Product Name: Farmoz Strike-Out WP Insecticide
Page: 1 of 6
This revision issued: October, 2006
Section 1 - Identification of Chemical Product and Company
Farmoz Pty Ltd, Suite 1, Level 4, Building B Telephone (02)9431 7800 (24 hours)
207 Pacific Highway St Leonards, NSW 2068 Fax (02)9431 7700
ACN 050 328 973
Substance: Chlorpyrifos is an organochlorine derivative.
Trade Name: Farmoz Strike-Out WP Insecticide
Product Use: Agricultural insecticide for use as described on the product label.
Creation Date: October, 2006
Revision Date: October, 2006
Section 2 - Hazards Identification
Statement of Hazardous Nature
This product is classified as: Hazardous according to the criteria of ASCC Australia.
Dangerous according to the Australian Dangerous Goods (ADG) Code.
Risk Phrases: R24/25. Toxic in contact with skin and if swallowed.
Safety Phrases: S20, S36. When using, do not eat or drink. Wear suitable protective clothing.
SUSDP Classification: S6
ADG Classification: Class 6.1 (ORGANOPHOSPHORUS PESTICIDE, SOLID, TOXIC)
UN Number: 2783
Emergency Overview
Physical Description & colour: Off-white powder in a water soluble measure pack.
Odour: No odour.
Major Health Hazards: Chlorpyrifos is harmful to humans. Poisoning from chlorpyrifos may affect the central
nervous system, the cardiovascular system, and the respiratory system. It is also a skin and eye irritant. While some
organophosphates are readily absorbed through the skin, studies in humans suggest that skin absorption of
chlorpyrifos is limited. Signs and symptoms associated with mild exposures to organophosphate and carbamate
pesticides include: headache, fatigue, dizziness, loss of appetite with nausea, stomach cramps and diarrhoea; blurred
vision associated with excessive tearing; contracted pupils of the eye; excessive sweating and salivation; slowed
heartbeat, often fewer than 50 per minute; rippling of surface muscles just under the skin. These symptoms may be
mistaken for those of flu, heat stroke or heat exhaustion, or upset stomach. Moderately severe organophosphate and
carbamate insecticide poisoning cases exhibit all the signs and symptoms found in mild poisonings, but in addition,
the victim: is unable to walk; often complains of chest discomfort and tightness; exhibits marked constriction of the
pupils (pinpoint pupils); exhibits muscle twitching; has involuntary urination and bowel movement. Severe poisonings
are indicated by incontinence, unconsciousness and seizures.
Potential Health Effects
See section 11 for Chronic exposure studies.
Inhalation
Short term exposure: Symptoms are described fully above. Not expected to be likely due to the presentation of
the product.
Skin Contact:
Short term exposure: Symptoms are described fully above.
Eye Contact:
Short term exposure: This product is believed to be not irritating to eyes.
Ingestion:
Short term exposure: Symptoms are described fully above.
Long Term exposure: No data for health effects associated with long term ingestion.
Carcinogen Status:
ASCC: No significant ingredient is classified as carcinogenic by ASCC.
NTP: No significant ingredient is classified as carcinogenic by NTP.
IARC: No significant ingredient is classified as carcinogenic by IARC.
MATERIAL SAFETY DATA SHEET
Issued by: Farmoz Pty Ltd Phone: (02)9431 7800
Product Name: Farmoz Strike-Out WP Insecticide
Page: 2 of 6
This revision issued: October, 2006
Section 3 - Composition/Information on Ingredients
TWA (mg/m3) STEL (mg/m3)
Ingredients CAS No Conc,%
Chlorpyrifos 2921-88-2 50 0.2 not set
Other non hazardous ingredients secret to 100 not set not set
This is a commercial product whose exact ratio of components may vary slightly. Minor quantities of other non
hazardous ingredients are also possible.
The TWA exposure value is the average airborne concentration of a particular substance when calculated over a normal 8 hour working day for a 5
day working week. The STEL (Short Term Exposure Limit) is an exposure value that should not be exceeded for more than 15 minutes and should
not be repeated for more than 4 times per day. There should be at least 60 minutes between successive exposures at the STEL. The term "peak "is
used when the TWA limit, because of the rapid action of the substance, should never be exceeded, even briefly.
Section 4 - First Aid Measures
General Information:
You should call The Poisons Information Centre if you feel that you may have been poisoned, burned or irritated by
this product. The number is 13 1126 from anywhere in Australia (0800 764 766 in New Zealand) and is available at all
times. Have this MSDS with you when you call.
