Page 1/5
Material Safety Data Sheet
According to 91/155 EEC
Printing date 20.04.2005 Reviewed on 20.04.2005
* 1 Identification of substance:
路 Product details: Reagent for water analysis
路 Product name: DPD No.3
路 Catalog number: 00511089, (4)511080, (4)511081, 511083, (4)511082
路 Supplier:
Tintometer GmbH
Schleefstra脽e 8a-12
D - 44287 Dortmund phone: +49(0)231 94510-0
Made in Germany
路 Informing department: Department Laboratory
路 Emergency information:
Poison Center Berlin, Germany
phone: +49(0)30 19240
* 2 Composition/Data on components:
路 Description: Preparation contains anorganic compounds.
路 Dangerous components: Void
3 Hazards identification
路 Hazard designation: void
路 Information pertaining to particular dangers for man and environment
The product does not have to be labelled due to the calculation procedure of the "General Classification guideline for
preparations of the EU" in the latest valid version.
路 Classification system
The classification is in line with current EC lists. It is expanded, however, by information from technical literature and by
information furnished by supplier companies.
* 4 First aid measures
路 General information Instantly remove any clothing soiled by the product.
路 After inhalation Supply fresh air; consult doctor in case of symptoms.
路 After skin contact Instantly rinse with water.
路 After eye contact Rinse opened eye for several minutes under running water.
路 After swallowing
Drink copious amounts of water, induce vomiting.
In case of persistent symptoms consult doctor.
路 The following symptoms may occur:
After swallowing of large amounts:
sickness
vomiting
drop in blood pressure
absorption
路 Danger Danger of disturbed cardiac rhythm.
GB
(Contd. on page 2)
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Page 2/5
Material Safety Data Sheet
According to 91/155 EEC
Printing date 20.04.2005 Reviewed on 20.04.2005
Product name: DPD No.3
(Contd. of page 1)
* 5 Fire fighting measures
路 Suitable extinguishing agents Use fire fighting measures that suit the environment.
路 Special hazards caused by the material, its products of combustion or resulting gases:
Formation of toxic gases is possible during heating or in case of fire.
Hydrogen chloride (HCl)
dipotassium oxide
路 Protective equipment:
Wear self-contained breathing apparatus.
Wear full protective suit.
路 Additional information
Ambient fire may liberate hazardous vapours.
Collect contaminated fire fighting water separately. It must not enter drains.
Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.
* 6 Accidental release measures
路 Person-related safety precautions:
Avoid causing dust.
Wear protective equipment. Keep unprotected persons away.
路 Measures for environmental protection: Do not allow product to reach sewage system or water bodies.
路 Measures for cleaning/collecting:
Collect mechanically.
Ensure adequate ventilation.
Dispose of contaminated material as waste according to item 13.
路 Additional information: No dangerous materials are released.
* 7 Handling and storage
路 Handling
路 Information for safe handling: No special measures required.
路 Information about protection against explosions and fires: The product is not flammable
路 Storage
路 Requirements to be met by storerooms and containers: Store in cool location.
路 Information about storage in one common storage facility: Not required.
路 Further information about storage conditions:
Store under dry conditions.
Protect from humidity and keep away from water.
Protect from the effects of light.
Protect from heat and direct sunlight.
路 Storage class Not required.
* 8 Exposure controls and personal protection
路 Additional information about design of technical systems: No further data; see item 7.
路 Components with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace.
路 Additional information: The lists that were valid during the compilation were used as basis.
路 Personal protective equipment
路 General protective and hygienic measures
Do not eat, drink or smoke while working.
Wash hands during breaks and at the end of the work.
路 Breathing equipment: Use breathing protection against the effects of fumes/dust/aerosol.
路 Recommended filter device for short term use: Filter P1
路 Protection of hands: Preventive skin protection by use of skin-protecting agents is recommended.
(Contd. on page 3)
GB
DR
Page 3/5
Material Safety Data Sheet
According to 91/155 EEC
Printing date 20.04.2005 Reviewed on 20.04.2005
Product name: DPD No.3
(Contd. of page 2)
路 Material of gloves
nitrile
Recommended thickness of the material: 鈮? 0.11 mm
路 Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed.
