixtures with water even if diluted.
路 Bacterial toxicity: sulphates toxic > 2.5 g/l
路 Additional ecological information:
路 BSB5-value:
124-04-9 adipic acid
BSB5 0.598 g/g (-)
路 General notes:
Water hazard class 1 (German Regulation) (Self-assessment acc. VwVwS Annex 4): slightly hazardous for water.
Do not allow undiluted product or large quantities of it to reach ground water, water bodies or sewage system.
Must not reach sewage water or drainage ditch undiluted or unneutralized.
Rinse off of bigger amounts into drains or the aquatic environment may lead to decreased pH-values. A low pH-value harms
aquatic organisms. In the dilution of the use-level the pH-value is considerably increased, so that after the use of the product the
aqueous waste, emptied into drains, is only low water-dangerous.
13 Disposal considerations
路 Product:
路 Recommendation Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
路 European waste catalogue
16 05 06 laboratory chemicals, consisting of or containing dangerous substances, including mixtures of laboratory chemicals
路 Uncleaned packagings:
路 Recommendation: Disposal must be made according to official regulations.
路 Recommended cleaning agent: Water, if necessary with cleaning agent.
GB
(Contd. on page 6)
DR
Page 6/6
Material Safety Data Sheet
According to 91/155 EEC
Printing date 16.04.2007 Reviewed on 16.04.2007
Product name: Phosphate No.1 LR
(Contd. of page 5)
* 14 Transport information
路 Land transport ADR/RID (cross-border)
路 ADR/RID-GGVS/E Class: -
路 Maritime transport IMDG:
-
路 IMDG Class:
No
路 Marine pollutant:
路 Air transport ICAO-TI and IATA-DGR:
-
路 ICAO/IATA Class:
路 Transport/Additional information: Not dangerous according to the above specifications.
15 Regulatory information
路 Designation according to EC guidelines:
The product has been classified and labelled in accordance with EC Directives / Ordinance on Hazardous Materials (GefStoffV)
路 Code letter and hazard designation of product:
Xi Irritant
路 Risk phrases:
41 Risk of serious damage to eyes.
路 Safety phrases:
24 Avoid contact with skin.
26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
39 Wear eye/face protection.
60 This material and its container must be disposed of as hazardous waste.
路 National regulations
路 Information about limitation of use: Employment restrictions concerning young persons must be observed.
16 Other information
These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product features
and shall not establish a legally valid contractual relationship.
路 Relevant R-phrases
20/22 Harmful by inhalation and if swallowed.
36 Irritating to eyes.
41 Risk of serious damage to eyes.
51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
路 Department issuing data specification sheet: Technical Department
路 * Data compared to the previous version altered.
GB
DR
|