Atropine tablets 0.6mg and activated charcoal should be available in the area where this product is used, or in a
nearby unlocked medicine cabinet. If swallowed, splashed on skin or inhaled, contact a Poisons Information Centre or
a doctor at once. Remove any contaminated clothing and wash skin thoroughly. If swallowed, use of activated
charcoal may be advised. Give atropine if instructed. The usual instruction is to give one atropine tablet every 5
minutes until dryness of the mouth occurs.
Inhalation: First aid is not generally required. If in doubt, contact a Poisons Information Centre or a doctor. See
instructions above about treatment with atropine.
Skin Contact: No specific health data is available for this product. If any unusual symptoms become evident, or if in
doubt, contact a Poisons Information Centre or a doctor. See instructions above about treatment with atropine.
Eye Contact: First aid is not generally required. If in doubt, contact a Poisons Information Centre or a doctor.
Ingestion: If swallowed, rinse mouth thoroughly with water and contact a Poisons Information Centre, or call a
doctor at once. Give activated charcoal if instructed. See instructions above about treatment with atropine.
Section 5 - Fire Fighting Measures
Fire and Explosion Hazards: There is no risk of an explosion from this product under normal circumstances if it is
involved in a fire.
Fire decomposition products from this product may be toxic if inhaled. Take appropriate protective measures.
Extinguishing Media: Preferred extinguishing media are carbon dioxide, dry chemical, foam, water fog. Water fog
or fine spray is the preferred medium for large fires.
Fire Fighting: When fighting fires involving significant quantities of this product, wear a splash suit complete with
self contained breathing apparatus.
Flash point: Not flammable.
Upper Flammability Limit: No data.
Lower Flammability Limit: No data.
Autoignition temperature: No data.
Flammability Class: No data.
Section 6 - Accidental Release Measures
Accidental release: In the event of a major spill, prevent spillage from entering drains or water courses. Evacuate
the spill area and deny entry to unnecessary and unprotected personnel. Wear full protective chemically resistant
clothing including face mask, face shield, gauntlets and self contained breathing apparatus. See above under
Personal Protection regarding Australian Standards relating to personal protective equipment. Suitable materials for
protective clothing include rubber, PVC. Stop leak if safe to do so, and contain spill. Because of the toxicity of this
product, special personal care should be taken in any cleanup operation. Sweep up and shovel or collect recoverable
product into labelled containers for recycling or salvage, and dispose of promptly. After spills, wash area preventing
runoff from entering drains. If a significant quantity of material enters drains, advise emergency services. Full details
regarding disposal of used containers, spillage and unused material may be found on the label. If there is any conflict
between this MSDS and the label, instructions on the label prevail. Ensure legality of disposal by consulting
regulations prior to disposal. Thoroughly launder protective clothing before storage or re-use. Advise laundry of nature
of contamination when sending contaminated clothing to laundry.
MATERIAL SAFETY DATA SHEET
Issued by: Farmoz Pty Ltd Phone: (02)9431 7800
Product Name: Farmoz Strike-Out WP Insecticide
Page: 3 of 6
This revision issued: October, 2006
Section 7 - Handling and Storage
Handling: Keep exposure to this product to a minimum, and minimise the quantities kept in work areas. Check
Section 8 of this MSDS for details of personal protective measures, and make sure that those measures are followed.
The measures detailed below under "Storage" should be followed during handling in order to minimise risks to
persons using the product in the workplace. Also, avoid contact or contamination of product with incompatible
materials listed in Section 10.
Storage: This product is a Scheduled Poison. Observe all relevant regulations regarding sale, transport and storage
of this class of poison. Store in a cool, well ventilated area. Check containers periodically for leaks. Containers should
be kept closed in order to minimise contamination. Make sure that the product does not come into contact with
substances listed under "Materials to avoid" in Section 10. If you keep more than 1000kg or 1000L of Toxic
Substances of Packaging Group III, you will require a license to do so. If you have any doubts, we suggest you
contact your licensing authority in order to clarify your obligations. Check packaging - there may be further storage
instructions on the label.
Section 8 - Exposure Controls and Personal Protection
The following Australian Standards will provide general advice regarding safety clothing and equipment:
Respiratory equipment: AS/NZS 1715, Protective Gloves: AS 2161, Industrial Clothing: AS2919, Industrial Eye
Protection: AS1336 and AS/NZS 1337, Occupational Protective Footwear: AS/NZS2210.
