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Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 03/30/2004 Reviewed on 03/30/2004
1 Identification of substance
Product details
Trade name: Ultra-Spheres (All Sizes)
Application of the substance / the preparation: Solder
Manufacturer/Supplier:
Kester Tel.(847) 297-1600
515 E. Touhy Ave. Fax.(847) 390-9338
Des Plaines, IL 60018
Information department:
MSDS Coordinator Tel. (847) 699-5755
Emergency information:
CHEMTREC 24-Hour Emergency Telephone Number: (800)424-9300
CHEMTREC 24-Hour Emergency Telephone Number (Outside of the U.S. and Canada): (703)527-3887
2 Composition/Data on components
Chemical characterization
Description: Mixture of the substances listed below with nonhazardous additions.
Dangerous components:
7440-31-5 tin 0-100%
7439-92-1 lead 0-100%
7440-36-0 antimony 0-100%
7440-50-8 copper 0-100%
7440-22-4 silver 0-100%
7440-69-9 bismuth 0-100%
7440-66-6 Zinc 0-100%
Additional information:
Composition and weight percent of solder alloys varies widely and can be determined by product label.
3 Hazards identification
WHMIS Hazard Symbols
<=
Information pertaining to particular dangers for man and environment:
The product has to be labelled due to the calculation procedure of international guidelines.
Harmful by inhalation and if swallowed.
Danger of cumulative effects.
Possible risk of impaired fertility.
Contains lead. Should not be used on surfaces liable to be chewed or sucked by children.
(Contd. on page 2)
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Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 03/30/2004 Reviewed on 03/30/2004
Trade name: Ultra-Spheres (All Sizes)
(Contd. of page 1)
NFPA ratings (scale 0 - 4)
Health = 2
0 Fire = 0
2 0 Reactivity = 0
HMIS-ratings (scale 0 - 4)
HEALTH *2 Health = *2
Fire = 0
FIRE 0
Reactivity = 0
REACTIVITY 0
4 First aid measures
General information:
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours
after the accident.
After inhalation: Supply fresh air; consult doctor in case of complaints.
After skin contact: Immediately wash with water and soap and rinse thoroughly.
After eye contact: Rinse opened eye for several minutes under running water.
After swallowing: Induce vomiting, if person is conscious. Seek medical help.
5 Fire fighting measures
Suitable extinguishing agents:
CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
Special hazards caused by the material, its products of combustion or resulting gases:
Melted solder above 1000掳F will liberate toxic lead and/or antimony fumes.
Protective equipment: Wear self-contained respiatory protective device.
6 Accidental release measures
Person-related safety precautions: Not required.
Measures for environmental protection: Do not allow to enter sewers/ surface or ground water.
Measures for cleaning/collecting:
Melted solder will solidify on cooling and can be scraped up. Use caution to avoid breathing fumes if a gas torch is
used to cut up large pieces.
7 Handling and storage
Handling:
Information for safe handling: Ensure good ventilation/exhaustion at the workplace.
Information about protection against explosions and fires: Keep respiratory protective device available.
Storage:
Requirements to be met by storerooms and receptacles: No special requirements.
(Contd. on page 3)
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Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 03/30/2004 Reviewed on 03/30/2004
Trade name: Ultra-Spheres (All Sizes)
(Contd. of page 2)
Information about storage in one common storage facility: Not required.
Further information about storage conditions: Store in dry conditions.
8 Exposure controls and personal protection
Additional information about design of technical systems: No further data; see item 7.
Components with limit values that require monitoring at the workplace:
7440-31-5 tin
PEL 2 mg/m鲁
Metal
REL 2 mg/m鲁
Tin, Metal
TLV 2 mg/m鲁
7439-92-1 lead
PEL 0.05* mg/m鲁
as Pb
REL <0.1* mg/m鲁
as Pb; *Blood Pb <0.06 mg/100 g whole blood
TLV 0.05 mg/m鲁
as Pb; BEI
7440-36-0 antimony
PEL 0.5 mg/m鲁
REL 0.5 mg/m鲁
as Sb
TLV 0.5 mg/m鲁
7440-50-8 copper
PEL 0.1*;1** mg/m鲁
*fume **dusts & mists
REL 0.1*;1** mg/m鲁
*Copper fume, as Cu **Copper dusts & mists, as Cu
TLV 0.2*, 1** mg/m鲁
*fume; ** dusts&mists, as Cu
7440-22-4 silver
PEL 0.01 mg/m鲁
REL 0.01 mg/m鲁
TLV 0.1 mg/m鲁
Personal protective equipment:
General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Wash hands before breaks and at the end of work.
Immediately remove all soiled and contaminated clothing.
Store protective clothing separately.
Breathing equipment:
When ventilation is not sufficient to remove fumes from the breathing zone, a safety approved respirator or self-
contained breathing apparatus should be worn.
(Contd. on page 4)
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Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 03/30/2004 Reviewed on 03/30/2004
Trade name: Ultra-Spheres (All Sizes)
(Contd. of page 3)
Protection of hands:
S Protective gloves
Material of gloves:
Cloth gloves
Nitrile rubber, NBR
Natural rubber, NR
Penetration time of glove material:
The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be
observed.
