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Material Safety Data Sheet
RHODACAL DSB
Date Prepared: 12/01/04 Supersedes Date: 7/31/03
1. PRODUCT AND COMPANY DESCRIPTION
Rhodia Canada Inc
HOME, PERSONAL CARE & INDUSTRIAL INGREDIENTS
3265 Wolfedale Road
Mississauga ON L5C 1V8
Emergency Phone Numbers:
FOR EMERGENCIES INVOLVING A SPILL, LEAK, FIRE, EXPOSURE OR ACCIDENT CONTACT: CANUTEC at
613-996-6666 (call collect) or Rhodia CAERS (Communication and Emergency Response System) at 800-916-
3232.
For Product Information:
(905) 270-5534
Product Use:
HOUSEHOLD DETERGENT, AGRICULTURE CHEMICAL, OIL FIELD, EMULSIFIER.
Chemical Name or Synonym:
SODIUM ALKYL DIPHENYL OXIDE SULFONATE
Prepared By:
Product Safety Service Center, Mississauga, Ontario, (905) 270-5534.
2. COMPOSITION/INFORMATION ON INGREDIENTS
WHMIS
Component CAS Reg Number Percentage
Hazard
SODIUM ALKYL DIPHENYL OXIDE SULFONATE 119345-04-9 Y > 45
WATER/INERTS ************ N 50
3. HAZARDS IDENTIFICATION
A. EMERGENCY OVERVIEW:
Physical Appearance and Odor:
straw colored / liquid, moderate odor.
Warning Statements:
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WARNING!! EYE IRRITANT.
B. POTENTIAL HEALTH EFFECTS:
Acute Eye:
Irritant. May cause redness, irritation, tearing, burns, eye damage.
Acute Skin:
Low acute dermal toxicity. Slightly irritating. May cause redness, irritation.
Acute Inhalation:
Low acute inhalation toxicity. Mists may cause upper respiratory tract irritation.
Acute Ingestion:
Low acute oral toxicity. May cause nausea, vomiting, abdominal cramps.
Chronic Effects:
This product does not contain any ingredient designated by IARC, NTP, ACGIH or OSHA as probable or
suspected human carcinogens.
4. FIRST AID MEASURES
FIRST AID MEASURES FOR ACCIDENTAL:
Eye Exposure:
Hold eyelids open and flush with a steady, gentle stream of water for at least 15 minutes. Seek immediate
medical attention.
Skin Exposure:
In case of contact, immediately wash with plenty of soap and water for at least 5 minutes. Seek medical attention
if irritation developes or persists. Remove contaminated clothing and shoes. Clean contaminated clothing and
shoes before re-use.
Inhalation:
If respiratory irritation or distress occurs remove victim to fresh air. Seek medical attention if respiratory irritation
or distress continues.
Ingestion:
If victim is conscious and alert, give 1-2 glasses of water to drink. Do not give anything by mouth to an
unconscious person. Seek medical attention. Do not leave victim unattended.
MEDICAL CONDITIONS POSSIBLY AGGRAVATED BY EXPOSURE:
NOTES TO PHYSICIAN: All treatments should be based on observed signs and symptoms of distress in the
patient. Consideration should be given to the possibility that overexposure to materials other than this product
may have occurred.
NOTES TO PHYSICIAN:
All treatments should be based on observed signs and symptoms of distress in the patient. Consideration should
be given to the possibility that overexposure to materials other than this product may have occurred.
5. FIRE FIGHTING MEASURES
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FIRE HAZARD DATA:
Flash Point:
> 93 C (200 F). Flammability Class: WILL BURN.
Method Used:
Closed cup
Flammability Limits (vol/vol%): Lower: Upper:
No Data No Data
Extinguishing Media:
Recommended (small fires): carbon dioxide, dry chemical, Recommended (large fire): alcohol foam, universal
foam, water spray.
Special Fire Fighting Procedures:
Firefighters should wear NIOSH/MSHA approved self-contained breathing apparatus and full protective clothing.
Unusual Fire and Explosion Hazards:
Hazardous Decomposition Materials (Under Fire Conditions): oxides of sulfur oxides of carbon
Hazardous Decomposition Materials (Under Fire Conditions):
oxides of sulfur
oxides of carbon
6. ACCIDENTAL RELEASE MEASURES
Evacuation Procedures and Safety:
Containment of Spill: Dike spill using absorbent or impervious materials such as earth, sand or clay.