TWA (mg/m3) STEL (mg/m3)
ASCC Exposure limits
chlorpyrifos 0.2 not set
The ADI for chlorpyrifos is set at 0.003mg/kg/day. The corresponding NOEL is set at 0.03mg/kg/day. ADI means
Acceptable Daily Intake and NOEL means No-observable-effect-level. Values taken from Australian ADI List, Dec
2005.
Ventilation: No special ventilation requirements are normally necessary for this product. However make sure that
the work environment remains clean and that dusts and vapours are minimised.
Eye Protection: Eye protection is not normally necessary when this product is being used. However, if in doubt,
wear suitable protective glasses or goggles.
Skin Protection: It is essential that all skin areas are adequately covered by impermeable gloves, overalls, hair
covering, apron and face shield. See below for suitable material types.
Protective Material Types: We suggest that protective clothing be made from the following materials: rubber,
PVC.
Respirator: If there is a significant chance that dusts are likely to build up in the area where this product is being
used, we recommend that you use a suitable Dust Mask.
Safety deluge showers should be provided near to where this product is being used.
Section 9 - Physical and Chemical Properties:
Physical Description & colour: Off-white powder in a water soluble measure pack.
Odour: No odour.
Boiling Point: Not applicable.
Freezing/Melting Point: Decomposes before melting.
Volatiles: No specific data. Expected to be low at 100掳C.
Vapour Pressure: No data.
Vapour Density: No data.
Specific Gravity: No data.
Water Solubility: Soluble.
pH: No data.
Volatility: No data.
Odour Threshold: No data.
Evaporation Rate: No data.
Coeff Oil/water distribution: Chlorpyrifos 4.7 (log P octanol/water)
Autoignition temp: No data.
Section 10 - Stability and Reactivity
Reactivity: This product is unlikely to react or decompose under normal storage conditions. However, if you have
any doubts, contact the supplier for advice on shelf life properties.
Conditions to Avoid: This product should be kept in a cool place, preferably below 30掳C. Containers should be
kept dry.
MATERIAL SAFETY DATA SHEET
Issued by: Farmoz Pty Ltd Phone: (02)9431 7800
Product Name: Farmoz Strike-Out WP Insecticide
Page: 4 of 6
This revision issued: October, 2006
Incompatibilities: strong acids, strong bases, strong oxidising agents.
Fire Decomposition: Carbon dioxide, and if combustion is incomplete, carbon monoxide and smoke. Nitrogen and
its compounds, and under some circumstances, oxides of nitrogen. Occasionally hydrogen cyanide gas. Oxides of
sulfur (sulfur dioxide is a respiratory hazard) and other sulfur compounds. Most will have a foul odour. Oxides of
phosphorus and other phosphorus compounds. Hydrogen chloride gas, other compounds of chlorine. Water. Carbon
monoxide poisoning produces headache, weakness, nausea, dizziness, confusion, dimness of vision, disturbance of
judgment, and unconsciousness followed by coma and death. Hydrogen cyanide poisoning signs and symptoms are
weakness, dizziness, headache, nausea, vomiting, coma, convulsions, and death. Death results from respiratory
arrest. Hydrogen cyanide gas acts very rapidly; symptoms and death can both occur quickly.
Polymerisation: This product is unlikely to undergo polymerisation processes.
Section 11 - Toxicological Information
Toxicity: An information profile for Chlorpyrifos is available at http://extoxnet.orst.edu/pips/ghindex.html
Acute toxicity: Chlorpyrifos is harmful to humans. Symptoms of acute exposure to organophosphate or
cholinesterase-inhibiting compounds may include the following: numbness, tingling sensations, incoordination,
headache, dizziness, tremor, nausea, abdominal cramps, sweating, blurred vision, difficulty breathing or respiratory
depression, and slow heartbeat. Very high doses may result in unconsciousness, incontinence, and convulsions or
fatality. Persons with respiratory ailments, recent exposure to cholinesterase inhibitors, cholinesterase impairment, or
liver malfunction are at increased risk from exposure to chlorpyrifos. The oral LD50 for chlorpyrifos in rats is 95 to 270
mg/kg. The LD50 for chlorpyrifos is 60 mg/kg in mice, 1000 mg/kg in rabbits, 32 mg/kg in chickens, 500 to 504 mg/kg
in guinea pigs, and 800 mg/kg in sheep. The dermal LD50 is greater than 2000 mg/kg in rats, and 1000 to 2000
mg/kg in rabbits. The 4-hour inhalation LC50 for chlorpyrifos in rats is greater than 0.2 mg/L.