Eye protection:
R Tightly sealed goggles
Safety glasses
9 Physical and chemical properties
General Information
Form: Solid
Color: Silver grey
Odor: Mild
Change in condition
Melting point/Melting range: > 100掳C (> 212掳F)
Boiling point/Boiling range: 1740掳C (3164掳F)
Flash point: Not applicable.
Danger of explosion: Product does not present an explosion hazard.
Density at 20掳C (68掳F): > 7 g/cm鲁
Solubility in / Miscibility with
Water: Insoluble.
10 Stability and reactivity
Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
Materials to be avoided: Strong acids, strong oxidizers.
Dangerous reactions No dangerous reactions known.
Dangerous products of decomposition: No dangerous decomposition products known.
USA
(Contd. on page 5)
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Material Safety Data Sheet
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Trade name: Ultra-Spheres (All Sizes)
(Contd. of page 4)
11 Toxicological information
Acute toxicity:
Primary irritant effect:
on the skin: No irritant effect.
on the eye: Smoke during soldering can cause eye irritation.
through inhalation: May cause respiratory irritation.
through ingestion: May be harmful if swallowed.
Sensitization: No sensitizing effects known.
Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for preparations:
Harmful
12 Ecological information
General notes: Do not allow product to reach ground water, water course or sewage system.
13 Disposal considerations
Product:
Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
Uncleaned packagings:
Recommendation: Disposal must be made according to official regulations.
14 Transport information
DOT regulations:
Hazard class: -
Land transport ADR/RID (cross-border):
ADR/RID class: -
Maritime transport IMDG:
IMDG Class: -
Marine pollutant: No
Air transport ICAO-TI and IATA-DGR:
ICAO/IATA Class: -
Transport/Additional information: Not dangerous according to the above specifications.
15 Regulations
USA The following information relates to product regulation specific to the USA.
(Contd. on page 6)
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Material Safety Data Sheet
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Printing date 03/30/2004 Reviewed on 03/30/2004
Trade name: Ultra-Spheres (All Sizes)
(Contd. of page 5)
SARA (Superfund Amendments and Reauthorization Act)
Section 355 (extremely hazardous substances):
None of the ingredient is listed.
Section 313 (Specific toxic chemical listings):
7439-92-1 lead
7440-36-0 antimony
7440-50-8 copper
7440-22-4 silver
7440-66-6 Zinc
7440-43-9 cadmium
7440-02-0 nickel
TSCA (Toxic Substances Control Act):
All ingredients are listed.
California Proposition 65
Chemicals known to cause cancer:
WARNING: This product contains a chemical known to the State of California to cause cancer.
7439-92-1 lead
Chemicals known to cause reproductive toxicity:
WARNING: This product contains a chemical known to the State of California to cause birth defects and/or other
reproductive harm.
7439-92-1 lead
Carcinogenicity categories
EPA (Environmental Protection Agency)
7439-92-1 lead B2
7440-50-8 copper D
7440-22-4 silver D
7440-43-9 cadmium B1
IARC (International Agency for Research on Cancer)
7439-92-1 lead 2B
7440-43-9 cadmium 1
7440-02-0 nickel 2B
NTP (National Toxicology Program)
7440-43-9 cadmium R
7440-02-0 nickel R
TLV (Threshold Limit Value established by ACGIH)
7440-43-9 cadmium 2
7440-02-0 nickel 1
NIOSH-Ca (National Institute for Occupational Safety and Health)
7440-43-9 cadmium
7440-02-0 nickel
(Contd. on page 7)
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Material Safety Data Sheet
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Printing date 03/30/2004 Reviewed on 03/30/2004
Trade name: Ultra-Spheres (All Sizes)
(Contd. of page 6)
OSHA-Ca (Occupational Safety & Health Administration)
7440-43-9 cadmium
CANADA: The following information relates to product regulation specific to Canada.
Workplace Hazardous Materials Identification (WHMIS):
This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products
Regulation (CPR) and the MSDS contains all of the information required by the CPR.
WHMIS Classification:
D2A
D2B
Components on Ingredient List for WHMIS:
lead
tin
antimony
copper
silver
EUROPEAN UNION
The following information relates to product regulation specific to the directives of the Euopean Union.
Risk phrases:
Harmful by inhalation and if swallowed.
Danger of cumulative effects.
Possible risk of impaired fertility.
Safety phrases:
Keep out of the reach of children.
Wear suitable protective clothing and gloves.
If swallowed, seek medical advice immediately and show this container or label.
Dispose of this material and its container to hazardous or special waste collection point.
Special labeling of certain preparations:
Contains lead. Should not be used on surfaces liable to be chewed or sucked by children.
16 Other information
The information contained herein is based on data considered accurate and is offered solely for information,
consideration and investigation. Kester extends no warranties, makes no representations and
assumes no responsibilty as to the accuracy, completeness or suitability of this data for any purchaser's use. The
data on this Material Safety Data Sheet relates only to this product and does not relate to use with any other
material or in any process. All chemical products should be used only by, or under the direction of, technically
qualified personnel who are aware of the hazards involved and the necessity for reasonable care in handling.
Hazard communication regulations require that employees must be trained on how to use a Material Safety Data
Sheet as a source for hazard information.
Department issuing MSDS: Product Safety
Contact: Stacey Pole, MSDS Coordinator Tel:(847)699-5755
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