Material Safety Data Sheet
HMIS
NFPA Personal Protective Equipment
Health Hazard
2
0 Fire Hazard
0
2 0
Reactivity
0 See Section 15.
Section 1. Chemical Product and Company Identification Page Number: 1
Catalog
Lead oxide, red L1085
Common Name/
Number(s).
Trade Name
1314-41-6
CAS#
Manufacturer OG5425000
RTECS
SPECTRUM CHEMICAL MFG. CORP.
14422 S. SAN PEDRO STREET TSCA 8(b) inventory: Lead
TSCA
oxide, red
GARDENA, CA 90248
Not available.
Commercial Name(s) Not available.
CI#
Lead tetroxide
Synonym
IN CASE OF EMERGENCY
Lead tetroxide
Chemical Name CHEMTREC (24hr) 800-424-9300
Not available. CALL (310) 516-8000
Chemical Family
Pb3O4
Chemical Formula
SPECTRUM CHEMICAL MFG. CORP.
Supplier
14422 S. SAN PEDRO STREET
GARDENA, CA 90248
Section 2.Composition and Information on Ingredients
Exposure Limits
3
STEL (mg/m3) CEIL (mg/m3)
Name CAS # TWA (mg/m ) % by Weight
1) Lead oxide, red 1314-41-6 0.05 100
Lead oxide, red
Toxicological Data
LD50: Not available.
on Ingredients
LC50: Not available.
Section 3. Hazards Identification
Potential Acute Health Effects Hazardous in case of eye contact (irritant). Slightly hazardous in case of inhalation (lung irritant). Non-irritant for
skin. Prolonged exposure may result in skin burns and ulcerations. Over-exposure by inhalation may cause
respiratory irritation.
CARCINOGENIC EFFECTS: Classified + (PROVEN) by OSHA+ (PROVEN) by NIOSH.
Potential Chronic Health
MUTAGENIC EFFECTS: Not available.
Effects
TERATOGENIC EFFECTS: Not available.
DEVELOPMENTAL TOXICITY: Not available.
Repeated or prolonged exposure is not known to aggravate medical condition.
Continued on Next Page
Page Number: 2
Lead oxide, red
Section 4. First Aid Measures
Eye Contact Check for and remove any contact lenses. Do not use an eye ointment. Seek medical attention.
Skin Contact No known effect on skin contact, rinse with water for a few minutes.
Serious Skin Contact Not available.
Inhalation Allow the victim to rest in a well ventilated area. Seek immediate medical attention.
Serious Inhalation Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or
waistband. If breathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth
resuscitation. Seek medical attention.
Ingestion Do not induce vomiting. Loosen tight clothing such as a collar, tie, belt or waistband. If the victim is not
breathing, perform mouth-to-mouth resuscitation. Seek immediate medical attention.
Serious Ingestion Not available.
Section 5. Fire and Explosion Data
Non-flammable.
Flammability of the Product
Not applicable.
Auto-Ignition Temperature
Not applicable.
Flash Points
Not applicable.
Flammable Limits
Not available.
Products of Combustion
Not applicable.
Fire Hazards in Presence of
Various Substances
Explosion Hazards in Presence Risks of explosion of the product in presence of mechanical impact: Not available.
Risks of explosion of the product in presence of static discharge: Not available.
of Various Substances
Not applicable.
Fire Fighting Media
and Instructions
Not available.
Special Remarks on
Fire Hazards
Special Remarks on Explosion Not available.
Hazards
Section 6. Accidental Release Measures
Small Spill Use appropriate tools to put the spilled solid in a convenient waste disposal container.
Large Spill Oxidizing material.
Stop leak if without risk. Avoid contact with a combustible material (wood, paper, oil, clothing...). Keep substance
damp using water spray. Do not touch spilled material. Prevent entry into sewers, basements or confined areas;
dike if needed. Call for assistance on disposal. Be careful that the product is not present at a concentration level
above TLV. Check TLV on the MSDS and with local authorities.
Continued on Next Page
Page Number: 3
Lead oxide, red
Section 7. Handling and Storage
Keep locked up Keep away from heat. Keep away from sources of ignition. Keep away from combustible
Precautions
material Do not breathe dust. Avoid contact with eyes Wear suitable protective clothing If you feel unwell, seek
medical attention and show the label when possible.
Oxidizing materials should be stored in a separate safety storage cabinet or room.
Storage
Section 8. Exposure Controls/Personal Protection
Engineering Controls Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below
recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to
airborne contaminants below the exposure limit.
Personal Protection Splash goggles. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent.
Gloves.
Personal Protection in Case of Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used
a Large Spill to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist
BEFORE handling this product.
U.S.A: TWA: 0.05 (mg/m3) from ACGIH [1996]
Exposure Limits
Consult local authorities for acceptable exposure limits.
Section 9. Physical and Chemical Properties
Physical state and appearance Solid. Not available.
Odor
Not available.
Taste
685.57 g/mole
Molecular Weight
Bright red powder
Color
Not applicable.
pH (1% soln/water)
Not available.
Boiling Point
Not available.
Melting Point
Not available.
Critical Temperature
9.1 (Water = 1)
Specific Gravity
Not applicable.