Chronic toxicity: Repeated or prolonged exposure to organophosphates may result in the same effects as acute
exposure including the delayed symptoms. Other effects reported in workers repeatedly exposed include impaired
memory and concentration, disorientation, severe depressions, irritability, confusion, headache, speech difficulties,
delayed reaction times, nightmares, sleepwalking, and drowsiness or insomnia. Rats and mice given technical
chlorpyrifos in the diet for 104 weeks showed no adverse effects other than cholinesterase inhibition. Two-year
feeding studies using doses of 1 and 3 mg/kg/day of chlorpyrifos in rats showed moderate depression of
cholinesterase. Cholinesterase levels recovered when the experimental feeding was discontinued. Identical results
occurred in a 2-year feeding study with dogs. Human volunteers who ingested 0.1 mg/kg/day of chlorpyrifos for 4
weeks showed significant plasma cholinesterase inhibition.
Reproductive effects: Current evidence indicates that chlorpyrifos does not adversely affect reproduction.
Teratogenic effects: Available evidence suggests that chlorpyrifos is not teratogenic. No birth defects were seen in
the offspring of male and female rats fed 1.0 mg/kg/day during a three-generation reproduction and fertility study.
Mutagenic effects: There is no evidence that chlorpyrifos is mutagenic. No evidence of mutagenicity was found in
any of four tests performed.
Carcinogenic effects: There is no evidence that chlorpyrifos is carcinogenic.
Organ toxicity: Chlorpyrifos primarily affects the nervous system through inhibition of cholinesterase, an enzyme
required for proper nerve functioning.
Fate in humans and animals: Chlorpyrifos is readily absorbed into the bloodstream through the gastrointestinal tract
if it is ingested, through the lungs if it is inhaled, or through the skin if there is dermal exposure. In humans,
chlorpyrifos and its principal metabolites are eliminated rapidly.
Section 12 - Ecological Information
Effects on birds: Chlorpyrifos is moderately to very highly toxic to birds.
Effects on aquatic organisms: Chlorpyrifos is very highly toxic to freshwater fish, aquatic invertebrates and
estuarine and marine organisms. Cholinesterase inhibition was observed in acute toxicity tests of fish exposed to very
low concentrations of this insecticide. Application of concentrations as low as 0.01 pounds of active ingredient per
acre may cause fish and aquatic invertebrate deaths. Due to its high acute toxicity and its persistence in sediments,
chlorpyrifos may represent a hazard to sea bottom dwellers. Smaller organisms appear to be more sensitive than
larger ones.
Effects on other organisms: Aquatic and general agricultural uses of chlorpyrifos pose a serious hazard to wildlife
and honeybees.
Environmental Fate:
Breakdown in soil and groundwater: Chlorpyrifos is moderately persistent in soils. The half-life of chlorpyrifos in
soil is usually between 60 and 120 days, but can range from 2 weeks to over 1 year, depending on the soil type,
climate, and other conditions. Chlorpyrifos adsorbs strongly to soil particles and it is not readily soluble in water. It is
therefore immobile in soils and unlikely to leach or to contaminate groundwater. TCP, the principal metabolite of
chlorpyrifos, adsorbs weakly to soil particles and appears to be moderately mobile and persistent in soils.
Breakdown in water: The concentration and persistence of chlorpyrifos in water will vary depending on the type of
formulation. The rate of hydrolysis is constant in acidic to neutral waters, but increases in alkaline waters. In water at
pH 7.0 and 25掳C, it had a half-life of 35 to 78 days.
MATERIAL SAFETY DATA SHEET
Issued by: Farmoz Pty Ltd Phone: (02)9431 7800
Product Name: Farmoz Strike-Out WP Insecticide
Page: 5 of 6
This revision issued: October, 2006
Breakdown in vegetation: Chlorpyrifos may be toxic to some plants, such as lettuce. Residues remain on plant
surfaces for approximately 10 to 14 days. Data indicate that this insecticide and its soil metabolites can accumulate in
certain crops.
Section 13 - Disposal Considerations
Disposal: There are many pieces of legislation covering waste disposal and they differ in each state and territory, so
each user must refer to laws operating in their area. In some areas, certain wastes must be tracked. The Hierarchy of
Controls seems to be common - the user should investigate: Reduce, Reuse, and Recycle and only if all else fails
should disposal be considered. Note that properties of a product may change in use, so that the following suggestions
may not always be appropriate. The following may help you in properly addressing this matter for this product. Special
help is available for the disposal of Agricultural Chemicals. The product label will give general advice regarding
disposal of small quantities, and how to cleanse containers. However, for help with the collection of unwanted rural
chemicals, contact ChemClear 1800 008 182 http://www.chemclear.com.au/ and for help with the disposal of empty
drums, contact DrumMuster http://www.drummuster.com.au/ where you will find contact details for your area.