Containment of Spill:
Dike spill using absorbent or impervious materials such as earth, sand or clay.
Cleanup and Disposal of Spill:
Absorb with a damp, inert absorbent. Clean up residual material by washing area with water. Collect washings for
disposal.
Environmental and Regulatory Reporting:
7. HANDLING AND STORAGE
Minimum/Maximum Storage Temperatures:
> 4 C (39 F)
Handling:
Avoid breathing vapors and mists. Avoid direct or prolonged contact with skin and eyes. In cold weather, this
product may stratify and freeze. This does not damage the product. If freezing occurs, thaw and remix before
using. Frozen material may be thawed in a warm room. Avoid localized overheating. Vent drums while heating.
Mix thoroughly to assure homogeneity.
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Storage:
Store in closed containers. Store in an area that is clean, well-ventilated, away from ignition sources, away from
incompatible materials (see Section 10. Stability and Reactivity).
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Introductory Remarks:
These recommendations provide general guidance for handling this product. Because specific work environments
and material handling practices vary, safety procedures should be developed for each intended application. While
developing safe handling procedures, do not overlook the need to clean equipment and piping systems for
maintenance and repairs. Waste resulting from these procedures should be handled in accordance with Section
13: Disposal Considerations.
Assistance with selection, use and maintenance of worker protection equipment is generally available from
equipment manufacturers.
Exposure Guidelines:
No exposure limits were found for this product or any of its ingredients.
Engineering Controls:
Where engineering controls are indicated by use conditions or a potential for excessive exposure exists, the
following traditional exposure control techniques may be used to effectively minimize employee exposures.
Respiratory Protection:
When respirators are required, select NIOSH/MSHA approved equipment based on actual or potential airborne
concentrations and in accordance with the appropriate regulatory standards and/or industrial recommendations.
Eye/Face Protection:
Eye and face protection requirements will vary dependent upon work environment conditions and material
handling practices. Appropriate ANSI Z87 approved equipment should be selected for the particular use intended
for this material.
Eye contact should be prevented through use of chemical safety glasses with side shields or splash proof
goggles. An emergency eye wash must be readily accessible to the work area.
Skin Protection:
Skin contact should be minimized through use of gloves and suitable long-sleeved clothing (i.e., shirts and pants).
Consideration must be given both to durability as well as permeation resistance.
Work Practice Controls:
Personal hygiene is an important work practice exposure control measure and the following general measures
should be taken when working with or handling this material:
(1) Do not store, use, and/or consume foods, beverages, tobacco products, or cosmetics in areas where
this material is stored.
(2) Wash hands and face carefully before eating, drinking, using tobacco, applying cosmetics, or using
the toilet.
(3) Wash exposed skin promptly to remove accidental splashes or contact with this material.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical and Chemical properties here represent typical properties of this product. Contact the business area
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using the Product Information phone number in Section 1 for its exact specifications.
Physical Appearance:
straw colored / liquid.
Odor:
moderate odor.
pH:
7 to 9 at 10 wt/wt%.
Specific Gravity:
Not Available
Density:
1.14 to 1.16 g/ml at 25 C (77 F).
Water Solubility:
soluble
Melting Point Range:
Not Available
Boiling Point Range:
100 C (212 F) at 760 mmHg
Vapor Pressure:
< 23 mmHg at 25 C (77 F)
Vapor Density:
Not Available
Percent Volatiles by Volume:
50
10. STABILITY AND REACTIVITY
Chemical Stability:
This material is stable under normal handling and storage conditions described in Section 7.
Conditions To Be Avoided:
heat
open flame
spark
Materials/Chemicals To Be Avoided:
strong acids
strong oxidizing agents
The Following Hazardous Decomposition Products Might Be Expected:
Decomposition Type: thermal
oxides of sulfur
oxides of carbon
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Hazardous Polymerization Will Not Occur.
Avoid The Following To Inhibit Hazardous Polymerization:
not applicable
11. TOXICOLOGICAL INFORMATION
Acute Eye Irritation:
Toxicological Information and Interpretation:
eye - eye irritation, rabbit. Moderately irritating.
