Product Name: Spraybuff BB5
Page: 1 of 5
This revision issued: June, 2008
Section 1 - Identification of Chemical Product and Company
Farmoz Pty Ltd, Suite 1, Level 4, Building B Telephone (02)9431 7800 (24 hours)
207 Pacific Highway St Leonards, NSW 2068 Fax (02)9431 7700
ACN 050 328 973
Solution of inorganic acid, surfactant and other proprietary ingredients.
Substance:
Spraybuff BB5
Trade Name:
pH buffer for agricultural use.
Product Use:
Creation Date: January, 2004
Revision Date: June, 2008
Section 2 - Hazards Identification
Statement of Hazardous Nature
This product is classified as: Hazardous according to the criteria of ASCC Australia.
Dangerous according to the Australian Dangerous Goods (ADG) Code.
Risk Phrases: R21, R25, R34, R41. Harmful in contact with skin. Toxic if swallowed. Causes burns. Risk of serious
damage to eyes.
Safety Phrases: S20, S24, S26, S28, S45, S46, S1/2, S36/37/39. When using, do not eat or drink. Avoid contact
with skin. In case of contact with eyes, rinse immediately with plenty of water and contact a doctor or Poisons
Information Centre. After contact with skin, wash immediately with plenty of soap and water. In case of accident or if
you feel unwell, contact a doctor or Poisons Information Centre immediately (show the label where possible). If
swallowed, contact a doctor or Poisons Information Centre immediately and show this container or label. Keep locked
up and out of reach of children. Wear suitable protective clothing, gloves and eye/face protection.
SUSDP Classification: S5
ADG Classification: Class 8 (PHOSPHORIC ACID)
UN Number: 1805
Emergency Overview
Physical Description & colour: Clear, almost colourless liquid.
Odour: Mild odour.
Major Health Hazards: toxic if swallowed, causes burns, may cause serious damage to eyes, harmful in contact
with skin.
Potential Health Effects
Inhalation
Short term exposure: Significant inhalation exposure is considered to be unlikely. Available data indicates that this
product is not harmful. In addition product is unlikely to cause any discomfort or irritation.
Long Term exposure: No data for health effects associated with long term inhalation.
Skin Contact:
Short term exposure: Available data shows that this product is harmful, but symptoms are not available. In
addition product is corrosive to the skin. Capable of causing moderate to severe burns with ulceration. Can penetrate
to deeper layers of skin, resulting in third degree burns. Corrosion will continue until product is removed or
neutralised. Severity depends on concentration and duration of exposure. Burns may not be immediately painful; the
onset of pain may be minutes to hours.
Long Term exposure: No data for health effects associated with long term skin exposure.
Eye Contact:
Short term exposure: This product is corrosive to eyes. It will cause severe pain, and corrosion of the eye and
surrounding facial tissues. Unless exposure is quickly treated, permanent blindness and facial scarring is likely.
Long Term exposure: No data for health effects associated with long term eye exposure.
Ingestion:
Short term exposure: Significant oral exposure is considered to be unlikely. Available data shows that this product
is toxic, but further symptoms are not available. However, this product is corrosive to the gastrointestinal tract.
MATERIAL SAFETY DATA SHEET
Issued by: Farmoz Pty Ltd Phone: (02)9431 7800
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
Product Name: Spraybuff BB5
Page: 2 of 5
This revision issued: June, 2008
Capable of causing moderate to severe burns with ulceration. Can penetrate to deeper layers of skin, resulting in third
degree burns. Corrosion will continue until product is removed or neutralised. Severity depends on concentration and
duration of exposure.
Long Term exposure: No data for health effects associated with long term ingestion.
Carcinogen Status:
ASCC: No significant ingredient is classified as carcinogenic by ASCC.
NTP: No significant ingredient is classified as carcinogenic by NTP.
IARC: No significant ingredient is classified as carcinogenic by IARC.
Section 3 - Composition/Information on Ingredients
TWA ((mg///m33) STEL ((mg///m33)
TWA (m g m 3)) STEL (m g m 3))
IIIngrrediiientts
n gre d e nts CAS No Conc,,,%
Conc %
CAS No
ng ed en s CAS No Conc % TWA mg m STEL mg m
Phosphoric acid 7664-38-2 30-32 1 3
Ethoxylated nonyl phenol 9016-45-9 10-20 not set not set
Other non hazardous ingredients secret to 100 not set not set
This is a commercial product whose exact ratio of components may vary slightly. Minor quantities of other non
hazardous ingredients are also possible.
