MATERIAL SAFETY DATA SHEET
K21220260
06 00
Section 1 -- PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NUMBER DATE OF PREPARATION HMIS CODES
Health 2*
K21220260 28-FEB-08 Flammability 0
Reactivity 0
PRODUCT NAME
KRYLON COMMERCIAL COATINGS鈩? Better Quality Interior Latex Eggshell
Paint, Antique White
MANUFACTURER'S NAME
THE SHERWIN-WILLIAMS COMPANY
Diversified Brands
Cleveland, OH 44115
TELEPHONE NUMBERS and WEBSITES
Product Information
(800) 247-3266
Regulatory Information
(216) 566-2902 www.paintdocs.com
Medical Emergency
(216) 566-2917
Transportation Emergency for Chemical Emergency ONLY (spill, leak,
(800) 424-9300 fire, exposure, or accident)
Section 2 -- COMPOSITION/INFORMATION ON INGREDIENTS
% by WT CAS No. INGREDIENT UNITS VAPOR PRESSURE
1 107-21-1 Ethylene Glycol
ACGIH TLV 100 mg/m3 CEILI (aerosol) 0.12 mm
OSHA PEL 50 ppm CEILING
0.1 14464-46-1 Cristobalite
ACGIH TLV 0.025 mg/m3 as Resp. Dust
OSHA PEL 0.05 mg/m3 as Resp. Dust
16 471-34-1 Calcium Carbonate
ACGIH TLV 10 mg/m3 as Dust
OSHA PEL 15 mg/m3 Total Dust
OSHA PEL 5 mg/m3 Respirable Fraction
13 13463-67-7 Titanium Dioxide
ACGIH TLV 10 mg/m3 as Dust
OSHA PEL 10 mg/m3 Total Dust
OSHA PEL 5 mg/m3 Respirable Fraction
Section 3 -- HAZARDS IDENTIFICATION
ROUTES OF EXPOSURE
INHALATION of vapor or spray mist.
EYE or SKIN contact with the product, vapor or spray mist.
Continued on page 2
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EFFECTS OF OVEREXPOSURE
EYES: Irritation.
SKIN: Prolonged or repeated exposure may cause irritation.
INHALATION: Irritation of the upper respiratory system.
In a confined area vapors in high concentration may cause headache,
nausea or dizziness.
Prolonged overexposure to solvent ingredients in Section 2 may cause
adverse effects to the liver and urinary systems.
SIGNS AND SYMPTOMS OF OVEREXPOSURE
Redness and itching or burning sensation may indicate eye or excessive
skin exposure.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE
None generally recognized.
CANCER INFORMATION
For complete discussion of toxicology data refer to Section 11.
Section 4 -- FIRST AID MEASURES
EYES: Flush eyes with large amounts of water for 15 minutes.
Get medical attention.
SKIN: Wash affected area thoroughly with soap and water.
Remove contaminated clothing and launder before re-use.
INHALATION: If affected, remove from exposure. Restore breathing.
Keep warm and quiet.
INGESTION: Do not induce vomiting.
Get medical attention immediately.
Section 5 -- FIRE FIGHTING MEASURES
FLASH POINT LEL UEL
Not Applicable N.A. N.A.
FLAMMABILITY CLASSIFICATION
Not Applicable
EXTINGUISHING MEDIA
Carbon Dioxide, Dry Chemical, Alcohol Foam
UNUSUAL FIRE AND EXPLOSION HAZARDS
Closed containers may explode (due to the build-up of pressure) when
exposed to extreme heat.
During emergency conditions overexposure to decomposition products may
cause a health hazard. Symptoms may not be immediately apparent. Obtain
medical attention.
SPECIAL FIRE FIGHTING PROCEDURES
Full protective equipment including self-contained breathing apparatus
should be used.
Water spray may be ineffective. If water is used, fog nozzles are
preferable. Water may be used to cool closed containers to prevent
pressure build-up and possible autoignition or explosion when exposed to
extreme heat.
Section 6 -- ACCIDENTAL RELEASE MEASURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
Remove all sources of ignition. Ventilate the area.
Remove with inert absorbent.
Continued on page 3
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Section 7 -- HANDLING AND STORAGE
STORAGE CATEGORY
Not Applicable
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE
Keep container closed when not in use. Transfer only to approved
containers with complete and appropriate labeling. Do not take internally.
Keep out of the reach of children.
Section 8 -- EXPOSURE CONTROLS/PERSONAL PROTECTION
PRECAUTIONS TO BE TAKEN IN USE
Use only with adequate ventilation.
Avoid contact with skin and eyes. Avoid breathing vapor and spray mist.
Wash hands after using.
This coating may contain materials classified as nuisance particulates
(listed "as Dust" in Section 2) which may be present at hazardous levels
only during sanding or abrading of the dried film. If no specific dusts
are listed in Section 2, the applicable limits for nuisance dusts are ACGIH
TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3
(total dust), 5 mg/m3 (respirable fraction).
