MSDS: PERFECT GLUE 1 Revised: 24-May-2005
SECTION 1: IDENTIFICATION
PRODUCT IDENTIFIER: PERFECT GLUE 1
DATE OF PREPARATION: FEBRUARY 27, 2003
PRODUCT USE: ADHESIVE
MANUFACTURED BY: MACCO ADHESIVES
15885 SPRAGUE RD.
STRONGSVILLE, OHIO 44136, U.S.A.
ICI PAINTS (CANADA)
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CONCORD, ONTARIO L4K 2A5, CANADA
EMERGENCY AND MSDS TELEPHONE NUMBER: 1-800-545-2643
MSDS PREPARED BY: PRODUCT SAFETY AND TOXICOLOGY DEPARTMENT
ICI PAINTS NORTH AMERICA
SECTION 2: COMPOSITION/INFORMATION ON INGREDIENTS
INGREDIENT WT.%
CHEMICAL NAME: SILICA 10-20
COMMON NAME: SILICON DIOXIDE
CAS NUMBER: 112945-52-5
CHEMICAL NAME: POLY(OXY(METHYL-1,2-ETHANEDIYL)), .ALPHA.,.ALPHA.', 20-30
.ALPHA."-1,2,3-PROPANETRIYLTRIS(.O-(3-
(DIMETHOXYMETHYLSILYL)PROPOXY)-
COMMON NAME: SILYL TERMINATED POLYETHER
CAS NUMBER: 151865-59-7
CHEMICAL NAME: SILANE, ETHENYLTRIMETHOXY- 1-5
COMMON NAME: VINYLTRIMETHOXYSILANE
CAS NUMBER: 2768-02-7
CHEMICAL NAME: SILANE, DICHLORODIMETHYL-, REACTION PRODUCTS 1-5
WITH SILICA
COMMON NAME: SILICA
CAS NUMBER: 68611-44-9
CHEMICAL NAME: POLY(OXY(METHYL-1,2-ETHANEDIYL)), .ALPHA.-(3- 50-60
(DIMETHOXYMETHYLSILYL)PROPOXY)-
COMMON NAME: SILYL TERMINATED POLYETHER
CAS NUMBER: 75009-88-0
SECTION 3: HAZARDS IDENTIFICATION
PRIMARY ROUTE(S) OF EXPOSURE: INHALATION, SKIN CONTACT, EYE CONTACT,
INGESTION.
EFFECTS OF OVEREXPOSURE:
INHALATION: IRRITATION OF RESPIRATORY TRACT. PROLONGED INHALATION
MAY LEAD TO MUCOUS MEMBRANE IRRITATION.
SKIN CONTACT: IRRITATION OF SKIN. PROLONGED OR REPEATED CONTACT CAN
CAUSE DERMATITIS, DEFATTING.
EYE CONTACT: IRRITATION OF EYES.
INGESTION: INGESTION MAY CAUSE GASTRO-INTESTINAL DISTURBANCES.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: EYE, SKIN, RESPIRATORY
DISORDERS
SECTION 4: FIRST-AID MEASURES
INHALATION: REMOVE TO FRESH AIR. RESTORE AND SUPPORT CONTINUED
BREATHING. GET EMERGENCY MEDICAL ATTENTION. HAVE
TRAINED PERSON GIVE OXYGEN IF NECESSARY. GET MEDICAL
HELP FOR ANY BREATHING DIFFICULTY.
SKIN CONTACT: WASH THOROUGHLY WITH SOAP AND WATER. IF ANY PRODUCT
REMAINS, GENTLY RUB PETROLEUM JELLY, VEGETABLE OR
MINERAL/BABY OIL ONTO SKIN. REPEATED APPLICATIONS MAY BE
NEEDED. REMOVE CONTAMINATED CLOTHING.
EYE CONTACT: FLUSH IMMEDIATELY WITH LARGE AMOUNTS OF WATER,
ESPECIALLY UNDER LIDS FOR AT LEAST 15 MINUTES. IF
IRRITATION OR OTHER EFFECTS PERSIST, OBTAIN MEDICAL
TREATMENT.
INGESTION: IF SWALLOWED, OBTAIN MEDICAL TREATMENT IMMEDIATELY.
SECTION 5: FIRE-FIGHTING MEASURES
FLASH POINT (SETA): ABOVE 200F/93C LOWER EXPLOSIVE LIMIT: NOT AVAILABLE
UPPER EXPLOSIVE LIMIT: 19.9 %
FIRE EXTINGUISHING MEDIA:
DRY CHEMICAL OR FOAM
WATER FOG
CARBON DIOXIDE.
