Zep Manufacturing Co. of Canada
Material Safety Data Sheet
11627 178th Street
Edmonton, Alberta T5S 1N6
1-800-I-BUY-ZEP
and Safe Handling and Disposal Information
Section 1. Chemical Product and Company Identification
Product name CITRUS CLEANER
Product Use General-purpose cleaner.
Product Code 0455
Date of issue Supersedes09/17/03
08/02/06
Emergency For MSDS Information:
Telephone Technical Services Group
Zep Manufacturing of Canada
Numbers
Telephone: (780) 453-8100 (Business Hours 8:00-5:00)
For a Medical or Transportation Emergency:
CANUTEC (24 Hours)
(613) 996-6666 - Call Collect
Prepared by Technical Services Group
Zep Manufacturing Co. of Canada
11627 178th Street
Edmonton, Alberta T5S 1N6
Printing date: 04/08/06
Date of Preparation : 08/02/06
Section 2. Composition, Information on Ingredients
Name of Hazardous Ingredients CAS # % by Weight Toxicity Data
D-LIMONENE; orange distillate; citrus terpene; cyclohexene, 5989-27-5 3-7 LD50 Rat Oral >5000 mg/kg
1-methyl-4-(1-methylethenyl)-, (R)- LD50 Rabbit Dermal >5000 mg/kg
MONOETHANOLAMINE; 2-aminoethanol; MEA 141-43-5 1-5 LD50 Rat. Oral 1720 mg/kg
LD50 Rabbit Dermal >1000 mg/kg
PROPYLENE GLYCOL; 1,2-dihydroxypropane,1,2-propanediol 57-55-6 1-5 LD50 Rat. Oral 200 mg/kg
LD50 Mouse. Oral 240 mg/kg
LD50 Dog. Oral 260 mg/kg
LD50 Rabbit. Dermal 208 mg/kg
ETHYLENE GLYCOL MONOBUTYL ETHER; 111-76-2 1-5 LD50 Rat Oral 1746 mg/kg
2-butoxyethanol; butyl cellosolv LD50 Rabbit Dermal 680 mg/kg
LC50 Rat Inhalation 450 ppm (4
(Female) hour(s))
Section 3. Hazards Identification
Acute Effects Routes of EntrySkin contact, Inhalation.
Skin Prolonged or repeated contact may dry skin and cause irritation. Skin inflammation is characterized by itching, scaling,
or reddening. May cause sensitization by skin contact.
Eyes Causes eye irritation. Inflammation of the eye is characterized by redness, watering, and itching.
Inhalation May cause respiratory tract irritation.
Ingestion No data on acute toxicity of the product when ingested. May cause mild gastric irritation, abdonimal spasms, nau
and faintness.
Chronic Effects Prolonged or repeated contact may dry skin and cause irritation. The substance may be toxic to blood,
kidneys, liver. Repeated or prolonged exposure to the substance can produce target organs damage.
Additional information : See Toxicological Information (section 11)
Section 4. First Aid Measures
Eye Contact In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical
attention if irritation develops.
Skin Contact In case of contact, immediately flush skin with plenty of water. Get medical attention if irritation develops.
If excessive quantities inhaled, remove to fresh air. If symptoms persist, seek immediate medical attention.
Inhalation
Ingestion Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to
an unconscious person. If affected person is conscious, give plenty of water to drink. Get medical attention
immediately.
Section 5. Fire Fighting Measures
Flammable LimitsNot determined.
Flash Point Closed cup: >51掳C (124掳F)(Tagliabue.)
COMBUSTIBLE.
Flammability
Auto-ignition Temperature
Fire-Fighting Procedures Use DRY chemicals, CO water spray or foam. Cool closed containers exposed to fire with
2,
water. Wear special protective clothing and positive pressure, self-contained breathing
apparatus.
Fire Hazard Combustible liquid and vapor.
Products of Combustion Carbon Dioxide, Carbon Monoxide and other organic materials..