Section 14 - Transport Information
ADG Code: 2783, ORGANOPHOSPHORUS PESTICIDE, SOLID, TOXIC
Hazchem Code: 2X
Special Provisions: SP61, SP109, SP274
Dangerous Goods Class: Class 6.1, Toxic Substances.
Packaging Group: III
Packaging Method: 3.8.6
Class 6 Toxic Substances shall not be loaded in the same vehicle or packed in the same freight container with
Classes 1 (Explosives), 3 (Flammable Liquids where the Flammable Liquid is nitromethane), 5.1 (Oxidising Agents
where the Toxic Substances are Fire Risk Substances), 5.2 (Organic Peroxides where the Toxic Substances are Fire
Risk Substances), 8 (Corrosive Substances where the Toxic Substances are cyanides and the Corrosives are acids),
Foodstuffs and foodstuff empties. They may however be loaded in the same vehicle or packed in the same freight
container with Classes, 2.1 (Flammable Gases), 2.2 (Non-Flammable, Non-Toxic Gases), 2.3 (Toxic Gases), 3
(Flammable liquids, except where the flammable liquid is nitromethane), 4.1 (Flammable Solids), 4.2 (Spontaneously
Combustible Substances), 4.3 (Dangerous When Wet Substances), 5.1 (Oxidising Agents except where the Toxic
Substances are Fire Risk Substances), 5.2 (Organic Peroxides except where the Toxic Substances are Fire Risk
Substances), 7 (Radioactive Substances), 8 (Corrosive Substances except where the Toxic Substances are cyanides
and the Corrosives are acids), 9 (Miscellaneous Dangerous Goods)
Section 15 - Regulatory Information
AICS: This product is compliant with NICNAS regulations.
The following ingredient: chlorpyrifos, is mentioned in the SUSDP.
Section 16 - Other Information
Much of the Information in this MSDS came from Extoxnet, a Pesticide Information Project of Cooperative Extension
Offices of Cornell University, Oregon State University, the University of Idaho, and the University of California at Davis
and the Institute for Environmental Toxicology, Michigan State University.
This MSDS contains only safety-related information. For other data see product literature.
ADG Code Australian Code for the Transport of Dangerous Goods by Road and Rail
AICS Australian Inventory of Chemical Substances
ASCC Office of the Australian Safety and Compensation Council
CAS number Chemical Abstracts Service Registry Number
Hazchem Code Emergency action code of numbers and letters that provide information to
emergency services especially firefighters
IARC International Agency for Research on Cancer
NOS Not otherwise specified
NTP National Toxicology Program (USA)
R-Phrase Risk Phrase
SUSDP Standard for the Uniform Scheduling of Drugs & Poisons
UN Number United Nations Number
Contact Points:
Call Farmoz on (02)9431 7800 and ask for the technical manager. Fax: (02)9431 7700
MATERIAL SAFETY DATA SHEET
Issued by: Farmoz Pty Ltd Phone: (02)9431 7800
Product Name: Farmoz Strike-Out WP Insecticide
Page: 6 of 6
This revision issued: October, 2006
Police and Fire Brigade: Dial 000
Emergency contact: 1800 024 973 (24 hours)
If ineffective: Dial Poisons Information Centre
(13 1126 from anywhere in Australia)
The information contained in this Material Safety Data Sheet is provided in good faith and is believed to be correct at the date
hereof. However, it is expected that individuals receiving the information will exercise their independent judgement in determining
its appropriateness for a particular purpose. Farmoz Pty Ltd makes no representation as to the accuracy or comprehensiveness of
the information and to the full extent allowed by law excludes all liability whatsoever, whether with respect to negligence or
otherwise, for any loss or damage arising from or connection with the supply or use of the information in this Material Safety Data
Sheet.
Please read all labels carefully before using product.
This MSDS is prepared in accord with the ASCC document 鈥淣ational Code of Practice for the Preparation
of Material Safety Data Sheets鈥? 2nd Edition [NOHSC:2011(2003)]
Copyright 漏 Kilford & Kilford Pty Ltd, October, 2006.
http://www.kilford.com.au/ Phone (02)9251 4532
MATERIAL SAFETY DATA SHEET
Issued by: Farmoz Pty Ltd Phone: (02)9431 7800
|