UNUSUAL FIRE AND EXPLOSION HAZARDS:
CLOSED CONTAINERS MAY BURST IF EXPOSED TO EXTREME HEAT OR FIRE.
FIRE FIGHTING PROCEDURES: WATER MAY BE USED TO COOL AND PROTECT EXPOSED
CONTAINERS. FIREFIGHTERS SHOULD USE FULL
PROTECTIVE CLOTHING, EYE PROTECTION, AND SELF-
CONTAINED BREATHING APPARATUS.
HAZARDOUS DECOMPOSITION OR COMBUSTION PRODUCTS: CARBON MONOXIDE
CARBON DIOXIDE
OXIDES OF SILICON
SECTION 6: ACCIDENTAL RELEASE MEASURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED:
COMPLY WITH ALL APPLICABLE HEALTH AND ENVIRONMENTAL REGULATIONS.
ELIMINATE ALL SOURCES OF IGNITION. VENTILATE AREA. EVACUATE ALL
UNNECESSARY PERSONNEL.
LARGE SPILLS: SHUT OFF LEAK IF SAFE TO DO SO. DIKE AND CONTAIN SPILL. PUMP TO
STORAGE OR SALVAGE VESSELS. USE ABSORBENT TO PICK UP EXCESS
RESIDUE. KEEP SALVAGEABLE MATERIAL AND RINSE WATER OUT OF
SEWERS AND WATER COURSES.
SMALL SPILLS: USE ABSORBENT TO PICK UP RESIDUE AND DISPOSE OF PROPERLY.
SECTION 7: HANDLING AND STORAGE
HANDLING AND STORAGE: STORE BELOW 100F (38C).
KEEP AWAY FROM DIRECT SUNLIGHT, HEAT AND ALL
SOURCES OF IGNITION. KEEP CONTAINER TIGHTLY CLOSED
IN A WELL-VENTILATED AREA.
OTHER PRECAUTIONS:
USE ONLY WITH ADEQUATE VENTILATION. DO NOT TAKE
INTERNALLY. KEEP OUT OF REACH OF CHILDREN. AVOID
CONTACT WITH SKIN AND EYES, AND BREATHING OF VAPORS.
WASH HANDS THOROUGHLY AFTER HANDLING, ESPECIALLY
BEFORE EATING OR SMOKING. KEEP CONTAINERS TIGHTLY
CLOSED AND UPRIGHT WHEN NOT IN USE. AVOID CONDITIONS
WHICH RESULT IN FORMATION OF INHALABLE PARTICLES SUCH
AS SPRAYING OR ABRADING (SANDING) PAINTED SURFACES. IF
SUCH CONDITIONS CANNOT BE AVOIDED, USE APPROPRIATE
RESPIRATORY PROTECTION AS DIRECTED UNDER EXPOSURE
CONTROLS/PERSONAL PROTECTION. GROUND EQUIPMENT WHEN
TRANSFERRING TO PREVENT ACCUMULATION OF STATIC CHARGE.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
COMMON NAME: SILICON DIOXIDE
CAS NUMBER: 112945-52-5
ACGIH(TWA): 10 MG/M3 OSHA(TWA): 6 MG/M3
RESPIRATORY PROTECTION: WHERE RESPIRATORY PROTECTION IS REQUIRED, USE
ONLY NIOSH/MSHA APPROVED RESPIRATORS IN
ACCORDANCE WITH OSHA STANDARD 29 CFR 1910.134.
VENTILATION: PROVIDE DILUTION VENTILATION OR LOCAL EXHAUST TO
PREVENT BUILD-UP OF VAPORS. USE EXPLOSION-PROOF
EQUIPMENT.
PERSONAL PROTECTIVE EQUIPMENT:EYE WASH, SAFETY SHOWER, SAFETY GLASSES OR
GOGGLES. IMPERVIOUS GLOVES, IMPERVIOUS
CLOTHING.
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
VAPOR PRESSURE: NOT AVAILABLE SPECIFIC GRAVITY: 1.089
BOILING RANGE: 252-252F/22-122C WEIGHT PER GALLON: 9.07 / 10.89 IMP
PHYSICAL STATE: PASTE APPEARANCE: CLEAR
%VOLATILE BY VOLUME: 2.60
SOLUBILITY IN WATER: N
PH: NOT AVAILABLE
SECTION 10: STABILITY AND REACTIVITY
UNDER NORMAL CONDITIONS: STABLE STABLE BELOW 212 F (100 C)
(SEE SECTION 5: FIRE FIGHTING MEASURES)
MATERIALS TO AVOID: OXIDIZERS, ACIDS, WATER.
CONDITIONS TO AVOID: ELEVATED TEMPERATURES, MOISTURE, SPARKS,
OPEN FLAME, IGNITION SOURCES.