VENTILATION
Local exhaust preferable. General exhaust acceptable if the exposure to
materials in Section 2 is maintained below applicable exposure limits.
Refer to OSHA Standards 1910.94, 1910.107, 1910.108.
RESPIRATORY PROTECTION
If personal exposure cannot be controlled below applicable limits by
ventilation, wear a properly fitted organic vapor/particulate respirator
approved by NIOSH/MSHA for protection against materials in Section 2.
When sanding or abrading the dried film, wear a dust/mist respirator
approved by NIOSH/MSHA for dust which may be generated from this product,
underlying paint, or the abrasive.
PROTECTIVE GLOVES
Wear gloves which are recommended by glove supplier for protection
against materials in Section 2.
EYE PROTECTION
Wear safety spectacles with unperforated sideshields.
Section 9 -- PHYSICAL AND CHEMICAL PROPERTIES
PRODUCT WEIGHT 10.79 lb/gal 1292 g/l
SPECIFIC GRAVITY 1.30
BOILING POINT 212 - 388 F 100 - 197 C
MELTING POINT Not Available
VOLATILE VOLUME 67 %
EVAPORATION RATE Slower than ether
VAPOR DENSITY Heavier than air
SOLUBILITY IN WATER N.A.
pH 9.0
VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged)
0.81 lb/gal 97 g/l Less Water and Federally Exempt Solvents
0.29 lb/gal 35 g/l Emitted VOC
Continued on page 4
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Section 10 -- STABILITY AND REACTIVITY
STABILITY -- Stable
CONDITIONS TO AVOID
None known.
INCOMPATIBILITY
None known.
HAZARDOUS DECOMPOSITION PRODUCTS
By fire: Carbon Dioxide, Carbon Monoxide
HAZARDOUS POLYMERIZATION
Will not occur
Section 11 -- TOXICOLOGICAL INFORMATION
CHRONIC HEALTH HAZARDS
Crystalline Silica (Quartz, Cristobalite) is listed by IARC and NTP.
Long term exposure to high levels of silica dust, which can occur only when
sanding or abrading the dry film, may cause lung damage (silicosis) and
possibly cancer.
IARC's Monograph No. 93 reports there is sufficient evidence of
carcinogenicity in experimental rats exposed to titanium dioxide but
inadequate evidence for carcinogenicity in humans and has assigned a Group
2B rating. In addition, the IARC summary concludes, "No significant
exposure to titanium dioxide is thought to occur during the use of products
in which titanium is bound to other materials, such as paint."
Ethylene Glycol is considered an animal teratogen. It has been shown to
cause birth defects in rats and mice at high doses when given in drinking
water or by gavage. There is no evidence to indicate it causes birth
defects in humans.
TOXICOLOGY DATA
CAS No. Ingredient Name
107-21-1 Ethylene Glycol
LC50 RAT 4HR Not Available
LD50 RAT 4700 mg/kg
14464-46-1 Cristobalite
LC50 RAT 4HR Not Available
LD50 RAT Not Available
471-34-1 Calcium Carbonate
LC50 RAT 4HR Not Available
LD50 RAT Not Available
13463-67-7 Titanium Dioxide
LC50 RAT 4HR Not Available
LD50 RAT Not Available
Section 12 -- ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION
No data available.
Continued on page 5
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Section 13 -- DISPOSAL CONSIDERATIONS
WASTE DISPOSAL METHOD
Waste from this product is not hazardous as defined under the Resource
Conservation and Recovery Act (RCRA) 40 CFR 261.
Incinerate in approved facility. Do not incinerate closed container.
Dispose of in accordance with Federal, State/Provincial, and Local
regulations regarding pollution.
Section 14 -- TRANSPORT INFORMATION
US Ground (DOT)
Not Regulated for Transportation.
Canada (TDG)
Not Regulated for Transportation.
IMO
Not Regulated for Transportation.
Section 15 -- REGULATORY INFORMATION
SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION
CAS No. CHEMICAL/COMPOUND % by WT % Element
107-21-1 Ethylene Glycol 1
CALIFORNIA PROPOSITION 65
WARNING: This product contains chemicals known to the State of
California to cause cancer and birth defects or other reproductive harm.
TSCA CERTIFICATION
All chemicals in this product are listed, or are exempt from listing,
on the TSCA Inventory.
Section 16 -- OTHER INFORMATION
This product has been classified in accordance with the hazard criteria
of the Canadian Controlled Products Regulations (CPR) and the MSDS contains
all of the information required by the CPR.
The above information pertains to this product as currently formulated,
and is based on the information available at this time. Addition of
reducers or other additives to this product may substantially alter the
composition and hazards of the product. Since conditions of use are
outside our control, we make no warranties, express or implied, and assume
no liability in connection with any use of this information.
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