**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| Not available |3-(N-Methylpiperazine)-Propanal | 15.6 | unlisted |
|----------------|--------------------------------------|----------|-----------|
| 67-64-1 |Acetone | 84.4 | 200-662-2 |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: F
Risk Phrases: 11
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Highly flammable.
Potential Health Effects
Eye:
Produces irritation, characterized by a burning sensation, redness,
tearing, inflammation, and possible corneal injury.
Skin:
Exposure may cause irritation characterized by redness, dryness, and
inflammation.
Ingestion:
May cause central nervous system depression, kidney damage, and
liver damage. Symptoms may include: headache, excitement, fatigue,
nausea, vomiting, stupor, and coma. May cause liver and kidney
damage. May cause central nervous system depression, characterized
by excitement, followed by headache, dizziness, drowsiness, and
nausea. Advanced stages may cause collapse, unconsciousness, coma
and possible death due to respiratory failure.
Inhalation:
Inhalation of high concentrations may cause central nervous system
effects characterized by nausea, headache, dizziness, unconsciousness
and coma. Causes respiratory tract irritation. May cause liver and
kidney damage. May cause motor incoordination and speech
abnormalities.
Chronic:
Prolonged or repeated skin contact may cause dermatitis. Chronic
inhalation may cause effects similar to those of acute inhalation.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation. If breathing has ceased apply artificial respiration
using oxygen and a suitable mechanical device such as a bag and a
mask.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
Containers can build up pressure if exposed to heat and/or fire. As
in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. During a
fire, irritating and highly toxic gases may be generated by thermal
decomposition or combustion. Use water spray to keep fire-exposed
containers cool. Extremely flammable liquid and vapor. Vapors may be
heavier than air. They can spread along the ground and collect in
low or confined areas. May be ignited by heat, sparks, and flame.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam. For large fires, use water spray, fog, or
alcohol-resistant foam. Use water spray to cool fire-exposed
containers. Water may be ineffective. Do NOT use straight streams of
water. Cool containers with flooding quantities of water until well
after fire is out.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Wear
appropriate protective clothing to minimize contact with skin. Remove
all sources of ignition. Provide ventilation. A vapor suppressing
foam may be used to reduce vapors. Water spray may reduce vapor but
may not prevent ignition in closed spaces. Clean up residual material
by washing area with a 2-5% solution of soda ash.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Ground and bond
containers when transferring material. Avoid contact with eyes, skin,
and clothing. Empty containers retain product residue, (liquid and/or
vapor), and can be dangerous. Keep container tightly closed. Keep
away from heat, sparks and flame. Avoid ingestion and inhalation. Do
not pressurize, cut, weld, braze, solder, drill, grind, or expose
empty containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
Flammables-area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local exhaust ventilation to keep airborne concentrations below the
permissible exposure limits.
Exposure Limits
CAS# 0-00-1:
CAS# 67-64-1:
United Kingdom, WEL - TWA: 500 ppm TWA; 1210 mg/m3 TWA
United Kingdom, WEL - STEL: 1500 ppm STEL; 3620 mg/m3 STEL
United States OSHA: 1000 ppm TWA; 2400 mg/m3 TWA
Belgium - TWA: 500 ppm VLE; 1210 mg/m3 VLE
Belgium - STEL: 1000 ppm VLE; 2420 mg/m3 VLE
France - VME: 750 ppm VME; 1800 mg/m3 VME
Germany: 500 ppm TWA; 1200 mg/m3 TWA
Japan: 200 ppm OEL; 470 mg/m3 OEL
Malaysia: 500 ppm TWA; 1187 mg/m3 TWA
Netherlands: 750 ppm MAC; 1780 mg/m3 MAC
Russia: 200 mg/m3 TWA
Spain: 500 ppm VLA-ED; 1210 mg/m3 VLA-ED
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: colorless
Odor: sweetish odor - musky
pH: 7
Vapor Pressure: 180 mm Hg
Viscosity: Not available
Boiling Point: 133.2 deg F
Freezing/Melting Point: -139.6 deg F
Autoignition Temperature: 869 deg F ( 465.00 deg C)
Flash Point: -4 deg F ( -20.00 deg C)
Explosion Limits, lower: 2.5
Explosion Limits, upper: 12.8
Decomposition Temperature:
Solubility in water: Soluble.
Specific Gravity/Density: 0.79 (Water=1)
Molecular Formula: Solution
Molecular Weight: 0
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
High temperatures, incompatible materials, ignition sources,
temperatures above 220C.