Value for the permeation: Level 鈮? 6 (480 min)
路 Eye protection: Safety glasses
路 Body protection: Protective work clothing.
* 9 Physical and chemical properties:
Tablets
路 Form:
White
路 Colour:
Odourless
路 Odour:
路 Melting point/Melting range: Not determined
路 Boiling point/Boiling range: 1330掳C
Not applicable
路 Flash point:
Product is not selfigniting.
路 Self-inflammability:
Product is not explosive.
路 Danger of explosion:
2.160 g/cm鲁
路 Density at 20掳C
路 Solubility in / Miscibility with
Soluble
Water:
6.3
路 pH-value (13 g/l) at 20掳C:
路 Solvent content:
0.0 %
Organic solvents:
100.0 %
路 Solids content:
* 10 Stability and reactivity
路 Thermal decomposition / conditions to be avoided: To avoid thermal decomposition do not overheat.
路 Materials to be avoided:
acids
oxidizing agents
--> forms heat
路 Dangerous products of decomposition: see chapter 5
* 11 Toxicological information
路 Acute toxicity: Quantitative data on the toxicity of the preparation are not available.
路 LD/LC50 values that are relevant for classification:
7447-40-7 potassium chloride
Oral LD50 2600 mg/kg (rat)
7681-11-0 potassium iodide
Oral LD50 2779 mg/kg (rat)
路 Primary irritant effect:
路 on the skin: No irritant effect.
路 on the eye: Irritant effect.
路 Sensitization: Sensitizing effect by skin contact is possible by prolonged exposure.
(Contd. on page 4)
GB
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Page 4/5
Material Safety Data Sheet
According to 91/155 EEC
Printing date 20.04.2005 Reviewed on 20.04.2005
Product name: DPD No.3
(Contd. of page 3)
路 Additional toxicological information:
The product is not subject to classification according to the calculation method of the General EC Classification Guidelines for
Preparations as issued in the latest version.
When used and handled according to specifications, the product does not have any harmful effects according to our experience
and the information provided to us.
The usual precautionary measures should be adhered to general rules for handling chemicals.
* 12 Ecological information:
路 Information about elimination (persistence and degradability):
路 Other information:
Methods for the determination of biodegradability are not applicable to inorganic substances.
Quantitative data on the ecological effect of this product are not available.
路 Behaviour in environmental systems:
7447-40-7 potassium chloride
log P(o/w) - 0.46 (.)
路 Ecotoxical effects:
路 Acquatic toxicity:
7447-40-7 potassium chloride
EC50 825 mg/l/48h (Daphnia magna)
LC50 920 mg/l/96h (Gambusia affinis)
7681-11-0 potassium iodide
Daphnia EC50 2.7 mg/l/24h (Daphnia magna)
路 General notes:
Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for water.
Do not allow undiluted product or large quantities of it to reach ground water, water bodies or sewage system.
Must not reach sewage water or drainage ditch undiluted or unneutralized.
* 13 Disposal considerations
路 Product:
路 Recommendation Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
路 European waste catalogue
16 05 09 discarded chemicals other than those mentioned in 16 05 06, 16 05 07 or 16 05 08
路 Uncleaned packagings:
路 Recommendation: Disposal must be made according to official regulations.
路 Recommended cleaning agent: Water, if necessary with cleaning agent.
* 14 Transport information
路 Land transport ADR/RID (cross-border)
路 ADR/RID-GGVS/E Class: -
路 Maritime transport IMDG:
-
路 IMDG Class:
No
路 Marine pollutant:
路 Air transport ICAO-TI and IATA-DGR:
-
路 ICAO/IATA Class:
(Contd. on page 5)
GB
DR
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Material Safety Data Sheet
According to 91/155 EEC
Printing date 20.04.2005 Reviewed on 20.04.2005
Product name: DPD No.3
(Contd. of page 4)
路 Transport/Additional information: Not dangerous according to the above specifications.
* 15 Regulatory information
路 Designation according to EC guidelines:
Observe the normal safety regulations when handling chemicals
The product is not subject to identification regulations under EC Directives and the Ordinance on Hazardous Materials
(GefStoffV).
* 16 Other information
These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product features
and shall not establish a legally valid contractual relationship.
路 Department issuing data specification sheet: Technical Department
路 * Data compared to the previous version altered.
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DR
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