Zep Inc.
Material Safety Data Sheet
1310 Seaboard Industrial Blvd.
Atlanta, GA 30318
1-877-I-BUY-ZEP (428-9937)
and Safe Handling and Disposal Information
www.zep.com
Section 1. Chemical Product and Company Identification
Product name CITRUS CLEANER
Cleaner. Degreaser
Product use
Product code 0455
Date of issue Supersedes 03/17/04
04/27/07
Emergency For MSDS Information:
Telephone Compliance Services 1-877-I-BUY-ZEP (428-9937)
Numbers
For Medical Emergency
INFOTRAC: (877) 541-2016 Toll Free - All Calls
Recorded
For Transportation Emergency
CHEMTREC: (800) 424-9300 - All Calls Recorded
In the District of Columbia (202) 483-7616
Prepared By
Compliance Services
Printing date: 07/31/08
1420 Seaboard Industrial Blvd.
Atlanta, GA 30318
Section 2. Composition, Information on Ingredients
Name of hazardous ingredients CAS # % by Weight Exposure Limits
D-LIMONENE; orange distillate; citrus terpene; cyclohexene, 1-methyl- 5989-27-5 1-5 Not established
4-(1-methylethenyl)-, (R)-
MONOETHANOLAMINE; 2-aminoethanol; MEA 141-43-5 1-5 OSHA PEL / ACGIH TLV (United States).
TWA: 3 ppm 8 hour(s).
OSHA /ACGIH (United States).
STEL: 6 ppm 15 minute(s).
ETHYLENE GLYCOL MONOBUTYL ETHER; 2-butoxyethanol; butyl 111-76-2 1-5 ACGIH TLV (United States).
cellosolve TWA: 20 ppm 8 hour(s).
OSHA PEL (United States). Skin
TWA: 50 ppm 8 hour(s).
DIPROPYLENE GLYCOL N-BUTYL ETHER; 1-(2-butoxy-1-methoxy)- 29911-28-2 1-5 Not established
2-propanol; Glycol Ether DPNB
Section 3. Hazards Identification HMIS
Health 1
Routes of Entry Dermal contact. Eye contact. Inhalation.
Acute Effects
Fire Hazard 2
Prolonged or repeated contact may dry skin and cause irritation. Skin inflammation is
Skin Reactivity 0
characterized by itching, scaling, or reddening. Product may be dermal absorbed. May cause
skin sensitization.
Causes eye irritation. Inflammation of the eye is characterized by redness, watering and
Eyes Personal Protection B
itching.
Inhalation Avoid breathing vapors, spray or mists. Over-exposure by inhalation may cause respiratory
irritation. Can cause central nervous system (CNS) depression.
Ingestion Can cause gastrointestinal disturbances.
NOTE: MSDS data pertains to the product as delivered in the original shipping container(s). Risk of adverse health effects are lessened by
following all prescribed safety precautions, including use of proper personal protective equipment.
Ingredients: Not listed as carcinogen by OSHA, NTP or IARC.
Carcinogenic Effects
The substance may be toxic to blood, kidneys, lungs, liver, upper respiratory tract, skin, eyes, central
Chronic Effects
nervous system (CNS). Overexposure of this product by inhalation or absorption can produce central
nervous system depression resulting in headache, nausea and/or dizziness. Repeated or prolonged
exposure to the substance can produce target organs damage.
See Toxicological Information (section 11)
Section 4. First Aid Measures
Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water
Eye Contact
for at least 15 minutes. Get medical attention immediately.
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing
Skin Contact
contaminated clothing and shoes. Wash clothing before reuse. Get medical attention if irritation develops.
If inhaled, remove to fresh air. If irritation persists, get medical attention.
Inhalation
Do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an
Ingestion
unconscious person. If affected person is conscious, give plenty of water to drink. Get medical attention
immediately.
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Product code 0455 Product Name CITRUS CLEANER
Material Safety Data Sheet
Section 5. Fire Fighting Measures
Closed cup: >51掳C (123.8掳F). Flammable Limits Not determined. 2
Flash Point
(Tagliabue.) 1 0
COMBUSTIBLE.
Flammability
Combustible liquid and vapor.
Fire hazard
Use dry chemical, CO2, water spray (fog) or foam. Cool closed containers
Fire-fighting procedures
exposed to fire with water. Wear special protective clothing and positive
pressure, self-contained breathing apparatus.