Incompatibilities with Other Materials:
Acids (mineral, non-oxidizing, e.g. hydrochloric acid, hydrofluoric
acid, muriatic acid, phosphoric acid), acids (organic, e.g. acetic
acid, benzoic acid, formic acid, methanoic acid, oxalic acid),
alcohols and glycols (e.g. butyl alcohol, ethanol, methanol, ethylene
glycol), aldehydes (e.g. acetaldehyde, acrolein, chloral hydrate,
formaldehyde), amides (e.g. butyramide, diethyltoluamide, dimethyl
formamide), amines (aliphatic and aromatic, e.g. dimethyl amine,
propylamine, pyridine, triethylamine), azo, diazo, and hydrazines
(e.g. dimethyl hydrazine, hydrazine, methyl hydrazine), carbamates
(e.g. carbanolate, carbofuran), cyanides (e.g. potassium cyanide,
sodium cyanide), dithiocarbamates (e.g. ferbam, maneb, metham,
thiram), esters (e.g. butyl acetate, ethyl acetate, propyl formate),
ethers (e.g. dioxane, furfuran, tetrahydrofuran (THF)), hydrocarbons
(aromatic, e.g. benzene, chrysene, cumene, toluene), halogenated
organics (e.g. dibromoethane, hexachlorobenzene, methyl chloride,
trichloroethylene), isocyanates (e.g. methyl isocyanate), ketones
(e.g. acetone, acetophenone, MEK, MIBK), mercaptans and other
organic sulfides (e.g. butyl mercaptan, carbon disulfide,
methanethiol), metals (alkali and alkaline, e.g. cesium, potassium,
sodium), metals as powders (e.g. hafnium, raney nickel), metals as
non-powders (e.g. brass, bronze, iron), nitrides (e.g. potassium
nitride, sodium nitride), nitriles (e.g. acetonitrile, methyl
cyanide), nitro compounds (organic, e.g. nitrobenzene,
nitroglycerine, picric acid, trinitrotoluene), hydrocarbons
(aliphatic, unsaturated, e.g. cyclopentene, ethylene, heptene),
hydrocarbons (aliphatic, saturated, e.g. butane, heptane, isooctane),
peroxides and hydroperoxides (organic, e.g. acetyl peroxide, benzoyl
peroxide, butyl peroxide, methyl ethyl ketone peroxide), phenols and
cresols (e.g. carbolic acid, creosote, cresol, phenol, resorcinol),
organophosphates, phosphothioates (e.g. methylparathion, parathion,
phorate, thionazin), sulfides (i.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 0-00-1 unlisted.
CAS# 67-64-1: AL3150000
LD50/LC50:
Not available.
CAS# 67-64-1: Dermal, guinea pig: LD50 = >9400 uL/kg; Draize test,
rabbit, eye: 20 mg Severe; Draize test, rabbit, eye: 20 mg/24H
Moderate; Draize test, rabbit, eye: 10 uL Mild; Draize test, rabbit,
skin: 500 mg/24H Mild; Inhalation, mouse: LC50 = 44 gm/m3/4H;
Inhalation, rat: LC50 = 50100 mg/m3/8H; Oral, mouse: LD50 = 3 gm/kg;
Oral, rabbit: LD50 = 5340 mg/kg; Oral, rat: LD50 = 5800 mg/kg.
Carcinogenicity:
3-(N-Methylpiperazine)-Propanal -
Not listed by ACGIH, IARC, or NTP.
Acetone -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Rainbow trout LC50=5540 mg/L/96H
Sunfish (tap water), death at 14250
ppm/24H
Mosquito fish (turbid water) TLm=13000 ppm/48H
Cas#
67-64-1:
LC50 (96Hr.) rainbow trout = 5540 mg/L; Static conditions,
11-13 degrees C
LC50 (96Hr) Fathead Minnow = 7280-8120 mg/L;
Flow-through Conditions
LC50 (96Hr) Bluegill = 8300 mg/L
Other
For more information, see "HANDBOOK OF ENVIRONMENTAL FATE AND
EXPOSURE DATA."
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Products which are considered hazardous for supply are classified as Special
Waste and the disposal of such chemicals is covered by regulations which may
vary according to location. Contact a specialist disposal company or the local
waste regulator for advice. Empty containers must be decontaminated before
returning for recycling.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: FLAMMABLE LIQUID, N.O.S.
Hazard Class: 3
UN Number: 1993
Packing Group: II
IMO
Shipping Name: FLAMMABLE LIQUID, N.O.S.
Hazard Class: 3
UN Number: 1993
Packing Group: II
RID/ADR
Shipping Name: FLAMMABLE LIQUID, N.O.S.
Hazard Class: 3
UN Number: 1993
Packing group: II
USA RQ: CAS# 67-64-1: 5000 lb final RQ; 2270 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: F
Risk Phrases:
R 11 Highly flammable.
Safety Phrases:
S 9 Keep container in a well-ventilated place.
S 16 Keep away from sources of ignition - No
smoking.
S 23 Do not inhale gas/fumes/vapour/spray.
S 33 Take precautionary measures against static
discharges.
WGK (Water Danger/Protection)
CAS# 0-00-1: No information available.
CAS# 67-64-1: 0
Canada
CAS# 67-64-1 is listed on Canada's DSL List.
CAS# 0-00-1 is not listed on Canada's Ingredient Disclosure List.
CAS# 67-64-1 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 0-00-1 is not listed on the TSCA inventory.
It is for research and development use only.
CAS# 67-64-1 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
R 11 Highly flammable.
R 36 Irritating to eyes.
R 66 Repeated exposure may cause skin dryness or cracking.
R 67 Vapours may cause drowsiness and dizziness.
MSDS Creation Date: 12/02/1999 Revision #4 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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