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File Name: grevilliaag_com_au---msds_probuff_700.asp
Page聽1聽of聽4聽                                                           Probuff聽700聽


Issue聽Date:聽December聽2006聽 (Supersedes聽November聽2005)聽

MATERIAL聽SAFETY聽DATA聽SHEET聽
___________________________________________________________聽
1.聽 IDENTIFICATION聽
Product聽Name:聽PROBUFF聽700聽
Product聽Code:聽 PBUFF聽
Product聽 Use:聽 Acidifying聽 and聽 penetrating聽 surfactant.聽 Assists聽 with聽 uptake聽 of聽
foliar聽fertilizers聽and聽assists聽in聽management聽of聽spray聽droplet聽size.聽
Company聽Name:聽
GREVILLIA聽AG聽PTY聽LTD聽(ABN聽36聽083聽323聽817)聽
Address聽10聽Bult聽Drive聽Brendale聽Queensland聽4500聽Australia.聽
Emergency聽Tel聽24hr聽0428聽727聽300聽
Tel/Fax聽Tel:聽(07)聽3205聽1788聽Fax:聽(07)聽3205聽4327聽
______________________________________________________________聽
2.聽 HAZARD聽IDENTIFICATION聽
Not聽classified聽as聽hazardous聽under聽Worksafe聽Australia聽criteria聽
Proper聽Shipping聽Name:聽聽None聽Allocated聽
UN聽Number:聽聽None聽Allocated聽
DG聽Class聽None:聽 Allocated聽
Packing聽Group:聽 None聽Allocated聽
Hazchem聽Code:聽 None聽Allocated聽
Poisons聽Schedule:聽 Not聽Scheduled聽
______________________________________________________________聽
3.聽 COMPOSITION聽&聽INGREDIENTS:聽

Name聽 CAS聽 Proportion聽
Propionic聽acid聽 70颅09颅4聽 30颅40%聽
Soyal聽Phospholipids聽 8002颅43颅5聽 30颅40%聽
Nonyl聽phenol聽ethoxylates聽 26027颅38颅3聽 10颅30聽%聽
Water聽 balance聽
______________________________________________________________聽
4.聽 FIRST聽AID聽INFORMATION聽
If聽 Swallowed:聽 Rinse聽 mouth聽 and聽 drink聽 plenty聽 of聽 water.聽 Do聽 NOT聽 induce聽
Vomiting.聽Seek聽medical聽advice聽immediately.聽
If聽Eye聽Contact聽Occurs:聽 Flush聽with聽copious聽quantities聽of聽water聽for聽15聽minutes.聽
Seek聽medical聽attention.聽
If聽 Skin聽 Contact聽 Occurs:聽 Immediately聽 wash聽 effected聽 areas聽 thoroughly聽 with聽
water.聽Remove聽contaminated聽clothing聽and聽launder聽before聽re颅use.聽
If聽Inhalation聽of聽vapour聽occurs:聽Remove聽affected聽person聽to聽fresh聽air聽and聽seek聽
medical聽attention.聽

5.聽 FIRE聽FIGHTING聽MEASURES:聽
Extinguishing聽Media:聽聽聽Dry聽Chemical聽or聽Alcohol聽Foam聽
Special聽Procedures:聽 Wear聽breathing聽apparatus聽&聽Protective聽Clothing
Page聽2聽of聽4聽 Probuff聽700聽


Hazardous聽Decomposition聽Products:聽 May聽produce聽Carbon聽dioxide聽or聽carbon聽
monoxide聽
Unusual聽Hazards:聽 Vapours聽may聽travel聽to聽source聽of聽ignition聽

6.聽 ACCIDENTAL聽RELEASE聽MEASURES:聽
Spills聽鈥撀爉op聽up聽spills聽immediately聽with聽chemical聽absorbent.聽Prevent聽material聽
from聽 entering聽 drains.聽 Place聽 spilled聽 material聽 and聽 absorbent聽 into聽 disposable聽
containers聽for聽disposal聽at聽approved聽site.聽

