Material Safety Data Sheet
Zep Inc. Section 1. Chemical Product and Company Identification
1310 Seaboard Industrial Blvd.
Product name
Atlanta, GA 30318 ZEP CHLORI CLING 'N CLEAN
1-877-I-BUY-ZEP (428-9937)
Chlorinated Cleaner
Product use
www.zep.com
0681
Product code
Date of issue Supersedes 06/10/05
07/30/08
Emergency Telephone Numbers
For MSDS Information:
Compliance Services 1-877-I-BUY-ZEP (428-9937)
For Medical Emergency
INFOTRAC: (877) 541-2016 Toll Free - All Calls
Recorded
For Transportation Emergency
CHEMTREC: (800) 424-9300 - All Calls Recorded
In the District of Columbia (202) 483-7616
Prepared By
Printing date: 07/30/08
Compliance Services
1420 Seaboard Industrial Blvd.
Atlanta, GA 30318
Section 2. Hazards Identification
Emergency overview *Hazard Determination System (HDS): Health, Flammability, Reactivity
WARNING 2 0 0
CAUSES EYE IRRITATION.
HARMFUL IF SWALLOWED.
NOTE: MSDS data pertains to the product as delivered in the original shipping container(s). Risk of adverse effects are lessened by following all
prescribed safety precautions, including the use of proper personal protective equipment.
Dermal contact. Eye contact. Inhalation.
Acute Effects Routes of Entry
Causes eye irritation. Liquid in eye may cause irritation with possible damage if not rinsed
Eyes
immediately. Inflammation of the eye is characterized by redness, watering and itching.
May cause skin irritation. Skin inflammation is characterized by itching, scaling, or reddening.
Skin
Inhalation Avoid inhalation of vapor, spray or mist. Over-exposure by inhalation may cause respiratory
irritation.
Ingestion Harmful if swallowed. May cause burns to mouth, throat, and stomach. Can cause gastrointestinal
disturbances.
Repeated or prolonged contact with spray or mist may produce chronic eye irritation and severe
Chronic effects
skin irritation. Repeated or prolonged exposure to spray or mist may produce respiratory tract
irritation leading to frequent attacks of bronchial infection. Repeated or prolonged exposure to
the substance can produce mucous membranes damage.
Carcinogenicity Ingredients: Not listed as carcinogen by OSHA, NTP or IARC.
Additional Information: See Toxicological Information (Section 11)
Section 3. Composition/Information on Ingredients
Name of Hazardous Ingredients CAS number % by Weight
SODIUM HYPOCHLORITE; hypochlorous acid, sodium salt; bleach 7681-52-9 1 - 10
Section 4. First Aid Measures
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and
Eye Contact
remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention immediately.
Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Continue to rinse for at
Skin Contact
least 10 minutes. Wash clothing before reuse. Get medical attention if irritation develops.
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Inhalation
Get medical attention immediately.
Do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an
Ingestion
unconscious person. If affected person is conscious, give plenty of water to drink. Get medical attention
immediately.
Page: 1/3
Product Name ZEP CHLORI CLING 'N CLEAN
Material Safety Data Sheet
Product code 0681
National Fire Protection Association (U.S.A.)
Section 5. Fire Fighting Measures
0
None.
Flash Point 2 0
Flammable Limits Not applicable
Non-combustible.
Flammability
Incompatible with aluminum and magnesium. May release dangerous gases (chlorine). May
Fire hazard
emit toxic fumes under fire conditions.
Use an extinguishing agent suitable for the surrounding fire. Fire-fighters should wear
Fire-Fighting
appropriate protective equipment. Do not release runoff from fire to sewers or waterways.
Procedures
Section 6. Accidental Release Measures
Put on appropriate personal protective equipment (see section 8). Stop leak if without risk. Move containers
Spill Clean up
from spill area. Dilute with water and mop up if water-soluble or absorb with an inert dry material and place in
an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.
Section 7. Handling and Storage
Put on appropriate personal protective equipment (see section 8). Avoid contact with eyes, skin and clothing. DO
Handling
NOT breathe vapors or spray mist. Use only with adequate ventilation. Do not ingest. Do not reuse container. Do
not use with other products. Observe label precautions. Wash thoroughly after handling.
