Page 1/6
Material Safety Data Sheet
According to 91/155 EEC
Printing date 15.09.2005 Reviewed on 15.09.2005
* 1 Identification of substance:
路 Product details: Reagent for water analysis
路 Product name: Phosphate No.2 LR
路 Catalog number: 00513059, (4)513050, (4)513051, 513053
路 Supplier:
Tintometer GmbH
Schleefstra脽e 8a-12
D - 44287 Dortmund phone: +49(0)231 94510-0
Made in Germany
路 Informing department: Department Laboratory
路 Emergency information:
Poison Center Berlin, Germany
phone: +49(0)30 19240
* 2 Composition/Data on components:
路 Description: Preparation contains anorganic compounds.
路 Dangerous components:
CAS: 7681-57-4 disodium disulphite @ Xn; R 22-31-41 10-20%
G
EINECS: 231-673-0
EC Number: 016-063-00-2
CAS: 12054-85-2 ammonium heptamolybdate tetrahydrate 5-10%
EINECS: 234-722-4
路 Additional information For the wording of the listed risk phrases refer to section 16.
* 3 Hazards identification
路 Hazard designation:
@
G Xi Irritant
路 Information pertaining to particular dangers for man and environment
The product has to be labelled due to the calculation procedure of the "General Classification guideline for preparations of the
EU" in the latest valid version.
R 31 Contact with acids liberates toxic gas.
R 41 Risk of serious damage to eyes.
路 Classification system
The classification is in line with current EC lists. It is expanded, however, by information from technical literature and by
information furnished by supplier companies.
* 4 First aid measures
路 General information Instantly remove any clothing soiled by the product.
路 After inhalation Supply fresh air; consult doctor in case of symptoms.
路 After skin contact Instantly wash with water and soap and rinse thoroughly.
(Contd. on page 2)
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Page 2/6
Material Safety Data Sheet
According to 91/155 EEC
Printing date 15.09.2005 Reviewed on 15.09.2005
Product name: Phosphate No.2 LR
(Contd. of page 1)
路 After eye contact
Rinse opened eye for several minutes under running water.
Call a doctor immediately.
路 After swallowing
Seek medical treatment.
Drink copious amounts of water, induce vomiting.
路 The following symptoms may occur:
after inhalation:
breathing difficulty
coughing
after swallowing:
sickness
vomiting
mucous membrane irritation
gastric or intestinal trouble
* 5 Fire fighting measures
路 Suitable extinguishing agents Use fire fighting measures that suit the environment.
路 Special hazards caused by the material, its products of combustion or resulting gases:
Formation of toxic gases is possible during heating or in case of fire.
Nitrogen oxides (NOx)
Sulphur oxides (SOx)
sodium oxide
路 Protective equipment:
Wear self-contained breathing apparatus.
Wear full protective suit.
路 Additional information
Ambient fire may liberate hazardous vapours.
Collect contaminated fire fighting water separately. It must not enter drains.
Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.
* 6 Accidental release measures
路 Person-related safety precautions:
Put on breathing apparatus.
Wear protective equipment. Keep unprotected persons away.
路 Measures for environmental protection: Do not allow product to reach sewage system or water bodies.
路 Measures for cleaning/collecting:
Dispose of contaminated material as waste according to item 13.
Collect mechanically.
Ensure adequate ventilation.
* 7 Handling and storage
路 Handling
路 Information for safe handling: No special measures required.
路 Information about protection against explosions and fires: No special measures required.
路 Storage
路 Requirements to be met by storerooms and containers: Store in cool location.
路 Information about storage in one common storage facility:
Do not store together with acids.
Store away from oxidizing agents.
路 Further information about storage conditions:
Protect from heat and direct sunlight.
(Contd. on page 3)
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Page 3/6
Material Safety Data Sheet
According to 91/155 EEC
Printing date 15.09.2005 Reviewed on 15.09.2005
Product name: Phosphate No.2 LR
(Contd. of page 2)
Store under dry conditions.