7.聽 HANDLING聽&聽STORAGE:聽
Storage:聽 Store聽 material聽 in聽 original聽 containers.聽 Do聽 not聽 transfer聽 to聽 other聽
containers聽 which聽 may聽 have聽 other聽 chemical聽 contaminants聽 present.聽 Reseal聽
container聽 when聽 not聽 in聽 use.聽 Store聽 out聽 of聽 direct聽 sunlight.聽 Store聽 away聽 from聽
incompatible聽items聽as聽per聽Section聽10.聽
Handling:聽Avoid聽skin聽&聽eye聽contact.聽

8.聽 EXPOSURE聽CONTROL聽AND聽PERSONAL聽PROTECTION:聽
Ventilation:聽ensure聽adequate聽ventilation聽when聽using聽this聽material.聽
Personal聽 protective聽 clothing:聽 Use聽 gloves聽 and聽 eye/face聽 protection聽 when聽
pouring聽 this聽 material.聽 Use聽 of聽 long聽 sleeves聽 and聽 long聽 pants聽 is聽 strongly聽
recommended.聽Wash聽clothing聽after聽each聽work聽period.聽
Wash聽hands聽and聽face聽thoroughly聽when聽leaving聽work聽area聽of聽before聽ingestion聽
of聽food.聽

9.聽 PHYSICAL聽AND聽CHEMICAL聽PROPERTIES:聽
Appearance:聽聽Dark聽brown聽liquid聽
Odour:聽聽聽Pungent,聽vinegar颅like聽odour聽
Melting聽Point:聽聽聽聽聽N/A聽鈥撀爌roduct聽is聽a聽liquid聽
Boiling聽Point:聽聽聽聽not聽determined聽
Volatile聽Component:聽聽not聽determined聽
Specific聽Gravity:聽聽聽1.035聽
Flammability:聽聽聽Not聽flammable聽
Solubility:聽聽Disperses聽in聽water.聽
10. STABILITY聽AND聽REACTIVITY聽
Stability:聽 Stable聽under聽normal聽conditions.聽
Hazardous聽Polymerization聽 Hazardous聽polymerization聽is聽not聽possible.聽
Materials聽to聽Avoid:聽 Avoid聽contact聽with聽alkaline聽materials.聽
______________________________________________________________聽
11. TOXICOLOGICAL聽INFORMATION聽
Primary聽 routes聽 for聽 long聽 term聽 exposure聽 to聽 this聽 item聽 are聽 via聽 inhalation聽 or聽 skin聽
contact.聽 To聽 prevent聽 this聽 type聽 of聽 exposure,聽 please聽 refer聽 to聽 Exposure聽 Control聽
above.聽
Acute:聽
Skin:聽May聽cause聽irritation聽and聽redness途聽
Eyes:聽Will聽cause聽irritation,聽tearing聽and聽redness.
Page聽3聽of聽4聽 Probuff聽700聽