Vapor Pressure
Not available.
Vapor Density
Not available.
Volatility
Not available.
Odor Threshold
Not available.
Water/Oil Dist. Coeff.
Not available.
Ionicity (in Water)
Not available.
Dispersion Properties
Insoluble in cold water.
Solubility
Section 10. Stability and Reactivity Data
The product is stable.
Stability
Not available.
Instability Temperature
Not available.
Conditions of Instability
Slightly reactive to reactive with reducing agents, combustible materials.
Incompatibility with various
substances
Continued on Next Page
Page Number: 4
Lead oxide, red
Non-corrosive in presence of glass.
Corrosivity
Not available.
Special Remarks on
Reactivity
Not available.
Special Remarks on
Corrosivity
No.
Polymerization
Section 11. Toxicological Information
Routes of Entry Eye contact. Inhalation. Ingestion.
Toxicity to Animals LD50: Not available.
LC50: Not available.
Chronic Effects on Humans CARCINOGENIC EFFECTS: Classified + (PROVEN) by OSHA+ (PROVEN) by NIOSH.
Other Toxic Effects on Slightly hazardous in case of inhalation (lung irritant).
Humans Non-irritant for skin.
Special Remarks on Not available.
Toxicity to Animals
Special Remarks on Not available.
Chronic Effects on Humans
Special Remarks on other Not available.
Toxic Effects on Humans
Section 12. Ecological Information
Not available.
Ecotoxicity
Not available.
BOD5 and COD
Possibly hazardous short term degradation products are not likely. However, long term degradation products may
Products of Biodegradation
arise.
The product itself and its products of degradation are not toxic.
Toxicity of the Products
of Biodegradation
Not available.
Special Remarks on the
Products of Biodegradation
Section 13. Disposal Considerations
Waste Disposal
Section 14. Transport Information
DOT Classification CLASS 5.1: Oxidizing material.
: Oxidizing Solid, n.o.s. (Lead Tetroxide) : UN1479 PG: III
Identification
Not available.
Special Provisions for
Transport
Continued on Next Page
Page Number: 5
Lead oxide, red
DOT (Pictograms)
OXIDIZER
5.1
Section 15. Other Regulatory Information and Pictograms
California prop. 65: This product contains the following ingredients for which the State of California has found to
Federal and State
cause cancer, birth defects or other reproductive harm, which would require a warning under the statute: Lead
Regulations
oxide, red
California prop. 65: This product contains the following ingredients for which the State of California has found to
cause reproductive harm (female) which would require a warning under the statute: Lead oxide, red
California prop. 65: This product contains the following ingredients for which the State of California has found to
cause reproductive harm (male) which would require a warning under the statute: Lead oxide, red
California prop. 65: This product contains the following ingredients for which the State of California has found to
cause birth defects which would require a warning under the statute: Lead oxide, red
California prop. 65: This product contains the following ingredients for which the State of California has found to
cause cancer which would require a warning under the statute: Lead oxide, red
Massachusetts RTK: Lead oxide, red
TSCA 8(b) inventory: Lead oxide, red
SARA 313 toxic chemical notification and release reporting: Lead oxide, red
CERCLA: Hazardous substances.: Lead oxide, red
California prop. 65: This product contains the following ingredients for which the State of California has found
California
to cause cancer which would require a warning under the statute: Lead oxide, red
Proposition 65
Warnings California prop. 65: This product contains the following ingredients for which the State of California has found
to cause birth defects which would require a warning under the statute: Lead oxide, red
Other Regulations OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).
CLASS C: Oxidizing material.
Other Classifications WHMIS (Canada)
DSCL (EEC) R36- Irritating to eyes.
R45- May cause cancer.
Health Hazard
HMIS (U.S.A.) 2 National Fire Protection Flammability
0
Association (U.S.A.)
Fire Hazard
0
0
2
Health Reactivity
Reactivity
0
Specific hazard
Personal Protection
E
WHMIS (Canada)
(Pictograms)
DSCL (Europe)
(Pictograms)
TDG (Canada)
(Pictograms)
5.1
ADR (Europe)
(Pictograms)
Continued on Next Page
Page Number: 6
Lead oxide, red
Protective Equipment Gloves.
Lab coat.
Dust respirator. Be sure to use an
approved/certified respirator or
equivalent. Wear appropriate respirator
when ventilation is inadequate.
Splash goggles.
Section 16. Other Information
L3235
MSDS Code
Not available.
References
Other Special Not available.
Considerations
Validated by Sonia Owen on 8/11/2006. Verified by Sonia Owen.
Printed 9/12/2006.
CALL (310) 516-8000
Notice to Reader
All chemicals may pose unknown hazards and should be used with caution. This Material Safety Data Sheet (MSDS) applies only to the material as packaged. If this product is
combined with other materials, deteriorates, or becomes contaminated, it may pose hazards not mentioned in this MSDS. It shall be the user's responsibility to develop proper
methods of handling and personal protection based on the actual conditions of use. While this MSDS is based on technical data judged to be reliable, Spectrum Quality Products,
Inc. assumes no responsibility for the completeness or accuracy of the information contained herein.
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