The TWA exposure value is the average airborne concentration of a particular substance when calculated over a normal 8 hour working day for a 5
day working week. The STEL (Short Term Exposure Limit) is an exposure value that should not be exceeded for more than 15 minutes and should
not be repeated for more than 4 times per day. There should be at least 60 minutes between successive exposures at the STEL. The term "peak "is
used when the TWA limit, because of the rapid action of the substance, should never be exceeded, even briefly.
Section 4 - First Aid Measures
General Information:
You should call The Poisons Information Centre if you feel that you may have been poisoned, burned or irritated by
this product. The number is 13 1126 from anywhere in Australia (0800 764 766 in New Zealand) and is available at all
times. Have this MSDS with you when you call.
Inhalation: First aid is not generally required. If in doubt, contact a Poisons Information Centre or a doctor.
Skin Contact: If significant skin contact occurs, quickly contact a Poisons Information Centre, or call a doctor.
Gently blot or brush away excess chemical. Remove contaminated clothing, shoes and leather goods.(e.g.
watchbands, belts). Flush contaminated area with lukewarm , gently flowing water for at least 20-30 minutes, by the
clock. If irritation persists, continue flushing. DO NOT INTERRUPT FLUSHING. If necessary, keep emergency vehicle
waiting (show paramedics this MSDS and take their advice).
Eye Contact: Quickly and gently, blot or brush away chemical. Immediately flush the contaminated eye(s) with
lukewarm, gently flowing water for at least 20-30 minutes, by the clock, while holding the eyelid(s) open. Neutral
saline solution may be used as soon as it is available. DO NOT INTERRUPT FLUSHING. If necessary, keep
emergency vehicle waiting (show paramedics this MSDS and take their advice). Take care not to rinse contaminated
water into the unaffected eye or onto face. If irritation persists, repeat flushing. Call a Poisons Information Centre or a
doctor urgently.
Ingestion: If swallowed, rinse mouth thoroughly with water and contact a Poisons Information Centre. Urgent
hospital treatment is likely to be needed. Give activated charcoal if instructed.
Section 5 - Fire Fighting Measures
Fire and Explosion Hazards: There is no risk of an explosion from this product under normal circumstances if it is
involved in a fire.
Only small quantities of decomposition products are expected from this products at temperatures normally achieved in
a fire. This will only occur after heating to dryness.
Fire decomposition products from this product are likely to be irritating if inhaled.
Extinguishing Media: Water fog or fine spray is the preferred medium for large fires. Aim to dilute the material with
large quantities of water. If practical, contain diluted material and prevent from entering drains and water courses.
Fire Fighting: If a significant quantity of this product is involved in a fire, call the fire brigade. There is little danger of
a violent reaction or explosion if significant quantities of this product are involved in a fire. Recommended personal
protective equipment is liquid-tight chemical protective clothing and breathing apparatus.
Will not burn until water component is driven off.
Flash point:
Does not burn.
Upper Flammability Limit:
Does not burn.
Lower Flammability Limit:
Does not burn.
Autoignition temperature:
Does not burn.
Flammability Class:
MATERIAL SAFETY DATA SHEET
Issued by: Farmoz Pty Ltd Phone: (02)9431 7800
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
Product Name: Spraybuff BB5
Page: 3 of 5
This revision issued: June, 2008
Section 6 - Accidental Release Measures
Accidental release: In the event of a major spill, prevent spillage from entering drains or water courses. Evacuate
the spill area and deny entry to unnecessary and unprotected personnel. Wear full protective chemically resistant
clothing including eye/face protection, gauntlets and self contained breathing apparatus. See above under Personal
Protection regarding Australian Standards relating to personal protective equipment. Suitable materials for protective
clothing include rubber, PVC. Eye/face protective equipment should include a full face shield. If there is a significant
chance that vapours or mists are likely to build up in the cleanup area, we recommend that you use a respirator.
Usually, no respirator is necessary when using this product. However, if you have any doubts consult the Australian
Standard mentioned above.
Stop leak if safe to do so, and contain spill. Absorb onto sand, vermiculite or other suitable absorbent material. If spill
is too large or if absorbent material is not available, try to create a dike to stop material spreading or going into drains
or waterways. Because of the corrosiveness of this product, special personal care should be taken in any cleanup
operation. Sweep up and shovel or collect recoverable product into labelled containers for recycling or salvage, and
dispose of promptly. Recycle containers wherever possible after careful cleaning. Refer to product label for specific
instructions. After spills, wash area preventing runoff from entering drains. If a significant quantity of material enters
drains, advise emergency services. Contaminated area may be neutralised by washing with weak or dilute alkali.