Inhalation:聽 Will聽 cause聽 irritation聽 or聽 the聽 mucous聽 membranes聽 and聽 respiratory聽
tract.聽 Prolonged聽 inhalation聽 of聽 vapours聽 or聽 mists聽 of聽 this聽 material聽 will聽 result聽 in聽
irritation聽 of聽 the聽 nose,聽 throat聽 and聽 lungs.聽 Symptoms聽 may聽 include聽 sore聽 throat,聽
nasal聽irritation,聽hoarseness聽of聽voice,聽coughing.聽
Acute聽Toxicity聽颅聽Oral聽LD50聽(rat)聽>5000聽mg/kg聽for聽a聽similar聽formulation聽
Acute聽Toxicity聽鈥撀燚ermal聽LD50聽(rabbit)聽>5000聽mg/kg聽for聽a聽similar聽formulation聽
Acute聽 Toxicity聽 鈥撀? Inhalation聽 LC50聽 (rat)聽 (4hr)聽 >6.04聽 mg/l聽 for聽 a聽 similar聽
formulation聽
Chronic:聽
No聽information聽available聽
12. ECOLOGICAL聽INFORMATION聽
The聽following聽information聽refers聽to聽the聽active聽ingredient聽propionic聽acid:聽
Acute聽Toxicity聽颅聽Fish聽LC50聽(96聽hr)聽for聽bluegill聽sunfish聽is聽210聽mg/l.聽
LC50聽(96聽hr)聽for聽rainbow聽trout聽is聽130聽mg/l.聽
______________________________________________________________聽
13. DISPOSAL聽CONSIDERATIONS聽
Container聽 Disposal:聽 Do聽 not聽 re颅use聽 containers聽 for聽 any聽 purpose.聽 Containers聽
should聽 be聽 thoroughly聽 rinsed聽 with聽 water聽 immediately聽 when聽 empty.聽 Crush聽
empty聽containers聽after聽piercing聽(to聽prevent聽re颅use)聽and聽dispose聽of聽in聽approved聽
landfill聽site.聽
Spills:聽 Collect聽 spilled聽 material聽 on聽 chemical聽 absorbent聽 and聽 dispose聽 of聽 spilled聽
material聽and聽waste聽in聽sealable聽open颅top聽type聽containers聽for聽disposal.聽Prevent聽
from聽entering聽drains,聽waterways聽or聽sewers.聽

14. TRANSPORT聽INFORMATION聽
Considered聽non颅dangerous聽good聽by聽the聽Australian聽Code聽for聽Transport聽by聽
Road聽and聽Rail.聽
UN聽No:聽聽None聽allocated.聽
DG聽Class:聽聽None聽allocated聽
Hazchem聽Code:聽聽None聽allocated聽
Packing聽Group:聽聽None聽allocated聽

15. REGULATORY聽INFORMATION聽
Packaging聽Labelling:聽聽Caution.聽Keep聽Out聽of聽Reach聽of聽Children.聽聽Read聽Safety聽
Directions聽Before聽Opening聽
AICS聽Status:聽聽All聽components聽are聽listed聽on聽the聽AICS.聽
______________________________________________________________聽
16. OTHER聽INFORMATION:聽
The聽 information聽 in聽 this聽 material聽 safety聽 data聽 sheet聽 refers聽 to聽 the聽 concentrated聽
material.聽When聽 diluted聽 as聽 described聽 on聽 the聽 label聽 the聽 acute聽 health聽 effects聽 of聽
exposure聽may聽be聽less聽severe.聽

This聽material聽safety聽data聽sheet聽supersedes聽all聽previous聽issues.
Page聽4聽of聽4聽 Probuff聽700聽


It聽 is聽 the聽 responsibility聽 of聽 the聽 Purchasers聽 of聽 this聽 product聽 to聽 ensure聽 that聽 all聽
safety聽 information聽 and聽 environmental聽 information聽 is聽 provided聽 to聽 any聽 people聽
who聽may聽use聽this聽product.聽

The聽information聽contained聽within聽this聽safety聽data聽sheet聽is聽correct聽to聽the聽best聽
of聽our聽knowledge聽and聽is聽provided聽in聽good聽faith.聽Grevillia聽Ag聽cannot聽control聽the聽
conditions聽 in聽 which聽 it聽 is聽 used聽 so聽 therefore聽 each聽 user聽 must,聽 prior聽 to聽 usage,聽
assess聽and聽control聽the聽risks聽arising聽from聽their聽use聽of聽the聽material聽

Contact聽Normal聽Hours:聽Mr聽John聽Lever聽Phone:聽(07)聽3205聽1788聽
After聽Hours:聽Mr聽John聽Lever聽Phone:聽0428聽727聽300聽


鈥?..End聽of聽MSDS鈥?.

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