Store away from incompatible materials. Keep container tightly closed and sealed until ready for use. Keep container in
Storage
a cool, well-ventilated area. Store between the following temperatures: 40掳F - 120掳F (4.4掳C - 49掳C). Keep out of the
reach of children.
Section 8. Exposure Controls/Personal Protection
Product name Exposure limits
SODIUM HYPOCHLORITE; hypochlorous acid, sodium salt; ACGIH TLV (United States).
bleach TWA: 0.5 ppm 8 hour(s). Form: As Cl2
STEL: 1 ppm 15 minute(s). Form: As Cl2
OSHA PEL 1989 (United States).
TWA: 1 ppm 8 hour(s). Form: As Cl2
STEL: 3 ppm 15 minute(s). Form: As Cl2
Personal Protective Equipment (PPE)
Safety glasses.
Eyes
Wear appropriate protective clothing to prevent skin contact.
Body
Recommended: Rubber gloves. Neoprene gloves.
Respiratory Use with adequate ventilation. Provide exhaust ventilation or other engineering
controls to keep the airborne concentrations of vapors below their respective
occupational exposure limits.
Section 9. Physical and Chemical Properties
Liquid. Color Blue. Green.
Physical State
12.5-13.5 Odor Chlorine. [Slight]
pH
100掳C (212掳F) Vapor Pressure Not determined.
Boiling Point
1.08 Vapor Density Not determined.
Specific Gravity
Easily soluble in the following materials: cold water Evaporation Rate 1 (Water = 1)
Solubility
and hot water.
VOC (Consumer) 0.54 (g/l). (0.05%)
Section 10. Stability and Reactivity
The product is stable.
Stability and Reactivity
Do not use with other products. Incompatible with aluminum and magnesium. Slightly reactive or
Incompatibility
incompatible with the following materials: oxidizing materials, reducing materials, metals and
acids.
Hazardous Polymerization Will not occur.
Hazardous Decomposition Products May release dangerous gases (chlorine). carbon oxides (CO, CO2)
Page: 2/3
Product Name ZEP CHLORI CLING 'N CLEAN
Material Safety Data Sheet
Product code 0681
Section 11. Toxicological Information
Acute Toxicity
Exposure
Product/ingredient name Result Species Dose
Sodium Hypochlorite LD50 Dermal Rabbit >10000 mg/kg -
LD50 Oral Rat 8910 mg/kg -
LC50 Inhalation Vapor Rat >10.5 mg/L 0.25 hours
Section 12. Ecological Information
No known significant effects or critical hazards.
Environmental Effects
Aquatic Ecotoxicity
Product/ingredient name Test Result Species Exposure
Sodium Hypochlorite - Acute LC50 5.9 mg/L Fish - Minnows 96 hours
Section 13. Disposal Considerations
Waste Information
Waste must be disposed of in accordance with federal, state and local environmental control regulations. Consult your local or
regional authorities for additional information.
Waste Stream Code: D002
Classification: - [Hazardous waste]
Origin: - [RCRA waste.]
Section 14. Transport Information
Regulatory information UN number Proper shipping name Classes PG* Label
DOT Classification Not regulated. Not a DOT controlled material
(United States).
Not determined.
IMDG Class
NOTE: DOT classification applies to most package sizes. For specific container size classifications or for size exceptions, refer to
the Bill of Lading with your shipment.
PG* : Packing group
Section 15. Regulatory Information
U.S. Federal Regulations
SARA 313 toxic chemical notification and release reporting:
No products were found.
Clean Water Act (CWA) 307: No products were found.
Clean Water Act (CWA) 311: Sodium Hypochlorite (RQ 100 lbs)
Clean Air Act (CAA) 112 regulated toxic substances: No products were found.
All Components of this product are listed or exempt from listing on TSCA Inventory.
State Regulations
No products were found.
California Prop 65
Section 16. Other Information
To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any
liability whatsoever for the accuracy or completeness of the information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution.
Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.
*NOTE: Hazard Determination System (HDS) ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks
Although these ratings are not required on MSDSs under 29 CFR 1910.1200, the preparer may choose to provide them. HDS ratings are to be used with a fully implemented program to
relay the meanings of this scale.
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