Explosion hazard
Page: 1/3
Material Safety Data Sheet Product Name CITRUS CLEANER
Product Code 0455
Section 6. Accidental Release Measures
Spill Clean up Eliminate all ignition sources. Put on appropriate personal protective equipment (see Section 8). Absorb with an
inert material and place in an appropriate waste disposal container. To clean the floor and all objects
contaminated by this material, use detergent. Finish cleaning by spreading water on the contaminated surface and
dispose of according to local and regional authority requirements.
Section 7. Handling and Storage
Handling Store and use away from heat, sparks, open flame, or any other ignition source. Avoid contact with skin and
eyes. Wash contaminated clothing before reusing. Wash thoroughly after handling.
Storage Store and use away from heat, sparks, open flame, or any other ignition source. Keep container tightly closed in
a cool, well-ventilated place. Store between 40掳F - 120掳F.
Section 8. Exposure Controls, Personal Protection
Engineering Controls Good general ventilation should be sufficient to control airborne levels.
Personal Protection Protective Clothing (Pictograms)
Eyes Recommended: Use safety eyewear designed to protect against splash of
liquids.
Hands and Body For prolonged or repeated handling, use gloves.. (Nitrile gloves)
Respiratory Use with adequate ventilation. Provide local exhaust ventilation to maintain airborne concentrations below
established exposure limits. Local exhaust ventilation is preferred because it prevents contaminant dispersion into
the work area by controlling it at its source.
Exposure Limits
Name of Hazardous Ingredients CAS # Exposure Limits
Monoethanolamine 141-43-5 OSHA PEL / ACGIH TLV (United States).
TWA: 3 ppm 8 hour(s).
OSHA /ACGIH (United States).
STEL: 6 ppm 15 minute(s).
Ethylene Glycol Monobutyl Ethe 111-76-2 ACGIH TLV (United States).
TWA: 20 ppm 8 hour(s).
OSHA PEL (United States). Skin
TWA: 50 ppm 8 hour(s).
Consult local authorities for acceptable exposure limits.
Section 9. Physical and Chemical Properties
Physical State Thin liquid Color Orange.
Odor Citrus (Strong.)
pH 11.2 - 11.8
Vapor Pressure 0.004 kPa (0.03 mmHg) (at 20掳C)
Boiling Point Not available.
Vapor Density Not determined.
Freezing Point Not available.
Evaporation Rate1 compared to Water
Specific Gravity 1.01 (Water = 1)
VOC (Consumer) 100.7 g/l (9.99%; 0.84 lb/gal.)
Solubility Soluble in water.
Section 10. Stability and Reactivity
Stability and Reactivity The product is stable.
Incompatibility Avoid contact with strong oxidizers, excessive heat, sparks or open flame. Incompatible with some
strong acids.
Reactivity Will not occur.
Hazardous Decomposition Products Carbon Dioxide, Carbon Monoxide and other organic materials..
Section 11. Toxicological Information
Carcinogenic Effects Ingredients: Not listed as carcinogen by OSHA, NTP or IARC.
Reproductive Effects
Mutagenic Effects
Teratogenic Effects
Section 12. Ecological Information
Ecotoxicity Not available.
Biodegradable/OECD Not available.
Section 13. Disposal Considerations
Waste Stream Code: D001
Waste Information Waste must be disposed according to applicable
Classification: Hazardous Waste
regulations. Consult your local or regional
Origin: RCRA
authorities.
Page: 2/3
Material Safety Data Sheet Product Name CITRUS CLEANER
Product Code 0455
Section 14. Transport Information
Label
Regulatory UN Proper shipping Class Packing Additional
Information number name Group information
Not Not a TDG
TDG
regulated. controlled
Classification
material.
Limited Quantity: Small quantities of controlled goods are not regulated as Dangerous Goods according to the TDG regulations.
Section 15. Regulatory Information
WHMIS (Canada) Class B-3: Combustible liquid with a flash point between 37.8掳C (100掳F) and 93.3掳C (200掳F).
Class D-2B: Material causing other toxic effects (TOXIC).
Other Regulations Not available.
This product has been classifed according to the hazard criteria of the CPR and the MSDS contains all of the available information required by the CPR.
Section 16. Other Information
To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any
liability whatsoever for the accuracy or completeness of the information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with cautio
Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exis
|