Protect from humidity and keep away from water.
Protect from the effects of light.
路 Storage class Not required.
* 8 Exposure controls and personal protection
路 Additional information about design of technical systems: No further data; see item 7.
路 Components with limit values that require monitoring at the workplace:
7681-57-4 disodium disulphite
OES (Great Britain) Long-term value: 5 mg/m鲁
路 Additional information: The lists that were valid during the compilation were used as basis.
路 Personal protective equipment
路 General protective and hygienic measures
Take off immediately all contaminated clothing
Wash hands during breaks and at the end of the work.
Avoid contact with the eyes.
Do not eat, drink or smoke while working.
路 Breathing equipment: Use breathing protection against the effects of fumes/dust/aerosol.
路 Recommended filter device for short term use: Filter P2
路 Protection of hands:
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Preventive skin protection by use of skin-protecting agents is recommended.
After use of gloves apply skin-cleaning agents and skin cosmetics.
路 Material of gloves
nitrile
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from
manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not
be calculated in advance and has therefore to be checked prior to the application.
Recommended thickness of the material: 鈮? 0.11 mm
路 Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed.
Value for the permeation: Level 鈮? 6 (480 min)
路 Eye protection: Tightly sealed safety glasses.
路 Body protection: Protective work clothing.
* 9 Physical and chemical properties:
Tablets
路 Form:
White
路 Colour:
Odourless
路 Odour:
路 Melting point/Melting range: Not determined
路 Boiling point/Boiling range: 300掳C
Not applicable
路 Flash point:
Product is not explosive.
路 Danger of explosion:
1.549 g/cm鲁
路 Density at 20掳C
路 Solubility in / Miscibility with
Soluble
Water:
4.72
路 pH-value (10.1 g/l) at 20掳C:
(Contd. on page 4)
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Material Safety Data Sheet
According to 91/155 EEC
Printing date 15.09.2005 Reviewed on 15.09.2005
Product name: Phosphate No.2 LR
(Contd. of page 3)
路 Solvent content:
0.0 %
Organic solvents:
100.0 %
路 Solids content:
* 10 Stability and reactivity
路 Thermal decomposition / conditions to be avoided: To avoid thermal decomposition do not overheat.
路 Materials to be avoided:
acids
oxidizing agents
--> forms heat
路 Dangerous reactions Contact with acids releases toxic gases
路 Dangerous products of decomposition:
Sulphur dioxide
Carbon monoxide and carbon dioxide
Nitrogen oxides (NOx)
Sulphur oxides (SOx)
see chapter 5
* 11 Toxicological information
路 Acute toxicity: Quantitative data on the toxicity of the preparation are not available.
路 LD/LC50 values that are relevant for classification:
10043-35-3 boric acid, crude natural, containing not more than 85 per cent of H3BO3 calculated on the dry weight
Oral LD50 2660 mg/kg (rat)
Dermal LD50 > 2000 mg/kg (rat)
7681-57-4 disodium disulphite
Oral LD50 1540 mg/kg (rat)
12054-85-2 ammonium heptamolybdate tetrahydrate
Oral LD50 3883 mg/kg (rat)
Dermal LD50 > 2000 mg/kg (rabbit)
路 Primary irritant effect:
路 on the skin: Irritant to skin and mucous membranes.
路 on the eye: Strong irritant with the danger of severe eye injury.
路 Sensitization: No sensitizing effect known.
路 Subacute to chronic toxicity:
CAS-No. 10043-35-3:
MERCK: Sensitization test (guinea pig): negative (OECD 406)
路 Experience with humans:
molybdenum(VI):
Can cause liver damages.
Can cause kidney damages.
路 Additional toxicological information:
The product shows the following dangers according to the calculation method of the General EC Classification Guidelines for
Preparations as issued in the latest version:
Irritant
* 12 Ecological information:
路 Information about elimination (persistence and degradability):
路 Other information: Quantitative data on the ecological effect of this product are not available.