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
SECTION 11: TOXICOLOGICAL INFORMATION
COMMON NAME: SILICON DIOXIDE
CAS NUMBER: 112945-52-5
CARCINOGENICITY LISTED BY: NTP: NO IARC: NO OSHA: NO ACGIH: NO
LD50: 3160.00 MG/KG ORL RAT
COMMON NAME: SILYL TERMINATED POLYETHER
CAS NUMBER: 151865-59-7
CARCINOGENICITY LISTED BY: NTP: NO IARC: NO OSHA: NO ACGIH: NO
LD50: 5000.00 MG/KG ORL RAT
COMMON NAME: VINYLTRIMETHOXYSILANE
CAS NUMBER: 2768-02-7
CARCINOGENICITY LISTED BY: NTP: NO IARC: NO OSHA: NO ACGIH: NO
LD50: 11.30 ML/KG ORL RAT
LD50: 3.54 ML/KG SKN RBT
COMMON NAME: SILICA
CAS NUMBER: 68611-44-9
CARCINOGENICITY LISTED BY: NTP: NO IARC: NO OSHA: NO ACGIH: NO
COMMON NAME: SILYL TERMINATED POLYETHER
CAS NUMBER: 75009-88-0
CARCINOGENICITY LISTED BY: NTP: NO IARC: NO OSHA: NO ACGIH: NO
LD50: 5000.00 MG/KG ORL RAT
SUPPLEMENTAL HEALTH INFORMATION: CONTAINS A CHEMICAL THAT IS
MODERATELY TOXIC BY INGESTION.
CARCINOGENICITY: NO CARCINOGENIC EFFECTS ARE ANTICIPATED
REPRODUCTIVE EFFECTS: NO REPRODUCTIVE EFFECTS ARE ANTICIPATED
MUTAGENICITY: NO MUTAGENIC EFFECTS ARE ANTICIPATED
TERATOGENICITY: NO TERATOGENIC EFFECTS ARE ANTICIPATED
SECTION 12: ECOLOGICAL INFORMATION
NO ECOLOGICAL TESTING HAS BEEN DONE BY ICI PAINTS ON THIS RODUCT AS A WHOLE.
SECTION 13: DISPOSAL CONSIDERATIONS
WASTE DISPOSAL: DISPOSE IN ACCORDANCE WITH ALL APPLICABLE REGULATIONS.
AVOID DISCHARGE TO NATURAL WATERS.
SECTION 14: TRANSPORT INFORMATION
DOT: ADHESIVE
IMDG: NOT AVAILABLE
IATA: NOT AVAILABLE
TDG: NOT AVAILABLE
SECTION 15: REGULATORY INFORMATION
SARA SARA CERCLA HAZ AIR MARINE
302 313 302.4 POLLUTANT POLTNT
THIS PRODUCT CONTAINS NO SARA 302, CERCLA 302.4 OR HAZARDOUS AIR POLLUTANT
CHEMICALS. IT ALSO CONTAINS NO CHEMICALS WHICH ARE SUBJECT TO THE
REPORTING REQUIREMENTS UNDER SARA 313. AS OF THE DATE OF THIS MSDS, ALL OF
THE COMPONENTS IN THIS PRODUCT ARE LISTED (OR ARE OTHERWISE EXEMPT FROM
LISTING) ON THE TSCA INVENTORY. THIS PRODUCT HAS BEEN CLASSIFIED IN
ACCORDANCE WITH THE HAZARD CRITERIA OF THE CPR (CONTROLLED PRODUCTS
REGULATIONS) & THE MSDS CONTAINS ALL THE INFORMATION REQUIRED BY THE CPR.
SECTION 16: OTHER INFORMATION
THE INFORMATION CONTAINED HEREIN IS BASED ON DATA AVAILABLE AT THE TIME OF
PREPARATION OF THIS DATA SHEET AND WHICH ICI PAINTS BELIEVES TO BE RELIABLE.
HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF
THIS DATA. ICI PAINTS SHALL NOT BE RESPONSIBLE FOR THE USE OF THIS
INFORMATION, OR OF ANY PRODUCT, METHOD OR APPARATUS MENTIONED AND YOU
MUST MAKE YOUR OWN DETERMINATION OF ITS SUITABILITY AND COMPLETENESS FOR
YOUR OWN USE, FOR THE PROTECTION OF THE ENVIRONMENT, AND THE HEALTH AND
SAFETY OF YOUR EMPLOYEES AND USERS OF THIS MATERIAL. COMPLIES WITH OSHA
HAZARD COMMUNICATION STANDARD 29CFR1910.1200.
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