Acute Skin Irritation:
Toxicological Information and Interpretation:
skin - skin irritation, rabbit. Slightly irritating.
Acute Dermal Toxicity:
Toxicological Information and Interpretation:
LD50 - lethal dose 50% of test species, > 2000 mg/kg, rabbit.
Acute Respiratory Irritation:
No test data found for product.
Acute Inhalation Toxicity:
No test data found for product.
Acute Oral Toxicity:
Toxicological Information and Interpretation:
LD50 - lethal dose 50% of test species, > 2000 mg/kg, rat.
Chronic Toxicity:
This product does not contain any substances that are considered by OSHA, NTP, IARC or ACGIH to be
"probable" or "suspected" human carcinogens.
No additional test data found for product.
12. ECOLOGICAL INFORMATION
Ecotoxicological Information:
May cause adverse environmental impact if material reaches waterways.
Chemical Fate Information:
Inherently biodegradable.
13. DISPOSAL CONSIDERATIONS
Waste Disposal Method:
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Waste Management options should first consider possible re-use or recycling opportunities. Some provinces have
active "Waste Exchange" networks for re-use and recycling of wastes. Contact your local waste management
companies to explore available options. All waste management activities must obey local, provincial and federal
regulations. Possible disposal methods include the following:
Dewater (eg. evaporation) the product. Solidify the remaining mixture and dispose of in a secure landfill.
Alternatively, incinerate directly or in combination with a flammable solvent.
14. TRANSPORTATION INFORMATION
Transportation Status: IMPORTANT! Statements below provide additional data on listed DOT
classification.
The listed Transportation Classification does not address regulatory variations due to changes in package size,
mode of shipment or other regulatory descriptors.
TDG Status:
Shipping Name: NON DANGEROUS
IMO Status:
Shipping Name: NOT REGULATED
IATA Status:
Shipping Name: NOT REGULATED
15. REGULATORY INFORMATION
Inventory Status
Inventory Status
UNITED STATES (TSCA) Y
CANADA (DSL) Y
EUROPE (EINECS/ELINCS) Y
AUSTRALIA (AICS) N
JAPAN (MITI) N
SOUTH KOREA (KECL) Y
Y = All ingredients are on the inventory.
E = All ingredients are on the inventory or exempt from listing.
P = One or more ingredients fall under the polymer exemption or are on the no longer polymer list. All other
ingredients are on the inventory or exempt from listing.
N = Not determined or one or more ingredients are not on the inventory and are not exempt from listing.
Inventory Issues:
For European Inventory (EINECS/ELINCS) purposes, this product is identified as: Blend of: disodium dodecyl
(sulphonatophenoxy) benzenesulphonate and disodium 2,2'(or 3,3')-oxybis陋5(or 2)-dodecylbenzenesulphonate|.
WHMIS Classification:
D-2B : TOXIC MATERIAL
This product has been classified in accordance with the hazard criteria of the CPR (Controlled Products
Regulations) and the MSDS contains all the information required by the CPR.
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16. OTHER INFORMATION
National Fire Protection Association Hazard Ratings--NFPA(R):
Health Hazard Rating--Moderate
2
Flammability Rating--Slight
1
Instability Rating--Minimal
0
National Paint & Coating Hazardous Materials Identification System--HMIS(R):
Health Hazard Rating--Moderate
2
Flammability Rating--Slight
1
Reactivity Rating--Minimal
0
Reason for Revisions:
Change and/or addition made to Section 1, Section 2, Section 3, Section 4, Section 12, Section 15, International
Inventory Status, Section 15 Regulatory Review and Update.
Key Legend Information:
ACGIH - American Conference of Governmental Industrial Hygienists
OSHA - Occupational Safety and Health Administration
TLV - Threshold Limit Value
PEL - Permissable Exposure Limit
TWA - Time Weighted Average
STEL - Short Term Exposure Limit
NTP - National Toxicology Program
IARC - International Agency for Research on Cancer
ND - Not determined
RPI - Rhodia Established Exposure Limits
Disclaimer:
The information herein is given in good faith but no warranty, expressed or implied, is made.
** End of MSDS Document **
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