(Contd. on page 5)
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Material Safety Data Sheet
According to 91/155 EEC
Printing date 15.09.2005 Reviewed on 15.09.2005
Product name: Phosphate No.2 LR
(Contd. of page 4)
路 Behaviour in environmental systems:
10043-35-3 boric acid, crude natural, containing not more than 85 per cent of H3BO3 calculated on the dry weight
log P(o/w) 0.76 (25掳C) (.)
路 Mobility and bioaccumulation potential:
Depending on the concetration, nitrogen compounds may contribute to the eutrophication of water supplies.
路 Ecotoxical effects:
路 Acquatic toxicity:
10043-35-3 boric acid, crude natural, containing not more than 85 per cent of H3BO3 calculated on the dry weight
EC50 133 mg/l/48h (Daphnia magna)
LC50 5600 mg/l/96h (Gambusia affinis)
7681-57-4 disodium disulphite
EC50 89 mg/l/48h (Daphnia magna)
LC50 150-220 mg/l/96h (Onchorhynchus mykiss)
路 Remark:
Toxic for fish:
NH4+ > 0.3 mg/l
molybdenum compounds in general: > 25 mg/l
路 Algeal toxicity:
CAS No. 7681-57-4 Desmodesmus subspicatus IC50: 48mg/l/72 h
molybdenum compounds: Sc. quadricauda toxic from 54 mg/l
7681-57-4 disodium disulphite
IC50 48 mg/l/72h (Desmodesmus subspicatus)
路 Bacterial toxicity:
CAS No. 7681-57-4 Pseudomonas putida EC50: 56 mg/l/17 h
7681-57-4 disodium disulphite
EC50 56 mg/l/17h (Pseudomonas putida)
路 Protozoa: molybdenum compounds: Microregma toxic from 27 mg/l
路 Additional ecological information:
路 CSB-value:
7681-57-4 disodium disulphite
COD 0.168 g/g (.)
路 General notes:
Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for water.
Do not allow undiluted product or large quantities of it to reach ground water, water bodies or sewage system.
Must not reach sewage water or drainage ditch undiluted or unneutralized.
* 13 Disposal considerations
路 Product:
路 Recommendation
Disposal must be made according to official regulations.
Hand over to disposers of hazardous waste.
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
路 European waste catalogue
16 05 07 discarded inorganic chemicals consisting of or containing dangerous substances
路 Uncleaned packagings:
路 Recommendation: Disposal must be made according to official regulations.
路 Recommended cleaning agent: Water, if necessary with cleaning agent.
GB
(Contd. on page 6)
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Material Safety Data Sheet
According to 91/155 EEC
Printing date 15.09.2005 Reviewed on 15.09.2005
Product name: Phosphate No.2 LR
(Contd. of page 5)
* 14 Transport information
路 Land transport ADR/RID (cross-border)
路 ADR/RID-GGVS/E Class: -
路 Maritime transport IMDG:
-
路 IMDG Class:
No
路 Marine pollutant:
路 Air transport ICAO-TI and IATA-DGR:
-
路 ICAO/IATA Class:
路 Transport/Additional information: Not dangerous according to the above specifications.
* 15 Regulatory information
路 Designation according to EC guidelines:
The product has been classified and labelled in accordance with EC Directives / Ordinance on Hazardous Materials (GefStoffV)
路 Code letter and hazard designation of product:
Xi Irritant
路 Risk phrases:
31 Contact with acids liberates toxic gas.
41 Risk of serious damage to eyes.
路 Safety phrases:
26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
39 Wear eye/face protection.
60 This material and its container must be disposed of as hazardous waste.
16 Other information
These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product features
and shall not establish a legally valid contractual relationship.
路 Relevant R-phrases
22 Harmful if swallowed.
31 Contact with acids liberates toxic gas.
41 Risk of serious damage to eyes.
路 Department issuing data specification sheet: Technical Department
路 * Data compared to the previous version altered.
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