Section 6. Accidental Release Measures
Eliminate all ignition sources. Put on appropriate personal protective equipment (see section 8). Absorb with
Spill Clean up
an inert material and place in an appropriate waste disposal container. To clean the floor and all objects
contaminated by this material, use [***]. detergent. Finish cleaning by spreading water on the contaminated
surface and dispose of according to local and regional authority requirements.
Section 7. Handling and Storage
Keep away from heat, sparks and flame. Avoid contact with eyes, skin and clothing. Avoid breathing vapors, spray
Handling
or mists. Use only with adequate ventilation. Do not ingest. Wash thoroughly after handling.
Store and use away from heat, sparks, open flame or any other ignition source. Keep container tightly closed in a
Storage
cool, well-ventilated place. Store between the following temperatures: 40掳F - 120掳F (4.4掳C - 49掳C). Keep away
from food, drink and animal feeding stuffs. Keep out of the reach of children.
Section 8. Exposure Controls, Personal Protection
Personal Protection Protective Clothing (Pictograms)
Safety glasses.
Eyes
For prolonged or repeated handling, use gloves. Recommended: Rubber
Body
gloves. Neoprene gloves. Nitrile gloves.
Respiratory Use with adequate ventilation. Provide local exhaust ventilation to maintain airborne concentrations below
established exposure limits. Local exhaust ventilation is preferred because it prevents contaminant dispersion into the
work area by controlling it at its source.
Section 9. Physical and Chemical Properties
Physical State Liquid. (Thin liquid) Clear. Orange.
Color
Citrus
11.0 - 12.0 Odor
pH
0.004 kPa (0.03 mm Hg) (at 20掳C)
Not determined. Vapor Pressure
Boiling Point
Not determined.
Specific Gravity 1.01 (Water = 1) Vapor Density
1 compared with Water
Evaporation Rate
Soluble in water.
Solubility
100.7 g/l (9.99%; 0.84 lb/gal.)
VOC (Consumer)
Section 10. Stability and Reactivity
The product is stable.
Stability and Reactivity
Reactive with oxidizing agents.
Incompatibility
Slightly reactive to reactive with acids. Keep away from heat, sparks and flame.
Hazardous Polymerization Will not occur.
Hazardous Decomposition Products carbon oxides (CO, CO2)
Section 11. Toxicological Information
ORAL (LD50): Acute: >5000 mg/kg [Rat].
Toxicity to Animals
DERMAL (LD50): Acute: >5000 mg/kg [Rabbit].
Monoethanolamine:^[25,45,50,70
ORAL (LD50): Acute: 1720 mg/kg [Rat.].
DERMAL (LD50): Acute: >1000 mg/kg [Rabbit].
Ethylene Glycol Monobutyl Ether:^[25,45,50,70
ORAL (LD50): Acute: 1746 mg/kg [Rat].
DERMAL (LD50): Acute: 680 mg/kg [Rabbit].
VAPOR (LC50): Acute: 450 ppm 4 hour(s) [Rat (Female)].
Section 12. Ecological Information
Not available.
Ecotoxicity
Biodegradable/OECD Not available.
Section 13. Disposal Considerations
Waste must be disposed of in accordance with federal, Waste Stream Code: D001
Waste
Classification: - (Hazardous waste.)
state and local environmental control regulations.
Information
Origin: - (RCRA waste.)
Consult your local or regional authorities.
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Product code 0455 Product Name CITRUS CLEANER
Material Safety Data Sheet
Section 14. Transport Information
Proper shipping name Not applicable.
Not a DOT controlled material (United States). UN number Not applicable.
DOT Classification
NOTE: DOT classification applies to most package sizes. For specific container size classifications or for size exceptions, refer to
the Bill of Lading with your shipment.
Not a TDG-controlled material.
TDG Classification
Section 15. Regulatory Information
SARA 313 toxic chemical notification and release reporting:
U.S. Federal Regulations
Ethylene Glycol Monobutyl Ether
Clean Water Act (CWA) 311: No products were found.
Clean Air Act (CAA) 112 regulated toxic substances: No products were found.
All Components of this product are listed or exempt from listing on TSCA inventory.
California Prop. 65: No products were found.
State Regulations
Class B-3: Combustible liquid with a flash point between 37.8掳C (100掳F) and 93.3掳C (200掳F).
WHMIS (Canada)
Class D-2B: Material causing other toxic effects (Toxic).
Section 16. Other Information
To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any
liability whatsoever for the accuracy or completeness of the information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution.
Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.
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