Baking soda, washing soda and limestone are suitable. This material may be suitable for approved landfill. Ensure
legality of disposal by consulting regulations prior to disposal. Thoroughly launder protective clothing before storage
or re-use. Advise laundry of nature of contamination when sending contaminated clothing to laundry.
Section 7 - Handling and Storage
Handling: Keep exposure to this product to a minimum, and minimise the quantities kept in work areas. Check
Section 8 of this MSDS for details of personal protective measures, and make sure that those measures are followed.
The measures detailed below under "Storage" should be followed during handling in order to minimise risks to
persons using the product in the workplace. Also, avoid contact or contamination of product with incompatible
materials listed in Section 10.
Storage: This product is a Scheduled Poison. Observe all relevant regulations regarding sale, transport and storage
of this class of poison. Store in a cool, well ventilated area. Check containers periodically for corrosion and leaks.
Containers should be kept closed in order to minimise contamination. Make sure that the product does not come into
contact with substances listed under "Materials to avoid" in Section 10. If you keep more than 1000kg or 1000L of
Corrosive Substances of Packaging Group III, you will require a license to do so. If you have any doubts, we suggest
you contact your licensing authority in order to clarify your obligations. Check packaging - there may be further
storage instructions on the label.
Section 8 - Exposure Controls and Personal Protection
The following Australian Standards will provide general advice regarding safety clothing and equipment:
Respiratory equipment: AS/NZS 1715, Protective Gloves: AS 2161, Industrial Clothing: AS2919, Industrial Eye
Protection: AS1336 and AS/NZS 1337, Occupational Protective Footwear: AS/NZS2210.
TWA (mg/m3) STEL (mg/m3)
Exposure Limits
Phosphoric acid 1 3
Ventilation: No special ventilation requirements are normally necessary for this product. However make sure that
the work environment remains clean and that vapours and mists are minimised.
Eye Protection: Your eyes must be completely protected from this product by splash resistant goggles with face
shield. All surrounding skin areas must be covered. Emergency eye wash facilities must also be available in an area
close to where this product is being used.
Skin Protection: Because of the dangerous nature of this product, make sure that all skin areas are completely
covered by impermeable gloves, overalls, hair covering, apron and face shield. See below for suitable material types.
Protective Material Types: We suggest that protective clothing be made from the following materials: rubber,
PVC.
Respirator: Usually, no respirator is necessary when using this product. However, if you have any doubts consult
the Australian Standard mentioned above.
Eyebaths or eyewash stations and safety deluge showers should be provided near to where this product is being
used.
Section 9 - Physical and Chemical Properties:
Clear, almost colourless liquid.
Physical Description & colour:
Mild odour.
Odour:
Approximately 100掳C at 100kPa.
Boiling Point:
MATERIAL SAFETY DATA SHEET
Issued by: Farmoz Pty Ltd Phone: (02)9431 7800
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
Product Name: Spraybuff BB5
Page: 4 of 5
This revision issued: June, 2008
Approximately 5掳C.
Freezing/Melting Point:
Water component.
Volatiles:
2.37 kPa at 20掳C (water vapour pressure).
Vapour Pressure:
No data.
Vapour Density:
Approx 1.15-1.20
Specific Gravity:
Completely soluble in water.
Water Solubility:
Corrosive
pH:
No data.
Volatility:
No data.
Odour Threshold:
No data.
Evaporation Rate:
No data
Coeff Oil/water distribution:
Does not burn.
Autoignition temp:
Section 10 - Stability and Reactivity
Reactivity: Most strong acids react with inorganic and organic bases such as amines to form salts. They also react
with many metals liberating hydrogen gas. These reactions are often rapid and sometimes liberate much heat. They
can also decompose many organic materials such as esters, in a reaction called hydrolysis.
Conditions to Avoid: This product should be kept in a cool place, preferably below 30掳C. Under no circumstances
should the container be sealed.
Incompatibilities: bases, zinc, tin, aluminium and their alloys.
Fire Decomposition: Only small quantities of decomposition products are expected from this products at
temperatures normally achieved in a fire. This will only occur after heating to dryness. Carbon dioxide, and if
combustion is incomplete, carbon monoxide and smoke. Water.
Polymerisation: This product is unlikely to undergo polymerisation processes.
Section 11 - Toxicological Information
Local Effects:
Target Organs: There is no data to hand indicating any particular target organs.
Classification of Hazardous Ingredients
Ingredient Risk Phrases
Phosphoric Acid Conc鈮?25%: C; R34
Section 12 - Ecological Information
This product does not degrade naturally. It will not cause ecological problems because it does not enter biological
systems.
Section 13 - Disposal Considerations
Disposal: Containers should be emptied as completely as practical before disposal. If possible, recycle containers
either in-house or send to recycle company. If this is not practical, send to a commercial waste disposal site. Please
do NOT dispose into sewers or waterways. Special help is available for the disposal of Agricultural Chemicals. The
product label will give general advice regarding disposal of small quantities, and how to cleanse containers. However,
for help with the collection of unwanted rural chemicals, contact ChemClear 1800 008 182
http://www.chemclear.com.au/ and for help with the disposal of empty drums, contact DrumMuster
http://www.drummuster.com.au/ where you will find contact details for your area.
Section 14 - Transport Information
ADG Code: 1805, PHOSPHORIC ACID
Hazchem Code: 2R
Special Provisions: 223
Limited quantities: ADG 7 specifies a Limited Quantity value of 5 L for this class of product.
Dangerous Goods Class: Class 8, Corrosive Substances.
Packaging Group: III
Packaging Method: P001, IBC03, LP01
MATERIAL SAFETY DATA SHEET
Issued by: Farmoz Pty Ltd Phone: (02)9431 7800
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
Product Name: Spraybuff BB5
Page: 5 of 5
This revision issued: June, 2008
Class 8 Corrosive Substances shall not be loaded in the same vehicle or packed in the same freight container with
Classes 1 (Explosives), 4.3 (Dangerous When Wet Substances), 5.1 (Oxidising Agents), 5.2 (Organic Peroxides), 6
(Toxic Substances where the Toxic Substances are cyanides and the Corrosives are acids), 7 (Radioactive
Substances), Foodstuffs and foodstuff empties. They may however be loaded in the same vehicle or packed in the
same freight container with Classes 2.1 (Flammable Gases), 2.2 (Non-Flammable, Non-Toxic Gases), 2.3 (Poisonous
Gases), 3 (Flammable liquids), 4.1 (Flammable Solids), 4.2 (Spontaneously Combustible Substances), 6 (Toxic
Substances except where the Toxic Substances are cyanides and the Corrosives are acids) and 9 (Miscellaneous
Dangerous Goods).
Section 15 - Regulatory Information
AICS: All of the significant ingredients in this formulation are to be found in the public AICS Database.
The following ingredients: Phosphoric acid, are mentioned in the SUSDP.
Section 16 - Other Information
This MSDS contains only safety-related information. For other data see product literature.
Acronyms:
Australian Code for the Transport of Dangerous Goods by Road and Rail, 7th Edition
ADG Code
Australian Inventory of Chemical Substances
AICS
Chemical Abstracts Service Registry Number
CAS number
Emergency action code of numbers and letters that provide information to emergency
Hazchem Number
services especially firefighters
International Agency for Research on Cancer
IARC
Office of the Australian Safety and Compensation Council
ASCC
Not otherwise specified
NOS
National Toxicology Program (USA)
NTP
Risk Phrase
R-Phrase
Standard for the Uniform Scheduling of Drugs & Poisons
SUSDP
United Nations Number
UN Number
Contact Points:
Call Farmoz on (02)9431 7800 Fax: (02)9431 7700 and ask for the technical manager.
Police and Fire Brigade: Dial 000
Emergency contact: 1800 024 973 (24 hours)
If ineffective: Dial Poisons Information Centre
(13 1126 from anywhere in Australia)
The information contained in this Material Safety Data Sheet is provided in good faith and is believed to be correct at the date
hereof. However, it is expected that individuals receiving the information will exercise their independent judgement in determining
its appropriateness for a particular purpose. Farmoz Pty Ltd makes no representation as to the accuracy or comprehensiveness of
the information and to the full extent allowed by law excludes all liability whatsoever, whether with respect to negligence or
otherwise, for any loss or damage arising from or connection with the supply or use of the information in this Material Safety Data
Sheet.
Please read all labels carefully before using product.
This MSDS is prepared in accord with the ASCC document 鈥淣ational Code of Practice for the Preparation
of Material Safety Data Sheets鈥? 2nd Edition [NOHSC:2001(2003)]
Copyright 漏 Kilford & Kilford Pty Ltd, June, 2008.
http://www.kilford.com.au/ Phone (02)9251 4532
MATERIAL SAFETY DATA SHEET
Issued by: Farmoz Pty Ltd Phone: (02)9431 7800
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
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